公开(公告)号：US4503205A

公开(公告)日：1985-03-05

申请号：US562243

申请日：1983-12-16

申请人： Mahmoud Aldissi ,  Raimond Liepins

发明人： Mahmoud Aldissi ,  Raimond Liepins

IPC分类号： C08F38/00 ,  C08F4/06 ,  C08F4/00 ,  C08F4/14 ,  C08F138/00 ,  C08F210/00 ,  C08F238/00 ,  C08G65/38

CPC分类号： C08F38/00

摘要： A soluble polyene polymer and a method of making the same are disclosed. The polymer is of the class suitable for doping to produce an electrically conductive polymer. The method is generally applicable to acetylenic and aromatic monomers, proven examples of which include acetylene, benzene, anthracene and napthalene. In accordance with the method, the monomer is dissolved in arsenic trifluoride. Arsenic pentafluoride is then introduced into the solution to induce polymerization by what is speculated to be an ionic polymerization reaction. The resulting polymer differs from other polyene polymers in that it is soluble in common organic solvents, and further in that it can be melted without undergoing decomposition, thereby rendering it particularly suitable for processing to form various polymeric articles.

摘要翻译： 公开了可溶性多烯聚合物及其制备方法。 该聚合物具有适于掺杂以产生导电聚合物的类别。 该方法通常适用于炔属和芳族单体，其实例包括乙炔，苯，蒽和萘。 按照该方法，将单体溶解在三氟化砷中。 然后将五氟化砷引入溶液中以通过所推测的离子聚合反应诱导聚合。 所得到的聚合物与其它多烯聚合物的不同之处在于它可溶于常用的有机溶剂，并且还可以熔融而不会分解，从而使其特别适用于加工形成各种聚合物制品。

公开(公告)号：US4755326A

公开(公告)日：1988-07-05

申请号：US635020

申请日：1984-07-27

申请人： Raimond Liepins ,  Mahmoud Aldissi

发明人： Raimond Liepins ,  Mahmoud Aldissi

IPC分类号： C08G61/12 ,  H01B1/12 ,  H01B1/06

CPC分类号： C08G61/122 ,  H01B1/127 ,  H01B1/128

摘要： Polymers with conjugated backbones, both polyacetylene and polyaromatic heterocyclic types, are doped with electron-donor agents to increase their electrical conductivity. The electron-donor agents are either electride dopants made in the presence of lithium or dopants derived from alkalides made in the presence of lithium. The dopants also contain a metal such as cesium and a trapping agent such as a crown ether.

摘要翻译： 具有共轭骨架的聚合物（聚乙炔和多芳族杂环类型）掺杂有电子给体试剂以增加其导电性。 电子给体试剂是在锂存在下制备的电子掺杂剂或衍生自在锂存在下制备的碱金属的掺杂剂。 掺杂剂还含有诸如铯和捕获剂如冠醚的金属。

公开(公告)号：US4390567A

公开(公告)日：1983-06-28

申请号：US242807

申请日：1981-03-11

申请人： Raimond Liepins

发明人： Raimond Liepins

IPC分类号： C03C17/34 ,  C23C16/00 ,  C23C18/08 ,  H05H1/22 ,  B05D7/24 ,  C23C11/00

CPC分类号： G21B1/19 ,  C03C17/3405 ,  C23C16/00 ,  C23C18/08 ,  Y02E30/16 ,  Y10S376/916

摘要： Very smooth polymeric coatings or films graded in atomic number and density can readily be formed by first preparing the coating or film from the desired monomeric material and then contacting it with a fluid containing a metal or a mixture of metals for a time sufficient for such metal or metals to sorb and diffuse into the coating or film. Metal resinate solutions are particularly advantageous for this purpose. A metallic coating can in turn be produced on the metal-loaded film or coating by exposing it to a low pressure plasma of air, oxygen, or nitrous oxide. The process permits a metallic coating to be formed on a heat sensitive substrate without the use of elevated temperatures.

摘要翻译： 以原子序数和密度分级的非常光滑的聚合物涂层或薄膜可以容易地通过首先从所需的单体材料制备涂层或膜，然后使其与含有金属或金属混合物的流体接触足够长的时间 或金属吸附并扩散到涂层或膜中。 金属树脂酸盐溶液对于此目的是特别有利的。 通过将金属涂层暴露于空气，氧气或一氧化二氮的低压等离子体，可以在金属负载的膜或涂层上产生金属涂层。 该方法允许在热敏基材上形成金属涂层而不使用升高的温度。

公开(公告)号：US4876032A

公开(公告)日：1989-10-24

申请号：US91251

申请日：1987-08-27

申请人： Raimond Liepins ,  Betty S. Jorgensen ,  Leila Z. Liepins

发明人： Raimond Liepins ,  Betty S. Jorgensen ,  Leila Z. Liepins

IPC分类号： C08G61/12 ,  C08G75/32 ,  H01B1/12

CPC分类号： H01B1/128 ,  C08G61/122 ,  C08G75/32 ,  H01B1/127

摘要： High-temperature electrically conducting polymers. The in situ reactions: AgNO.sub.3 +RCHO.fwdarw.AG.sup.0 +RCOOH and R.sub.3 M.fwdarw.M.sup.0 3R, where M=Au or Pt have been found to introduce either substantial bulk or surface conductivity in high-temperature polymers. The reactions involving the R.sub.3 M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrrone.

摘要翻译： 高温导电聚合物。 原位反应：AgNO3 + RCHO-> AG0 + RCOOH和R3M-> M03R，其中M = Au或Pt已被发现在高温聚合物中引入实质的体积或表面电导率。 引起涉及R3M的反应进行热反应，表明使用激光装置在聚合物材料的选定区域或体积中引发这种反应的可能性。 迄今为止成功研究的聚合物是聚苯基喹喔啉，聚酰基喹喔啉，聚喹啉，聚噻唑和吡咯酮。

公开(公告)号：US5271870A

公开(公告)日：1993-12-21

申请号：US371859

申请日：1989-06-27

申请人： Raimond Liepins ,  Betty S. Jorgensen ,  Leila Z. Liepins

发明人： Raimond Liepins ,  Betty S. Jorgensen ,  Leila Z. Liepins

IPC分类号： C08G61/12 ,  C08G75/32 ,  H01B1/12 ,  H01B1/00 ,  H01B1/20

CPC分类号： C08G61/122 ,  C08G75/32 ,  H01B1/127 ,  H01B1/128

摘要： High-temperature electrically conducting polymers. The in situ reactions: AgNO.sub.3 +RCHO.fwdarw.Ag.degree.+RCOOH and R.sub.3 M.fwdarw.M.degree.+3R, where M=Au or Pt have been found to introduce either substantial bulk or surface conductivity in high-temperature polymers. The reactions involving the R.sub.3 M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrrone.

摘要翻译： 高温导电聚合物。 原位反应：AgNO3 + RCHO-> Ag DEG + RCOOH和R3M-> M DEG + 3R，其中M = Au或Pt已被发现在高温聚合物中引入实质的体积或表面电导率。 引起涉及R3M的反应进行热反应，表明使用激光装置在聚合物材料的选定区域或体积中引发这种反应的可能性。 迄今为止成功研究的聚合物是聚苯基喹喔啉，聚酰基喹喔啉，聚喹啉，聚噻唑和吡咯酮。

公开(公告)号：US4500562A

公开(公告)日：1985-02-19

申请号：US471393

申请日：1983-03-02

申请人： Randy K. Jahn ,  Raimond Liepins

发明人： Randy K. Jahn ,  Raimond Liepins

IPC分类号： B05D7/24 ,  B05D1/04 ,  B05D1/06

CPC分类号： B05D1/62

摘要： A method and apparatus for forming an improved poly-p-xylylene film. Solid di-para-xylylene dimer is sublimed in a sublimation furnace at approximately 100.degree. to 200.degree. C. and subsequently conducted to a pyrolysis furnace where it is pyrolyzed to the diradical p-xylylene monomer while in the vapor state at approximately 600 degrees C. The diradical monomer is then introduced into a deposition chamber for deposition onto a suitable substrate. The deposition chamber includes electrodes for producing a low pressure plasma through which the diradical monomer passes prior to deposition. The interaction of the diradical monomer with the low pressure plasma results in the formation of poly-p-xylylene film which is exceptionally hard and thermally stable.

摘要翻译： 用于形成改进的聚对二甲苯膜的方法和设备。 固体二对二甲苯二聚体在升华炉中在约100至200℃下升华，随后被导入热解炉中，在热解炉中将其热解至双基对二甲苯单体，同时在约600℃的蒸汽状态 然后将双基单体引入沉积室中以沉积到合适的基底上。 沉积室包括用于产生低压等离子体的电极，双相单体在沉积之前通过该等离子体。 双基单体与低压等离子体的相互作用导致聚对二甲苯膜的形成，其特别硬和热稳定。

公开(公告)号：US4464416A

公开(公告)日：1984-08-07

申请号：US467104

申请日：1983-02-16

申请人： Raimond Liepins

发明人： Raimond Liepins

IPC分类号： C03C17/34 ,  C23C16/00 ,  C23C18/08 ,  H05H1/22 ,  B05D3/06

CPC分类号： G21B1/19 ,  C03C17/3405 ,  C23C16/00 ,  C23C18/08 ,  Y02E30/16

摘要： Very smooth polymeric coatings or films graded in atomic number and densityan readily be formed by first preparing the coating or film from the desired monomeric material and then contacting it with a fluid containing a metal or a mixture of metals for a time sufficient for such metal or metals to sorb and diffuse into the coating or film. Metal resinate solutions are particularly advantageous for this purpose. A metallic coating can in turn be produced on the metal-loaded film or coating by exposing it to a low pressure plasma of air, oxygen, or nitrous oxide. The process permits a metallic coating to be formed on a heat sensitive substrate without the use of elevated temperatures.

摘要翻译： 以原子序数和密度分级的非常光滑的聚合物涂层或薄膜可以容易地通过首先从所需的单体材料制备涂层或膜，然后使其与含有金属或金属混合物的流体接触足够长的时间 或金属吸附并扩散到涂层或膜中。 金属树脂酸盐溶液对于此目的是特别有利的。 通过将金属涂层暴露于空气，氧气或一氧化二氮的低压等离子体，可以在金属负载的膜或涂层上产生金属涂层。 该方法允许在热敏基材上形成金属涂层而不使用升高的温度。