公开(公告)号：US20090023857A1

公开(公告)日：2009-01-22

申请号：US11913119

申请日：2006-07-04

申请人： Masami Kanamaru ,  Masanori Sera ,  Yutaka Minami

发明人： Masami Kanamaru ,  Masanori Sera ,  Yutaka Minami

IPC分类号： C08L23/24

CPC分类号： C08L23/0869 ,  C08F8/44 ,  C08F110/14 ,  C08F255/08 ,  C08L23/02 ,  C08L51/06 ,  C08L2666/02 ,  C09D151/06 ,  C08F2500/01 ,  C08F2500/03 ,  C08F8/12

摘要： A water dispersible resin composition capable of forming a flat and smooth coating film with a solidified surface upon application to a base material and excellent in storage stability is provided. It is a water dispersible resin composition comprising 0.01 to 5 parts by mass of a surfactant (C) relative to 100 parts by mass of a combination of 5 to 70% by mass of a side-chain crystalline resin (A) with 95 to 30% by mass of water (B) as well as a water dispersible polyolefin-based resin composition comprising a combination of 5 to 80% by mass of a modified side-chain crystalline polyolefin-based resin with 95 to 20% by mass of water, in which for example, a side-chain crystalline olefin-based polymer (G) obtained by polymerization of one kind or more of higher α-olefins having 10 or more carbon atoms is modified with a radical initiator and an organic acid, organic acid anhydride or organic acid ester.

摘要翻译： 提供了一种能够在涂敷于基材上时形成具有固化表面的平坦且光滑的涂膜的水分散性树脂组合物，并且具有优异的储存稳定性。 相对于100质量份的5〜70质量％的侧链结晶性树脂（A）与95〜30重量份的侧链结晶性树脂（A）的组合，为0.01〜5质量份表面活性剂（C）的水分散性树脂组合物 水（B）的质量百分比以及水分散性聚烯烃类树脂组合物，其含有5〜80质量％的改性侧链结晶聚烯烃类树脂和95〜20质量％的水， 其中例如通过使一种或多种具有10个或更多个碳原子的高级α-烯烃聚合得到的侧链结晶烯烃基聚合物（G）用自由基引发剂和有机酸改性，有机酸酐 或有机酸酯。

公开(公告)号：US20050031883A1

公开(公告)日：2005-02-10

申请号：US10488940

申请日：2002-09-17

申请人： Masanori Sera ,  Yutaka Minami ,  Masami Kanamaru

发明人： Masanori Sera ,  Yutaka Minami ,  Masami Kanamaru

IPC分类号： B32B27/32 ,  C08F4/642 ,  C08F10/08 ,  C08F110/08 ,  C08F210/08 ,  C08J5/18 ,  C08L23/02 ,  C08L23/10 ,  C08L23/20 ,  B32B27/08

CPC分类号： C08L23/20 ,  B32B27/32 ,  C08F10/08 ,  C08F110/08 ,  C08F210/08 ,  C08J5/18 ,  C08J2323/02 ,  C08J2323/20 ,  C08L23/02 ,  C08L23/10 ,  C08L2314/06 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08L2666/06 ,  C08L2666/04 ,  C08F2500/03 ,  C08F2500/01 ,  C08F2500/15 ,  C08F2500/26 ,  C08F210/14 ,  C08F210/16 ,  C08F2500/20

摘要： The wrap film and the shrink film of the present invention are formed from a resin composition comprising a specific 1-butene base polymer satisfying the following items (1) to (4) and an olefin base polymer, and they are excellent in a safety and satisfy characteristics for a wrap film or a shrink film: (1) a crystalline resin in which a melting point (Tm-D) defined as a peak top of a peak observed at a highest temperature side in a melting endothermic curve obtained by holding a sample at −10° C. for 5 minutes under nitrogen atmosphere by means of a differential scanning calorimeter (DSC) and then elevating the temperature at 10° C./minute is 0 to 100° C.; (2) a stereospecific index {(mmmm)/(mmrr+rmmr)} is 20 or less; (3) a molecular weight distribution (Mw/Mn) measured by a gel permeation chromatography (GPC) method is 4.0 or less; and (4) a weight average molecular weight (Mw) measured by the GPC method is 10,000 to 1,000,000.

摘要翻译： 本发明的保鲜膜和收缩膜由包含满足下述（1）〜（4）的特定1-丁烯基聚合物的树脂组合物和烯烃类聚合物形成，其安全性和 满足保鲜膜或收缩膜的特性：（1）将熔融吸热曲线中熔点（Tm-D）定义为在最高温度侧观察到的峰的熔点（Tm-D）的结晶树脂， 在差示扫描量热仪（DSC）中，在氮气气氛下，在-10℃下取样5分钟，然后升温10℃/分钟，温度为0〜100℃。 （2）立体特异性指数{（mmmm）/（mmrr + rmmr）}为20以下; （3）通过凝胶渗透色谱法（GPC）法测定的分子量分布（Mw / Mn）为4.0以下， 和（4）通过GPC法测定的重均分子量（Mw）为10,000〜1,000,000。

公开(公告)号：US07214755B2

公开(公告)日：2007-05-08

申请号：US10505046

申请日：2003-02-19

申请人： Yutaka Minami ,  Masami Kanamaru ,  Masanori Sera ,  Tatsuya Egawa ,  Takenori Fujimura

发明人： Yutaka Minami ,  Masami Kanamaru ,  Masanori Sera ,  Tatsuya Egawa ,  Takenori Fujimura

IPC分类号： C08F110/14 ,  C08F210/14 ,  C08F4/6192

CPC分类号： C08F110/14 ,  C08F10/00 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/18 ,  C08F2500/15

摘要： A crystalline higher α-olefin polymer which is obtained from a C10 or more α-olefin and satisfies either (1) the melting point (Tm) as measured with a differential scanning calorimeter (DSC) is 20 to 100° C. or (2) in an examination of spin-lattice relaxation time (T1) by solid NMR analysis, a single T1 is observed at the temperatures not lower than the melting point; and a process for producing the α-olefin polymer with a specific metallocene catalyst. The crystalline higher α-olefin polymer is excellent in low-temperature characteristics, rigidity, heat resistance, compatibility with lubricating oils, mixability with inorganic fillers, and secondary processability.

摘要翻译： 由差示扫描量热仪（DSC）测得的，由C 10〜10以上的α-烯烃得到的满足（1）熔点（Tm）的结晶高级α-烯烃聚合物为20 至（100）℃，或（2）在通过固体NMR分析检查自旋晶格弛豫时间（T 1 N 2）时，在温度下观察到单个T 1 不低于熔点; 以及用特定的茂金属催化剂生产α-烯烃聚合物的方法。 结晶高级α-烯烃聚合物的低温特性，刚性，耐热性，与润滑油的相容性，与无机填料的混合性以及二次加工性优异。

公开(公告)号：US20050119374A1

公开(公告)日：2005-06-02

申请号：US10505046

申请日：2003-02-19

申请人： Yutaka Minami ,  Masami Kanamaru ,  Masanori Sera ,  Tatsuya Egawa ,  Takenori Fujimura

发明人： Yutaka Minami ,  Masami Kanamaru ,  Masanori Sera ,  Tatsuya Egawa ,  Takenori Fujimura

IPC分类号： C08F4/642 ,  C08F10/00 ,  C08F110/14 ,  C08L67/00

CPC分类号： C08F110/14 ,  C08F10/00 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/18 ,  C08F2500/15

摘要： A crystalline higher (x-olefin polymer which is obtained from a C10 or more α-olefin and satisfies either (1) the melting point (Tm) as measured with a differential scanning calorimeter (DSC) is 20 to 100° C. or (2) in an examination of spin-lattice relaxation time (T1) by solid NMR analysis, a single T1 is observed at the temperatures not lower than the melting point; and a process for producing the α-olefin polymer with a specific metallocene catalyst. The crystalline higher α-olefin polymer is excellent in low-temperature characteristics, rigidity, heat resistance, compatibility with lubricating oils, mixability with inorganic fillers, and secondary processability.

摘要翻译： 由差示扫描量热仪（DSC）测得的结晶高（X-α-烯烃聚合物，由C 10以上的α-烯烃得到并满足（1）熔点（Tm） 20至100℃或（2）通过固体NMR分析检查自旋晶格弛豫时间（T 1 N 2）时，在 不低于熔点的温度;以及用特定的茂金属催化剂生产α-烯烃聚合物的方法，结晶高级α-烯烃聚合物的低温特性，刚性，耐热性，与润滑油的相容性，混合性 无机填料，二次加工性能。

公开(公告)号：US07763677B2

公开(公告)日：2010-07-27

申请号：US11913119

申请日：2006-07-04

申请人： Masami Kanamaru ,  Masanori Sera ,  Yutaka Minami

发明人： Masami Kanamaru ,  Masanori Sera ,  Yutaka Minami

IPC分类号： C08L23/18 ,  A61K9/16

CPC分类号： C08L23/0869 ,  C08F8/44 ,  C08F110/14 ,  C08F255/08 ,  C08L23/02 ,  C08L51/06 ,  C08L2666/02 ,  C09D151/06 ,  C08F2500/01 ,  C08F2500/03 ,  C08F8/12

摘要： A water dispersible resin composition capable of forming a flat and smooth coating film with a solidified surface upon application to a base material and excellent in storage stability is provided. It is a water dispersible resin composition comprising 0.01 to 5 parts by mass of a surfactant (C) relative to 100 parts by mass of a combination of 5 to 70% by mass of a side-chain crystalline resin (A) with 95 to 30% by mass of water (B) as well as a water dispersible polyolefin-based resin composition comprising a combination of 5 to 80% by mass of a modified side-chain crystalline polyolefin-based resin with 95 to 20% by mass of water, in which for example, a side-chain crystalline olefin-based polymer (G) obtained by polymerization of one kind or more of higher α-olefins having 10 or more carbon atoms is modified with a radical initiator and an organic acid, organic acid anhydride or organic acid ester.

摘要翻译： 提供了一种能够在涂敷于基材上时形成具有固化表面的平坦且光滑的涂膜的水分散性树脂组合物，并且具有优异的储存稳定性。 相对于100质量份的5〜70质量％的侧链结晶性树脂（A）与95〜30重量份的侧链结晶性树脂（A）的组合，为0.01〜5质量份表面活性剂（C）的水分散性树脂组合物 水（B）的质量百分比以及水分散性聚烯烃类树脂组合物，其含有5〜80质量％的改性侧链结晶聚烯烃类树脂和95〜20质量％的水， 其中例如通过使一种或多种具有10个或更多个碳原子的高级α-烯烃聚合得到的侧链结晶烯烃基聚合物（G）用自由基引发剂和有机酸改性，有机酸酐 或有机酸酯。

公开(公告)号：US20070088124A1

公开(公告)日：2007-04-19

申请号：US10511099

申请日：2003-04-15

申请人： Masanori Sera ,  Yutaka Minami ,  Masami Kanamaru

发明人： Masanori Sera ,  Yutaka Minami ,  Masami Kanamaru

IPC分类号： C08L23/00 ,  C08L21/00 ,  B32B27/00

CPC分类号： C08L23/02 ,  C08K5/54 ,  C08K9/06 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08L23/18 ,  C08L23/24 ,  C08L2666/06

摘要： The present invention relates to a thermoplastic resin composition, which contains 0.1 to 99.9% by mass of a thermoplastic resin (1) and 0.1 to 99.9% by mass of a higher α-olefin polymer (3) containing 50 mol % or more of an α-olefin having 10 or more carbon atoms, or contains 0.1 to 99.9% by mass of a thermoplastic resin (1), more than 0% to not more than 99.8% by mass of an elastomer (2), and 0.1 to 99.9% by mass of a higher α-olefin polymer (3) containing 50 mol % or more of an α-olefin having 10 or more carbon atoms, and a molded article, a sheet, and a film produced from the composition. The composition has excellent mechanical properties including high elastic modulus and impact resistant strength, without impairing heat resistance and mold workability.

摘要翻译： 本发明涉及含有0.1〜99.9质量％的热塑性树脂（1）和0.1〜99.9质量％的含有50摩尔％以上的高分子量α-烯烃聚合物（3）的热塑性树脂组合物 含有10个以上碳原子的α-烯烃，或含有0.1〜99.9质量％的热塑性树脂（1），大于0％以上且99.8质量％以下的弹性体（2），0.1〜99.9质量％ 的含有50摩尔％以上的碳原子数为10以上的α-烯烃的高级α-烯烃聚合物（3），以及由该组合物制造的成型品，片材和膜。 该组合物具有优异的机械性能，包括高弹性模量和抗冲击强度，而不损害耐热性和模具加工性。

公开(公告)号：US07459503B2

公开(公告)日：2008-12-02

申请号：US10509329

申请日：2003-04-11

申请人： Masami Kanamaru ,  Yutaka Minami ,  Ryo Aburatani ,  Tomio Tatsumi ,  Takenori Fujimura

发明人： Masami Kanamaru ,  Yutaka Minami ,  Ryo Aburatani ,  Tomio Tatsumi ,  Takenori Fujimura

IPC分类号： C08F8/06 ,  C08F8/46

CPC分类号： C09J123/12 ,  C08L2023/42 ,  C08L2666/02 ,  C09J123/10

摘要： The present invention relates to a method for producing a modified propylene-based polymer containing modifying a propylene-based polymer by a radical initiator and an organic acid, a modified propylene-based polymer obtained by the method, and an adhesive composition containing the modified propylene-based polymer. The propylene-based polymer is a propylene homopolymer satisfying the conditions of (a) mmmm=20 to 60 mol %, (b) [rrrr/(1-mmmm)]≦0.1, (c) rmrm>2.5 mol %, (d) mmxrr/(mr)2≦2.0, and (e) the weight ratio (W25) of components eluted at 25° C. or lower in a temperature programmed chromatography is 20 to 100% by weight, or a propylene copolymer satisfying the condition of (h) the stereoregularity index (P) obtained by 13C-NMR measurement is 55 to 90 mol %.The modified propylene-based polymer of the invention can make a polyolefin, etc. more adhesive, stronger, or flexible, to be useful for a high-adhesive sealant or an polyolefin with increased compatibility to an inorganic filler, etc., particularly as a resin for a hot-melt adhesive.

摘要翻译： 本发明涉及通过自由基引发剂和有机酸改性丙烯类聚合物的改性丙烯类聚合物的制造方法，该方法得到的改性丙烯类聚合物和含有改性丙烯的粘合剂组合物 基聚合物。 丙烯类聚合物是满足（a）mmmm = 20〜60mol％，（b）[rrrr /（1-mmmm）] <= 0.1，（c）rmrm> 2.5mol％的条件的丙烯均聚物， d）mmxrr /（mr）2 <= 2.0，（e）在温度程序化色谱法中在25℃以下洗脱的组分的重量比（W25）为20〜100重量％，或者满足 （h）由13 C-NMR测定得到的立构规整度指数（P）的条件为55〜90摩尔％。 本发明的改性丙烯类聚合物可以使聚烯烃等具有更好的粘合性，更强或柔性，可用于具有增加与无机填料等的相容性的高粘合密封剂或聚烯烃，特别是作为 用于热熔胶的树脂。

公开(公告)号：US07067604B2

公开(公告)日：2006-06-27

申请号：US10834269

申请日：2004-04-29

申请人： Yutaka Minami ,  Masami Kanamaru ,  Koji Kakigami ,  Hideo Funabashi

发明人： Yutaka Minami ,  Masami Kanamaru ,  Koji Kakigami ,  Hideo Funabashi

IPC分类号： C08F10/08

CPC分类号： C08F10/08 ,  C08F4/65912 ,  C08F110/08 ,  C08F210/08 ,  C08L23/20 ,  C08F4/65927 ,  C08F2500/15 ,  C08F2500/03 ,  C08F2500/20 ,  C08F210/14 ,  C08F210/16 ,  C08F210/06

摘要： 1-butene based polymer satisfying following requirements (1″) to (4″) provides formed product having low stickiness, superior flexibility and transparency. (1″) Crystalline resin having melting point (Tm−P), not observed or in the range of 0 to 100° C., wherein said melting point defined as the peak top of the peak observed in the highest temperature zone of the melting heat absorption curve obtained by heating a sample of said polymer at a rate of 10° C./minute using Differential Scanning Calorimeter (DSC), after melting said sample in advance at 190° for 5 minutes under nitrogen atmosphere, followed by cooling it to −10° C. at a rate of 5° C./minutes, and keeping it at −10° C. for 5 minutes. (2″) Stereoregularity index {(mmmm)/(mmrr+rmmr)} is at most 20. (3″) Molecular weight distribution (Mw/Mn) measured by Gel Permeation Chromatography (GPC) method is at most 4.0. (4″) Weight average molecular weight (Mw) measured by GPC method is in the range of 10,000 to 1,000,000.

摘要翻译： 满足以下要求（1“）至（4”）的1-丁烯基聚合物提供具有低粘性，优异的柔性和透明度的成型产品。 （1“）具有熔点（Tm-P），未观察到或在0〜100℃的范围内的结晶性树脂，其中，所述熔点定义为在最高温度区域观察到的峰的峰顶 使用差示扫描量热计（DSC）以10℃/分钟的速率加热所述聚合物的样品，在氮气气氛下预先在190℃下熔融5分钟之后将样品熔融之后冷却，得到熔融热吸收曲线 至-10℃，速度为5℃/分钟，并将其保持在-10℃下5分钟。 （2“）立体规则指数{（mmmm）/（mmrr + rmmr至多为20.（3”）通过凝胶渗透色谱（GPC）法测定的分子量分布（Mw / Mn）为4.0以下（4“ ''）通过GPC法测量的重均分子量（Mw）在10,000至1,000,000的范围内。

公开(公告)号：US20050119428A1

公开(公告)日：2005-06-02

申请号：US10505264

申请日：2003-02-19

申请人： Yutaka Minami ,  Masami Kanamaru ,  Toyozo Fujioka ,  Tomoaki Takebe ,  Masao Inoue

发明人： Yutaka Minami ,  Masami Kanamaru ,  Toyozo Fujioka ,  Tomoaki Takebe ,  Masao Inoue

IPC分类号： C08F4/642 ,  C08F10/08 ,  C08F110/08 ,  C08F210/08 ,  C08F210/18 ,  C09J123/20 ,  C08F4/44

CPC分类号： C08F10/08 ,  C08F110/08 ,  C08F210/08 ,  C08F210/18 ,  C09J123/20 ,  Y10S526/941 ,  Y10S526/943 ,  Y10T428/2878 ,  C08F2500/17 ,  C08F2500/15 ,  C08F2500/03 ,  C08F210/16 ,  C08F2500/20 ,  C08F210/06 ,  C08F210/14

摘要： A 1-butene polymer satisfying the following (1), (2) and either (3) or (3′): a process for producing the polymer; a resin modifier comprising the polymer; and a hot-melt adhesive containing the polymer. (1) The intrinsic viscosity [η] as measured in tetralin solvent at 135° C. is 0.01 to 0.5 dL/g. (2) The polymer is a crystalline resin having a melting point (Tm-D) of 0 to 100° C., the melting point being defined as the top of the peak observed on the highest-temperature side in a melting endothermic curve obtained with a differential scanning calorimeter (DSC) in a test in which a sample is held in a nitrogen atmosphere at −10° C. for 5 min and then heated at a rate of 10° C./min. (3) The stereoregularity index {(mmmm)/(mmrr+rmmr)} is 30 or lower. (3′) The mesopentad content (mmmm) determined from a nuclear magnetic resonance (NMR) spectrum is 68 to 73%.

摘要翻译： 满足以下（1），（2）和（3）或（3'）的1-丁烯聚合物：制备聚合物的方法; 包含所述聚合物的树脂改性剂; 和含有聚合物的热熔性粘合剂。 （1）在135℃下在四氢化萘溶剂中测定的特性粘度η为0.01〜0.5dL / g。 （2）聚合物是熔点（Tm-D）为0〜100℃的结晶性树脂，熔点定义为在获得的熔融吸热曲线中在最高温度侧观察到的峰的顶部 在差示扫描量热仪（DSC）中，将试样在-10℃的氮气气氛中保持5分钟，然后以10℃/ min的速度加热。 （3）立构规整度指数{（mmmm）/（mmrr + rmmr为30以下。（3'）由核磁共振（NMR）光谱确定的孔隙度含量（mmmm）为68〜73％。

公开(公告)号：US08445618B2

公开(公告)日：2013-05-21

申请号：US12094692

申请日：2006-11-29

申请人： Takenori Fujimura ,  Masami Kanamaru ,  Takuji Okamoto ,  Yutaka Minami

发明人： Takenori Fujimura ,  Masami Kanamaru ,  Takuji Okamoto ,  Yutaka Minami

IPC分类号： C08F210/00 ,  C08F10/14

CPC分类号： C08F110/14 ,  C08F2500/01 ,  C08F2500/20 ,  C08F2500/03

摘要： A highly crystalline higher α-olefin polymer that is excellent in compatibility with a thermoplastic resin, particularly a polyolefin, compatibility with a lubricant oil, a fuel oil and wax, mixing property with an inorganic filler, and secondary working property, and a process for production thereof are provided. The highly crystalline higher α-olefin polymer is obtained by polymerizing a monomer containing 80% by mol or more of a higher α-olefin having from 22 to 40 carbon atoms, and satisfies the following items (1) and (2). (1) The melting point (Tm), which is observed, by using a differential scanning calorimeter (DSC), from a melting endothermic curve obtained by maintaining a specimen at 190° C. for 5 minutes under a nitrogen atmosphere, cooling the specimen to −10° C. at a rate of 5° C./min, maintaining at −10° C. for 5 minutes, and then elevating a temperature thereof to 190° C. at a rate of 10° C./min, is from 55 to 100° C. (2) Standards weight average molecular weight (Mw) measured by a gel permeation chromatography (GPC) based on polystyrene is from 1,000 to 5,000,000, and the molecular weight distribution (Mw/Mn) measured thereby is 5.0 or less.

摘要翻译： 与热塑性树脂，特别是聚烯烃的相容性优异的高结晶性高级α-烯烃聚合物，与润滑油，燃料油和蜡的相容性，与无机填料的混合性能和二次加工性能的方法 提供其生产。 通过聚合含有80摩尔％以上的具有22〜40个碳原子的较高级α-烯烃的单体，可以得到高结晶性的高级α-烯烃聚合物，并且满足下述（1）和（2）。 （1）通过使用差示扫描量热计（DSC）从在氮气氛下将试样在190℃下保持5分钟而获得的熔融吸热曲线观察到的熔点（Tm），冷却试样 至-10℃，以5℃/ min的速率，在-10℃保持5分钟，然后以10℃/ min的速率升温至190℃， （2）通过基于聚苯乙烯的凝胶渗透色谱法（GPC）测定的标准重均分子量（Mw）为1,000〜5,000,000，由此测定的分子量分布（Mw / Mn）为 5.0以下