Catalysts for the polymerization of unsaturated compounds
    7.
    发明授权
    Catalysts for the polymerization of unsaturated compounds 有权
    用于不饱和化合物聚合的催化剂

    公开(公告)号:US07273940B2

    公开(公告)日:2007-09-25

    申请号:US10959212

    申请日:2004-10-07

    IPC分类号: C07D333/12

    摘要: Bisimine compounds of the formula (I) where the symbols have the following meanings: A is a nonmetal selected from among N, S, O and P, R1 is a radical of the formula NR5R6, R2 is a radical of the formula NR5R6 or NR7R8, alkyl, aryl or cycloalkyl, R5 and R6 together with the N atom form a 5-, 6- or 7-membered ring in which one or more of the —CH— or —CH2— groups may be replaced by suitable heteroatom groups and which may be saturated or unsaturated and unsubstituted or substituted or be fused with further carbacyclic or heterocarbacyclic 5- or 6-membered rings which may in turn be saturated or unsaturated and substituted or unsubstituted, and R7 and R8 are, independently of one another, alkyl, aryl or cycloalkyl radicals, and R3, R4 are, independently of one another, H or alkyl, aryl or cycloalkyl radicals, and n is 1 or 2, are used to prepare bisimidinato complexes which can be used in the polymerization of unsaturated compounds.

    摘要翻译: 式(I)的双亚胺化合物,其中符号具有以下含义:A是选自N,S,O和P的非金属,R 1是式NR的基团, 5,R 6,R 2是下式的基团NR 5 R 6或NR 6 烷基,芳基或环烷基,R 5和R 6以及N原子一起形成一个 5-,6-或7-元环,其中一个或多个-CH-或-CH 2 - 亚基可以被合适的杂原子基团取代,并且可以是饱和或不饱和和未取代的或 取代或与另外的碳环或杂碳环五或六元环稠合,其又可以是饱和的或不饱和的和取代或未取代的,R 7和R 8是 独立地为烷基,芳基或环烷基,R 3,R 4彼此独立地为H或烷基,芳基或环烷基,以及 n为1或2, 用于制备可用于不饱和化合物聚合的双嘧啶络合物。

    Polymerization catalyst
    10.
    发明授权
    Polymerization catalyst 失效
    聚合催化剂

    公开(公告)号:US06743932B2

    公开(公告)日:2004-06-01

    申请号:US09827099

    申请日:2001-04-06

    IPC分类号: C07F1700

    摘要: An organometallic compound of the formula I where M1 is selected from among Fe, Ru and Os and M2 is selected from among the transition metals of groups IV to VI of the Periodic Table, which can be prepared by reacting an organometallic compound of the formula II with a transition metal compound of the formula III, M2L1L2(L3)x+1  III where the variables are as defined above and the organometallic compound of the formula II can, if desired, be doubly deproteinated beforehand, can be used as part of a catalyst system for the polymerization or copolymerization of olefins. This catalyst system comprises one or more organometallic compounds of the formula I and at least one activator. The compound of the formula I can also be used to produce a solid catalyst comprising at least one organometallic compound of the formula I, at least one activator and a solid support by impregnating a support material with one or more organometallic compounds of the formula I and at least one activator. This solid catalyst can be used in a process for the polymerization or copolymerization of olefins in bulk, in suspension or in the gas phase.

    摘要翻译: 式I的有机金属化合物,其中M 1选自Fe,Ru和Os,M 2选自周期表IV至VI族的过渡金属,它们可以通过使有机金属 式II化合物与式III的过渡金属化合物,其中变量如上所定义,如果需要,可以预先将式II的有机金属化合物双重去蛋白化,可用作催化剂体系的一部分,用于 烯烃的聚合或共聚。 该催化剂体系包含一种或多种式I的有机金属化合物和至少一种活化剂。 式I化合物还可用于制备包含至少一种式I的有机金属化合物,至少一种活化剂和固体载体的固体催化剂,其通过用一种或多种式I的有机金属化合物浸渍载体材料和 至少一种活化剂。 该固体催化剂可用于本体,悬浮液或气相中烯烃聚合或共聚的方法。