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142 条记录 (耗时 0.025 秒)

    Process for the separation of unbranched hydrocarbons from their branched isomers
    6.
    发明授权
    Process for the separation of unbranched hydrocarbons from their branched isomers 失效
    从支链异构体中分离未分支烃的方法

    公开(公告)号：US08658849B2

    公开(公告)日：2014-02-25

    申请号：US12668436

    申请日：2008-06-30

    申请人： Markus Schubert ,  Ulrich Mueller ,  Christoph Kiener ,  Ingo Richter ,  William Dolan ,  Frank Poplow

    发明人： Markus Schubert ,  Ulrich Mueller ,  Christoph Kiener ,  Ingo Richter ,  William Dolan ,  Frank Poplow

    IPC分类号： C07C7/13

    CPC分类号： C07C7/12 ,  B01J20/22 ,  B01J20/226 ,  B01J2220/56 ,  C07C7/135 ,  C10G25/003 ,  C07C9/00

    摘要： The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of—contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.

    摘要翻译： 本发明涉及从含有非支链烃和非支链烃的至少一种支链异构体的流体混合物中分离至少一种未分支的C 4 -C 20烃的方法，其包括使流体混合物与 吸附剂，其包含多孔金属有机骨架材料，该材料包含与至少一种金属离子配位结合的至少一种至少二齿有机化合物，以获得非支化烃被吸附，其中至少一种至少二齿有机化合物是单环， 衍生自选自吡咯，α-吡啶酮和γ-吡啶酮的至少一种杂环的双环或多环系统，并且具有至少两个环氮并且是未取代的或带有一个或多个独立地选自以下的取代基： 的卤素，C 1-6 - 烷基，苯基，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，苯基和OC 1-6 - 烷基 ，其中取代基C 1-6 - 烷基和苯基是未取代的或具有一个或多个独立地选自卤素，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH， 和OC 1-6烷基。 本发明还涉及所述多孔金属 - 有机骨架材料在从其支化异构体中分离未分支烃的方法中的用途。

    Process for preparing porous organic framework materials
    9.
    发明授权
    Process for preparing porous organic framework materials 有权
    制备多孔有机骨架材料的方法

    公开(公告)号：US07847115B2

    公开(公告)日：2010-12-07

    申请号：US12161024

    申请日：2007-02-08

    申请人： Markus Schubert ,  Ulrich Mueller ,  Hendrick Mattenheimer

    发明人： Markus Schubert ,  Ulrich Mueller ,  Hendrick Mattenheimer

    IPC分类号： C07F3/00 ,  C07F15/00 ,  C07F5/02

    CPC分类号： C07F3/003 ,  C07F19/005

    摘要： The present invention relates to a process for preparing porous organic frameworks by reaction of a reaction mixture in a liquid phase comprising the appropriate starting compounds in the presence of a nonaqueous organic solvent in the presence of and/or with liberation of water, wherein the latter is withdrawn from the liquid phase of the reaction mixture during the reaction. Here, frameworks having relatively high specific surface areas can be obtained in a reproducible way.

    摘要翻译： 本发明涉及一种制备多孔有机骨架的方法，该方法通过在非水有机溶剂存在下和/或与水的释放下在包含合适的起始化合物的液相中反应混合物进行反应，其中后者 在反应期间从反应混合物的液相中排出。 这里，可以以可再现的方式获得比表面积相对较高的框架。

    ALUMINIUM AMINOCAROBXYLATES AS POROUS METAL ORGANIC FRAMEWORKS
    10.
    发明申请
    ALUMINIUM AMINOCAROBXYLATES AS POROUS METAL ORGANIC FRAMEWORKS 失效
    作为多孔金属有机骨架的氨基铝酸铵

    公开(公告)号：US20100154635A1

    公开(公告)日：2010-06-24

    申请号：US12601022

    申请日：2008-05-20

    申请人： Markus Schubert ,  Ulrich Mueller ,  Christoph Kiener

    发明人： Markus Schubert ,  Ulrich Mueller ,  Christoph Kiener

    IPC分类号： B01D53/02 ,  C07F5/06

    CPC分类号： B01D53/02 ,  B01D2253/204 ,  B01D2253/306 ,  B01D2257/108 ,  B01D2257/504 ,  B01D2257/702 ,  B01D2259/4525 ,  B01J20/226 ,  B01J20/28042 ,  B01J20/28066 ,  B01J20/30 ,  B01J31/1691 ,  B01J31/1805 ,  B01J31/2226 ,  B01J2531/31 ,  C07F5/069 ,  F17C11/00 ,  F17C11/005 ,  Y02C10/08 ,  Y02P20/152

    摘要： The present invention relates to a porous metal organic framework comprising an at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is AlIII and the at least bidentate organic compound is an at least monoamino-substituted aromatic dicarboxylic acid selected from the group consisting of terephthalic acid, 2,6-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid, 1,5-naphthalenedicarboxylic acid and derivatives thereof in which at least one CH group in the ring has been replaced by nitrogen, wherein the framework in powder form has a specific surface area determined by the Langmuir method (N2, 77 K) of at least 2500 m2/g.In addition, the invention relates to shaped bodies comprising these materials, their preparation and their use for the storage and separation of gases.

    摘要翻译： 本发明涉及一种多孔金属有机骨架，其包含与至少一种金属离子配位的至少二齿有机化合物，其中至少一种金属离子是AlIII，并且该至少二齿有机化合物是至少一个氨基取代的芳族二羧酸 选自对苯二甲酸，2,6-萘二甲酸，1,4-萘二甲酸，1,5-萘二甲酸及其衍生物的酸，其中环中的至少一个CH基团已被氮取代，其中 粉末形式的框架具有由Langmuir方法（N2，77K）确定的至少2500m2 / g的比表面积。 此外，本发明涉及包含这些材料的成型体，它们的制备及其用于储存和分离气体的用途。