公开(公告)号：US07902323B1

公开(公告)日：2011-03-08

申请号：US09346353

申请日：1999-07-02

申请人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

发明人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

IPC分类号： C08J3/11 ,  C08J3/18 ,  C08G73/00 ,  H01B1/12

CPC分类号： H01B1/128 ,  C08G61/12

摘要： Methods of forming materials containing precursors to electrically conductive polymers and electrically conductive polymers are described which have a high degree of crystallinity. The high degree of crystallinity is achieved by preparing the materials under conditions which provide a high degree of mobility to the polymer molecules permitting them to associate with one another to form a crystalline state. High levels of electrical conductivity are achieved in in the electrically conductive materials without stretch orienting the material. The enhanced electrical conductivity is isotropic as compared to a stretch oriented film which has isotropic electrical conductivity. In the preferred embodiment, additives are added to a solution containing a solvent and the precursor or electrically conductive polymer. The additives are preferably plasticizer of diluents. As the solvent is removed the material dries and contains a higher degree of crystallinity than in the absence of the additive.

摘要翻译： 描述了形成具有高结晶度的导电聚合物和导电聚合物前体的材料的方法。 通过在允许它们彼此结合以形成结晶状态的聚合物分子提供高度迁移率的条件下制备材料来实现高结晶度。 在导电材料中实现高水平的导电性而不使材料拉伸定向。 与具有各向同性电导率的拉伸取向膜相比，增强的导电性是各向同性的。 在优选的实施方案中，将添加剂加入到含有溶剂和前体或导电聚合物的溶液中。 添加剂优选稀释剂的增塑剂。 当除去溶剂时，与没有添加剂相比，材料干燥并含有更高的结晶度。

公开(公告)号：US06210606B1

公开(公告)日：2001-04-03

申请号：US09268527

申请日：1999-03-12

申请人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

发明人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

IPC分类号： H01B112

CPC分类号： C08G61/12 ,  H01B1/128 ,  Y10T428/249958

摘要： Polycrystalline materials containing crystallites of precursors to electrically conductive polymers and electrically conductive polymers are described which have an adjustable high degree of crystallinity. The intersticial regions between the crystallites contains amorphous material containing precursors to electrically conductive polymers and/or electrically conductive polymers. The degree of crystallinity is achieved by preparing the materials under conditions which provide a high degree of mobility to the polymer molecules permitting them to associate with one another to form a crystalline state. This is preferable achieved by including additives, such as plasticizers and diluents, to the solution from which the polycrystalline material is formed. The morphology of the polycrystalline material is adjustable to modify the properties of the material such as the degree of crystallinity, crystal grain size, glass transition temperature, thermal coefficient of expansion and degree of electrical conductivity. High levels of electrical conductivity are achieved in the electrically conductive polycrystalline materials without stretch orienting the material. The enhanced electrical conductivity is isotropic as compared to a stretch oriented film which has isotropic electrical conductivity.

摘要翻译： 描述了具有可调高结晶度的导电聚合物和导电聚合物的前体微晶的多晶材料。 微晶之间的区域包含含有导电聚合物和/或导电聚合物的前体的无定形材料。 通过在允许它们彼此结合以形成结晶状态的聚合物分子提供高度迁移率的条件下制备材料来实现结晶度。 优选通过将诸如增塑剂和稀释剂的添加剂添加到形成多晶材料的溶液中来实现。 可以调节多晶材料的形态，以改变材料的性质，例如结晶度，晶粒尺寸，玻璃化转变温度，热膨胀系数和电导率。 在导电多晶材料中实现高水平的导电性而不使材料拉伸取向。 与具有各向同性电导率的拉伸取向膜相比，增强的导电性是各向同性的。

公开(公告)号：US06241913B1

公开(公告)日：2001-06-05

申请号：US08722283

申请日：1996-09-27

申请人： Marie Angelopoulos ,  Yun-Hsin Liao

发明人： Marie Angelopoulos ,  Yun-Hsin Liao

IPC分类号： H01B112

CPC分类号： C08G73/1071 ,  C08G2261/312 ,  C08L101/12 ,  H01B1/128

摘要： The present invention is directed to a polymer selected from a precursor to an electrically conductive polymer and an electrically conductive polymer. The polymer has a branched structure. The polymer is formed from polymerization of momomers of which at least one monomer has more than one polymerizable site. One of the polymerizable monomers or units can have structural formula X—(M)n where X is a base element of the unit, M is the polymerization functional site, n is the number of M sites; and n>1. The polymer can be formed from more than one polymerization unit having different base elements, polymerization functional units and different values of n.

摘要翻译： 本发明涉及一种选自导电聚合物的前体和导电聚合物的聚合物。 聚合物具有支链结构。 聚合物由其中至少一个单体具有多于一个可聚合位点的单体的聚合形成。 可聚合单体或单元之一可以具有结构式X-（M）n，其中X是单元的基础元素，M是聚合官能位点，n是M位点的数目; 而n> 1。 聚合物可由多于一个具有不同碱基元素，聚合官能单元和不同n值的聚合单元形成。

公开(公告)号：US5928566A

公开(公告)日：1999-07-27

申请号：US620619

申请日：1996-03-22

申请人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

发明人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

IPC分类号： C08K5/10 ,  C08G61/12 ,  C08K5/09 ,  C08K5/103 ,  C08K5/28 ,  C08K5/42 ,  C08K5/5419 ,  C08L71/02 ,  C08L79/00 ,  C08L83/04 ,  C08L101/00 ,  H01B1/12

CPC分类号： C08G61/12 ,  H01B1/128

摘要： Materials containing precursors to electrically conductive polymers and electrically conductive polymers are described which have a high degree of crystallinity. The high degree of crystallinity is achieved by preparing the materials under conditions which provide a high degree of mobility to the polymer molecules permitting them to associate with one another to form a crystalline state. High levels of electrical conductivity are achieved in in the electrically conductive materials without stretch orienting the material. The enhanced electrical conductivity is isotropic as compared to a stretch oriented film which has isotropic electrical conductivity.

摘要翻译： 描述了具有高结晶度的导电聚合物和导电聚合物的前体的材料。 通过在允许它们彼此结合以形成结晶状态的聚合物分子提供高度迁移率的条件下制备材料来实现高结晶度。 在导电材料中实现高水平的导电性而不使材料拉伸定向。 与具有各向同性电导率的拉伸取向膜相比，增强的导电性是各向同性的。

公开(公告)号：US08198396B2

公开(公告)日：2012-06-12

申请号：US12583030

申请日：2009-08-12

申请人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

发明人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

IPC分类号： C08G73/00 ,  C08G73/20 ,  H01B1/12 ,  C08F6/10

CPC分类号： H01B1/128

摘要： Methods of forming materials containing precursors to electrically conductive polymers and electrically conductive polymers are described which have a high degree of crystallinity. The high degree of crystallinity is achieved by preparing the materials under conditions which provide a high degree of mobility to the polymer molecules permitting them to associate with one another to form a crystalline state. High levels of electrical conductivity are achieved in in the electrically conductive materials without stretch orienting the material. The enhanced electrical conductivity is isotropic as compared to a stretch oriented film which has isotropic electrical conductivity. In the preferred embodiment, additives are added to a solution containing a solvent and the precursor or electrically conductive polymer. The additives are preferably plasticizer of diluents. As the solvent is removed the material dries and contains a higher degree of crystallinity than in the absence of the additive.

摘要翻译： 描述了形成具有高结晶度的导电聚合物和导电聚合物前体的材料的方法。 通过在允许它们彼此结合以形成结晶状态的聚合物分子提供高度迁移率的条件下制备材料来实现高结晶度。 在导电材料中实现高水平的导电性而不使材料拉伸定向。 与具有各向同性电导率的拉伸取向膜相比，增强的导电性是各向同性的。 在优选的实施方案中，将添加剂加入到含有溶剂和前体或导电聚合物的溶液中。 添加剂优选稀释剂的增塑剂。 当除去溶剂时，与不存在添加剂相比，材料干燥并含有更高的结晶度。

公开(公告)号：US5969024A

公开(公告)日：1999-10-19

申请号：US620631

申请日：1996-03-22

申请人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

发明人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

IPC分类号： C08G61/12 ,  H01B1/12 ,  C08K5/54 ,  C08G73/00

CPC分类号： H01B1/128 ,  C08G61/12

摘要： Methods of forming materials containing precursors to electrically conductive polymers and electrically conductive polymers are described which have a high degree of crystallinity. The high degree of crystallinity is achieved by preparing the materials under conditions which provide a high degree of mobility to the polymer molecules permitting them to associate with one another to form a crystalline state. High levels of electrical conductivity are achieved in in the electrically conductive materials without stretch orienting the material. The enhanced electrical conductivity is isotropic as compared to a stretch oriented film which has isotropic electrical conductivity. In the preferred embodiment, additives are added to a solution containing a solvent and the precursor or electrically conductive polymer. The additives are preferably plasticizer of diluents. As the solvent is removed the material dries and contains a higher degree of crystallinity than in the absence of the additive.

公开(公告)号：US20090304908A1

公开(公告)日：2009-12-10

申请号：US12583030

申请日：2009-08-12

申请人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

发明人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

IPC分类号： B05D5/12 ,  H01B1/12

CPC分类号： H01B1/128

摘要： Methods of forming materials containing precursors to electrically conductive polymers and electrically conductive polymers are described which have a high degree of crystallinity. The high degree of crystallinity is achieved by preparing the materials under conditions which provide a high degree of mobility to the polymer molecules permitting them to associate with one another to form a crystalline state. High levels of electrical conductivity are achieved in in the electrically conductive materials without stretch orienting the material. The enhanced electrical conductivity is isotropic as compared to a stretch oriented film which has isotropic electrical conductivity. In the preferred embodiment, additives are added to a solution containing a solvent and the precursor or electrically conductive polymer. The additives are preferably plasticizer of diluents. As the solvent is removed the material dries and contains a higher degree of crystallinity than in the absence of the additive.

摘要翻译： 描述了形成具有高结晶度的导电聚合物和导电聚合物前体的材料的方法。 通过在允许它们彼此结合以形成结晶状态的聚合物分子提供高度迁移率的条件下制备材料来实现高结晶度。 在导电材料中实现高水平的导电性而不使材料拉伸定向。 与具有各向同性电导率的拉伸取向膜相比，增强的导电性是各向同性的。 在优选的实施方案中，将添加剂加入到含有溶剂和前体或导电聚合物的溶液中。 添加剂优选稀释剂的增塑剂。 当除去溶剂时，与没有添加剂相比，材料干燥并含有更高的结晶度。

公开(公告)号：US20090032775A1

公开(公告)日：2009-02-05

申请号：US12137646

申请日：2008-06-12

申请人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

发明人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

IPC分类号： H01B1/12 ,  C08K5/09 ,  C08K5/10 ,  C08K5/5317

CPC分类号： C08G61/12 ,  H01B1/128 ,  Y10T428/249958

摘要： Polycrystalline materials containing crystallies of precursors to electrically conductive polymers and electrically conductive polymers are described which have an adjustable high degree of crystallinity. The intersticial regions between the crystallites contains amorphous material containing precursors to electrically conductive polymers and/or electrically conductive polymers. The degree of crystallinity is achieved by preparing the materials under conditions which provide a high degree of mobility to the polymer molecules permitting them to associate with one another to form a crystalline state. This is preferable achieved by including additives, such as plasticizers and diluents, to the solution from which the polycrystalline material is formed. The morphology of the polycrystalline material is adjustable to modify the properties of the material such as the degree of crystallinity, crystal grain size, glass transition temperature, thermal coefficient of expansion and degree of electrical conductivity. High levels of electrical conductivity are achieved in in the electrically conductive polycrystalline materials without stretch orienting the material. The enhanced electrical conductivity is isotropic as compared to a stretch oriented film which has isotropic electrical conductivity.

摘要翻译： 描述了具有可调节高结晶度的导电聚合物和导电聚合物的前体结晶的多晶材料。 微晶之间的区域包含含有导电聚合物和/或导电聚合物的前体的无定形材料。 通过在允许它们彼此结合以形成结晶状态的聚合物分子提供高度迁移率的条件下制备材料来实现结晶度。 优选通过将诸如增塑剂和稀释剂的添加剂添加到形成多晶材料的溶液中来实现。 可以调节多晶材料的形态，以改变材料的性质，例如结晶度，晶粒尺寸，玻璃化转变温度，热膨胀系数和电导率。 在导电多晶材料中实现高水平的导电性，而不拉伸定向该材料。 与具有各向同性电导率的拉伸取向膜相比，增强的导电性是各向同性的。

公开(公告)号：US06967236B1

公开(公告)日：2005-11-22

申请号：US09036458

申请日：1998-03-06

申请人： Marie Angelopoulos ,  Yun-Hsin Liao

发明人： Marie Angelopoulos ,  Yun-Hsin Liao

IPC分类号： C08F6/00 ,  C08J3/00 ,  H01B1/00 ,  H01B1/12

CPC分类号： H01B1/128 ,  C08J3/093 ,  C08J2300/12 ,  C08J2379/02

摘要： The present invention is directed to methods of solvating electrically conducting polymers and electrically conducting polymers by processing these materials in selected solvents comprising at least one of the solvents being a fluorinated solvent. High solubility and conductivity in the hundreds of S/cm are achieved by these methods. Excellent coatings are attained. These materials have application in EMI shielding, electrodes for displays, contacts for devices, ESD protection, corrosion protection and resists.

摘要翻译： 本发明涉及通过在选择的溶剂中处理这些材料来溶剂化导电聚合物和导电聚合物的方法，所述溶剂包括至少一种溶剂为氟化溶剂。 通过这些方法可实现数百S / cm的高溶解度和导电性。 获得优异的涂层。 这些材料适用于EMI屏蔽，显示器用电极，器件触点，ESD保护，防腐蚀和抗蚀剂。

公开(公告)号：US06616863B1

公开(公告)日：2003-09-09

申请号：US09208528

申请日：1998-12-09

申请人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

发明人： Marie Angelopoulos ,  Yun-Hsin Liao ,  Ravi F. Saraf

IPC分类号： H01B112

CPC分类号： C08G61/12 ,  H01B1/128

摘要： Materials containing precursors to electrically conductive polymers and electrically conductive polymers are described which have a high degree of crystallinity. The high degree of crystallinity is achieved by preparing the materials under conditions which provide a high degree of mobility to the polymer molecules permitting them to associate with one another to form a crystalline state. High levels of electrical conductivity are achieved in the electrically conductive materials without stretch orienting the material. The enhanced electrical conductivity is isotropic as compared to a stretch oriental film which has isotropic electrical conductivity.

摘要翻译： 描述了具有高结晶度的导电聚合物和导电聚合物的前体的材料。 通过在允许它们彼此结合以形成结晶状态的聚合物分子提供高度迁移率的条件下制备材料来实现高结晶度。 在导电材料中实现高水平的导电性而不使材料拉伸取向。 与具有各向同性电导率的拉伸东方薄膜相比，增强的导电性是各向同性的。