公开(公告)号：US5434204A

公开(公告)日：1995-07-18

申请号：US960766

申请日：1992-10-14

申请人： Masato Takaku ,  Mune Iwamoto ,  Masaru Honma ,  Atsushi Hashimoto

发明人： Masato Takaku ,  Mune Iwamoto ,  Masaru Honma ,  Atsushi Hashimoto

IPC分类号： C08K3/22 ,  C08K3/00 ,  C08K5/49 ,  C08K5/57 ,  C08L25/04 ,  C08L55/00 ,  C08L55/02 ,  C08K5/00

CPC分类号： C08K5/57

摘要： A colored styrenic resin composition comprises 100 parts by weight of a styrenic resin, 0.1 to 5 parts by weight of titanium oxide and 0.05 to 2.5 parts by weight of an organo-tin compound and in which the amount of the organo-tin compound is not less than 10% by weight on the basis of the amount of the titanium oxide. The resin composition ensures the production of injection-molded articles free of black streaks and, therefore, the articles formed from the resin composition of the invention have high commercial value. The colored styrenic resin composition is useful as a material for the production of housings of, for example, a variety of electric appliances and office machinery and equipment as well as miscellaneous goods.

摘要翻译： 有色苯乙烯树脂组合物包含100重量份苯乙烯树脂，0.1至5重量份氧化钛和0.05至2.5重量份有机锡化合物，其中有机锡化合物的量不是 基于氧化钛的量小于10重量％。 树脂组合物确保了没有黑色条纹的注塑制品的生产，因此，由本发明的树脂组合物形成的制品具有很高的商业价值。 有色苯乙烯树脂组合物可用作生产例如各种电器，办公机器和设备以及杂货的外壳的材料。

公开(公告)号：US5506304A

公开(公告)日：1996-04-09

申请号：US264911

申请日：1994-06-24

申请人： Shiro Otsuzuki ,  Mune Iwamoto ,  Akihiko Nakajima ,  Masato Takaku ,  Hisao Morita ,  Takao Kobayashi ,  Toshihiko Ando

发明人： Shiro Otsuzuki ,  Mune Iwamoto ,  Akihiko Nakajima ,  Masato Takaku ,  Hisao Morita ,  Takao Kobayashi ,  Toshihiko Ando

IPC分类号： C08F279/02 ,  C08L55/02

CPC分类号： C08F279/02 ,  Y10S525/942

摘要： A process for continuously preparing rubber modified styrene resins from styrene monomers and acrylonitryle monomers in the presence of a rubbery polymer in accordance with a continuous mass and/or solution polymerization method by the use of serial polymerization device comprising two or more reactors; said process comprising(1) a first step of feeding a polymeric materials to the first reactor to carry out the polymerization of monomers in a condition where the rubbery polymer is not inverted to the dispersed phase, and a second step of adding a polymeric materials to second reactors to carry out the polymerization of the monomers and to thus invert the rubbery polymer to the dispersed phase,(2) a ratio of the added materials to the materials used in the first step being in the range of from 10 to 220% by weight,whereby impact resistance and surface gloss can be remarkably improved.

摘要翻译： 根据连续质量和/或溶液聚合方法，通过使用包含两个或多个反应器的连续聚合装置，在橡胶状聚合物存在下，从苯乙烯单体和丙烯腈单体连续制备橡胶改性苯乙烯树脂的方法; 所述方法包括（1）在橡胶状聚合物不反转到分散相的状态下将聚合物材料供给到第一反应器以进行单体的聚合的第一步骤，以及将聚合物材料添加到 第二反应器进行单体的聚合，从而将橡胶状聚合物反转到分散相，（2）第一步中使用的材料与所用材料的比例在10-220％的范围内由 重量，从而可以显着提高耐冲击性和表面光泽度。

公开(公告)号：US5891962A

公开(公告)日：1999-04-06

申请号：US527718

申请日：1995-09-13

申请人： Shiro Otsuzuki ,  Mune Iwamoto ,  Akihiko Nakajima ,  Masato Takaku ,  Hisao Morita ,  Koji Kawano

发明人： Shiro Otsuzuki ,  Mune Iwamoto ,  Akihiko Nakajima ,  Masato Takaku ,  Hisao Morita ,  Koji Kawano

IPC分类号： C08F287/00 ,  C08L25/14 ,  C08L53/02 ,  C08L33/10 ,  C08F279/06

CPC分类号： C08F287/00 ,  C08L25/14 ,  C08L53/02

摘要： A transparent, rubber-modified styrene resin comprises 70 to 96 parts by weight of a copolymer formed of 20 to 70 wt. % of styrene monomer units and 30 to 80 wt. % of alkyl (meth)acrylate monomer units and 4 to 30 parts by weight of a rubbery polymer. The rubbery polymer is dispersed in the copolymer as particles having an average particle size of 0.1 to 2.0 .mu.m. At least 70 wt. % of the rubbery polymer is a styrene-butadiene block copolymer which is formed of 5 to 50 wt. % of styrene units and 50 to 95 wt. % of butadiene units, has a viscosity in a range of 3 to 60 cps when measured as a 5 wt. % styrene solution at 25.degree. C. and possesses a ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) in a range of 1.0 to 1.8. The copolymer and the rubbery polymer have substantially the same refractive index. Also disclosed is a production process of the transparent, rubber-modified styrene resin, which comprises polymerizing a styrene monomer and an alkyl (meth)acrylate to a high degree of polymerized conversion in the presence of the rubbery polymer so that the rubbery polymer is formed into particles while allowing the copolymer to occur with substantially the same refractive index as the rubbery polymer.

摘要翻译： 透明的橡胶改性苯乙烯树脂包含70至96重量份由20至70重量％ ％的苯乙烯单体单元和30〜80wt。 ％的（甲基）丙烯酸烷基酯单体单元和4至30重量份的橡胶状聚合物。 将橡胶状聚合物作为平均粒径为0.1〜2.0μm的粒子分散在共聚物中。 至少70wt。 橡胶状聚合物的％为苯乙烯 - 丁二烯嵌段共聚物，其为5〜50重量％ ％的苯乙烯单元和50至95wt。 丁二烯单元的％，当测量为5重量％时，其粘度在3至60cps的范围内。 ％苯乙烯溶液，并且具有在1.0至1.8的范围内的重均分子量（Mw）与数均分子量（Mn）之比（Mw / Mn）。 共聚物和橡胶状聚合物具有基本上相同的折射率。 还公开了透明橡胶改性苯乙烯树脂的制造方法，其包括在橡胶状聚合物的存在下使苯乙烯单体和（甲基）丙烯酸烷基酯聚合成高聚合转化率，从而形成橡胶状聚合物 同时使共聚物以与橡胶状聚合物基本相同的折射率发生。

公开(公告)号：US5473014A

公开(公告)日：1995-12-05

申请号：US34411

申请日：1993-03-19

申请人： Toshihiko Ando ,  Mune Iwamoto ,  Masahiro Kaneko ,  Kouzou Ichikawa ,  Akihiko Nakajima ,  Masato Takaku

发明人： Toshihiko Ando ,  Mune Iwamoto ,  Masahiro Kaneko ,  Kouzou Ichikawa ,  Akihiko Nakajima ,  Masato Takaku

IPC分类号： C08F287/00 ,  C08L51/04 ,  C08L53/02

CPC分类号： C08F287/00 ,  Y10S525/902

摘要： A rubber modified styrenic resin composition which can be obtained by dispersing rubber-like polymer particles in a homopolymer or a copolymer of a styrenic monomer. The rubber modified styrenic resin composition has:(a) a volume-average particle size of the rubber-like polymer particles is in the range of from 0.2 to 0.8 .mu.m,(b) a particle size distribution curve on the basis of the volume of the rubber-like polymer particles has one peak,(c) a ratio of a 5% value to a 95% value of the cumulative distribution of the particle size on the basis of the volume of the rubber-like polymer particles is in the range of from 3 to 45.The rubber-like polymer particles comprise (i) a styrene-butadiene block copolymer (I), and (ii)(1) a styrene-butadiene block copolymer (II), (2) a polybutadiene (III), or (3) a styrene-butadiene block copolymer (IV) and polybutadiene (V), wherein (I) contains 25-50 % styrene, (II) and (IV) contain 5-20% styrene, the weight ratio of: (I)/(II), (I)/(III) and (I)/(IV) is from 95/5 to 40/60 and {(I)+(IV)}/(V) is from 99/1 to 70/30 and (I) to (V) are of specified styrene solution viscosity.

摘要翻译： 橡胶改性苯乙烯树脂组合物，其可以通过将橡胶状聚合物颗粒分散在苯乙烯类单体的均聚物或共聚物中而获得。 橡胶改性苯乙烯树脂组合物具有：（a）橡胶状聚合物粒子的体积平均粒径在0.2〜0.8μm的范围内，（b）基于体积的粒径分布曲线 的橡胶状聚合物颗粒具有一个峰，（c）基于橡胶状聚合物颗粒的体积，5％值与粒径的累积分布的95％的比率在 橡胶状聚合物颗粒包含（i）苯乙烯 - 丁二烯嵌段共聚物（I）和（ii）（1）苯乙烯 - 丁二烯嵌段共聚物（II），（2）聚丁二烯（ III）或（3）苯乙烯 - 丁二烯嵌段共聚物（IV）和聚丁二烯（V），其中（I）含有25-50％苯乙烯，（II）和（IV）含有5-20％苯乙烯，重量比 的（I）/（II），（I）/（III）和（I）/（IV）为95/5至40/60，{（I）+（IV）} /（V） 99/1至70/30和（I）至（V）具有规定的苯乙烯溶液粘度。

公开(公告)号：US6060564A

公开(公告)日：2000-05-09

申请号：US574682

申请日：1995-12-19

申请人： Mutsuko Uchida ,  Mune Iwamoto ,  Akihiko Nakajima ,  Masato Takaku ,  Hisato Morita ,  Koji Kawano

发明人： Mutsuko Uchida ,  Mune Iwamoto ,  Akihiko Nakajima ,  Masato Takaku ,  Hisato Morita ,  Koji Kawano

IPC分类号： B01J19/00 ,  B01J19/18 ,  C08F2/00 ,  C08F2/04 ,  C08F4/32 ,  C08F20/44 ,  C08F255/06 ,  C08F279/02 ,  C08F291/02 ,  C08F2/02

CPC分类号： C08F279/02 ,  B01J19/0013 ,  B01J19/18 ,  C08F20/44 ,  C08F255/06 ,  C08F291/02 ,  B01J2219/00063 ,  B01J2219/00094 ,  B01J2219/00162 ,  B01J2219/00168 ,  B01J2219/00182 ,  B01J2219/00184

摘要： A process for the (co)polymerization of a monomer material, which includes at least an acrylonitrile monomer as an essential component, at a temperature of 80.degree. C. or higher by bulk or solution polymerization while allowing said monomer material to evaporate. The (co)polymerization is conducted while providing a vapor phase over a polymerization mixture in a reaction tank. During the (co)polymerization, the temperature of the vapor phase is maintained in a range of from 30.degree. C. to 65.degree. C. so that the polymerization is conducted without substantially releasing vapor, which is evaporated from the polymerization mixture, to outside of the reaction tank. By cooling the vapor phase of the reaction tank and maintaining its temperature in the above specific range in accordance with the present invention, it is possible to avoid mixing of a gelled polymer in a product and also to effectively remove reaction heat at the time of the (co)polymerization.

摘要翻译： 通过本体或溶液聚合在80℃或更高的温度下使包含至少一种丙烯腈单体作为必要组分的单体材料（共）聚合同时允许所述单体材料蒸发的方法。 （共）聚合，同时在反应罐中的聚合混合物上提供气相。 在（共）聚合期间，气相的温度保持在30℃至65℃的范围内，使得聚合反应进行而基本上不会将从聚合混合物蒸发的蒸气释放到外部 的反应罐。 通过根据本发明冷却反应槽的气相并将其温度维持在上述特定范围内，可以避免凝胶聚合物在产物中的混合，并且还有效地除去反应釜中的反应热 （共）聚合。

公开(公告)号：US5552494A

公开(公告)日：1996-09-03

申请号：US361489

申请日：1994-12-22

申请人： Mune Iwamoto ,  Akihiko Nakajima ,  Masato Takaku ,  Hisao Morita ,  Toshihiko Ando ,  Tomofumi Shirafuji ,  Mutsuko Uchida

发明人： Mune Iwamoto ,  Akihiko Nakajima ,  Masato Takaku ,  Hisao Morita ,  Toshihiko Ando ,  Tomofumi Shirafuji ,  Mutsuko Uchida

IPC分类号： C08F6/00 ,  C08F279/04 ,  C08L55/02 ,  C08L51/04

CPC分类号： C08L55/02 ,  C08F279/04 ,  C08F6/001

摘要： A molding of an ABS-based resin is described. Rubber particles located at a depth of 0.5-1.5 .mu.m from a surface of the molding morphologically comprise at least the following two types of particles:(1) A particles having an a/b ratio not greater than 1.5, wherein a and b represent a major axis and a minor axis, respectively, and(2) B particles having an a/b ratio not smaller than 5, wherein a and b have the same meanings as defined abovewhen a section extending at the depth in parallel with the surface of the molding is observed in an electron micrograph taken by the ultrathin sectioning technique. Assuming that the total area of the rubber particles as observed in the electron micrograph is 100%, the total area of the A particles accounts for at least 10% and that of the B particles is in a range of 0.01-90%.

摘要翻译： 对ABS系树脂的成型进行说明。 至少形成以下两种类型的颗粒的至少一部分形成在距成型体表面0.5-1.5μm深的橡胶颗粒：（1）a / b比不大于1.5的颗粒，其中a和b表示 分别为长轴和短轴，（2）a / b比不小于5的B颗粒，其中a和b具有与上述相同的含义，当在与表面平行的深度处延伸的部分 在通过超薄切片技术拍摄的电子显微镜照片中观察到成型。 假设在电子显微镜照片中观察到的橡胶颗粒的总面积为100％，则A颗粒的总面积至少为10％，B颗粒的总面积在0.01-90％的范围内。

公开(公告)号：US4808661A

公开(公告)日：1989-02-28

申请号：US899867

申请日：1986-08-25

申请人： Mune Iwamoto ,  Norifumi Ito ,  Kazuo Sugazaki ,  Tetsuyuki Matsubara ,  Toshihiko Ando

发明人： Mune Iwamoto ,  Norifumi Ito ,  Kazuo Sugazaki ,  Tetsuyuki Matsubara ,  Toshihiko Ando

IPC分类号： C08L23/06 ,  C08F279/02 ,  C08L23/10 ,  C08L25/00 ,  C08L25/12 ,  C08L35/06 ,  C08L51/04 ,  C08L55/02 ,  C08L55/04

CPC分类号： C08L35/06 ,  C08F279/02 ,  C08L25/12 ,  C08L51/04 ,  C08L55/02

摘要： The invention provides a rubber dispersed copolymer resin having excellent heat resistance, impact strength and moldability and composed of (1) a dispersed phase formed of a rubbery polymer and copolymerized styrene-type, acrylonitrile-type and maleimide-type monomers, said rubbery polymer specifically controlled occluding the copolymer of monomers, being grafted with the copolymer and/or forming a multicomponent gel together with copolymers, and (2) a continuous phase formed at least of a specifically controlled copolymer of the styrenetype, acrylonitrile-type and maleimide-type monomers. The resin is useful as a molding material for electric appliances, electronic equipment and cars.

摘要翻译： 本发明提供了具有优异的耐热性，冲击强度和成型性的橡胶分散共聚物树脂，它由（1）由橡胶状聚合物和共聚苯乙烯型丙烯腈 - 型马来酰亚胺型单体形成的分散相组成，所述橡胶状聚合物特别 控制阻塞共聚物与共聚物接枝和/或与共聚物一起形成多组分凝胶，和（2）至少形成苯乙烯类，丙烯腈型和马来酰亚胺型单体的特异性控制共聚物的连续相 。 该树脂可用作电器，电子设备和汽车的成型材料。

公开(公告)号：US4460278A

公开(公告)日：1984-07-17

申请号：US337765

申请日：1982-01-07

申请人： Tetsuyuki Matsubara ,  Norifumi Ito ,  Yuzuru Ishida ,  Mune Iwamoto ,  Tetsuo Maeda

发明人： Tetsuyuki Matsubara ,  Norifumi Ito ,  Yuzuru Ishida ,  Mune Iwamoto ,  Tetsuo Maeda

IPC分类号： C08F2/00 ,  B01F7/00 ,  B01F7/24 ,  B01J19/18 ,  C08F2/02 ,  B01F15/06

CPC分类号： B01J19/18 ,  B01F7/00908 ,  B01F7/248 ,  B01J2219/00094 ,  B01J2219/00779 ,  B01J2219/185

摘要： Disclosed is a continuous bulk polymerization reactor comprising a cylindrical reaction vessel elongated in the direction of the reacting fluid and a shaft installed within the reaction vessel. A plurality of flow of double helical-ribbon agitators are attached to the shaft in such a way that they face in the same direction, and a plurality of baffles having a relative open area of 5 to 40% based on the cross-sectional area of the internal space of the reaction vessel, are disposed between any adjacent ones of the agitators. Thus the formation of stagnant fluid pockets is avoided and excellent piston flow properties are achieved.

摘要翻译： 公开了一种连续本体聚合反应器，其包括在反应流体的方向上延伸的圆柱形反应容器和安装在反应容器内的轴。 多个双螺旋带搅拌器的流动以这样的方式附接到轴上，使得它们面向相同的方向，并且多个挡板的相对开口面积为5至40％，基于横截面积 反应容器的内部空间设置在任何相邻的搅拌器之间。 因此避免了滞留流体袋的形成，并且实现了优异的活塞流动特性。

公开(公告)号：US6124426A

公开(公告)日：2000-09-26

申请号：US160061

申请日：1998-09-24

申请人： Ryuichi Sugimoto ,  Koji Kawano ,  Hiroya Honda ,  Mune Iwamoto ,  Shiro Otsuzuki ,  Kenichiro Matsuba ,  Tetsuo Maeda ,  Yozo Maeda

发明人： Ryuichi Sugimoto ,  Koji Kawano ,  Hiroya Honda ,  Mune Iwamoto ,  Shiro Otsuzuki ,  Kenichiro Matsuba ,  Tetsuo Maeda ,  Yozo Maeda

IPC分类号： C08F6/00 ,  C08F6/28

CPC分类号： C08F6/28 ,  C08F6/005

摘要： A method for removing volatile materials, comprises adding a blowing aid to a polymer composition containing volatile materials, mixing them in a static mixing apparatus, and extruding the resultant mixture by an extruding apparatus into a devolatilizing tank, thereby the mixture is made to be blown, to cause removal of the volatile materials. First, the blowing aid (6) is discharged with an addition nozzle apparatus (2), in a direction opposite to the direction of the flow of the polymer composition (1), to be added, and the polymer composition is introduced into the static mixing apparatus (3), at a pressure at which the blowing does not take place, thereby mixing them. Then, using the extruding apparatus (11), the resultant mixture is extruded into the devolatilizing tank (4), so that the polymer is made into a blown product at such a temperature and a pressure that the blowing coefficient B is 1.4 or more, thereby causing the removal of volatile materials.B=A'/A Expression (1)wherein A represents the cross-sectional area of an extruding apparatus, and A' represents the average cross-sectional area of the polymer composition in a direction perpendicular to the vertical direction of the blown polymer composition, at a point where the polymer composition is dropped from the lower part of an opening section of the extruding apparatus vertically 50 cm to 1 m. The method can give a polymer composition having residual volatile materials in very small amounts, by removing volatile materials continuously with high efficiency.

摘要翻译： 一种除去挥发性物质的方法，包括向含有挥发性物质的聚合物组合物中加入发泡助剂，将其混合在静态混合装置中，并通过挤出装置将所得混合物挤出到脱挥发分槽中，从而将混合物吹制 ，以除去挥发性物质。 首先，用添加喷嘴装置（2）沿着与聚合物组合物（1）的流动方向相反的方向排出吹塑助剂（6），并将聚合物组合物引入静态 混合装置（3）在不发生吹塑的压力下进行混合。 然后，使用挤出装置（11）将所得混合物挤出到脱挥发分槽（4）中，使得在吹塑系数B为1.4以上的温度和压力下将聚合物制成吹塑制品， 从而导致挥发性物质的去除。B = A'/ A表达式（1）其中A表示挤出装置的横截面积，A'表示聚合物组合物在垂直于...的方向上的平均横截面积 在聚合物组合物从挤出设备的开口部分的下部垂直延伸50cm至1μm的点处，吹塑聚合物组合物的垂直方向。 该方法可以通过以高效率连续除去挥发性物质，得到非常少的具有残留挥发性物质的聚合物组合物。

公开(公告)号：US5210132A

公开(公告)日：1993-05-11

申请号：US961026

申请日：1992-10-14

申请人： Tetsuyuki Matsubara ,  Norifumi Ito ,  Mune Iwamoto ,  Kazuo Sugazaki ,  Toshihiko Ando ,  Yasuo Furuta ,  Kouzo Ichikawa ,  Hitoshi Ozawa

发明人： Tetsuyuki Matsubara ,  Norifumi Ito ,  Mune Iwamoto ,  Kazuo Sugazaki ,  Toshihiko Ando ,  Yasuo Furuta ,  Kouzo Ichikawa ,  Hitoshi Ozawa

IPC分类号： C08F279/02 ,  C08F291/02

CPC分类号： C08F291/02 ,  C08F279/02

摘要： A process for preparing rubber modified high impact resins by dissolving a rubbery polymer in a monomer containing an aromatic vinyl monomer or a mixture of an aromatic vinyl monomer and a vinyl cyanide monomer followed by polymerizing the monomer, the two steps being carried out in at least two polymerization reactors with a particle disperser placed between the first and second reactors. High impact resins having excellent surface properties are obtained with a savings in a power consumption by controlling:(1) the relationship between the concentration of the polymerized monomer and the content of the rubbery polymer in the first reactor;(2) the relationship between the volume occupied by the polymerizing liquid in the first reactor and the inner volume of the particle disperser; and(3) the peripheral linear velocity of a shearing stirrer in the particle disperser.

摘要翻译： 通过将橡胶状聚合物溶解在含有芳族乙烯基单体或芳香族乙烯基单体和乙烯基氰单体的混合物的单体中，然后使单体聚合，制备橡胶改性的高冲击性树脂的方法，这两个步骤至少进行 两个具有放置在第一和第二反应器之间的分散器的聚合反应器。 通过控制：（1）聚合单体的浓度与第一反应器中橡胶状聚合物的含量之间的关系，可以节省功耗，获得具有优异表面性能的高冲击性树脂; （2）第一反应器中的聚合液体占据的体积与粒子分散器的内体积之间的关系; 和（3）粒子分散器中的剪切搅拌器的外围线速度。