Visible ray polymerization initiator and visible ray polymerizable
composition
    4.
    发明授权
    Visible ray polymerization initiator and visible ray polymerizable composition 失效
    可见光聚合引发剂和可见光可聚合组合物

    公开(公告)号:US5744511A

    公开(公告)日:1998-04-28

    申请号:US634259

    申请日:1996-04-18

    CPC分类号: G03F7/029 Y10S522/908

    摘要: A visible-ray polymerizable composition comprising: (1) a monomer comprising a (meth)acrylate monomer; and (2) a visible-ray polymerization initiator comprising: (A) a coumarin dye; (B) at least one photo acid generator selected from the group consisting of a halo-alkyl substituted s-triazine derivative and a diphenyliodonium salt compound; and (C) an aryl borate compound.

    摘要翻译: 一种可见光可聚合组合物,其包含:(1)包含(甲基)丙烯酸酯单体的单体; 和(2)可见光聚合引发剂,其包含:(A)香豆素染料; (B)选自卤代烷基取代的s-三嗪衍生物和二苯基碘鎓盐化合物的至少一种光酸反应产物; 和(C)芳基硼酸盐化合物。

    Dental adhesive composition
    7.
    发明授权
    Dental adhesive composition 有权
    牙科粘合剂组成

    公开(公告)号:US06759449B2

    公开(公告)日:2004-07-06

    申请号:US10181413

    申请日:2002-07-23

    IPC分类号: A61K6083

    摘要: This invention discloses a dental adhesive composition comprising (A) a polymerizable monomer comprising an acidic-group containing polymerizable monomer such as 11-methacryloyloxy-1,1-undecane dicarboxylic acid, (B) a mixed filler of a spherical filler substantially consisting of a non-crosslinking polymethyl methacrylate and a spherical filler substantially consisting of a non-crosslinking polyethyl methacrylate; and (C) a polymerization initiator; and a dental adhesive kit comprising the above dental adhesive composition in combination with a dental primer comprising (D) an acidic-group containing polymerizable monomer, (E) an aryl borate, (F) an organosulfinic acid salt and (G) water. The dental adhesive composition exhibits good operability and improved adhesion performance.

    摘要翻译: 本发明公开了一种牙科用粘合剂组合物,其包含(A)包含含有酸性基团的可聚合单体如11-甲基丙烯酰氧基-1,1-十一烷二羧酸的可聚合单体,(B)基本上由 非交联聚甲基丙烯酸甲酯和基本上由非交联聚甲基丙烯酸乙酯组成的球形填料; 和(C)聚合引发剂; 和含有(D)含酸性基团的可聚合单体,(E)芳基硼酸盐,(F)有机亚磺酸盐和(G)水)的牙科底漆组合的上述牙科粘合剂组合物的牙科粘合剂试剂盒。 牙科粘合剂组合物表现出良好的可操作性和改进的粘合性能。

    Photo-curable reparative material for dental use
    8.
    发明授权
    Photo-curable reparative material for dental use 有权
    用于牙科用途的光固化修复材料

    公开(公告)号:US06849670B2

    公开(公告)日:2005-02-01

    申请号:US10088347

    申请日:2001-07-19

    摘要: A photocurable dental restorative comprising (i) 100 parts by weight of a polymerizable monomer, (ii) 0.01 to 5 parts by weight of a photopolymerization initiator of acylphosphine oxide, and (iii) 200 to 1900 parts by weight of an inorganic filler, wherein the inorganic filler (iii) is a mixed filler of: (A) irregular-shaped inorganic particles having an average particle size of not smaller than 0.1 μm but smaller than 1 μm; (B) spherical inorganic particles having an average primary particle size of not smaller than 0.1 μm but not larger than 5 μm; and (C) fine inorganic particles having an average primary particle size of not larger than 0.1 μm; which are so blended as to satisfy the following mass ratios {circle around (1)} to {circle around (3)}: {circle around (1)} mA/(mB+mC)=0.2 to 3 {circle around (2)} mB/(mB+mC)=0.5 to 0.99 {circle around (3)} mC/(mB+mC)=0.01 to 0.5 where mA, mB and mC are masses of the inorganic particles (A) to (C). The restorative features excellent handling property, and makes it possible to obtain a cured product having a high fracture toughness and excellently glossy surface.

    摘要翻译: 一种光固化性牙科修复剂,其包含(i)100重量份的可聚合单体,(ii)0.01至5重量份的酰基氧化膦的光聚合引发剂,和(iii)200至1900重量份的无机填料,其中 无机填充剂(iii)是以下混合填料:(A)平均粒径为0.1μm以上且小于1μm的不规则形状的无机粒子;(B)平均一次粒径为 不小于0.1μm,但不大于5μm; 和(C)平均一次粒径不大于0.1μm的无机细颗粒;它们被共混以满足以下质量比:圆周(1至{周围(3:{圆周(1mA / (mB + mC)= 0.2〜3(圆周(2mB /(mB + mC))= 0.5〜0.99(圆周(3mC /(mB + mC))= 0.01〜0.5其中mA,mB和mC为 无机粒子(A)〜(C)。修复体具有优异的处理性,可以得到断裂韧性高,表面光滑的固化物。

    Dental filling/restoration kit
    9.
    发明授权
    Dental filling/restoration kit 有权
    牙科填充/恢复套件

    公开(公告)号:US08506298B2

    公开(公告)日:2013-08-13

    申请号:US12602921

    申请日:2008-06-05

    IPC分类号: A61C5/04 A61C5/00

    CPC分类号: A61K6/083 C08L33/00 C08L43/02

    摘要: Provided is a dental filling/restoration kit, in which a pretreatment material and a filling/restoring material can be cured by only one irradiation with light, which enables further improved adhesion between a tooth and the filling/restoring material, which prevents the filling/restoring material from being easily colored, to thereby exhibit its excellent sensuousness. Specifically provided is a dental filling/restoration kit which includes: a filling/restoring material (A) containing 100 parts by mass of a radical-polymerizable monomer (a) containing 3 to 30 parts by mass of a water-soluble radical-polymerizable monomer having no acidic group (a1), a photopolymerization initiator (b), and a filler (c), the filler (c) being contained in an amount of 80 to 2,000 parts by mass relative to 100 parts by mass of the radical-polymerizable monomer (a); and a pretreatment material (B) containing a radical-polymerizable monomer having an acidic group (d) and water (e).

    摘要翻译: 提供了一种牙科填充/恢复套件,其中预处理材料和填充/恢复材料可以仅通过一次光照射而固化,这使得能够进一步改善牙齿和填充/恢复材料之间的粘附性,从而防止填充/ 恢复材料容易着色,从而表现出优异的感觉。 具体地提供一种牙科填充/修复试剂盒,其包括:含有100质量份含有3〜30质量份水溶性自由基聚合性单体的自由基聚合性单体(a)的填充恢复材料(A) 没有酸性基团(a1),光聚合引发剂(b)和填料(c),填料(c)相对于100质量份的可自由基聚合的组分为80〜2000质量份 单体(a); 和含有具有酸性基团(d)和水(e)的自由基聚合性单体的预处理材料(B)。

    Polymerizable composition, organic glass and ophthalmic lens
    10.
    发明授权
    Polymerizable composition, organic glass and ophthalmic lens 失效
    可聚合组合物,有机玻璃和眼科镜片

    公开(公告)号:US5475074A

    公开(公告)日:1995-12-12

    申请号:US187475

    申请日:1994-01-28

    CPC分类号: G02B1/04 C08F212/34

    摘要: A polymerizable composition containing;(A) 100 parts by weight of a vinylbenzyl compound of the formula (I), ##STR1## wherein each of R.sup.1 and R.sup.2 is independently a halogen atom, each of h and i is independently 0, 1 or 2, each of X.sup.1, X.sup.2 and X.sup.3 is independently an oxygen atom or a sulfur atom, and each of j, k and m is 0 or 1, provided that when k is 0, j is 0, that when m is 0, each of j and k is 0, that when j is 0 and when each of k and m is 1, X.sup.1 and X.sup.2 cannot be sulfur atoms at the same time, and that when each of m, k and j is 1, X.sup.1, X.sup.2 and X.sup.3 cannot be sulfur atoms at the same time,and(B) 0.1 to 20 parts by weight of 2,4-diphenyl-4-methyl-1-pentene.The polymerizable composition can give a molded article which is free from coloring in heat treatment, has sufficient properties as an ophthalmic lens such as a high refractive index, a high Abbe's number and a low specific gravity, is excellent in transparency, light resistance, heat resistance and impact resistance, and is therefore suitable as an organic glass such as an ophthalmic lens and a lens for an optical device.

    摘要翻译: 一种可聚合组合物, (A)100重量份式(I)的乙烯基苄基化合物,其中R 1和R 2各自独立地为卤素原子,h和i各自独立地为0,1或 如图2所示,X1,X2和X3各自独立地为氧原子或硫原子,j,k和m各自为0或1,条件是当k为0时,j为0,当m为0时, j和k为0时,当j为0时,当k和m各自为1时,X1和X2不能同时为硫原子,当m,k和j分别为1时,X1,X2 并且X3不能同时为硫原子,(B)为0.1〜20重量份的2,4-二苯基-4-甲基-1-戊烯。 可聚合组合物可以得到在热处理中不着色的模塑制品,作为高折射率,高阿贝数和低比重的眼用透镜具有足够的性能,透明性,耐光性,耐热性优异 电阻和抗冲击性,因此适合作为有机玻璃如眼用透镜和用于光学装置的透镜。