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    Crystalline polymer of higher α-olefin and process for producing the same
    2.
    发明授权
    Crystalline polymer of higher α-olefin and process for producing the same 有权
    高级α-烯烃的结晶聚合物及其制备方法

    公开(公告)号：US07214755B2

    公开(公告)日：2007-05-08

    申请号：US10505046

    申请日：2003-02-19

    申请人： Yutaka Minami ,  Masami Kanamaru ,  Masanori Sera ,  Tatsuya Egawa ,  Takenori Fujimura

    发明人： Yutaka Minami ,  Masami Kanamaru ,  Masanori Sera ,  Tatsuya Egawa ,  Takenori Fujimura

    IPC分类号： C08F110/14 ,  C08F210/14 ,  C08F4/6192

    CPC分类号： C08F110/14 ,  C08F10/00 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/18 ,  C08F2500/15

    摘要： A crystalline higher α-olefin polymer which is obtained from a C10 or more α-olefin and satisfies either (1) the melting point (Tm) as measured with a differential scanning calorimeter (DSC) is 20 to 100° C. or (2) in an examination of spin-lattice relaxation time (T1) by solid NMR analysis, a single T1 is observed at the temperatures not lower than the melting point; and a process for producing the α-olefin polymer with a specific metallocene catalyst. The crystalline higher α-olefin polymer is excellent in low-temperature characteristics, rigidity, heat resistance, compatibility with lubricating oils, mixability with inorganic fillers, and secondary processability.

    摘要翻译： 由差示扫描量热仪（DSC）测得的，由C 10〜10以上的α-烯烃得到的满足（1）熔点（Tm）的结晶高级α-烯烃聚合物为20 至（100）℃，或（2）在通过固体NMR分析检查自旋晶格弛豫时间（T 1 N 2）时，在温度下观察到单个T 1 不低于熔点; 以及用特定的茂金属催化剂生产α-烯烃聚合物的方法。 结晶高级α-烯烃聚合物的低温特性，刚性，耐热性，与润滑油的相容性，与无机填料的混合性以及二次加工性优异。

    WATER-DISPERSIBLE RESIN COMPOSITION AND WATER-DISPERSIBLE POLYOLEFIN RESIN COMPOSITION
    3.
    发明申请
    WATER-DISPERSIBLE RESIN COMPOSITION AND WATER-DISPERSIBLE POLYOLEFIN RESIN COMPOSITION 失效
    水分散树脂组合物和水不溶性聚烯烃树脂组合物

    公开(公告)号：US20090023857A1

    公开(公告)日：2009-01-22

    申请号：US11913119

    申请日：2006-07-04

    申请人： Masami Kanamaru ,  Masanori Sera ,  Yutaka Minami

    发明人： Masami Kanamaru ,  Masanori Sera ,  Yutaka Minami

    IPC分类号： C08L23/24

    CPC分类号： C08L23/0869 ,  C08F8/44 ,  C08F110/14 ,  C08F255/08 ,  C08L23/02 ,  C08L51/06 ,  C08L2666/02 ,  C09D151/06 ,  C08F2500/01 ,  C08F2500/03 ,  C08F8/12

    摘要： A water dispersible resin composition capable of forming a flat and smooth coating film with a solidified surface upon application to a base material and excellent in storage stability is provided. It is a water dispersible resin composition comprising 0.01 to 5 parts by mass of a surfactant (C) relative to 100 parts by mass of a combination of 5 to 70% by mass of a side-chain crystalline resin (A) with 95 to 30% by mass of water (B) as well as a water dispersible polyolefin-based resin composition comprising a combination of 5 to 80% by mass of a modified side-chain crystalline polyolefin-based resin with 95 to 20% by mass of water, in which for example, a side-chain crystalline olefin-based polymer (G) obtained by polymerization of one kind or more of higher α-olefins having 10 or more carbon atoms is modified with a radical initiator and an organic acid, organic acid anhydride or organic acid ester.

    摘要翻译： 提供了一种能够在涂敷于基材上时形成具有固化表面的平坦且光滑的涂膜的水分散性树脂组合物，并且具有优异的储存稳定性。 相对于100质量份的5〜70质量％的侧链结晶性树脂（A）与95〜30重量份的侧链结晶性树脂（A）的组合，为0.01〜5质量份表面活性剂（C）的水分散性树脂组合物 水（B）的质量百分比以及水分散性聚烯烃类树脂组合物，其含有5〜80质量％的改性侧链结晶聚烯烃类树脂和95〜20质量％的水， 其中例如通过使一种或多种具有10个或更多个碳原子的高级α-烯烃聚合得到的侧链结晶烯烃基聚合物（G）用自由基引发剂和有机酸改性，有机酸酐 或有机酸酯。

    Water-dispersible resin composition and water-dispersible polyolefin resin composition
    5.
    发明授权
    Water-dispersible resin composition and water-dispersible polyolefin resin composition 失效
    水分散性树脂组合物和水分散性聚烯烃树脂组合物

    公开(公告)号：US07763677B2

    公开(公告)日：2010-07-27

    申请号：US11913119

    申请日：2006-07-04

    申请人： Masami Kanamaru ,  Masanori Sera ,  Yutaka Minami

    发明人： Masami Kanamaru ,  Masanori Sera ,  Yutaka Minami

    IPC分类号： C08L23/18 ,  A61K9/16

    CPC分类号： C08L23/0869 ,  C08F8/44 ,  C08F110/14 ,  C08F255/08 ,  C08L23/02 ,  C08L51/06 ,  C08L2666/02 ,  C09D151/06 ,  C08F2500/01 ,  C08F2500/03 ,  C08F8/12

    摘要： A water dispersible resin composition capable of forming a flat and smooth coating film with a solidified surface upon application to a base material and excellent in storage stability is provided. It is a water dispersible resin composition comprising 0.01 to 5 parts by mass of a surfactant (C) relative to 100 parts by mass of a combination of 5 to 70% by mass of a side-chain crystalline resin (A) with 95 to 30% by mass of water (B) as well as a water dispersible polyolefin-based resin composition comprising a combination of 5 to 80% by mass of a modified side-chain crystalline polyolefin-based resin with 95 to 20% by mass of water, in which for example, a side-chain crystalline olefin-based polymer (G) obtained by polymerization of one kind or more of higher α-olefins having 10 or more carbon atoms is modified with a radical initiator and an organic acid, organic acid anhydride or organic acid ester.

    摘要翻译： 提供了一种能够在涂敷于基材上时形成具有固化表面的平坦且光滑的涂膜的水分散性树脂组合物，并且具有优异的储存稳定性。 相对于100质量份的5〜70质量％的侧链结晶性树脂（A）与95〜30重量份的侧链结晶性树脂（A）的组合，为0.01〜5质量份表面活性剂（C）的水分散性树脂组合物 水（B）的质量百分比以及水分散性聚烯烃类树脂组合物，其含有5〜80质量％的改性侧链结晶聚烯烃类树脂和95〜20质量％的水， 其中例如通过使一种或多种具有10个或更多个碳原子的高级α-烯烃聚合得到的侧链结晶烯烃基聚合物（G）用自由基引发剂和有机酸改性，有机酸酐 或有机酸酯。

    Thermoplastic resin composition
    6.
    发明申请
    Thermoplastic resin composition 审中-公开
    热塑性树脂组合物

    公开(公告)号：US20070088124A1

    公开(公告)日：2007-04-19

    申请号：US10511099

    申请日：2003-04-15

    申请人： Masanori Sera ,  Yutaka Minami ,  Masami Kanamaru

    发明人： Masanori Sera ,  Yutaka Minami ,  Masami Kanamaru

    IPC分类号： C08L23/00 ,  C08L21/00 ,  B32B27/00

    CPC分类号： C08L23/02 ,  C08K5/54 ,  C08K9/06 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08L23/18 ,  C08L23/24 ,  C08L2666/06

    摘要： The present invention relates to a thermoplastic resin composition, which contains 0.1 to 99.9% by mass of a thermoplastic resin (1) and 0.1 to 99.9% by mass of a higher α-olefin polymer (3) containing 50 mol % or more of an α-olefin having 10 or more carbon atoms, or contains 0.1 to 99.9% by mass of a thermoplastic resin (1), more than 0% to not more than 99.8% by mass of an elastomer (2), and 0.1 to 99.9% by mass of a higher α-olefin polymer (3) containing 50 mol % or more of an α-olefin having 10 or more carbon atoms, and a molded article, a sheet, and a film produced from the composition. The composition has excellent mechanical properties including high elastic modulus and impact resistant strength, without impairing heat resistance and mold workability.

    摘要翻译： 本发明涉及含有0.1〜99.9质量％的热塑性树脂（1）和0.1〜99.9质量％的含有50摩尔％以上的高分子量α-烯烃聚合物（3）的热塑性树脂组合物 含有10个以上碳原子的α-烯烃，或含有0.1〜99.9质量％的热塑性树脂（1），大于0％以上且99.8质量％以下的弹性体（2），0.1〜99.9质量％ 的含有50摩尔％以上的碳原子数为10以上的α-烯烃的高级α-烯烃聚合物（3），以及由该组合物制造的成型品，片材和膜。 该组合物具有优异的机械性能，包括高弹性模量和抗冲击强度，而不损害耐热性和模具加工性。

    Chlorinated propylene polymer, process for producing the same and use of the same
    7.
    发明授权
    Chlorinated propylene polymer, process for producing the same and use of the same 失效
    氯化丙烯聚合物，其生产方法和使用方法相同

    公开(公告)号：US07645837B2

    公开(公告)日：2010-01-12

    申请号：US10569139

    申请日：2004-08-27

    申请人： Ryo Aburatani ,  Masanori Sera ,  Yutaka Minami

    发明人： Ryo Aburatani ,  Masanori Sera ,  Yutaka Minami

    IPC分类号： C08F10/00

    CPC分类号： C08F8/20 ,  C08F2/00 ,  C08F14/02 ,  Y10S526/943 ,  C08F10/06

    摘要： A chlorinated propylene-based polymer of the present invention having a weight average molecular weight (Mw) as measured by gel permeation chromatography (GPC) of 5,000 to 100,000 and a chlorine content of 0.1 to 70% by mass has the following properties: (1) it has a high solubility in a non-aromatic solvent having a low environmental burden even when it has a low degree of chlorination, and (2) it can be inhibited from suffering a decrease in the properties inherent to polypropylenes, such as durability, mechanical properties, appearance and hydrophobicity, by regulating its degree of chlorination at a low value.

    摘要翻译： 通过凝胶渗透色谱法（GPC）测定的重均分子量（Mw）为5,000〜100,000，氯含量为0.1〜70质量％的本发明的氯化丙烯系聚合物具有以下性质：（1 ）即使氯化程度低，也具有环境负荷低的非芳香族溶剂的高溶解性，（2）能够抑制聚丙烯固有的性能降低等耐久性， 机械性能，外观和疏水性，通过将其氯化度调节到较低值。

    Higher alpha-olefin copolymers and process for preparation thereof
    8.
    发明申请
    Higher alpha-olefin copolymers and process for preparation thereof 失效
    高级α-烯烃共聚物及其制备方法

    公开(公告)号：US20050049373A1

    公开(公告)日：2005-03-03

    申请号：US10925037

    申请日：2004-08-25

    申请人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

    发明人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

    IPC分类号： C08F4/645 ,  C08F4/659 ,  C08F4/6592 ,  C08F210/14 ,  C08F4/44

    CPC分类号： C08F210/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F2500/20 ,  C08F2500/03

    摘要： An object of the present invention is to provide crystalline high α-olefin copolymers which have excellent compatibility with thermoplastic resins, especially polyolefins, and compatibility with lubricant oils, fuel oils or waxes, excellent miscibility with inorganic fillers and secondary processability, and which have narrow temperature ranges for melting and crystallization, and to provide a process for preparation thereof. The present invention provides a crystalline higher α-olefin copolymer obtained by copolymerizing at least two higher α-olefins having 10 or more carbon atoms or at least one higher α-olefin having 10 or more carbon atoms with at least one other olefin, wherein it satisfies the following (1) to (3): (1): the content of higher α-olefin units is 50 mol % or greater, (2): the melting point (Tm) which is measured, by using a differential scanning calorimeter (DSC), from the melting endothermic curve obtained by maintaining the copolymer at 190° C. for 5 minutes under a nitrogen atmosphere, cooling it to −10° C. at a rate of 5° C./min, maintaining it at −10° C. for 5 minutes, and then elevating its temperature to 190° C. at 10° C./min is in the range of 20 to 100° C., and (3): in the intensity distribution of wide-angle X-ray scattering, a single peak X1 resulting from crystallization of side chains is observed at 15 deg

    摘要翻译： 本发明的目的是提供与热塑性树脂特别是聚烯烃具有优异相容性的结晶高α-烯烃共聚物，与润滑油，燃料油或蜡的相容性，与无机填料的混溶性和二次加工性，并且具有窄 熔化和结晶的温度范围，并提供其制备方法。 本发明提供通过使至少两种具有10个或更多个碳原子的高级α-烯烃或至少一个具有10个或更多个碳原子的高级α-烯烃与至少一种其它烯烃共聚得到的结晶高级α-烯烃共聚物，其中 满足以下（1）〜（3）：（1）：高级α-烯烃单元的含量为50摩尔％以上，（2）：使用差示扫描量热计测定的熔点（Tm） （DSC）中，从在氮气气氛下将共聚物在190℃下保持5分钟而获得的熔融吸热曲线，以5℃/ min的速度将其冷却至-10℃， 10℃下5分钟，然后在10℃/分钟将其温度升至190℃/分钟在20至100℃的范围内，和（3）：在广角度的强度分布 在15度<2度<30度观察到X射线散射，由侧链结晶产生的单峰X1。

    Higher alpha-olefin copolymers and process for preparation thereof
    9.
    发明申请
    Higher alpha-olefin copolymers and process for preparation thereof 有权
    高级α-烯烃共聚物及其制备方法

    公开(公告)号：US20060111526A1

    公开(公告)日：2006-05-25

    申请号：US11324304

    申请日：2006-01-04

    申请人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

    发明人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

    IPC分类号： C08F4/44

    CPC分类号： C08F210/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F2500/20 ,  C08F2500/03

    摘要： An object of the present invention is to provide crystalline high α-olefin copolymers which have excellent compatibility with thermoplastic resins, especially polyolefins, and compatibility with lubricant oils, fuel oils or waxes, excellent miscibility with inorganic fillers and secondary processability, and which have narrow temperature ranges for melting and crystallization, and to provide a process for preparation thereof. The present invention provides a crystalline higher α-olefin copolymer obtained by copolymerizing at least two higher α-olefins having 10 or more carbon atoms or at least one higher α-olefin having 10 or more carbon atoms with at least one other olefin, wherein it satisfies the following (1) to (3): (1): the content of higher α-olefin units is 50 mol % or greater, (2): the melting point (Tm) which is measured, by using a differential scanning calorimeter (DSC), from the melting endothermic curve obtained by maintaining the copolymer at 190° C. for 5 minutes under a nitrogen atmosphere, cooling it to −10° C. at a rate of 5° C./min, maintaining it at −10° C. for 5 minutes, and then elevating its temperature to 190° C. at 10° C./min is in the range of 20 to 100° C., and (3): in the intensity distribution of wide-angle X-ray scattering, a single peak X1 resulting from crystallization of side chains is observed at 15 deg

    摘要翻译： 本发明的目的是提供与热塑性树脂特别是聚烯烃具有优异相容性的结晶高α-烯烃共聚物，与润滑油，燃料油或蜡的相容性，与无机填料的混溶性和二次加工性，并且具有窄 熔化和结晶的温度范围，并提供其制备方法。 本发明提供通过使至少两种具有10个或更多个碳原子的高级α-烯烃或至少一个具有10个或更多个碳原子的高级α-烯烃与至少一种其它烯烃共聚得到的结晶高级α-烯烃共聚物，其中 满足以下（1）〜（3）：（1）：高级α-烯烃单元的含量为50摩尔％以上，（2）：使用差示扫描量热计测定的熔点（Tm） （DSC）中，从在氮气气氛下将共聚物在190℃下保持5分钟而获得的熔融吸热曲线，以5℃/ min的速度将其冷却至-10℃， 10℃下5分钟，然后在10℃/分钟将其温度升至190℃/分钟在20至100℃的范围内，和（3）：在广角度的强度分布 在15度<2度<30度观察到X射线散射，由侧链结晶产生的单峰X1。

    Heat-storage material composition
    10.
    发明授权
    Heat-storage material composition 失效
    储热材料组成

    公开(公告)号：US07714081B2

    公开(公告)日：2010-05-11

    申请号：US10577496

    申请日：2004-10-27

    申请人： Masanori Sera ,  Yutaka Minami ,  Takenori Fujimura

    发明人： Masanori Sera ,  Yutaka Minami ,  Takenori Fujimura

    IPC分类号： C08L23/00 ,  C08L23/02

    CPC分类号： C09K5/063

    摘要： The present invention relates to a heat storage material composition comprising 20 to 100% by weight of a heat storage material, 80 to 0% by weight of crystalline polyolefin (B) and 50 to 0% by weight of an elastomer (C), and the heat storage material described above contains a side chain-crystalline polymer (A), wherein the heat storage material described above comprises preferably a higher α-olefin polymer (a) containing 50 mole % or more of higher α-olefin having 10 or more carbon atoms and a petroleum wax (b) in which a melting point (Tm) is higher by 10° C. or more than that of the polymer (a). Provided is a heat storage material composition which has less bleeding and stickiness and is excellent in stability at high temperature and which can meet a change in temperature such as a difference in room temperature when applied to a material for floor heating and can avoid a heating state deviated to high temperature or low temperature.

    摘要翻译： 本发明涉及一种储热材料组合物，其包含20至100重量％的蓄热材料，80至0重量％的结晶聚烯烃（B）和50至0重量％的弹性体（C），以及 上述储热材料含有侧链状聚合物（A），其中上述储热材料优选包含含有50摩尔％以上的具有10个以上的高级α-烯烃的高级α-烯烃聚合物（a） 碳原子和熔点（Tm）高于聚合物（a）的10℃以上的石油蜡（b）。 本发明提供一种蓄热材料组合物，其具有较少的渗透性和粘性，并且在高温下的稳定性优异，并且当施加到用于地板加热的材料时可以满足诸如室温差的温度变化并且可以避免加热状态 偏向高温或低温。