摘要:
The invention concerns a process and unit for regenerating a catalyst for the production of aromatic compounds, in particular for reforming, the catalyst being in a moving bed, comprising combustion, oxychlorination and calcining steps, in which at least one chlorinating agent, at least one oxygen-containing gas, and water are introduced into the oxychlorination step such that the H2O/HCl molar ratio is 1 to 50, the oxychlorination step being carried out in the presence of an oxychlorination gas containing less than 21% of oxygen and at least 50 ppm by weight of chlorine (based on HCl), and at a temperature of 350-600° C., and in which the combustion step is carried out in at least two combustion zones, each zone being separated from the adjacent zones, and at least one gas charged with oxygen is introduced into each zone, the gases produced being extracted from each zone, and in which the severity of the operating conditions increases in the direction of flow of the catalyst.
摘要翻译:本发明涉及用于再生催化剂的方法和单元,所述催化剂用于生产芳族化合物,特别是重整催化剂在移动床中,包括燃烧,氧氯化和煅烧步骤,其中至少一种氯化剂,至少一种 将含氧气体和水引入到氧氯化步骤中,使得H 2 O / HCl摩尔比为1至50,氧氯化步骤在含有小于21%氧气和至少50%的氧氯化气体存在下进行 ppm(基于HCl),并且在350-600℃的温度下,并且其中燃烧步骤在至少两个燃烧区域中进行,每个区域与相邻区域分离,并且在 将至少一个带有氧气的气体引入每个区域,所产生的气体从每个区域提取,并且其中操作条件的严重性在催化剂流动方向上增加。
摘要:
A vessel for regenerating a catalyst for reforming or for aromatic compound production comprising a support, at least one noble metal and chlorine, the catalyst being in the form of a moving bed, said vessel comprising at least one combustion zone (A) provided with at least one conduit (9) for introducing oxygen gas and at least one conduit (5) for evacuating gasses from the combustion step, at least one oxychlorination zone (B) and at least one calcining zone (C) provided with at least one conduit (18) for introducing an oxygen-containing gas, said vessel also comprising at least one conduit (1) for introducing catalyst into the vessel, at least one conduit (3) for introducing catalyst from the combustion zone into the following oxychlorination zone (B), and at least one conduit (21) for evacuating gases from the oxychlorination zone comprising at least one means (20) for introducing least one chlorinating agent and at least one means (19) for introducing water and at least one means (17) for introducing an oxygen containing gas.
摘要:
The invention concerns a process for regenerating a catalyst for the production of aromatic compounds, in particular for reforming, comprising combustion (A), oxychlorination (B) and calcining (C) steps, in which at least one chlorinating agent (conduit 19), at least one oxygen-containing gas (conduit 18), and water (conduit 20) are introduced into the oxychlorination step such that the H.sub.2 O/HCl molar ratio is 3 to 50, the oxychlorination step being carried out in the presence of an oxychlorination gas containing less than 21% of oxygen and at least 50 ppm by weight of chlorine (based on HCl), and at a temperature of 350-600.degree. C.
摘要翻译:本发明涉及用于再生用于生产芳族化合物,特别是用于重整的催化剂的方法,其包括燃烧(A),氧氯化(B)和煅烧(C)步骤,其中至少一种氯化剂(导管19) 将至少一种含氧气体(导管18)和水(导管20)引入氧氯化步骤,使得H 2 O / HCl摩尔比为3至50,氧氯化步骤在氧氯化气体存在下进行 含有少于21%的氧和至少50重量ppm的氯(基于HCl),并且在350-600℃的温度下
摘要:
The invention concerns a process and unit for regenerating a catalyst for the production of aromatic compounds, in particular for reforming, the catalyst being in a moving bed, comprising combustion, oxychlorination and calcining steps, in which at least one chlorinating agent, at least one oxygen-containing gas, and water are introduced into the oxychlorination step such that the H.sub.2 O/HCl molar ratio is 1 to 50, the oxychlorination step being carried out in the presence of an oxychlorination gas containing less than 21% of oxygen and at least 50 ppm by weight of chlorine (based on HCl), and at a temperature of 350-600.degree. C., and in which the combustion step is carried out in at least two combustion zones, each zone being separated from the adjacent zones, and at least one gas charged with oxygen is introduced into each zone, the gases produced being extracted from each zone, and in which the severity of the operating conditions increases in the direction of flow of the catalyst.
摘要翻译:本发明涉及用于再生催化剂的方法和单元,所述催化剂用于生产芳族化合物,特别是重整催化剂在移动床中,包括燃烧,氧氯化和煅烧步骤,其中至少一种氯化剂,至少一种 将含氧气体和水引入到氧氯化步骤中,使得H 2 O / HCl摩尔比为1至50,氧氯化步骤在含有小于21%氧气和至少50%的氧氯化气体存在下进行 氯化氢(基于HCl),并且在350-600℃的温度下,并且其中燃烧步骤在至少两个燃烧区域中进行,每个区域与相邻区域分离,并且在 将至少一个带有氧气的气体引入每个区域,所产生的气体从每个区域提取,并且其中操作条件的严重性在催化剂流动方向上增加。
摘要:
The invention concerns a process for isomerising a feed containing essentially hydrocarbons, preferably paraffins containing principally 4 to 8, preferably princiapply to 6 and more principally 5 and/or 6 carbon atoms per molecule, comprising a fractionation zone and at least two isomersation reaction zones, said process comprising carrying out the following steps:(1) sending the feed to a fractionation zone;(2) drawing off at least a portion of the liquid circulating in said zone, via at least two draw-off levels; and(3) sending the major portion of the liquid drawn off in step (2) to at least two isomerisation zones, each isomerisation zone being associated with a draw-off level.
摘要:
The invention concerns a process for isomerising a feed containing essentially hydrocarbons, preferably paraffins preferably containing 5 and/or 6 carbon atoms per molecule, in which said feed is treated in a distillation zone comprising an exhausting zone and a rectification zone associated with an isomerisation reaction zone, in the presence of an isomerisation catalyst and a gas stream containing hydrogen, characterized in that the reaction zone is at least partially internal to the distillation zone, and wherein the hydrogen-containing gas is fed by a dedicated gas distributor to the bottom of at least one catalytic bed within the isomerization reaction zone.
摘要:
The invention concerns a process for isomerizing a feed containing essentially hydrocarbons, preferably paraffins containing principally 4 to 8, preferably principally 4 to 6 and more preferably principally 5 and/or 6 carbon atoms per molecule, comprising a fractionation zone and at least two isomerization reaction zones, said process comprising carrying out the following steps: (1) sending the feed to a fractionation zone; (2) drawing off at least a portion of the liquid circulating in said zone, via at least two draw-off levels; (3) sending the major portion of the liquid drawn off in step (2) to at least two isomerization zones, each isomerization zone being associated with a draw-off level; (4) sending the major portion of the effluents from step (3) to the fractionation zone, substantially adjacent to the draw-off levels; (5) recovering an effluent from the fractionation zone.