摘要:
The invention discloses core/shell type catalyst particles comprising a Mcore/Mshell structure with Mcore=inner particle core and Mshell=outer particle shell, wherein the medium diameter of the catalyst particle (dcore+shell) is in the range of 20 to 100 nm, preferably in the range of 20 to 50 nm. The thickness of the outer shell (tshell) is about 5 to 20% of the diameter of the inner particle core of said catalyst particle, preferably comprising at least 3 atomic layers. The core/shell type catalyst particles, particularly the particles comprising a Pt-based shell, reveal a high specific activity. The catalyst particles are preferably supported on suitable support materials such as carbon black and are used as electrocatalysts for fuel cells.
摘要:
The invention is directed to core/shell type catalyst particles comprising a Mcore/Mshell structure with Mcore=inner particle core and Mshell=outer particle shell, wherein the medium diameter of the catalyst particle (dcore+shell) is in the range of 20 to 100 nm, 5 preferably in the range of 20 to 50 nm. The thickness of the outer shell (tshell) is about 5 to 20% of the diameter of the inner particle core of said catalyst particle, preferably comprising at least 3 atomic layers. The inner particle core (Mcore) of the particles comprises metal or ceramic materials, whereas the material of the outer shell (Mshell) comprises precious metals and/or alloys thereof. The core/shell type catalyst particles are preferably supported on suitable support materials such as carbon black and can be used as electrocatalysts for fuel cells and for other catalytic applications.
摘要:
The invention discloses core/shell, type catalyst particles comprising a Mcore/Mshell structure with Mcore=inner particle core and Mshell=outer particle shell, wherein the medium diameter of the catalyst particle (dcore+shell) is in the range of 20 to 100 nm, preferably in the range of 20 to 50 nm. The thickness of the outer shell (tshell) is about 5 to 20% of the diameter of the inner particle core of said catalyst particle, preferably comprising at least 3 atomic layers. The core/shell type catalyst particles, particularly the particles comprising a Pt˜based shell reveal a high specific activity. The catalyst particles are preferably supported on suitable support materials such as carbon black and are used as electrocatalysts for fuel cells.
摘要:
The invention discloses core/shell type catalyst particles comprising a Mcore/Mshell structure with Mcore=inner particle core and Mshell−outer particle shell, wherein the medium diameter of the catalyst particle (dcore+shell) is ≧20 nm. The thickness of the outer shell (tshell) comprises at least 3 atomic layers. The core/shell type catalyst particles, particularly the particles comprising a Pt-based shell, reveal a high specific activity. The catalyst particles are preferably supported on suitable support materials such as carbon black and are used as electrocatalysts for fuel cells.
摘要:
The invention is directed to core/shell type catalyst particles comprising a Mcore/Mshell structure with Mcore=inner particle core and Mshell=outer particle shell, wherein the medium diameter of the catalyst particle (dcore+shell) is in the range of 20 to 100 nm, 5 preferably in the range of 20 to 50 nm. The thickness of the outer shell (tshell) is about 5 to 20% of the diamet the inner particle core of said catalyst particle, preferably comprising at least 3 atomic layers. The inner particle core (Mcore) of the particles comprises metal or ceramic materials, whereas the material of the outer shell (Mshell) comprises precious metals and/or alloys thereof. The core/shell type catalyst particles are preferably supported on suitable support materials such as carbon black and can be used as electrocatalysts for fuel cells and for other catalytic applications.
摘要:
The invention discloses core/shell type catalyst particles comprising a Mcore/Mshell structure with Mcore=inner particle core and Mshell=outer particle shell, wherein the medium diameter of the catalyst particle (dcore+shell) is in the range of 20 to 100 nm, preferably in the range of 20 to 50 nm. The thickness of the outer shell (tshell) is about 5 to 20% of the diameter of the inner particle core of said catalyst particle, preferably comprising at least 3 atomic layers. The core/shell type catalyst particles, particularly the particles comprising a Pt-based shell, reveal a high specific activity. The catalyst particles are preferably supported on suitable support materials such as carbon black and are used as electrocatalysts for fuel cells.
摘要:
A method for regenerating a particle filter of an internal combustion engine, of a diesel engine in particular, in which a characteristic quantity for the particle loading is determined to initiate regeneration. More accurate correlation of the particle mass is achieved in that a corrected loading characteristic quantity is formed from the loading characteristic quantity by modifying the loading characteristic quantity using a compression factor which takes into account different degrees of compression of the particles as a function of different operating states of the engine.
摘要:
A battery of rod making machines of the tobacco processing industry (such as plain or filter cigarette makers or filter rod makers) is separated from a battery of processing machines (such as cigarette packing or filter tipping machines) by a magazine which is provided with compartments for discrete containers. Articles which are turned out by the making machines are introduced into so-called trays, and groups of filled trays are introduced into containers which are delivered into the compartments of the magazine for temporary storage, or directly to the processing machines, A container which is to furnish articles to a processing machine is relieved of filled trays, and the contents of the filled trays are conveyed to one or more selected processing machines. The thus emptied trays are returned into containers, and such containers are thereupon delivered into the magazine or directly to one or more selected rod making machines.
摘要:
A method for operating a particulate filter situated in an exhaust gas area of an internal combustion engine and a device for carrying out the method are described. A measure of the particulate matter burn-off rate is detected for influencing and/or monitoring the particulate matter burn-off rate or for influencing and/or monitoring the particulate filter temperature. A secondary air flow supplied by a secondary air pump is blown into the exhaust gas area upstream from the particulate filter. The secondary air flow is determined as a function of the detected measure of the particulate matter burn-off rate. If necessary, the secondary air flow may be enriched by an oxygen flow or nitrogen flow supplied by an air separation unit. The method prevents the particulate filter from being damaged by an unacceptably high particulate matter burn-off rate or an unacceptably high particulate filter temperature.
摘要:
A procedure to operate a particle filter disposed in an exhaust gas area of an internal combustion engine and a device to implement the procedure are proposed. The particle filter is regenerated if required by the particles lodged in the filter, whereby the particle filter is heated for regeneration by manipulation of the exhaust gas temperature upstream in front of the particle filter. During the regeneration of the particle filter, the exhaust gas temperature is established to a specified exhaust gas temperature set point, which is dependent upon at least one parameter of the particle filter during the regeneration. The procedural approach according to the invention allows for a quick regeneration of the particle filter without endangering the particle filter with an inadmissibly high temperature.