公开(公告)号：US09701595B2

公开(公告)日：2017-07-11

申请号：US13732840

申请日：2013-01-02

Applicant: Margaret M. Wu ,  Steven P. Rucker ,  Jo Ann M. Canich

Inventor： Margaret M. Wu ,  Steven P. Rucker ,  Jo Ann M. Canich

IPC: C07C5/03 ,  C07C2/30 ,  C08F10/00 ,  C08F10/14 ,  C10G50/02 ,  C10M107/08 ,  C10M107/10 ,  C10M111/04 ,  C08F4/659 ,  C08F4/6592

CPC classification number: C07C2/30 ,  C07C5/03 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/14 ,  C10G50/02 ,  C10G2300/1088 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/703 ,  C10G2400/10 ,  C10G2400/22 ,  C10M107/08 ,  C10M107/10 ,  C10M111/04 ,  C10M2205/0265 ,  C10M2205/0285 ,  C10N2220/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2220/033 ,  C10N2270/00 ,  C08F4/65908 ,  C08F4/64048

Abstract: This disclosure relates to a liquid syndiotactic polyalphaolefin, sPAO, comprising one or more C4 to C24 monomers, said sPAO having: a) an rr triad content of 5 to 50% as measured by 13C NMR; b) an mr triad content of 25 to 60% as measured by 13C NMR, where the mr to mm triad ratio is at least 1.0; c) a pour point of Z° C. or less, where Z=0.0648X−51.2, where X=kinematic viscosity at 100° C. as reported in centistokes (cSt); d) a kinematic viscosity at 100° C. of 100 cSt or more (alternatively 200 cSt or more); e) a ratio of mr triads to rr triad (as determined by 13C NMR) of less than 9; f) a ratio of vinylidene to 1,2-disubstituted olefins (as determined by 1H NMR) of less than 8; g) a viscosity index of 120 or more; and h) an Mn of 40,000 or less. This disclosure further relates to processes to make and use sPAOs, including those having any combination of characterics a) to h).

公开(公告)号：US08530712B2

公开(公告)日：2013-09-10

申请号：US12971546

申请日：2010-12-17

Applicant: Margaret M. Wu ,  Steven P. Rucker ,  Jo Ann M. Canich

Inventor： Margaret M. Wu ,  Steven P. Rucker ,  Jo Ann M. Canich

IPC: C07C9/22 ,  C07C11/00 ,  C10M107/02

CPC classification number: C07C2/30 ,  C07C5/03 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/14 ,  C10G50/02 ,  C10G2300/1088 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/703 ,  C10G2400/10 ,  C10G2400/22 ,  C10M107/08 ,  C10M107/10 ,  C10M111/04 ,  C10M2205/0265 ,  C10M2205/0285 ,  C10N2220/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2220/033 ,  C10N2270/00 ,  C08F4/65908 ,  C08F4/64048

Abstract: This disclosure relates to a liquid syndiotactic polyalphaolefin, sPAO, comprising one or more C4 to C24 monomers, said sPAO having: a) an rr triad content of 5 to 50% as measured by 13C NMR; b) an mr triad content of 25 to 60% as measured by 13C NMR, where the mr to mm triad ratio is at least 1.0; c) a pour point of Z ° C. or less, where Z=0.0648X−51.2, where X=kinematic viscosity at 100° C. as reported in centistokes (cSt); d) a kinematic viscosity at 100° C. of 100 cSt or more (alternatively 200 cSt or more); e) a ratio of mr triads to rr triad (as determined by 13C NMR) of less than 9; f) a ratio of vinylidene to 1,2-disubstituted olefins (as determined by 1H NMR) of less than 8; g) a viscosity index of 120 or more; and h) an Mn of 40,000 or less. This disclosure further relates to processes to make and use sPAOs, including those having any combination of characteristics a) to h).

Abstract translation: 本公开涉及包含一种或多种C 4至C 24单体的液体间同立构聚α-烯烃sPAO，所述sPAO具有：a）通过13 C NMR测量的rr三单元组含量为5-50％; b）通过13 C NMR测量的mr三元组含量为25至60％，其中mr至mm三单元组比为至少1.0; c）Z℃或更低的倾点，其中Z = 0.0648X-51.2，其中X =以厘沲（cSt）报告的100℃下的运动粘度; d）100℃下的运动粘度为100cSt以上（或者200cSt以上）; e）mr三单元组与三元组的比率（通过13 C NMR测定）小于9; f）亚乙烯基与1,2-二取代烯烃的比例（通过1 H NMR确定）小于8; g）粘度指数为120以上; 和h）40,000以下的Mn。 本公开还涉及制备和使用sPAO的方法，包括具有a）至h）特征组合的那些。

公开(公告)号：US20110160502A1

公开(公告)日：2011-06-30

申请号：US12971546

申请日：2010-12-17

Applicant: Margaret M. Wu ,  Steven P. Rucker ,  Jo Ann M. Canich

Inventor： Margaret M. Wu ,  Steven P. Rucker ,  Jo Ann M. Canich

IPC: C07C11/00 ,  C07C2/02

CPC classification number: C07C2/30 ,  C07C5/03 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/14 ,  C10G50/02 ,  C10G2300/1088 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/703 ,  C10G2400/10 ,  C10G2400/22 ,  C10M107/08 ,  C10M107/10 ,  C10M111/04 ,  C10M2205/0265 ,  C10M2205/0285 ,  C10N2220/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2220/033 ,  C10N2270/00 ,  C08F4/65908 ,  C08F4/64048

Abstract: This disclosure relates to a liquid syndiotactic polyalphaolefin, sPAO, comprising one or more C4 to C24 monomers, said sPAO having: a) an rr triad content of 5 to 50% as measured by 13C NMR; b) an mr triad content of 25 to 60% as measured by 13C NMR, where the mr to mm triad ratio is at least 1.0; c) a pour point of Z ° C. or less, where Z=0.0648X-51.2, where X=kinematic viscosity at 100° C. as reported in centistokes (cSt); d) a kinematic viscosity at 100° C. of 100 cSt or more (alternatively 200 cSt or more); e) a ratio of mr triads to rr triad (as determined by 13C NMR) of less than 9; f) a ratio of vinylidene to 1,2-disubstituted olefins (as determined by 1H NMR) of less than 8; g) a viscosity index of 120 or more; and h) an Mn of 40,000 or less. This disclosure further relates to processes to make and use sPAOs, including those having any combination of characteristics a) to h).

Abstract translation: 本公开涉及包含一种或多种C 4至C 24单体的液体间同立构聚α-烯烃sPAO，所述sPAO具有：a）通过13 C NMR测量的rr三单元组含量为5-50％; b）通过13 C NMR测量的mr三元组含量为25至60％，其中mr至mm三单元组比为至少1.0; c）Z℃或更低的倾点，其中Z = 0.0648X-51.2，其中X =以厘沲（cSt）报告的100℃下的运动粘度; d）100℃下的运动粘度为100cSt以上（或者200cSt以上）; e）mr三单元组与三元组的比率（通过13 C NMR测定）小于9; f）亚乙烯基与1,2-二取代烯烃的比例（通过1 H NMR确定）小于8; g）粘度指数为120以上; 和h）40,000以下的Mn。 本公开还涉及制备和使用sPAO的方法，包括具有a）至h）特征组合的那些。

公开(公告)号：US20130131410A1

公开(公告)日：2013-05-23

申请号：US13732840

申请日：2013-01-02

Applicant: Margaret May-Som Wu ,  Steven P. Rucker ,  Jo Ann M. Canich

Inventor： Margaret May-Som Wu ,  Steven P. Rucker ,  Jo Ann M. Canich

IPC: C07C2/30 ,  C07C5/03

CPC classification number: C07C2/30 ,  C07C5/03 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/14 ,  C10G50/02 ,  C10G2300/1088 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/703 ,  C10G2400/10 ,  C10G2400/22 ,  C10M107/08 ,  C10M107/10 ,  C10M111/04 ,  C10M2205/0265 ,  C10M2205/0285 ,  C10N2220/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2220/033 ,  C10N2270/00 ,  C08F4/65908 ,  C08F4/64048

Abstract: This disclosure relates to a liquid syndiotactic polyalphaolefin, sPAO, comprising one or more C4 to C24 monomers, said sPAO having: a) an rr triad content of 5 to 50% as measured by 13C NMR; b) an mr triad content of 25 to 60% as measured by 13C NMR, where the mr to mm triad ratio is at least 1.0; c) a pour point of Z ° C. or less, where Z=0.0648X−51.2, where X=kinematic viscosity at 100° C. as reported in centistokes (cSt); d) a kinematic viscosity at 100° C. of 100 cSt or more (alternatively 200 cSt or more); e) a ratio of mr triads to rr triad (as determined by 13C NMR) of less than 9; f) a ratio of vinylidene to 1,2-disubstituted olefins (as determined by 1H NMR) of less than 8; g) a viscosity index of 120 or more; and h) an Mn of 40,000 or less. This disclosure further relates to processes to make and use sPAOs, including those having any combination of characterics a) to h).

Abstract translation: 本公开涉及包含一种或多种C 4至C 24单体的液体间同立构聚α-烯烃sPAO，所述sPAO具有：a）通过13 C NMR测量的rr三单元组含量为5-50％; b）通过13 C NMR测量的mr三元组含量为25至60％，其中mr至mm三单元组比为至少1.0; c）Z℃或更低的倾点，其中Z = 0.0648X-51.2，其中X =以厘沲（cSt）报告的100℃下的运动粘度; d）100℃下的运动粘度为100cSt以上（或者200cSt以上）; e）mr三单元组与三元组的比率（通过13 C NMR测定）小于9; f）亚乙烯基与1,2-二取代烯烃的比例（通过1 H NMR确定）小于8; g）粘度指数为120以上; 和h）40,000以下的Mn。 本公开还涉及制备和使用sPAO的方法，包括具有特征a）至h）的任何组合的方法。

公开(公告)号：US08058461B2

公开(公告)日：2011-11-15

申请号：US12715068

申请日：2010-03-01

Applicant: Alexander Z. Voskoboynikov ,  Mikhail V. Nikulin ,  Aleksey A. Tsarev ,  Andrey F. Asachenko ,  Alexander V. Babkin ,  Garth R. Giesbrecht ,  Jo Ann M. Canich

Inventor： Alexander Z. Voskoboynikov ,  Mikhail V. Nikulin ,  Aleksey A. Tsarev ,  Andrey F. Asachenko ,  Alexander V. Babkin ,  Garth R. Giesbrecht ,  Jo Ann M. Canich

IPC: C08F4/6592 ,  B01J31/22 ,  C07F17/00

CPC classification number: C07F17/00 ,  Y10S526/943

Abstract: This invention relates to transition metal compounds, catalyst systems comprising said compounds and polymerization processes using such catalyst systems, where the transition metal compound is represented by the formula: This invention also relates to process to produce such compounds.

Abstract translation: 本发明涉及过渡金属化合物，包含所述化合物的催化剂体系和使用这种催化剂体系的聚合方法，其中过渡金属化合物由下式表示：本发明还涉及制备这些化合物的方法。

公开(公告)号：US07868197B2

公开(公告)日：2011-01-11

申请号：US11300240

申请日：2005-12-14

Applicant: Alexander Z. Voskoboynikov ,  Alexey N. Ryabov ,  Mikhail V. Nikulin ,  Alexander V. Lygin ,  Dmitry V. Uborsky ,  Catalina L. Coker ,  Jo Ann M. Canich

Inventor： Alexander Z. Voskoboynikov ,  Alexey N. Ryabov ,  Mikhail V. Nikulin ,  Alexander V. Lygin ,  Dmitry V. Uborsky ,  Catalina L. Coker ,  Jo Ann M. Canich

IPC: C07F17/00 ,  C08F4/6192 ,  C08F4/6592 ,  B01J31/22

CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/65925 ,  C08F2420/02 ,  C08F2420/06 ,  Y10S526/943 ,  C08F4/65927 ,  C08F4/6592 ,  C08F110/06 ,  C08F2500/02 ,  C08F2500/03 ,  C08F210/16 ,  C08F210/14 ,  C08F110/02

Abstract: Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.

Abstract translation: 描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配体，其与金属原子π键合，并且包括至少一个与配体的可键合环位置上的sp2碳原子键合的卤素取代基，其中或 至少一个配体在其环状结构中具有一个或多个环杂原子。 当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

公开(公告)号：US07763562B2

公开(公告)日：2010-07-27

申请号：US11302998

申请日：2005-12-14

Applicant: Alexander Z. Voskoboynikov ,  Vyatcheslav V. Izmer ,  Andrey F. Asachenko ,  Mikhail V. Nikulin ,  Alexey N. Ryabov ,  Artyom Y. Lebedev ,  Catalina L. Coker ,  Jo Ann M. Canich

Inventor： Alexander Z. Voskoboynikov ,  Vyatcheslav V. Izmer ,  Andrey F. Asachenko ,  Mikhail V. Nikulin ,  Alexey N. Ryabov ,  Artyom Y. Lebedev ,  Catalina L. Coker ,  Jo Ann M. Canich

IPC: C08F4/64 ,  C08F4/6392 ,  C08F4/6592 ,  B01J31/22 ,  C07F17/00

CPC classification number: C07F17/00 ,  B01J31/2295 ,  B01J2231/12 ,  B01J2531/48 ,  C08F4/65912 ,  C08F10/06 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/06 ,  Y10S526/943 ,  C08F2500/03 ,  C08F210/14 ,  C08F2500/01 ,  C08F110/06 ,  C08F2500/20 ,  C08F210/06 ,  C08F10/00 ,  C08F4/65927

Abstract: This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.

Abstract translation: 本发明涉及由下式表示的过渡金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是：1）通过茚基环的4,5,6或7位与Y键合的取代或未取代的茚基配体，或2）通过四个，五个键连接到Y上的取代或未取代的杂茚基配体 或六位的杂茚基环，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个 六，七或八位的芴基环，或者4）取代或未取代的异芴基配体，其通过杂烯基环的一个，二个，三个，四个，五个或六个位置与Y键合，条件是键合位置 与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的15或16位桥连杂原子取代基; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。

公开(公告)号：US20100113717A1

公开(公告)日：2010-05-06

申请号：US12641123

申请日：2009-12-17

Applicant: Alexander Z. Voskoboynikov ,  Alexey N. Ryabov ,  Catalina L. Coker ,  Jo Ann M. Canich

Inventor： Alexander Z. Voskoboynikov ,  Alexey N. Ryabov ,  Catalina L. Coker ,  Jo Ann M. Canich

IPC: C08F4/16 ,  C07F17/00 ,  B01J31/12 ,  B01J31/14

CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65927 ,  C08F4/65925 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/01 ,  C08F2500/20 ,  C08F210/06

Abstract: A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.

Abstract translation: 制备取代的茂金属化合物的方法包括使第一化合物与转移剂反应，其中第一化合物包含选自元素周期表第3,4,5或6族的过渡金属原子的络合物，或 镧系元素金属原子或锕系金属原子和至少一个单键或多环配体，其与M键合并被至少一个卤素或磺酸盐取代基取代，并且转移剂包含烃基，取代的烃基，卤代烃基，取代的卤代烃基 ，甲硅烷基或甲锗烷基，其能够在反应条件下替代所述第一化合物的所述至少一个卤素或磺酸盐取代基。

公开(公告)号：US07709670B2

公开(公告)日：2010-05-04

申请号：US11302997

申请日：2005-12-14

Applicant: Alexander Z. Voskoboynikov ,  Alexey N. Ryabov ,  Catalina L. Coker ,  Jo Ann M. Canich

Inventor： Alexander Z. Voskoboynikov ,  Alexey N. Ryabov ,  Catalina L. Coker ,  Jo Ann M. Canich

IPC: C07F17/00 ,  C07F7/00

CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65927 ,  C08F4/65925 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/01 ,  C08F2500/20 ,  C08F210/06

Abstract: A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.

Abstract translation: 制备取代的茂金属化合物的方法包括使第一化合物与转移剂反应，其中第一化合物包含选自元素周期表第3,4,5或6族的过渡金属原子的络合物，或 镧系元素金属原子或锕系金属原子和至少一个单键或多环配体，其与M键合并被至少一个卤素或磺酸盐取代基取代，并且转移剂包含烃基，取代的烃基，卤代烃基，取代的卤代烃基 ，甲硅烷基或甲锗烷基，其能够在反应条件下替代所述第一化合物的所述至少一个卤素或磺酸盐取代基。

公开(公告)号：US20090239999A1

公开(公告)日：2009-09-24

申请号：US12480988

申请日：2009-06-09

Applicant: Jo Ann M. Canich ,  Peijun Jiang

Inventor： Jo Ann M. Canich ,  Peijun Jiang

IPC: C08L23/00 ,  C08F110/06

CPC classification number: C08F10/06 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/06 ,  Y10S526/943 ,  C08F4/65927 ,  C08F210/16 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/20

Abstract: This invention relates to a propylene polymer comprising a component having a crystallinity of 10% or less and a component having a crystallinity of 20% or more, said propylene polymer having: a) a melting point of X ° C. or more where X=−0.0038(Tp)2+0.36(Tp)+150, where Tp is the temperature of polymerization in ° C.; b) an Mw of 10,000 g/mol or more; c) a heat of fusion of from 1-70 J/g; d) Stereodefects per 10,000 monomer units of Y or less where Y=2.35(Tp)−100 (where Tp is the temperature of polymerization in ° C.) for the portion of the blend that is insoluble in hexane at 23° C.; e) a dot T-Peel on Kraft paper of 1 N or more; and f) a branching factor of 0.98 or less, where the branching factor is the ratio of g′ measured at Mz to g′ measured at Mw, and process to produce such polymers.

Abstract translation: 本发明涉及包含结晶度为10％以下的成分和结晶度为20％以上的成分的丙烯聚合物，所述丙烯类聚合物具有：a）熔点X℃以上，X = -0.0038（Tp）2 + 0.36（Tp）+150，其中Tp是以℃表示的聚合温度。 b）10,000g / mol以上的Mw; c）熔化热为1-70J / g; d）对于在23℃下不溶于己烷的共混物部分，每10,000单位单元的Y = 2.35（Tp）-100（其中Tp是聚合温度）的Y或更低的单位单位的立体缺陷度。 e）N型牛皮纸上的T型剥皮; 和f）0.98或更小的支化因子，其中支化因子是在Mw下测量的在Mz测量的g'与g'的比率，以及产生这种聚合物的方法。