公开(公告)号：US4678768A

公开(公告)日：1987-07-07

申请号：US747618

申请日：1985-06-21

申请人： Masahito Fujita ,  Makoto Miyazaki ,  Masami Kizaki ,  Yukio Nagashima ,  Yuichi Shimbori

发明人： Masahito Fujita ,  Makoto Miyazaki ,  Masami Kizaki ,  Yukio Nagashima ,  Yuichi Shimbori

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F4/658 ,  C08F10/00

CPC分类号： C08F10/00

摘要： A catalyst component for polymerization of olefins which is prepared by contacting a product obtained by contacting (A) a magnesium alkoxide, (B) a silicon compound having the hydrogen-silicon bond, and (C) a titanium compound with one another, with (D) (a) a hydrocarbon, (b) a halogenated hydrocarbon, and/or (c) a halide of an element selected from the elements of Groups IIIa, IVa, and Va of the Periodic Table.

摘要翻译： 一种用于烯烃聚合的催化剂组分，其通过使（A）烷氧化镁，（B）具有氢 - 硅键的硅化合物和（C）钛化合物）与（A） D）（a）烃，（b）卤代烃，和/或（c）选自元素周期表Ⅲa，IVa和Va族元素的元素的卤化物。

公开(公告)号：US4634687A

公开(公告)日：1987-01-06

申请号：US811556

申请日：1985-12-19

申请人： Masahito Fujita ,  Masami Kizaki ,  Makoto Miyazaki ,  Naomi Inaba

发明人： Masahito Fujita ,  Masami Kizaki ,  Makoto Miyazaki ,  Naomi Inaba

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00

CPC分类号： C08F10/00

摘要： A cocatalyst employed with a titanium-containing catalyst, said titanium-containing catalyst comprising titanium atoms, halogen atoms, and an electron donor compound, said cocatalyst comprising(a) an organoaluminum compound represented by the formula R.sup.1 R.sup.2 R.sup.3 (wherein R.sup.1, R.sup.2, and R.sup.3 which may be the same or different, each denote a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group, or a hydrogen atom;(b) an organoaluminum compound represented by the formula R.sub.3-n.sup.4 AlX.sub.n (wherein R.sup.4 denotes a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group; X denotes a halogen atom; and n.gtoreq.1),(c) an electron donor compound containing a nitrogen atom, sulfur atom, oxygen atom, or phosphorus atom, and(d) an aromatic carboxylic acid ester.The catalyst is useful for the polymerization of olefins.

摘要翻译： 一种与含钛催化剂一起使用的助催化剂，所述含钛催化剂包含钛原子，卤素原子和电子给体化合物，所述助催化剂包括（a）由式R 1 R 2 R 3表示的有机铝化合物（其中R1，R2和R3 + L可以相同或不同，各自表示C1-20烷基，烯基，环烷基，芳基，芳烷基或烷氧基或氢原子;（b）由式R3-n4AlXn（式 其中R4表示C1-20烷基，烯基，环烷基，芳基，芳烷基或烷氧基; X表示卤素原子; n表示1），（c）含有氮原子，硫原子， 氧原子或磷原子，和（d）芳族羧酸酯，该催化剂可用于烯烃的聚合。

公开(公告)号：US4716206A

公开(公告)日：1987-12-29

申请号：US927551

申请日：1986-11-05

申请人： Masahito Fujita ,  Masami Kizaki ,  Makoto Miyazaki ,  Naomi Inaba

发明人： Masahito Fujita ,  Masami Kizaki ,  Makoto Miyazaki ,  Naomi Inaba

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00

CPC分类号： C08F10/00

摘要： A process for homopolymerizing an olefin or copolymerizing an olefin with another olefin in the presence of a catalyst composed of(a) a solid catalyst component containing magnesium atoms, titanium atoms, halogen atoms, and an electron donor compound,(b) an organoaluminum compound represented by the formula R.sup.1 R.sup.2 R.sup.3 Al (wherein R.sup.1, R.sup.2, and R.sup.3, which may be the same or different, each denote a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group, or a hydrogen atom;(c) an organoaluminum compound represented by the formula R.sup.4.sub.3-n AlX.sub.n (wherein R.sup.4 denotes a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group; X denotes a halogen atom; and n.gtoreq.1),(d) an electron donor compound containing a nitrogen atom, sulfur atom, oxygen atom, or phosphorus atom, and(e) an aromatic ester compound.

公开(公告)号：US6083860A

公开(公告)日：2000-07-04

申请号：US5925

申请日：1998-01-12

申请人： Hideki Matsuo ,  Masahiro Kokubo ,  Takashi Ohbayashi ,  Yuji Tashiro ,  Tadashi Suzuki ,  Masami Kizaki ,  Haruo Hashimoto ,  Yasuo Shimizu ,  Takaaki Sakurai ,  Hiroyuki Aoki

发明人： Hideki Matsuo ,  Masahiro Kokubo ,  Takashi Ohbayashi ,  Yuji Tashiro ,  Tadashi Suzuki ,  Masami Kizaki ,  Haruo Hashimoto ,  Yasuo Shimizu ,  Takaaki Sakurai ,  Hiroyuki Aoki

IPC分类号： C03C17/00 ,  C03C17/22 ,  C03C17/30 ,  C04B35/589 ,  C04B41/45 ,  C08G77/62 ,  C23C26/00 ,  C04B35/56

CPC分类号： C04B41/009 ,  C03C17/007 ,  C03C17/225 ,  C03C17/30 ,  C04B35/589 ,  C04B41/4554 ,  C08G77/62 ,  C23C26/00 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/479

摘要： A method for forming dense ceramics, particularly a ceramic coating by a low temperature treatment is provided. The method for forming ceramics according to the invention is characterized in that a polysilazane having a number-average molecular weight of 100 to 50,000 or a modified polysilazane thereof is subjected to a heat treatment, then exposed to an atmosphere containing water vapor or immersed in distilled water containing a catalyst, or both, or is brought into contact with Pd.sup.2+ ions and water, the polysilazane having a skeleton comprising the unit represented by the following general formula (I): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 each independently represents a hydrogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, a group other than the above and having a carbon atom directly attached to the silicon atom, an alkylsilyl group, an alkylamino group and an alkoxy group; with the proviso that at least one of R.sup.1, R.sup.2 and R.sup.3 is a hydrogen atom. A method wherein said modified polysilazane is only fired at a temperature of 400.degree. C. or below is also provided.

摘要翻译： 提供了通过低温处理形成致密陶瓷，特别是陶瓷涂层的方法。 根据本发明的陶瓷形成方法的特征在于将数均分子量为100〜50,000的聚硅氮烷或其改性聚硅氮烷进行热处理，然后暴露于含有水蒸气的气氛或浸渍在蒸馏水中 含有催化剂的水或两者，或者与Pd 2+离子和水接触，所述聚硅氮烷具有包含由以下通式（I）表示的单元的骨架：其中R1，R2和R3各自独立地表示氢原子， 烷基，烯基，环烷基，芳基，除上述以外的基团，并且具有与硅原子直接连接的碳原子，烷基甲硅烷基，烷基氨基和烷氧基; 条件是R 1，R 2和R 3中的至少一个是氢原子。 其中所述改性聚硅氮烷仅在400℃或更低的温度下烧制的方法。

公开(公告)号：US5747623A

公开(公告)日：1998-05-05

申请号：US543157

申请日：1995-10-13

申请人： Hideki Matsuo ,  Masahiro Kokubo ,  Takashi Ohbayashi ,  Yuji Tashiro ,  Tadashi Suzuki ,  Masami Kizaki ,  Haruo Hashimoto ,  Yasuo Shimizu ,  Takaaki Sakurai ,  Hiroyuki Aoki

发明人： Hideki Matsuo ,  Masahiro Kokubo ,  Takashi Ohbayashi ,  Yuji Tashiro ,  Tadashi Suzuki ,  Masami Kizaki ,  Haruo Hashimoto ,  Yasuo Shimizu ,  Takaaki Sakurai ,  Hiroyuki Aoki

IPC分类号： C03C17/00 ,  C03C17/22 ,  C03C17/30 ,  C04B35/589 ,  C04B41/45 ,  C08G77/62 ,  C23C26/00 ,  C04B35/58

CPC分类号： C04B41/009 ,  C03C17/007 ,  C03C17/225 ,  C03C17/30 ,  C04B35/589 ,  C04B41/4554 ,  C08G77/62 ,  C23C26/00 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/479

摘要： A method for forming dense ceramics, particularly a ceramic coating by a low temperature treatment is provided. The method for forming ceramics according to the invention is characterized in that a polysilazane having a number-average molecular weight of 100 to 50,000 or a modified polysilazane thereof is subjected to a heat treatment, then exposed to an atmosphere containing water vapor or immersed in distilled water containing a catalyst, or both, or is brought into contact with Pd.sup.2+ ions and water, the polysilazane having a skeleton comprising the unit represented by the following general formula (I): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 each independently represents a hydrogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, a group other than the above and having a carbon atom directly attached to the silicon atom, an alkylsilyl group, an alkylamino group and an alkoxy group; with the proviso that at least one of R.sub.1, R.sup.2 and R.sup.3 is a hydrogen atom. A method wherein said modified polysilazane is only fired at a temperature of 400.degree. C. or below is also provided.

摘要翻译： 提供了通过低温处理形成致密陶瓷，特别是陶瓷涂层的方法。 根据本发明的陶瓷形成方法的特征在于将数均分子量为100〜50,000的聚硅氮烷或其改性聚硅氮烷进行热处理，然后暴露于含有水蒸气的气氛或浸渍在蒸馏水中 含有催化剂的水或两者，或者与Pd 2+离子和水接触，所述聚硅氮烷具有包含由以下通式（I）表示的单元的骨架：其中R 1，R 2和R 3各自 独立地表示氢原子，烷基，烯基，环烷基，芳基，除上述以外的具有直接与硅原子连接的碳原子的基团，烷基甲硅烷基，烷基氨基和烷氧基 组; 条件是R 1，R 2和R 3中的至少一个是氢原子。 其中所述改性聚硅氮烷仅在400℃或更低的温度下烧制的方法。