公开(公告)号：US07153585B2

公开(公告)日：2006-12-26

申请号：US10498242

申请日：2002-12-13

申请人： Marc Audenaert ,  Denis Huze ,  Emmanuel Rastelletti

发明人： Marc Audenaert ,  Denis Huze ,  Emmanuel Rastelletti

IPC分类号： B05D1/04 ,  B05D1/22 ,  B32B15/04 ,  B32B15/08 ,  H05C1/00

CPC分类号： C09D177/06 ,  C08K5/544 ,  C09D177/00 ,  C09D177/02 ,  Y10T428/31678 ,  Y10T428/31681 ,  C08L2666/28

摘要： The invention concerns to the use of a powder comprising 99.95 to 95% of at least one polyamide and 0.05 to 5% of at least one silane for coating metals. This powder may be prepared by simple dry blending of the constituents. The silane can also be added to the molten polyamide in a mixing device and the resulting product reduced to powder. The addition of silane makes it possible to significantly improve electrostatic application by preventing a substantial portion of the powder from falling off during the electrostatic discharge which follows application, while providing lasting adhesion between the coating and metal. Advantageously, the silane is chosen from aminopropyltriethoxysilane and aminopropyltrimethoxysilane. The invention also concerns a method of coating an object with a film resulting from melting a thin layer of the powder.

摘要翻译： 本发明涉及使用包含99.95至95％的至少一种聚酰胺和0.05至5％的至少一种硅烷来涂覆金属的粉末。 这种粉末可以通过简单的混合组分来制备。 硅烷也可以在混合装置中加入到熔融聚酰胺中，并将所得产物还原成粉末。 通过添加硅烷，可以通过防止大部分粉末在施加的静电放电期间脱落，同时提供涂层和金属之间的持久粘合，从而显着改善静电施加。 有利地，硅烷选自氨基丙基三乙氧基硅烷和氨基丙基三甲氧基硅烷。 本发明还涉及一种用熔融薄层粉末形成的膜涂覆物体的方法。

公开(公告)号：US20050064102A1

公开(公告)日：2005-03-24

申请号：US10498242

申请日：2002-12-13

申请人： Marc Audenaert ,  Denis Huze ,  Emmanuel Rastelleti

发明人： Marc Audenaert ,  Denis Huze ,  Emmanuel Rastelleti

IPC分类号： C08K5/544 ,  C09D5/03 ,  C09D5/46 ,  C09D177/00 ,  C09D177/02 ,  C09D177/06 ,  C09D183/00 ,  C09D183/08 ,  B05D3/02

CPC分类号： C09D177/06 ,  C08K5/544 ,  C09D177/00 ,  C09D177/02 ,  Y10T428/31678 ,  Y10T428/31681 ,  C08L2666/28

摘要： The invention concerns to the use of a powder comprising 99.95 to 95% of at least one polyamide and 0.05 to 5% of at least one silane for coating metals. This powder may be prepared by simple dry blending of the constituents. The silane can also be added to the molten polyamide in a mixing device and the resulting product reduced to powder. The addition of silane makes it possible to significantly improve electrostatic application by preventing a substantial portion of the powder from falling off during the electrostatic discharge which follows application, while providing lasting adhesion between the coating and metal. Advantageously, the silane is chosen from aminopropyltriethoxysilane and aminopropyltrimethoxysilane. The invention also concerns a method of coating an object with a film resulting from melting a thin layer of the powder.

摘要翻译： 本发明涉及使用包含99.95至95％的至少一种聚酰胺和0.05至5％的至少一种硅烷来涂覆金属的粉末。 这种粉末可以通过简单的混合组分来制备。 硅烷也可以在混合装置中加入到熔融聚酰胺中，并将所得产物还原成粉末。 通过添加硅烷，可以通过防止大部分粉末在施加的静电放电期间脱落，同时提供涂层和金属之间的持久粘合，从而显着改善静电施加。 有利地，硅烷选自氨基丙基三乙氧基硅烷和氨基丙基三甲氧基硅烷。 本发明还涉及一种用熔融薄层粉末形成的膜涂覆物体的方法。

公开(公告)号：US20080293883A1

公开(公告)日：2008-11-27

申请号：US11718041

申请日：2005-10-26

申请人： Bernard Pees ,  Marc Audenaert ,  Maliha Khusrawy ,  Helene Egret

发明人： Bernard Pees ,  Marc Audenaert ,  Maliha Khusrawy ,  Helene Egret

IPC分类号： C08L77/00

CPC分类号： C08J3/201 ,  B29K2105/162 ,  B82Y30/00 ,  C08J5/005 ,  C08J2377/00 ,  C08K3/346 ,  C08K9/08 ,  C08L77/00

摘要： The present invention concerns a process for preparing a polymer nanocomposite composition, the process comprising: a) mixing a melted polyamide of inherent viscosity under 1 and a nanofiller to disperse the nanofiller in said polyamide; and b) subjecting the previous mixture to polymerization conditions to polymerize the polyamide and to form the polymer nanocomposite composition. Advantageously the inherent viscosity of the polyamide is under 0.9 and preferably between 0.4 and 0.8. Step a) is carried out in an extruder or a mixer. Advantageously a mono or twin-screw extruder is used. Step b) could be made either in melted state or in solid state. It is easier to make it in the same apparatus as step a). Should step a) is carried out in an extruder, step b) is made in the same extruder. Polymerization of step b) can be carried with a catalyst and/or by having the extruder zones in which step b) takes place to operate under vacuum.

摘要翻译： 本发明涉及一种制备聚合物纳米复合材料组合物的方法，该方法包括：a）将特性粘度低于1的熔融聚酰胺与纳米填料混合，以将纳米填料分散在所述聚酰胺中; 和b）使先前的混合物进行聚合条件以聚合聚酰胺并形成聚合物纳米复合组合物。 有利地，聚酰胺的特性粘度在0.9以下，优选在0.4和0.8之间。 步骤a）在挤出机或混合器中进行。 有利的是使用单螺杆或双螺杆挤出机。 步骤b）可以以熔融状态或固态进行。 在与步骤a）相同的装置中更容易。 如果步骤a）在挤出机中进行，则步骤b）在相同的挤出机中制备。 步骤b）的聚合可以用催化剂和/或通过使挤出机区域在步骤b）中进行以在真空下操作。

公开(公告)号：US20050170179A1

公开(公告)日：2005-08-04

申请号：US11043665

申请日：2005-01-26

申请人： Marc Audenaert ,  Michel Foucher ,  Isabelle Letellier-Delahaye ,  Alain Vitoux

发明人： Marc Audenaert ,  Michel Foucher ,  Isabelle Letellier-Delahaye ,  Alain Vitoux

IPC分类号： A47L15/50 ,  B05D1/04 ,  B32B1/00 ,  C09D5/03

CPC分类号： C09D5/033 ,  A47L15/50 ,  C09D5/032 ,  Y10T428/2982

摘要： The present invention relates to the use of a powder for coating articles, this powder comprising, by volume, 99 to 65% of at least one thermoplastic polymer and 1 to 35% of beads of a material that retains its initial shape at the processing temperatures for obtaining the coating. This powder may be prepared by simply dry-blending the constituents. The invention also relates to this powder. The invention relates in particular to rough coatings obtained from powders, for a dishwasher basket, which contain solid or hollow glass or ceramic beads added by dry-blending them with the polyamide powder. Because of their roughness, these coatings improve the drying in dishwashers. The addition of glass beads furthermore improves the quality of the fluidization.

摘要翻译： 本发明涉及用于涂覆制品的粉末的用途，该粉末体积包含99至65％的至少一种热塑性聚合物和1至35％的在加工温度下保持其初始形状的材料的珠粒 用于获得涂层。 该粉末可以通过简单干混组分来制备。 本发明还涉及该粉末。 本发明特别涉及通过将其与聚酰胺粉末干混而添加的固体或中空玻璃或陶瓷珠而获得的用于洗碗机篮的粉末的粗糙涂层。 由于它们的粗糙度，这些涂层改善了洗碗机中的干燥。 玻璃珠的添加进一步提高了流化的质量。

公开(公告)号：US08329801B2

公开(公告)日：2012-12-11

申请号：US12440322

申请日：2007-09-07

申请人： Marc Audenaert ,  Jean-Charles Durand

发明人： Marc Audenaert ,  Jean-Charles Durand

IPC分类号： C08K3/26 ,  B32B15/08

CPC分类号： C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  C09D5/03 ,  C09D5/033 ,  C09D177/00 ,  C09D177/02 ,  C09J177/02 ,  Y10T428/31681

摘要： The invention provides a self-adhesive composition in powder form for the coating of metallic substrates, composed of homopolyamide (A) selected from PA11 and PA12, copolyamide (B), calcium carbonate and, optionally, at least one component selected from a pigment or dye, an anti-crater agent or spreading agent, a reductant, an antioxidant, a reinforcing filler, a UV stabilizer, a fluidizing agent and a corrosion inhibitor, said composition being devoid of silane-type adhesion promoter or of an adhesion promoter containing an epoxy, alcohol and/or carboxylic acid function, or derivatives thereof, and having a dry-state modulus and/or a wet-state modulus of greater than or equal to 2200 MPa [Standard NF EN ISO 527]. The invention also relates to a composite material comprising a metallic substrate directly coated with a coating film resulting from the melting of said composition, the adhesion of the coating film to the metallic substrate being greater than 3 after 2000 hours of salt fog before and after drying, in accordance with Standard NFT 58-112.

摘要翻译： 本发明提供了一种用于涂覆金属基材的粉末形式的自粘组合物，其由选自PA11和PA12的均聚酰胺（A），共聚酰胺（B），碳酸钙和任选的至少一种选自颜料或 染料，抗火山口剂或铺展剂，还原剂，抗氧化剂，增强填料，UV稳定剂，流化剂和腐蚀抑制剂，所述组合物不含硅烷型粘合促进剂或含有 环氧，醇和/或羧酸官能团或其衍生物，并且具有大于或等于2200MPa的干态模量和/或湿态模量[标准NF EN ISO 527]。 本发明还涉及一种复合材料，其包括直接涂覆有由所述组合物熔化产生的涂膜的金属基材，在干燥前后的盐雾后2000小时后，涂膜对金属基材的粘附性大于3 ，符合NFT 58-112标准。

公开(公告)号：US20100113670A1

公开(公告)日：2010-05-06

申请号：US12440322

申请日：2007-09-07

申请人： Marc Audenaert ,  Jean-Charles Durand

发明人： Marc Audenaert ,  Jean-Charles Durand

IPC分类号： C09D177/00

CPC分类号： C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  C09D5/03 ,  C09D5/033 ,  C09D177/00 ,  C09D177/02 ,  C09J177/02 ,  Y10T428/31681

摘要： The invention provides a self-adhesive composition in powder form for the coating of metallic substrates, composed of homopolyamide (A) selected from PA11 and PA12, copolyamide (B), calcium carbonate and, optionally, at least one component selected from a pigment or dye, an anti-crater agent or spreading agent, a reductant, an antioxidant, a reinforcing filler, a UV stabilizer, a fluidizing agent and a corrosion inhibitor, said composition being devoid of silane-type adhesion promoter or of an adhesion promoter containing an epoxy, alcohol and/or carboxylic acid function, or derivatives thereof, and having a dry-state modulus and/or a wet-state modulus of greater than or equal to 2200 MPa [Standard NF EN ISO 527]. The invention also relates to a composite material comprising a metallic substrate directly coated with a coating film resulting from the melting of said composition, the adhesion of the coating film to the metallic substrate being greater than 3 after 2000 hours of salt fog before and after drying, in accordance with Standard NFT 58-112.

摘要翻译： 本发明提供了一种用于涂覆金属基材的粉末形式的自粘组合物，其由选自PA11和PA12的均聚酰胺（A），共聚酰胺（B），碳酸钙和任选的至少一种选自颜料或 染料，抗火山口剂或铺展剂，还原剂，抗氧化剂，增强填料，UV稳定剂，流化剂和腐蚀抑制剂，所述组合物不含硅烷型粘合促进剂或含有 环氧，醇和/或羧酸官能团或其衍生物，并且具有大于或等于2200MPa的干态模量和/或湿态模量[标准NF EN ISO 527]。 本发明还涉及一种复合材料，其包括直接涂覆有由所述组合物熔化产生的涂膜的金属基材，在干燥前后的盐雾后2000小时后，涂膜对金属基材的粘附性大于3 ，符合NFT 58-112标准。