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公开(公告)号：US11103837B1
公开(公告)日：2021-08-31
申请号：US14207913
申请日：2014-03-13
摘要： An article having a nanoporous membrane and a nanoporous graphene sheet layered on the nanoporous membrane with the nanoporous membrane and the nanoporous graphene sheet in direct contact. A method of: depositing a layer of a diblock copolymer onto a graphene sheet, etching a minor phase of the diblock copolymer and a portion of the graphene in contact with the minor phase to form a nanoporous article having a nanoporous graphene sheet and a nanoporous layer of a polymer, and removing the nanoporous layer of a polymer.
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公开(公告)号：US10525421B1
公开(公告)日：2020-01-07
申请号：US14207912
申请日：2014-03-13
摘要： An article having a nanoporous membrane and a nanoporous graphene sheet layered on the nanoporous membrane. A method of: depositing a layer of a diblock copolymer onto a graphene sheet, and etching a minor phase of the diblock copolymer and a portion of the graphene in contact with the minor phase to form a nanoporous article having a nanoporous graphene sheet and a nanoporous layer of a polymer. A method of: depositing a hexaiodo-substituted macrocycle onto a substrate having a Ag(111) surface; coupling the macrocycle to form a nanoporous graphene sheet; layering the graphene sheet and substrate onto a nanoporous membrane with the graphene sheet in contact with the nanoporous membrane; and etching away the substrate.
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3.发明授权Methods for preparing linked peptide rings and peptide nanotubes obtained thereby 有权制备由此获得的连接肽环和肽纳米管的方法公开(公告)号：US08975368B2
公开(公告)日：2015-03-10
申请号：US12855379
申请日：2010-08-12
摘要： Peptide nanotube polymers and methods of making such are disclosed. The peptide nanotube polymers are comprised of alternating monomers of the first peptide ring and monomers of the second peptide ring covalently bonded to one another via a linker, and can be functionalized. The described peptide nanotube polymers can enjoy the combined properties of healing and toughness, self-reporting, and tunability and actuation.
摘要翻译： 公开了肽纳米管聚合物及其制备方法。 肽纳米管聚合物由第一肽环的交替单体和通过连接体彼此共价结合的第二肽环的单体组成，并且可以被官能化。 所描述的肽纳米管聚合物可以享受愈合和韧性，自我报告以及可调和致动的组合性质。
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公开(公告)号：US20140274656A1
公开(公告)日：2014-09-18
申请号：US14200542
申请日：2014-03-07
CPC分类号： C07F7/28 , B22F9/18 , B22F9/30 , C04B35/5611 , C04B35/5626 , C04B35/58007 , C04B35/58014 , C04B2235/3232 , C04B2235/5454 , C04B2235/6562 , C04B2235/80 , C07F11/00
摘要： A compound having the moiety M-[(C≡C)n-M′]m. Each M and each M′ is a transition metal. Each n is 1 or 2, and m is 2 or more. A method of reacting a transition metal halide with 1,2-dilithioacetylene or 1,4-dilithiodiacetylene to form a transition metal compound.
摘要翻译： 具有部分M - [（C≡C）n -M'] m的化合物。 每个M和每个M'是过渡金属。 n为1或2，m为2以上。 使过渡金属卤化物与1,2-二硫代乙炔或1,4-二碘二乙炔反应形成过渡金属化合物的方法。
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公开(公告)号：US20130012617A1
公开(公告)日：2013-01-10
申请号：US13613152
申请日：2012-09-13
CPC分类号： C08K7/26 , C04B35/78 , C04B38/085 , C08G65/4006 , C08G77/045 , C08G77/50 , C08G77/52 , C08G77/56 , C08K7/22 , C08L71/00 , C08L83/04
摘要： Disclosed herein is a composition having a thermoset polymer and a plurality of hollow microsphere homogenously dispersed in the composition. The polymer is a cyanate ester thermoset, a phthalonitrile thermoset, a crosslinked acetylene thermoset, or a hydrosilation thermoset. Also disclosed herein is a method of: providing a thermosetting compound; adding microspheres to the thermosetting compound; and mixing the thermosetting compound while initiating crosslinking of the thermosetting compound.
摘要翻译： 本文公开了具有热固性聚合物和均匀分散在组合物中的多个中空微球的组合物。 聚合物是氰酸酯热固性材料，邻苯二甲腈热固性材料，交联乙炔热固性材料或硅氢化硅热固体。 本文还公开了一种方法：提供热固性化合物; 将微球加入到热固性化合物中; 并且在引发热固性化合物的交联的同时混合该热固性化合物。
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公开(公告)号：US08288454B2
公开(公告)日：2012-10-16
申请号：US12539039
申请日：2009-08-11
CPC分类号： C08K7/26 , C04B35/78 , C04B38/085 , C08G65/4006 , C08G77/045 , C08G77/50 , C08G77/52 , C08G77/56 , C08K7/22 , C08L71/00 , C08L83/04
摘要： Disclosed herein is a composition having a thermoset polymer and a plurality of hollow microsphere homogenously dispersed in the composition. The polymer is a cyanate ester thermoset, a phthalonitrile thermoset, a crosslinked acetylene thermoset, or a hydrosilation thermoset. Also disclosed herein is a method of: providing a thermosetting compound; adding microspheres to the thermosetting compound; and mixing the thermosetting compound while initiating crosslinking of the thermosetting compound.
摘要翻译： 本文公开了具有热固性聚合物和均匀分散在组合物中的多个中空微球的组合物。 聚合物是氰酸酯热固性材料，邻苯二甲腈热固性材料，交联乙炔热固性材料或硅氢化硅热固体。 本文还公开了一种方法：提供热固性化合物; 将微球加入到热固性化合物中; 并且在引发热固性化合物的交联的同时混合该热固性化合物
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7.发明授权Polymers made from polyhedral oligomeric silsesquioxanes acetylene-containing compounds 有权由多面体低聚倍半硅氧烷含乙炔的化合物制成的聚合物公开(公告)号：US08263727B1
公开(公告)日：2012-09-11
申请号：US13479386
申请日：2012-05-24
IPC分类号： C08G77/20
CPC分类号： C08F238/02 , C08F230/08 , C08G77/04 , C08G77/50 , C08G77/52 , C08G77/60 , C09D183/14 , C09D183/16
摘要： A compound having the formula below. Each R is methyl or phenyl; R2 comprises one or more of silane, siloxane, and aromatic groups; n is a nonnegative integer; and m is 1 or 2. The dashed bond is a single bond and the double dashed bond is a double bond, or the dashed bond is a double bond and the double dashed bond is a triple bond. A polymer made by a hydrosilation reaction of a polyhedral oligomeric silsesquioxane having pendant siloxane groups with an acetylene- and silicon-containing compound having at least two vinyl or ethynyl groups, and a crosslinked polymer thereof. The reaction occurs between the pendant siloxane groups and the vinyl or ethynyl groups.
摘要翻译： 具有下式的化合物。 每个R是甲基或苯基; R2包括硅烷，硅氧烷和芳族基团中的一种或多种; n是非负整数; 并且m为1或2.虚线键为单键，双键键为双键，虚键为双键，双键键为三键。 通过具有侧硅氧烷基团的多面体低聚倍半硅氧烷与具有至少两个乙烯基或乙炔基的乙炔和含硅化合物及其交联聚合物的硅氢化反应制备的聚合物。 反应发生在侧链硅氧烷基团与乙烯基或乙炔基之间。
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8.发明申请Polyhedral Oligomeric Silsesquioxane and Carborane Containing Network Polymers 有权多面体低聚倍半硅氧烷和含有网络聚合物的碳硼烷公开(公告)号：US20100120989A1
公开(公告)日：2010-05-13
申请号：US12692724
申请日：2010-01-25
IPC分类号： C08F130/08
CPC分类号： C08F283/00 , C08F283/12 , C08F290/068 , C08F290/148 , C08G77/04 , C08G77/12 , C08G77/20 , C08G77/50 , C08G77/56 , C08L83/14
摘要： A thermoset and method of making such by crosslinking a mixture of a polyhedral oligomeric silsesquioxane having pendent siloxane groups or unsaturated carbon bonds and a siloxylcarborane compound having unsaturated carbon bonds.
摘要翻译： 一种热固性材料和通过交联具有侧基硅氧烷基团或不饱和碳键的多面体低聚倍半硅氧烷与具有不饱和碳键的硅氧烷基碳化硼化合物的混合物来制备的方法。
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公开(公告)号：US07705100B2
公开(公告)日：2010-04-27
申请号：US11468367
申请日：2006-08-30
IPC分类号： C08G77/56
CPC分类号： C08G77/56 , C07F7/081 , D01F11/14 , D06M11/77 , D06M11/79 , D06M11/80 , D06M15/227 , D06M15/643 , D06M15/647
摘要： A fiber of linear polymer coated with a siloxane-carborane polymer or a thermoset or ceramic made therefrom. An organic fiber coated with a siloxane-carborane polymer or a thermoset or ceramic made therefrom and a surfactant. An organic fiber coated with a siloxane-carborane polymer made from a hydrosilation reaction of a siloxane-carborane compound containing at least two unsaturated carbon-carbon bonds and a silane compound or a thermoset or ceramic made therefrom. A method of coating a fiber by contacting a fiber to an aqueous solution of a siloxane-carborane polymer and a surfactant or to a solution of a siloxane-carborane polymer in a non-halogenated organic solvent. A method of contacting a fiber to a solution of a siloxane-carborane polymer, drying the coating to a temperature that does not change the polymer to a thermoset or ceramic, and using the dried, coated fiber in a process that requires that the fiber be flexible.
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10.发明授权公开(公告)号：US07449535B2
公开(公告)日：2008-11-11
申请号：US11688317
申请日：2007-03-20
IPC分类号： C08G77/398
摘要： A carborane-siloxane compound is provided having the repeat unit Q contains any of —SiR2—, —SiR2—O—, —C≡C—C≡C—, carboranyl, and U′. Each R and R′ is alkyl, aryl, alkylaryl, haloalkyl, haloaryl, or mixtures thereof. Each U′ is derivable from hydrosilation of an alkenyl or alkynyl group. Each T is alkyl, aryl, alkylaryl, haloalkyl, haloaryl, mixtures thereof, —(O—SiR′2)xH, or the repeat unit. Each x and x′ is a positive integer. The compounds may be made be reacting a carborane-siloxane precursor having unsaturated end groups with a siloxane crosslinker in the presence of a hydrosilation catalyst.
摘要翻译： 提供了碳硼烷 - 硅氧烷化合物，其具有重复单元Q包含-SiR 2 - ， - SiR 2 -O - ， - C≡C≡C-，碳硼烷基 ， 和你'。 每个R和R'是烷基，芳基，烷基芳基，卤代烷基，卤代芳基或其混合物。 每个U'可衍生自烯基或炔基的硅氢化。 每个T是烷基，芳基，烷基芳基，卤代烷基，卤代芳基，它们的混合物， - （O-SiR'2）x H或重复单元。 每个x和x'是一个正整数。 化合物可以在硅氢化催化剂存在下使具有不饱和端基的碳硼烷 - 硅氧烷前体与硅氧烷交联剂反应。
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