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公开(公告)号：US20120175816A1
公开(公告)日：2012-07-12
申请号：US13395181
申请日：2010-09-01
IPC分类号： B29C45/78
CPC分类号： B29C45/37 , B29C33/3828 , B29C45/0025 , B29C2033/023 , B29K2879/08 , B29K2995/0013
摘要： To provide a method for manufacturing an injection-molded article that can control an amount of flash generated during molding, and obtain a molded article of a high degree of crystallinity.In injection molding of a polyarylene sulfide resin composition, injection molding is performed using a mold having a heat-insulating layer formed on an inner surface of a mold, and at a mold temperature of 100° C. or less.It is preferable for the thermal layer to have a thermal conductivity ratio of 5 W/(m·K) or less.Furthermore, a composition including a polyimide resin can be exemplified as a preferable heat-insulating layer.The heat-insulating layer is preferably the one including a polyimide resin.
摘要翻译： 提供一种能够控制成型时产生的闪光量的注射成型品的制造方法，得到高结晶度的成型品。 在聚芳硫醚树脂组合物的注射成型中，使用在模具的内表面上形成的具有隔热层的模具和模具温度为100℃以下的模具进行注射成型。 热层的导热率优选为5W /（m·K）以下。 此外，作为优选的绝热层，可以列举出包含聚酰亚胺树脂的组合物。 绝热层优选为包含聚酰亚胺树脂的绝热层。
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公开(公告)号：US20130217855A1
公开(公告)日：2013-08-22
申请号：US13703841
申请日：2011-06-07
IPC分类号： B29C33/38
CPC分类号： B29C33/3842 , B29C45/0025 , B29C45/78 , B29C2033/023 , B29C2945/76618 , B29K2995/0041
摘要： Provided is a method for manufacturing a mold for manufacturing a molded article, by which not only is the occurrence of flash suppressed but also the crystallization of the surface is sufficiently accelerated when the mold temperature during the molding of a crystalline thermoplastic resin is set at Tc2−100° C. or less. Based on a relationship between crystallization rate and resin temperature of the crystalline thermoplastic resin, a temperature at which the crystalline thermoplastic resin filled into a mold has a sufficiently fast crystallization rate near a cavity surface and a retention time during which the crystalline thermoplastic resin in the mold is retained at a temperature equal to at least at a temperature at which the resin has the sufficiently fast crystallization rate are derived, such that the derived temperature and the derived retention time allow the molded article to have a surface whose crystallinity falls within a desired range, and a heat-insulating layer which, when mold temperature is Tc2−100° C. or less, allows a time, during which temperature near surface of the mold cavity is retained at no less than the derived temperature, to fulfill the derived retention time is provided.
摘要翻译： 本发明提供一种制造模制品的模具的方法，当结晶热塑性树脂成型时的模具温度设定为Tc2时，不仅抑制了闪光的发生而且表面的结晶也被充分加速 -100℃以下。 基于结晶热塑性树脂的结晶速度与树脂温度之间的关系，填充到模具中的结晶热塑性树脂的温度在空腔表面附近具有足够快的结晶速率，并且其中结晶热塑性树脂在 模具保持在至少等于树脂具有足够快的结晶速率的温度的温度，使得衍生的温度和得到的保留时间使得模制品具有结晶度落在所需的温度范围内的表面 范围和绝热层，当模具温度为Tc2-100℃以下时，允许在模具腔表面附近的温度保持不低于导出温度的时间，以实现衍生的 提供保留时间。
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3.发明申请METHOD FOR MANUFACTURING AN INJECTION-MOLDED ARTICLE AND AN INJECTION-MOLDED ARTICLE 审中-公开注射成型制品和注射成型品的制造方法公开(公告)号：US20140031518A1
公开(公告)日：2014-01-30
申请号：US14003000
申请日：2012-02-29
IPC分类号： B29C45/00
CPC分类号： B29C45/0001 , B29C33/56 , B29K2081/00 , B29K2909/00 , B29K2995/0015 , B29K2995/0041
摘要： Provided is a method for manufacturing an injection-molded article, where the method is capable of obtaining a molded article having a high crystallinity while reducing the amount of flash generated and has excellent productivity. A polyarylene sulfide-based resin composition is injection-molded at a mold temperature of 100° C. or less using a mold on the inner surface of which a heat-insulating layer constituted of porous zirconia is formed. It is preferable that the heat-insulating layer is formed by a spraying method. Preferably, the heat-insulating layer has a thermal conductivity of 2 W/(m·K) or less. Preferably, the heat-insulating layer has a thickness of no less than 200 μm.
摘要翻译： 本发明提供一种注塑制品的制造方法，该方法能够在减少产生的闪光量的同时获得具有高结晶度的成型品，并具有优异的生产率。 聚芳硫醚类树脂组合物在模具温度为100℃以下的模具中使用在其内表面上形成由多孔氧化锆构成的绝热层的模具注塑成型。 绝热层优选通过喷涂法形成。 优选地，绝热层的热导率为2W /（m·K）以下。 优选地，绝热层的厚度不小于200μm。
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公开(公告)号：US06758989B2
公开(公告)日：2004-07-06
申请号：US10181449
申请日：2002-07-18
申请人： Takayuki Miyashita , Toshio Nakane
发明人： Takayuki Miyashita , Toshio Nakane
IPC分类号： C09K1900
CPC分类号： C08L77/12 , C08K3/01 , C08K7/00 , Y10T403/45
摘要： The present invention is to provide a liquid crystal polymer molded article which has an excellent low warpage and is able to be suitably used particularly as a connector or the like. That is, a molded article of a liquid crystal composition in which 100 parts by weight of a liquid crystal polymer (A) and 5-100 parts by weight of a non-fibrous filler (B) are compounded where the non-fibrous filler is so dispersed that, when a diffraction peak of the non-fibrous filler is measured by a transmission method and a reflection method by means of a wide-angle X-ray diffraction, the diffraction peak of the non-fibrous filler which can be confirmed by the reflection method is not confirmed by the transmission method.
摘要翻译： 本发明提供一种液晶聚合物成型体，其具有优异的低翘曲性，并且能够特别适合地用作连接器等。 也就是说，将非纤维状填料为100重量份的液晶聚合物（A）和5〜100重量份的非纤维状填料（B）配合的液晶组合物的成型品 分散，当通过透射法和通过广角X射线衍射的反射法测量非纤维状填料的衍射峰时，非纤维状填料的衍射峰可以通过 反射方法未被传输方法确认。
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5.发明授权
公开(公告)号：US5863405A
公开(公告)日：1999-01-26
申请号：US284546
申请日：1994-08-08
申请人： Takayuki Miyashita
发明人： Takayuki Miyashita
CPC分类号： H05K3/108 , H05K3/027 , H05K1/0284 , H05K2201/09118 , H05K2203/0723 , H05K2203/107 , H05K3/181 , Y10T29/49165
摘要： Conductive circuits are formed by first metallizing a surface of a molded synthetic resin substrate to form an electrically conductive metallic film coating thereon of a thickness (e.g., between 0.2 to 2 .mu.m) effective to exhibit sufficient electrical conductivity for subsequent electroplating thereon. Non-circuit portions of the metallic film coating are thereafter removed with laser light so as to expose an underlying surface portion of the substrate and thereby form a circuit pattern on the substrate surface which is established by a portion of the metallic film remaining on the substrate surface. An additional metal layer may then be electroplated directly onto the remaining portion of the metallic film to thereby form the conductive circuit.
摘要翻译： PCT No.PCT / JP94 / 00799 Sec。 371日期1994年8月8日 102（e）日期1994年8月8日PCT 1994年5月18日PCT公布。 第WO95 / 31884号公报 日期1995年11月23日通过首先对模制的合成树脂基板的表面进行金属化以在其上形成厚度（例如，0.2至2μm）之间的导电金属膜涂层形成导电电路，从而对后续的 在其上电镀。 然后用激光去除金属膜涂层的非电路部分，以暴露衬底的下表面部分，从而在衬底表面上形成电路图案，该电路图案由残留在衬底上的金属膜的一部分 表面。 然后可以将额外的金属层直接电镀到金属膜的剩余部分上，从而形成导电电路。
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公开(公告)号：US20140035200A1
公开(公告)日：2014-02-06
申请号：US14003401
申请日：2012-02-29
IPC分类号： B29C45/73
CPC分类号： B29C45/73 , B29C33/56 , B29C45/0025 , B29C45/7207 , B29C2045/7356 , B29C2945/76618 , B29K2081/00 , B29K2995/0015 , C08L81/02
摘要： Provided is a technology that sufficiently suppresses dimensional change in the usage environment even without applying heat treatment in advance to a resin-molded article constituted of a crystalline thermoplastic resin. A resin composition constituted of a crystalline thermoplastic resin is injection-molded using a mold on the inner surface of which a heat-insulating layer is formed. It is preferable, in the present invention, to use a mold on which a heat-insulating layer is formed, the layer being constituted of porous zirconia formed by spraying method and having a thermal conductivity of 2 W/(m·K) or less and a thickness of no less than 200 μm. The injection-molded article obtained by the manufacturing method of the present invention has a dimensional change rate of 0.2% or less when left for 2 hours in an environment of a mold temperature+20° C. where the mold temperature is that at the time of injection molding and is Tg+30° C. or more and Tg+80° C. or less, in which Tg is a glass transition temperature of the crystalline thermoplastic resin.
摘要翻译： 即使没有对由结晶性热塑性树脂构成的树脂成型品进行预先加热处理，也能充分地抑制使用环境的尺寸变化。 由结晶性热塑性树脂构成的树脂组合物在其内表面上形成有绝热层的模具注射成型。 在本发明中，优选使用形成有绝热层的模具，该层由通过喷涂法形成的导热率为2W /（m·K）以下的多孔氧化锆构成， 厚度不小于200μm。 通过本发明的制造方法获得的注塑制品在模具温度+ 20℃的环境中放置2小时时的尺寸变化率为0.2％以下，其中模具温度为当时的温度 的Tg + 30℃以上，Tg + 80℃以下，Tg是结晶性热塑性树脂的玻璃化转变温度。
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公开(公告)号：US07547403B2
公开(公告)日：2009-06-16
申请号：US10562116
申请日：2004-06-30
申请人： Takayuki Miyashita , Takashi Usami
发明人： Takayuki Miyashita , Takashi Usami
CPC分类号： H01M8/0213 , B29C47/0009 , B29C47/92 , B29C2947/92161 , B29C2947/922 , B29C2947/92209 , B29C2947/92695 , B29C2947/92704 , B29L2031/3468 , C08L89/00 , C08L89/005 , C09K19/38 , C09K19/52 , H01B1/24 , H01M8/0221 , H01M8/0226 , Y02P70/56
摘要： To provide a resin material excellent in electric conductivity and judiciously usable in the manufacture of fuel cell separators and so forth. An electroconductive resin composition which comprises 100 parts by weight of a liquid-crystalline polymer (A) and 200 to 500 parts by weight of at least one species of graphite (B) selected from synthetic graphite, flake graphite and amorphous graphite with a fixed carbon content of not less than 95% by weight and an average particle size of 50 to 200 μm as incorporated in the polymer, the composition resulting from melt-kneading under such conditions that the ratio Q/N, where Q (kg) is the hourly extrusion throughput rate during kneading and N (rpm) is the screw revolution rate, may amount to 0.1 to 1.5, the composition having a volume resistivity of not more than 2×10−2 Ω·cm.
摘要翻译： 提供导电性优异且在制造燃料电池隔板等方面可靠使用的树脂材料。 一种导电树脂组合物，其包含100重量份的液晶聚合物（A）和200至500重量份的选自合成石墨，片状石墨和具有固定碳的无定形石墨的至少一种石墨（B） 包含在聚合物中的不小于95重量％，平均粒径为50-200μm的组合物，在Q（N）的比例为Q / N的条件下熔融捏合得到的组合物，其中Q 捏合时的挤出生产率和N（rpm）是螺杆转速，可以达到0.1至1.5，该组合物的体积电阻率不超过2×10 -2Ω·cm。
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公开(公告)号：US20070123633A1
公开(公告)日：2007-05-31
申请号：US10562116
申请日：2004-06-30
申请人： Takayuki Miyashita , Takashi Usami
发明人： Takayuki Miyashita , Takashi Usami
IPC分类号： C08K3/04
CPC分类号： H01M8/0213 , B29C47/0009 , B29C47/92 , B29C2947/92161 , B29C2947/922 , B29C2947/92209 , B29C2947/92695 , B29C2947/92704 , B29L2031/3468 , C08L89/00 , C08L89/005 , C09K19/38 , C09K19/52 , H01B1/24 , H01M8/0221 , H01M8/0226 , Y02P70/56
摘要： To provide a resin material excellent in electric conductivity and judiciously usable in the manufacture of fuel cell separators and so forth. An electroconductive resin composition which comprises 100 parts by weight of a liquid-crystalline polymer (A) and 200 to 500 parts by weight of at least one species of graphite (B) selected from synthetic graphite, flake graphite and amorphous graphite with a fixed carbon content of not less than 95% by weight and an average particle size of 50 to 200 μm as incorporated in the polymer, the composition resulting from melt-kneading under such conditions that the ratio Q/N, where Q (kg) is the hourly extrusion through put rate during kneading and N (rpm) is the screw revolution rate, may amount to 0.1 to 1.5, the composition having a volume resistivity of not more than 2×10−2 Ω·cm.
摘要翻译： 提供导电性优异且在制造燃料电池隔板等方面可靠使用的树脂材料。 一种导电树脂组合物，其包含100重量份的液晶聚合物（A）和200至500重量份的选自合成石墨，片状石墨和具有固定碳的无定形石墨的至少一种石墨（B） 包含在聚合物中的不小于95重量％，平均粒径为50-200μm的组合物，在Q（N）的比例为Q / N的条件下熔融捏合得到的组合物，其中Q 捏合时的挤出速度为N（rpm），螺杆转速为0.1〜1.5，体积电阻率为2×10 -2Ω·cm以下。
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公开(公告)号：US20140263943A1
公开(公告)日：2014-09-18
申请号：US14342576
申请日：2012-08-30
IPC分类号： B29C45/00
CPC分类号： B29C45/00 , B29C33/38 , B29C33/3828 , B29C45/37 , B29C2033/023 , B29K2995/0015
摘要： Provided is a technology for solving the drawback such as chipping of a heat-insulating layer which is caused by the contact of a heat-insulating layer formed on a first mold with a second mold at the mold parting surface. A mold divided into two or more is provided in which a heat-insulating layer is formed on a substantially entire surface of an inner wall surface of the mold, and the heat-insulating layer does not exist on a mold parting surface. For example, the mold is provided with a first mold occupying a majority of a cavity and a second mold which forms at least a part of the cavity together with the first mold, in which the first mold is provided with a flange part, and a part of a surface of the flange part constitutes a part of the mold parting surface.
摘要翻译： 提供了一种解决由在模具分型面上与第一模具形成的隔热层与第二模具接触而导致的绝热层的切屑等缺点的技术。 提供分为两个或更多个的模具，其中在模具的内壁表面的大致整个表面上形成绝热层，并且绝热层不存在于模具分型面上。 例如，模具设置有占据空腔的大部分的第一模具和与第一模具一起形成空腔的至少一部分的第二模具，其中第一模具设置有凸缘部分，并且 凸缘部分的表面的一部分构成模具分离表面的一部分。
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公开(公告)号：US20140217638A1
公开(公告)日：2014-08-07
申请号：US14241467
申请日：2012-08-30
IPC分类号： B29C45/73
CPC分类号： B29C45/73 , B29C33/02 , B29C33/442 , B29C45/40 , B29C2033/023 , B29C2033/3864
摘要： Provided is a technology for suppressing, in a mold having a heat-insulating layer formed therein, a problem of chipping of the heat-insulating layer and the like even when a penetrating member is inserted through a through-hole provided in the mold. The mold is provided with a mold body having a convex part on an inner wall surface of the mold body, a heat-insulating layer arranged on the inner wall surface, and a through-hole which penetrates the convex part in a thickness direction of the mold body and through which the penetrating member can be inserted. An outer periphery of the through-hole is inside an outer periphery of a top surface of the convex part. A spacing between the outer periphery of the through-hole on the top surface of the convex part and the outer periphery of the top surface of the convex part is preferably 0.5 mm or less.
摘要翻译： 在通过设置在模具中的通孔插入穿透构件的情况下，提供了在具有形成有绝热层的模具中抑制绝热层等的问题的技术。 模具设置有在模具体的内壁面上具有凸部的模具体，配置在内壁面上的绝热层，以及贯通孔的厚度方向的凸部的贯通孔 模具主体，并且穿透构件可以穿过其插入。 通孔的外周在凸部的顶面的外周的内侧。 凸部的上表面的通孔的外周与凸部的上表面的外周之间的间隔优选为0.5mm以下。
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