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公开(公告)号:US5070059A
公开(公告)日:1991-12-03
申请号:US602589
申请日:1990-10-24
申请人: Masao Saito , Kengo Tsukahara , Noriko Takahashi , Yuzi Onda
发明人: Masao Saito , Kengo Tsukahara , Noriko Takahashi , Yuzi Onda
IPC分类号: C07C253/24 , B01J21/02 , B01J23/28 , C07B61/00 , C07C23/28 , C07C67/00 , C07C253/00 , C07C253/28 , C07C255/49 , C07C255/50 , C07C255/51
CPC分类号: C07C253/28 , B01J21/02 , B01J23/28
摘要: The present invention relates to a catalyst which comprises a vanadium oxide, a chromium oxide, a molybdenum oxide and a boron oxide supported on a silica carrier. This catalyst is suitable for use in the production of aromatic nitriles from alkyl-substituted aromatic compound by the catalytic reaction of a gas mixture containing an alkyl-substituted aromatic compound, ammonia and oxygen or a gas containing molecular oxygen over a catalyst. The present invention further relates to a process for producing the aromatic nitriles using said catalyst.
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公开(公告)号:US4985581A
公开(公告)日:1991-01-15
申请号:US336475
申请日:1989-04-12
申请人: Masao Saito , Kengo Tsukahara , Noriko Takahashi , Yuzi Onda
发明人: Masao Saito , Kengo Tsukahara , Noriko Takahashi , Yuzi Onda
IPC分类号: C07C253/24 , B01J21/02 , B01J23/28 , C07B61/00 , C07C23/28 , C07C67/00 , C07C253/00 , C07C253/28 , C07C255/49 , C07C255/50 , C07C255/51
CPC分类号: C07C253/28 , B01J21/02 , B01J23/28
摘要: The present invention relates to a catalyst which comprises a vanadium oxide, a chromium oxide, a molybdenum oxide and a boron oxide supported on a silica carrier. This catalyst is suitable for use in the production of aromatic nitriles from alkyl-substituted aromatic compound by the catalytic reaction of a gas mixture containing an alkyl-substituted aromatic compound, ammonia and oxygen or a gas containing molecular oxygen over a catalyst. The present invention further relates to a process for producing the aromatic nitriles using said catalyst.
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公开(公告)号:US4218398A
公开(公告)日:1980-08-19
申请号:US972257
申请日:1978-12-22
申请人: Masao Saito , Kinichi Mizuno , Yuzi Onda , Tetsuo Aoyama , Kumiko Kato
发明人: Masao Saito , Kinichi Mizuno , Yuzi Onda , Tetsuo Aoyama , Kumiko Kato
IPC分类号: C07C231/00 , C07C233/00 , C07C103/36
CPC分类号: C07C231/00 , C07C233/00
摘要: Dimethylformamide mg.multidot.produced by reaction of monomethylamine and trimethylamine at a molar ratio of trimethylamine to monomethylamine of 0.1-10, with carbon monoxide in the presence of 1-500 mg. atom of at least one of iodine, bromine, iodides and bromides as a catalyst in term of halogen per one mole of raw material methylamines at a temperature of 100.degree.-350.degree. C. under a pressure of at least 50 kg/cm.sup.2 gage. Dimethylformamide is produced in a very high yield with a high selectivity from monomethylamine and trimethylamine having less demand among three species of methylamines formed from methanol and ammonia.
摘要翻译: 二甲基甲酰胺通过一甲胺和三甲胺以三甲胺与一甲胺的摩尔比为0.1-10与一氧化碳在1-500mg存在下反应生成。 在100-350℃的温度下,在至少50kg / cm2的压力下,每1摩尔原料甲胺中的碘,溴,碘化物和溴化物中的至少一种作为催化剂的原子。 二甲基甲酰胺以非常高的产率以高的选择性从一甲胺和三甲胺生产,在甲醇和氨形成的三种甲胺中的需求较少。
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公开(公告)号:US4094905A
公开(公告)日:1978-06-13
申请号:US802524
申请日:1977-06-01
申请人: Kinichi Mizuno , Masao Saito , Yuzi Onda , Tetsuo Aoyama , Kumiko Kato
发明人: Kinichi Mizuno , Masao Saito , Yuzi Onda , Tetsuo Aoyama , Kumiko Kato
IPC分类号: C07B61/00 , B01J21/00 , B01J27/00 , B01J31/00 , C07C67/00 , C07C231/00 , C07C231/08 , C07C231/10 , C07C233/00 , C07C233/03 , C07C102/00
CPC分类号: C07C231/00 , C07C233/00
摘要: Dimethyl formamide is produced in high yield with high selectivity by reaction of monomethyl formamide with trimethylamine and carbon monoxide in the presence of a catalyst such as halogen elements, halides, inorganic acids, solid acids and metal carbonyls at a temperature of 150.degree. to 300.degree. C under a pressure of 20 kg/cm.sup.2 gage or higher.
摘要翻译: 在150〜300℃的温度下,在催化剂如卤素,卤化物,无机酸,固体酸和金属羰基化物的存在下,通过单甲基甲酰胺与三甲胺和一氧化碳的反应,可以高选择性生产二甲基甲酰胺。 C在20kg / cm2的压力或更高的压力下。
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公开(公告)号:US4935537A
公开(公告)日:1990-06-19
申请号:US263246
申请日:1988-10-27
申请人: Susumu Naito , Koichi Abe , Hidetaka Kiga , Yuzi Onda
发明人: Susumu Naito , Koichi Abe , Hidetaka Kiga , Yuzi Onda
IPC分类号: C07C65/05
摘要: A process for producing an acyloxynaphthoic acid represented by the general formula ##STR1## wherein R.sub.1 represents a hydrogen atom or an alkyl group, which comprises(a) oxidizing an acylalkylnaphthalene represented by the general formula ##STR2## wherein R.sub.1 is as defined, and R.sub.2 represents a lower alkyl group, with a peroxide, and(b) oxidizing the resulting acyloxyalkylnaphthalene represented by the general formula ##STR3## wherein R.sub.1 and R.sub.2 are as defined above, with molecular oxygen in an organic solvent in the presence of a catalyst comprising a bromine compound and a cobalt compound.
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公开(公告)号:US4801737A
公开(公告)日:1989-01-31
申请号:US761520
申请日:1985-08-01
申请人: Susumu Naito , Koichi Abe , Hidetaka Kiga , Yuzi Onda
发明人: Susumu Naito , Koichi Abe , Hidetaka Kiga , Yuzi Onda
摘要: A process for producing an acyloxynaphthoic acid represented by the general formula ##STR1## wherein R.sub.1 represents a hydrogen atom or an alkyl group, which comprises(a) oxidizing an acylalkylnaphthalene represented by the general formula ##STR2## wherein R.sub.1 is as defined, and R.sub.2 represents a lower alkyl group, with a peroxide, and(b) oxidizing the resulting acyloxyalkylnaphthalene represented by the general formula ##STR3## wherein R.sub.1 and R.sub.2 are as defined above, with molecular oxygen in an organic solvent in the presence of a catalyst comprising a bromine compound and a cobalt compound.
摘要翻译: 一种由通式(I)表示的酰氧基萘甲酸的制备方法,其中R1表示氢原子或烷基,其包括(a)氧化由通式(II)表示的酰基烷基萘,其中R1 R2表示低级烷基,与过氧化物反应,(b)氧化所得到的通式(III)表示的酰氧基烷基萘,其中R 1和R 2如上定义,分子氧在有机 溶剂在包含溴化合物和钴化合物的催化剂存在下进行。
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