摘要:
In a lithium ion secondary battery, a lithium-nickel-containing composite oxide that contains lithium and nickel is used as a positive electrode active material, and a negative electrode active material having a melting temperature of 1200° C. or less in a lithium-absorbed state is included in a negative electrode active material layer. By configuring as above, in the lithium ion secondary battery, it is possible to achieve higher capacity, higher output, and longer life, as well as further improved safety, and particularly in a nail penetration test, to suppress the heat generation due to internal short circuit and to reliably prevent the occurrence of thermal runaway.
摘要:
A lithium ion secondary battery includes a negative electrode that is shaped like waves in a section in the thickness direction. In the negative electrode, the ratio t1/t0 of the largest thickness t1 to the smallest thickness t0 is from 1.2 to 3.0. The negative electrode includes a thin-film negative electrode active material layer in which the ratio A/B of the volume A in a charged state to the volume B in a discharged state is 1.2 or more. The lithium ion secondary battery has high capacity, high power, long life, and improved safety. In particular, heat generation due to an internal short-circuit is significantly suppressed in a nail penetration test.
摘要:
The non-aqueous electrolyte secondary battery of the present invention is provided with an electrode plate group and a non-aqueous electrolyte, the electrode plate group including a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, a positive electrode lead connected to the positive electrode, and a negative electrode lead connected to the negative electrode. The energy density of the electrode plate group is 750 Wh/L or higher by volume, and the cross-sectional area of at least one of the positive electrode lead and the negative electrode lead is 5.5×10−5 to 1.2×10−2 cm2.
摘要:
In a lithium ion secondary battery including a flat-plate electrode assembly which is configured by stacking the positive electrode, the separator, and the negative electrode in the thickness direction thereof, each of the positive electrode and the negative electrode includes a current collector and an active material layer. Each of the current collector includes a substantially rectangular current collector body, a heat radiating portion, and a lead portion, and the heat radiating portions are projected toward the outside of the electrode assembly so as not to overlap with each other in the thickness direction of the electrode assembly. In this way, heat caused inside the lithium ion secondary battery can be diffused efficiently to the outside, and safety of the lithium ion secondary battery can be further increased, without complicating the battery structure and decreasing mechanical strength of the battery.
摘要:
The non-aqueous electrolyte secondary battery of the present invention is provided with an electrode plate group and a non-aqueous electrolyte, the electrode plate group including a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, a positive electrode lead connected to the positive electrode, and a negative electrode lead connected to the negative electrode. The energy density of the electrode plate group is 750 Wh/L or higher by volume, and the cross-sectional area of at least one of the positive electrode lead and the negative electrode lead is 5.5×10−5 to 1.2×10−2 cm2.
摘要:
In a lithium ion secondary battery including a flat-plate electrode assembly which is configured by stacking the positive electrode, the separator, and the negative electrode in the thickness direction thereof, each of the positive electrode and the negative electrode includes a current collector and an active material layer. Each of the current collector includes a substantially rectangular current collector body, a heat radiating portion, and a lead portion, and the heat radiating portions are projected toward the outside of the electrode assembly so as not to overlap with each other in the thickness direction of the electrode assembly. In this way, heat caused inside the lithium ion secondary battery can be diffused efficiently to the outside, and safety of the lithium ion secondary battery can be further increased, without complicating the battery structure and decreasing mechanical strength of the battery.
摘要:
A lithium secondary battery including: an electrode group, a non-aqueous electrolyte and a battery case housing the electrode group and the non-aqueous electrolyte, the electrode group including a positive electrode, a negative electrode and a separator layer interposed between the positive electrode and the negative electrode, wherein an end-of-charge voltage and an end-of-discharge voltage are set in such a manner that the electrode group has an energy density of not less than 700 Wh/L, the separator layer includes a porous heat-resistant layer, and a short circuit area A produced when an internal short circuit has occurred between the positive electrode and the negative electrode, and a reduced area B of the porous heat-resistant layer that is produced by heat generation satisfy 1≦(A+B)/A≦10.
摘要:
A lithium secondary battery including: an electrode group, a non-aqueous electrolyte and a battery case housing the electrode group and the non-aqueous electrolyte, the electrode group including a positive electrode, a negative electrode and a separator layer interposed between the positive electrode and the negative electrode, wherein an end-of-charge voltage and an end-of-discharge voltage are set in such a manner that the electrode group has an energy density of not less than 700 Wh/L, the separator layer includes a porous heat-resistant layer, and a short circuit area A produced when an internal short circuit has occurred between the positive electrode and the negative electrode, and a reduced area B of the porous heat-resistant layer that is produced by heat generation satisfy 1≦(A+B)/A≧10.
摘要:
A lithium secondary battery including: an electrode group, a non-aqueous electrolyte and a battery case housing the electrode group and the non-aqueous electrolyte, the electrode group including a positive electrode, a negative electrode and a separator layer interposed between the positive electrode and the negative electrode, wherein an end-of-charge voltage and an end-of-discharge voltage are set in such a manner that the electrode group has an energy density of not less than 700 Wh/L, the separator layer includes a porous heat-resistant layer, and a short circuit area A produced when an internal short circuit has occurred between the positive electrode and the negative electrode, and a reduced area B of the porous heat-resistant layer that is produced by heat generation satisfy 1≦(A+B)/A≦10.
摘要:
In the non-aqueous electrolyte secondary battery of the present invention, the separator includes a heat-resistant resin having chlorine atoms as an end group and the positive electrode active material includes a lithium-containing complex oxide containing aluminum atoms in its composition. Even if the chlorine atoms are liberated into the non-aqueous electrolyte, aluminum contained in the positive electrode active material is selectively leached into the non-aqueous electrolyte, thereby suppressing the leaching of other component elements. Consequently, there can be obtained a non-aqueous electrolyte secondary battery excellent in safety and high temperature storage characteristics.