CORE / SHELL-TYPE CATALYST PARTICLES COMPRISING METAL OR CERAMIC CORE MATERIALS AND METHODS FOR THEIR PREPARATION
    6.
    发明申请
    CORE / SHELL-TYPE CATALYST PARTICLES COMPRISING METAL OR CERAMIC CORE MATERIALS AND METHODS FOR THEIR PREPARATION 有权
    包含金属或陶瓷芯材的核心/壳型催化剂颗粒及其制备方法

    公开(公告)号:US20100092841A1

    公开(公告)日:2010-04-15

    申请号:US12438984

    申请日:2007-08-27

    摘要: The invention is directed to core/shell type catalyst particles comprising a Mcore/Mshell structure with Mcore=inner particle core and Mshell=outer particle shell, wherein the medium diameter of the catalyst particle (dcore+shell) is in the range of 20 to 100 nm, 5 preferably in the range of 20 to 50 nm. The thickness of the outer shell (tshell) is about 5 to 20% of the diamet the inner particle core of said catalyst particle, preferably comprising at least 3 atomic layers. The inner particle core (Mcore) of the particles comprises metal or ceramic materials, whereas the material of the outer shell (Mshell) comprises precious metals and/or alloys thereof. The core/shell type catalyst particles are preferably supported on suitable support materials such as carbon black and can be used as electrocatalysts for fuel cells and for other catalytic applications.

    摘要翻译: 本发明涉及包含Mcore / Mshell结构的核/壳型催化剂颗粒,其中Mcore =内颗粒核和Mshell =外颗粒壳,其中催化剂颗粒的介质直径(dcore +壳)在20至 100nm,优选在20〜50nm的范围内。 外壳的厚度(tshell)为所述催化剂颗粒的内颗粒核心的直径的约5至20%,优选包含至少3个原子层。 颗粒的内部颗粒核心(Mcore)包括金属或陶瓷材料,而外壳的材料(Mshell)包括贵金属和/或它们的合金。 核/壳型催化剂颗粒优选负载在合适的载体材料如炭黑上,并且可以用作燃料电池的电催化剂和用于其它催化应用。

    YELLO ANIONIC DISAZO DYES
    8.
    发明申请

    公开(公告)号:US20100199443A1

    公开(公告)日:2010-08-12

    申请号:US12748504

    申请日:2010-03-29

    IPC分类号: C09B31/02 C09B31/147

    摘要: The present invention relates to novel yellow anionic dyes, a process for their preparation, certain novel intermediates necessary for their preparation and the use of these dyes for dyeing natural or synthetic materials, in particular, paper. The dyes are of formula (14), (15) or (16) in which R1 represents hydrogen, C1-C4alkyl, C1-C4alkoxy or SO3H, R2 represents SO3H or CO2H, R3 represents hydrogen, C1-C4alkyl, halogen, hydroxy, C1-C4alkoxy, carboxy, NH2 or NHC1-C4alkyl, R3a represents hydrogen or NH2 and A1 and A2, independently of the other, is selected from the group consisting of an acetoacetylated amine, a derivative of barbituric acid, a 2,4,6-triaminopyrimidine derivative, a pyridone derivative, an aminopyrazole or a pyrazolone derivative and a benzoic acid derivative, or A1 and A2, each one independently of the other, represent a certain phenol residue.

    摘要翻译: 本发明涉及新型黄色阴离子染料,其制备方法,其制备所需的某些新型中间体以及用于染色天然或合成材料,特别是纸的这些染料的用途。 染料具有式(14),(15)或(16),其中R1表示氢,C1-C4烷基,C1-C4烷氧基或SO3H,R2表示SO3H或CO2H,R3表示氢,C1-C4烷基,卤素,羟基, C 1 -C 4烷氧基,羧基,NH 2或NHCl-C 4烷基,R 3a表示氢或NH 2,且A 1和A 2彼此独立地选自乙酰乙酰胺,巴比妥酸衍生物,2,4,6 三氯氨嘧啶衍生物,吡啶酮衍生物,氨基吡唑或吡唑啉酮衍生物和苯甲酸衍生物,或A1和A2各自独立地表示某一酚残基。

    Method for producing a fuel gas containing hydrogen for electrochemical cells and associated device
    9.
    发明申请
    Method for producing a fuel gas containing hydrogen for electrochemical cells and associated device 审中-公开
    用于生产电化学电池用氢气和相关装置的燃料气体的方法

    公开(公告)号:US20060168887A1

    公开(公告)日:2006-08-03

    申请号:US10535605

    申请日:2003-10-18

    IPC分类号: C10J3/46 B01J8/00

    摘要: The invention relates to a process and an apparatus for producing hydrogen-containing fuel gases for fuel cells by catalytic reforming of hydrocarbons and subsequent gas purification. The process is characterized in that the catalytic reforming comprises two successive stages of which the first stage comprises autothermal reforming and the second stage comprises low-temperature steam reforming at temperatures below 650° C. In the first stage (autothermal reforming, ATR stage), a feed mixture of hydrocarbons, oxygen and water or water vapour is reacted over a catalyst in an autothermal reforming reaction to convert it incompletely into a hydrogen-rich gas mixture. The mixture which still contains residual amounts of hydrocarbons is then reacted in a subsequent steam reforming stage (second stage, SR stage) to give a hydrogen-rich fuel gas. A fuel gas which has a temperature at the reactor outlet of 400-650° C. and contains a very high proportion of hydrogen is obtained. Owing to the low outlet temperatures, the fuel gas can be passed directly to a gas purification stage without use of additional heat exchangers. In addition to the improvement in the reformer efficiency, a more compact and cheaper reformer design is made possible by the invention. Process and apparatus are used for producing hydrogen or hydrogen-containing fuel gases for fuel cells, in particular for mobile and stationary applications.

    摘要翻译: 本发明涉及通过烃的催化重整和随后的气体净化来生产用于燃料电池的含氢燃料气体的方法和装置。 该方法的特征在于催化重整包括两个连续阶段,其中第一阶段包括自热重整,第二阶段包括低于650℃的低温蒸汽重整。在第一阶段(自热重整,ATR阶段) 烃,氧和水或水蒸气的进料混合物在自热重整反应中在催化剂上反应,将其不完全转化为富氢气体混合物。 然后仍然含有残留量的烃的混合物在随后的蒸汽重整阶段(第二阶段,SR阶段)中反应,得到富氢燃料气体。 获得在反应器出口处具有400-650℃的温度并且含有非常高比例的氢的燃料气体。 由于出口温度低,燃料气体可以直接通过气体净化阶段,而不需要额外的热交换器。 除了提高重整器效率之外,通过本发明可以实现更紧凑和更便宜的重整器设计。 工艺和设备用于生产用于燃料电池的氢或含氢燃料气体,特别是用于移动和固定应用。