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公开(公告)号：US10807874B2
公开(公告)日：2020-10-20
申请号：US16341545
申请日：2017-10-11
摘要： Provided is a mordenite zeolite which can be produced without using an organic structure-directing agent, and has superior multivalent metal cation exchange capability. The mordenite zeolite according to the present invention containing silicon, a divalent metal M and aluminum in a skeletal structure, wherein the mordenite zeolite has the following atomic ratios in the state of Na-form. The mordenite zeolite preferably has a BET specific surface area of 250 m2/g or more and 500 m2/g or less and a micropore volume of 0.07 cc/g or more and 0.25 cc/g or less in the state of Na-form or H-form. Si/(M+Al)=5 or more and 10 or less, M/(M+Al)=0.1 or more and less than 1, and Na/(M+Al)=1 or more and less than 2.
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公开(公告)号：US10526209B2
公开(公告)日：2020-01-07
申请号：US16096207
申请日：2017-04-26
摘要： The objective of the invention is to provide an MSE-type zeolite production method such that an MSE-type zeolite can be produced in a comparatively short heating time by using inexpensive tetraethylammonium ion. The production method of the present invention comprises steps of: (1) mixing a silica source, an alumina source, an alkali source, tetraethylammonium ion, and water in such a manner as to yield a reaction mixture of the composition represented by the molar ratios indicated below: SiO2/Al2O3=between 10 and 100 inclusive (Na2O+K2O)/SiO2=between 0.15 and 0.50 inclusive K2O/(Na2O+K2O)=between 0.05 and 0.7 inclusive TEA2O/SiO2=between 0.08 and 0.20 inclusive H2O/SiO2=between 5 and 50 inclusive; (2) using the MSE-type zeolite as a seed crystal, and adding this seed crystal to the mixture at a proportion of 5 to 30% by mass with respect to the silica component in the reaction mixture; and (3) heating, under hermetic seal at a temperature of 100 to 200° C., the reaction mixture whereto the seed crystal has been added.
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公开(公告)号：US20180362356A1
公开(公告)日：2018-12-20
申请号：US15780445
申请日：2015-12-04
发明人： Kenta Iyoki , Keiji Itabashi , Tatsuya Okubo
摘要： The purpose of the present invention is to provide a beta zeolite which includes zinc and has a small particle size. This beta zeolite includes a silicon oxide and a zinc oxide, and has an average particle size of 50 to 100 nm at a cumulative frequency of 50% in a particle size distribution measured by scanning electron microscope observation.
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公开(公告)号：US10710888B2
公开(公告)日：2020-07-14
申请号：US15780445
申请日：2015-12-04
发明人： Kenta Iyoki , Keiji Itabashi , Tatsuya Okubo
IPC分类号： C01B39/48 , C01B39/06 , C01B39/12 , B01J29/04 , B01J29/70 , B01J29/86 , B01J29/88 , C01B39/08 , B01J29/87 , C01B33/12 , C01G9/02 , C01D15/02 , C01F7/02
摘要： The purpose of the present invention is to provide a beta zeolite which includes zinc and has a small particle size. This beta zeolite includes a silicon oxide and a zinc oxide, and has an average particle size of 50 to 100 nm at a cumulative frequency of 50% in a particle size distribution measured by scanning electron microscope observation.
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公开(公告)号：US10669157B2
公开(公告)日：2020-06-02
申请号：US15492318
申请日：2017-04-20
IPC分类号： C01B39/02 , C01B39/36 , C01B39/42 , C01B39/46 , B01J29/70 , C01B39/26 , C01B39/38 , C30B5/00 , C30B29/34
摘要： Disclosed is a method for readily and inexpensively producing zeolite without using an organic structure-directing agent (organic SDA). Specifically disclosed is a method whereby a gel containing a silica source, an alumina source, an alkaline source and water is reacted with zeolite seed crystals, to produce a zeolite with the same kind of skeletal structure as the zeolite. The gel used is a gel of a composition whereby, when a zeolite is synthesized from this gel only, the synthesized zeolite comprises at least one of the kinds of composite building units of the target zeolite.
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公开(公告)号：US09844771B2
公开(公告)日：2017-12-19
申请号：US14775331
申请日：2014-03-10
CPC分类号： B01J29/7615 , B01D53/864 , B01D53/94 , B01D53/944 , B01D2253/1085 , B01D2255/2025 , B01D2255/20738 , B01D2255/502 , B01J20/186 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J2229/186 , B01J2229/37 , C01B39/46
摘要： To provide a hydrocarbon reforming/trapping material which is capable of adsorbing and reforming a hydrocarbon. A hydrocarbon reforming/trapping material of the present invention has an SiO2/Al2O3 ratio of from 7 to 12, and contains an Fe(II)-substituted beta zeolite which is ion-exchanged by Fe(II) ions. The amount of supported Fe(II) is preferably 0.001-0.5 mmol/g with respect to the Fe(II)-substituted beta zeolite. This Fe(II)-substituted beta zeolite is suitably produced by dispersing and mixing a beta zeolite having an SiO2/Al2O3 ratio of from 7 to 12 in an aqueous solution of a water-soluble compound of divalent iron, and mixing and stirring the solution, so that Fe(II) ions are supported on the beta zeolite.
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7.发明申请公开(公告)号：US20160030933A1
公开(公告)日：2016-02-04
申请号：US14775331
申请日：2014-03-10
CPC分类号： B01J29/7615 , B01D53/864 , B01D53/94 , B01D53/944 , B01D2253/1085 , B01D2255/2025 , B01D2255/20738 , B01D2255/502 , B01J20/186 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J2229/186 , B01J2229/37 , C01B39/46
摘要： To provide a hydrocarbon reforming/trapping material which is capable of adsorbing and reforming a hydrocarbon. A hydrocarbon reforming/trapping material of the present invention has an SiO2/Al2O3 ratio of from 7 to 12, and contains an Fe(II)-substituted beta zeolite which is ion-exchanged by Fe(II) ions. The amount of supported Fe(II) is preferably 0.001-0.5 mmol/g with respect to the Fe(II)-substituted beta zeolite. This Fe(II)-substituted beta zeolite is suitably produced by dispersing and mixing a beta zeolite having an SiO2/Al2O3 ratio of from 7 to 12 in an aqueous solution of a water-soluble compound of divalent iron, and mixing and stirring the solution, so that Fe(II) ions are supported on the beta zeolite.
摘要翻译： 提供能够吸附和重整烃的烃重整/捕获材料。 本发明的烃重整/捕集材料的SiO 2 / Al 2 O 3比例为7-12，并含有Fe（II） - 取代的β沸石，其被Fe（II）离子离子交换。 相对于Fe（II）取代的β沸石，负载的Fe（II）的量优选为0.001-0.5mmol / g。 这种Fe（II）取代的β沸石通过在二价铁的水溶性化合物的水溶液中分散并混合SiO 2 / Al 2 O 3比率为7至12的β沸石，并且将该溶液 ，使得Fe（II）离子负载在β沸石上。
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公开(公告)号：US20150086786A1
公开(公告)日：2015-03-26
申请号：US14391547
申请日：2013-04-09
发明人： Keiji Itabashi , Tatsuya Okubo , Kenta Iyoki
CPC分类号： C01B39/46 , B01D2253/1085 , B01D2253/306 , B01D2253/31 , B01D2255/502 , B01D2255/9202 , B01D2258/012 , B01D2258/014 , B01J20/18 , B01J20/28057 , B01J20/28071 , B01J20/28083 , B01J29/7007 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J39/04 , C01B39/06 , C01P2006/12 , C01P2006/16 , Y10T428/2982
摘要： The present invention provides a beta zeolite that is useful as a catalyst, adsorbent agent, or the like, and that is both microporous and mesoporous. The beta zeolite is characterized by (i) the SiO2/Al2O3 ratio being 8-30, and the SiO2/ZnO ratio being 8-1000, (ii) the micropore surface area being 300-800 m2/g, (iii) the micropore volume being 0.1-0.3 cm3/g, and (iv) having mesopores having, in the state as synthesized, a diameter of 2-6 nm and a volume of 0.001-0.3 cm3/g. The beta zeolite is favorably produced by means of adding and reacting a zinc silicate beta zeolite as a seed crystal with a reaction mixture containing a silica source, an alumina source, an alkali source, and water.
摘要翻译： 本发明提供了可用作催化剂，吸附剂等的β沸石，既是微孔的又是介孔的。 β沸石的特征在于（i）SiO 2 / Al 2 O 3比为8-30，SiO 2 / ZnO比为8-1000，（ii）微孔表面积为300-800m 2 / g，（iii）微孔 体积为0.1-0.3cm 3 / g，（iv）具有在合成状态下具有2-6nm直径和0.001-0.3cm 3 / g体积的介孔。 通过将硅酸锌β沸石作为晶种与含有二氧化硅源，氧化铝源，碱源和水的反应混合物加入和反应，β沸石有利地产生。
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公开(公告)号：US09656238B2
公开(公告)日：2017-05-23
申请号：US14414350
申请日：2013-07-16
IPC分类号： B01D53/56 , B01J20/18 , C01B39/46 , B01D53/02 , B01D53/94 , B01J20/28 , B01J29/76 , B01D53/04 , B01J20/30 , C01B39/02 , F01N3/08
CPC分类号： B01J20/18 , B01D53/02 , B01D53/04 , B01D53/9481 , B01D2253/108 , B01D2253/1085 , B01D2253/1122 , B01D2253/306 , B01D2253/311 , B01D2257/404 , B01D2257/702 , B01J20/186 , B01J20/28057 , B01J20/28071 , B01J20/3085 , B01J29/7615 , C01B39/02 , C01B39/46 , F01N3/0835 , F01N3/0842
摘要： The purpose of/problem to be addressed by the present invention is to provide: an Fe(II)-substituted beta-type zeolite useful for the catalytic removal of a variety of gases; and a production method therefor. The SiO2/Al2O3 ratio in this Fe(II)-substituted beta-type zeolite is equal to or more than 7 but less than 10. This Fe(II)-substituted beta-type zeolite is obtained by being subjected to ionic exchange with Fe(II) ions. It is preferable that the Fe(II) loading amount be in the range of 0.001-0.4 mmol/g of the Fe(II)-substituted beta-type zeolite. It is preferable that the Fe(II)-substituted beta-type zeolite be produced using a method in which a beta-type zeolite having an SiO2/Al2O3 ratio of equal to or more than 7 but less than 10 is dispersed in an Fe(II) water-soluble-compound aqueous solution, and then mixed and agitated to cause the beta-type zeolite to carry Fe(II) ions.
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10.发明申请Fe(II)-SUBSTITUTED BETA-TYPE ZEOLITE, PRODUCTION METHOD THEREFOR AND GAS ADSORBENT INCLUDING SAME, AND NITRIC OXIDE AND HYDROCARBON REMOVAL METHOD 有权Fe（II） - 沸石型沸石，其制备方法及其包括其的气体吸附剂，以及氮氧化物和碳氢化合物的去除方法公开(公告)号：US20150182941A1
公开(公告)日：2015-07-02
申请号：US14414350
申请日：2013-07-16
CPC分类号： B01J20/18 , B01D53/02 , B01D53/04 , B01D53/9481 , B01D2253/108 , B01D2253/1085 , B01D2253/1122 , B01D2253/306 , B01D2253/311 , B01D2257/404 , B01D2257/702 , B01J20/186 , B01J20/28057 , B01J20/28071 , B01J20/3085 , B01J29/7615 , C01B39/02 , C01B39/46 , F01N3/0835 , F01N3/0842
摘要： The purpose of/problem to be addressed by the present invention is to provide: an Fe(II)-substituted beta-type zeolite useful for the catalytic removal of a variety of gases; and a production method therefor. The SiO2/Al2O3 ratio in this Fe(II)-substituted beta-type zeolite is equal to or more than 7 but less than 10. This Fe(II)-substituted beta-type zeolite is obtained by being subjected to ionic exchange with Fe(II) ions. It is preferable that the Fe(II) loading amount be in the range of 0.001-0.4 mmol/g of the Fe(II)-substituted beta-type zeolite. It is preferable that the Fe(II)-substituted beta-type zeolite be produced using a method in which a beta-type zeolite having an SiO2/Al2O3 ratio of equal to or more than 7 but less than 10 is dispersed in an Fe(II) water-soluble-compound aqueous solution, and then mixed and agitated to cause the beta-type zeolite to carry Fe(II) ions.
摘要翻译： 本发明要解决的问题的目的是提供：用于催化除去各种气体的Fe（II） - 取代的β型沸石; 及其制造方法。 该Fe（II）取代的β型沸石中的SiO 2 / Al 2 O 3比例等于或大于7，但小于10.该Fe（II）取代的β型沸石通过与Fe进行离子交换而获得 （II）离子。 优选Fe（II）负载量在Fe（II）取代的β型沸石的0.001-0.4mmol / g的范围内。 优选使用SiO 2 / Al 2 O 3比例等于或大于7但小于10的β型沸石分散在Fe（II）取代的β型沸石中的方法制备Fe II）水溶性复合水溶液，然后混合搅拌，使β型沸石携带Fe（II）离子。
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