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1.发明申请METHOD AND APPARATUS FOR DETERMINING THE LENGTH OF SINGLE-WALLED CARBON NANOTUBES 失效用于确定单壁碳纳米管长度的方法和装置公开(公告)号：US20050160798A1
公开(公告)日：2005-07-28
申请号：US10836551
申请日：2004-04-30
申请人： Matteo Pasquali , Virginia Davis , Ingrid Stepanek-Basset , A. Nicholas Parra-Vasquez , Robert Hauge
发明人： Matteo Pasquali , Virginia Davis , Ingrid Stepanek-Basset , A. Nicholas Parra-Vasquez , Robert Hauge
CPC分类号： B82Y30/00 , B82Y15/00 , B82Y40/00 , C01B32/15 , C01B2202/02 , C01B2202/34 , G01N11/00 , Y10S977/88
摘要： The present invention is directed to at least one method and at least one apparatus for determining the length of single-wall carbon nanotubes (SWNTs). The method generally comprises the steps of: dispersing a sample of SWNTs into a suitable dispersing medium to form a solvent-suspension of solvent-suspended SWNTs; determining the mean SWNT diameter of the solvent-suspended SWNTs; introducing the solvent-suspended SWNTs into a viscosity-measuring device; obtaining a specific viscosity for the SWNT solvent-suspension; and determining the length of the SWNTs based upon the specific viscosity by solving, for example, the Kirkwood-Auer equation corrected by Batchelor's formula for the drag on a slender cylinder for “L,” to determine the length of the SWNTs. The apparatus generally comprises: a SWNT sample introduction mechanism; a dispersal chamber; a SWNT radius-determination chamber; and a viscosity determining chamber, wherein the SWNT sample introduction mechanism, the dispersal chamber, the SWNT radius-determination chamber, and the viscosity determination chamber are each operatively connected to at least one of the others.
摘要翻译： 本发明涉及用于确定单壁碳纳米管（SWNT）的长度的至少一种方法和至少一种装置。 该方法通常包括以下步骤：将SWNT样品分散到合适的分散介质中以形成溶剂悬浮的SWNT的溶剂 - 悬浮液; 确定溶剂悬浮的SWNT的平均SWNT直径; 将溶剂悬浮的SWNT引入粘度测量装置中; 获得SWNT溶剂 - 悬浮液的比粘度; 以及通过解决例如通过Batchelor公式修正的Kirkwood-Auer方程式来确定SWNTs的长度，以便通过在“L”的细长圆筒上拖动来确定SWNT的长度。 该装置通常包括：SWNT样品引入机构; 分散室; SWNT半径测定室; 和粘度确定室，其中SWNT样品引入机构，分散室，SWNT半径确定室和粘度确定室各自可操作地连接到至少其中之一。
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公开(公告)号：US08591854B2
公开(公告)日：2013-11-26
申请号：US12672605
申请日：2008-08-08
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/15 , C01B32/152
摘要： We have discovered that size dependent solubility of large fullerenes in strong acids is dependent on acid strength. This provides a scalable method for separating large fullerenes by size. According to some embodiments, a method for processing a fullerene starting material comprises large fullerenes comprises mixing the starting material with a first concentrated sulfuric acid solution so as to obtain a first dispersion comprising a first portion of the large fullerenes solubilized in the first concentrated sulfuric acid solution.
摘要翻译： 我们已经发现大富勒烯在强酸中的尺寸依赖性溶解度取决于酸强度。 这提供了一种用于按大小分离大富勒烯的可扩展方法。 根据一些实施方案，用于处理富勒烯起始材料的方法包括大的富勒烯，包括将起始材料与第一浓硫酸溶液混合，以获得第一分散体，其包含溶解在第一浓硫酸中的第一部分富勒烯 解。
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公开(公告)号：US20110318248A1
公开(公告)日：2011-12-29
申请号：US12672605
申请日：2008-08-08
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/15 , C01B32/152
摘要： We have discovered that size dependent solubility of large fullerenes in strong acids is dependent on acid strength. This provides a scalable method for separating large fullerenes by size. According to some embodiments, a method for processing a fullerene starting material comprises large fullerenes comprises mixing the starting material with a first concentrated sulfuric acid solution so as to obtain a first dispersion comprising a first portion of the large fullerenes solubilized in the first concentrated sulfuric acid solution.
摘要翻译： 我们已经发现大富勒烯在强酸中的尺寸依赖性溶解度取决于酸强度。 这提供了一种用于按大小分离大富勒烯的可扩展方法。 根据一些实施方案，用于处理富勒烯起始材料的方法包括大的富勒烯，包括将起始材料与第一浓硫酸溶液混合，以获得第一分散体，其包含溶解在第一浓硫酸中的第一部分富勒烯 解。
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4.发明授权Method and apparatus for determining the length of single-walled carbon nanotubes 失效用于确定单壁碳纳米管长度的方法和装置公开(公告)号：US06962092B2
公开(公告)日：2005-11-08
申请号：US10836551
申请日：2004-04-30
申请人： Matteo Pasquali , Virginia A. Davis , Ingrid Stepanek-Basset , A. Nicholas G. Parra-Vasquez , Robert H. Hauge
发明人： Matteo Pasquali , Virginia A. Davis , Ingrid Stepanek-Basset , A. Nicholas G. Parra-Vasquez , Robert H. Hauge
CPC分类号： B82Y30/00 , B82Y15/00 , B82Y40/00 , C01B32/15 , C01B2202/02 , C01B2202/34 , G01N11/00 , Y10S977/88
摘要： The present invention is directed to at least one method and at least one apparatus for determining the length of single-wall carbon nanotubes (SWNTs). The method generally comprises the steps of: dispersing a sample of SWNTs into a suitable dispersing medium to form a solvent-suspension of solvent-suspended SWNTs; determining the mean SWNT diameter of the solvent-suspended SWNTs; introducing the solvent-suspended SWNTs into a viscosity-measuring device; obtaining a specific viscosity for the SWNT solvent-suspension; and determining the length of the SWNTs based upon the specific viscosity by solving, for example, the Kirkwood-Auer equation corrected by Batchelor's formula for the drag on a slender cylinder for “L,” to determine the length of the SWNTs. The apparatus generally comprises: a SWNT sample introduction mechanism; a dispersal chamber; a SWNT radius-determination chamber; and a viscosity determining chamber, wherein the SWNT sample introduction mechanism, the dispersal chamber, the SWNT radius-determination chamber, and the viscosity determination chamber are each operatively connected to at least one of the others.
摘要翻译： 本发明涉及用于确定单壁碳纳米管（SWNT）的长度的至少一种方法和至少一种装置。 该方法通常包括以下步骤：将SWNT样品分散到合适的分散介质中以形成溶剂悬浮的SWNT的溶剂 - 悬浮液; 确定溶剂悬浮的SWNT的平均SWNT直径; 将溶剂悬浮的SWNT引入粘度测量装置中; 获得SWNT溶剂 - 悬浮液的比粘度; 以及通过解决例如通过Batchelor公式修正的Kirkwood-Auer方程式来确定SWNTs的长度，以便通过在“L”的细长圆筒上拖动来确定SWNT的长度。 该装置通常包括：SWNT样品引入机构; 分散室; SWNT半径测定室; 和粘度确定室，其中SWNT样品引入机构，分散室，SWNT半径确定室和粘度确定室各自可操作地连接到至少其中之一。
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5.发明授权Dissolution of graphite, graphite and graphene nanoribbons in superacid solutions and manipulation thereof 有权石墨，石墨烯和石墨烯纳米带在超强酸溶液中的溶解及其操作公开(公告)号：US09534319B2
公开(公告)日：2017-01-03
申请号：US13202352
申请日：2010-02-19
申请人： James M. Tour , Matteo Pasquali , Natnael Behabtu , Jay R. Lomeda , Dmitry V. Kosynkin , Amanda Duque , Micah J. Green , A. Nicholas Parra-Vasquez , Colin Young
发明人： James M. Tour , Matteo Pasquali , Natnael Behabtu , Jay R. Lomeda , Dmitry V. Kosynkin , Amanda Duque , Micah J. Green , A. Nicholas Parra-Vasquez , Colin Young
IPC分类号： C01B31/00 , C08L77/10 , C08L79/00 , D01F9/12 , B29C47/00 , B05D3/02 , C08K3/30 , C01B31/04 , B82Y30/00 , B82Y40/00 , D01D1/02 , D01D5/04
CPC分类号： D01D1/02 , B82Y30/00 , B82Y40/00 , C01B32/19 , C01B32/194 , C01B32/20 , C01B32/23 , D01D5/04 , D01F9/12
摘要： Methods for dissolving carbon materials such as, for example, graphite, graphite oxide, oxidized graphene nanoribbons and reduced graphene nanoribbons in a solvent containing at least one superacid are described herein. Both isotropic and liquid crystalline solutions can be produced, depending on the concentration of the carbon material The superacid solutions can be formed into articles such as, for example, fibers and films, mixed with other materials such as, for example, polymers, or used for functionalization of the carbon material. The superacid results in exfoliation of the carbon material to produce individual particles of the carbon material. In some embodiments, graphite or graphite oxide is dissolved in a solvent containing at least one superacid to form graphene or graphene oxide, which can be subsequently isolated. In some embodiments, liquid crystalline solutions of oxidized graphene nanoribbons in water are also described.
摘要翻译： 本文描述了将碳材料例如石墨，氧化石墨，氧化石墨烯纳米带和还原的石墨烯纳米带溶解在含有至少一种超强酸的溶剂中的方法。 根据碳材料的浓度，可以生产各向同性和液晶溶液。超强酸溶液可以形成为诸如纤维和薄膜的制品，与其它材料例如聚合物混合或使用 用于碳材料的官能化。 超强酸导致碳材料的剥离以产生碳材料的单个颗粒。 在一些实施方案中，将石墨或氧化石墨溶解在含有至少一种超强酸的溶剂中以形成石墨烯或氧化石墨烯，其可以随后分离。 在一些实施方案中，还描述了氧化石墨烯纳米带在水中的液晶溶液。
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6.发明申请Dissolution Of Graphite, Graphite And Graphene Nanoribbons In Superacid Solutions And Manipulation Thereof 有权石墨，石墨和石墨烯纳米带在超强酸溶液中的溶解及其操作公开(公告)号：US20120063988A1
公开(公告)日：2012-03-15
申请号：US13202352
申请日：2010-02-19
申请人： James M. Tour , Matteo Pasquali , Natnael Behabtu , Jay R. Lomeda , Dmitry V. Kosynkin , Amanda Duque , Micah J. Green , A. Nicholas Parra-Vasquez , Colin Young
发明人： James M. Tour , Matteo Pasquali , Natnael Behabtu , Jay R. Lomeda , Dmitry V. Kosynkin , Amanda Duque , Micah J. Green , A. Nicholas Parra-Vasquez , Colin Young
IPC分类号： C01B31/00 , C08L77/10 , C08L79/00 , D01F9/12 , B29C47/00 , B05D3/02 , C08K3/30 , C01B31/04 , B82Y30/00 , B82Y40/00
CPC分类号： D01D1/02 , B82Y30/00 , B82Y40/00 , C01B32/19 , C01B32/194 , C01B32/20 , C01B32/23 , D01D5/04 , D01F9/12
摘要： Methods for dissolving carbon materials such as, for example, graphite, graphite oxide, oxidized graphene nanoribbons and reduced graphene nanoribbons in a solvent containing at least one superacid are described herein. Both isotropic and liquid crystalline solutions can be produced, depending on the concentration of the carbon material The superacid solutions can be formed into articles such as, for example, fibers and films, mixed with other materials such as, for example, polymers, or used for functionalization of the carbon material. The superacid results in exfoliation of the carbon material to produce individual particles of the carbon material. In some embodiments, graphite or graphite oxide is dissolved in a solvent containing at least one superacid to form graphene or graphene oxide, which can be subsequently isolated. In some embodiments, liquid crystalline solutions of oxidized graphene nanoribbons in water are also described.
摘要翻译： 本文描述了将碳材料例如石墨，氧化石墨，氧化石墨烯纳米带和还原的石墨烯纳米带溶解在含有至少一种超强酸的溶剂中的方法。 根据碳材料的浓度，可以生产各向同性和液晶溶液。超强酸溶液可以形成为诸如纤维和薄膜的制品，与其它材料例如聚合物混合或使用 用于碳材料的官能化。 超强酸导致碳材料的剥离以产生碳材料的单个颗粒。 在一些实施方案中，将石墨或氧化石墨溶解在含有至少一种超强酸的溶剂中以形成石墨烯或氧化石墨烯，其可以随后分离。 在一些实施方案中，还描述了氧化石墨烯纳米带在水中的液晶溶液。
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7.发明申请Method for Producing Aligned Near Full Density Pure Carbon Nanotube Sheets, Ribbons, and Films From Aligned Arrays of as Grown Carbon Nanotube Carpets/Forests and Direct Transfer to Metal and Polymer Surfaces 审中-公开用于生成对称的近全密度纯碳纳米管片，丝带和从作为生长碳纳米管地毯/森林的对齐阵列的膜和直接转移到金属和聚合物表面的方法公开(公告)号：US20110262772A1
公开(公告)日：2011-10-27
申请号：US12671644
申请日：2008-07-31
申请人： Robert Hauge , Cary Pint , Ya-Qiong Xu , Matteo Pasquali
发明人： Robert Hauge , Cary Pint , Ya-Qiong Xu , Matteo Pasquali
CPC分类号： D01F9/12 , B29C43/22 , B29K2105/162 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C01B2202/08 , C08J5/005
摘要： Methods for preparing carbon nanotube layers are disclosed herein. Carbon nanotube layers may be films, ribbons, and sheets. The methods comprise preparing an aligned carbon nanotube array and compressing the array with a roller to create a carbon nanotube layer. Another method disclosed herein comprises preparing a carbon nanotube layer from an aligned carbon nanotube array grown on a grouping of lines of metallic catalyst. A composite material comprising at least one carbon nanotube layer and prepared by the process comprising a) compressing an aligned single-wall carbon nanotube array with a roller, and b) transferring the carbon nanotube layer to a polymer is also disclosed.
摘要翻译： 本文公开了制备碳纳米管层的方法。 碳纳米管层可以是膜，带和片。 所述方法包括制备对准的碳纳米管阵列并用辊压缩阵列以产生碳纳米管层。 本文公开的另一种方法包括从在一组金属催化剂上生长的排列的碳纳米管阵列制备碳纳米管层。 一种复合材料，其包含至少一个碳纳米管层，并通过包括以下步骤制备的方法制备：a）用辊压缩对齐的单壁碳纳米管阵列，和b）将碳纳米管层转移到聚合物上。
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8.发明申请NEAT CARBON NANOTUBE ARTICLES PROCESSED FROM SUPER ACID SOLUTIONS AND METHODS FOR PRODUCTION THEREOF 审中-公开从超酸溶液中处理的碳纳米管制品及其生产方法公开(公告)号：US20110110843A1
公开(公告)日：2011-05-12
申请号：US12740529
申请日：2008-10-29
申请人： Matteo Pasquali , Wen-Fang Hwang , Howard K. Schmidt , Natneal Behabtu , Virginia Davis , A. Nicholas G. Parra-Vasquez , Micah J. Green , Richard Booker , Colin c. Young , Hua Fan
发明人： Matteo Pasquali , Wen-Fang Hwang , Howard K. Schmidt , Natneal Behabtu , Virginia Davis , A. Nicholas G. Parra-Vasquez , Micah J. Green , Richard Booker , Colin c. Young , Hua Fan
CPC分类号： D01F11/12 , B29C48/0018 , B29C48/05 , B29C48/11 , B29C48/475 , B29C48/919 , B29K2105/162 , B29K2105/167 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/174 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C01B2202/28 , C01B2202/34 , D01D5/06 , D01F9/12
摘要： Articles comprising neat, aligned carbon nanotubes and methods for production thereof are disclosed. The articles and methods comprise extrusion of a super acid solution of carbon nanotubes followed by removal of the super acid solvent. The articles may be processed by wet-jet wet spinning, dry-jet wet spinning, and coagulant co-flow extrusion techniques.
摘要翻译： 公开了包含整齐排列的碳纳米管的制品及其生产方法。 制品和方法包括挤出碳纳米管的超酸溶液，然后除去超酸溶剂。 制品可以通过湿喷湿纺，干喷湿法纺丝和凝结剂共流挤出技术加工。
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公开(公告)号：US20090283405A1
公开(公告)日：2009-11-19
申请号：US12281444
申请日：2007-03-02
IPC分类号： C02F1/469
CPC分类号： B03C5/005 , B03C5/026 , B82Y30/00 , B82Y40/00 , C01B32/172 , C01B2202/02 , C01B2202/22 , Y10S977/742 , Y10S977/751
摘要： According to some embodiments, a method for separating a first fraction of a single wall carbon nanotubes and a second fraction of single wall carbon nanotubes includes, but is not limited to: flowing a solution comprising the nanotubes into a dielectrophoresis chamber; applying a DC voltage, in combination with an AC voltage, to the dielectrophoresis chamber; and collecting a first eluent from the dielectrophoresis chamber, wherein the first eluent comprises the first fraction and is depleted of the second fraction, wherein the first and second fractions differ by at least one of conductivity, diameter, length, and combinations thereof.
摘要翻译： 根据一些实施方案，用于分离单壁碳纳米管和第二部分单壁碳纳米管的第一部分的方法包括但不限于：将包含纳米管的溶液流动到介电电泳室中; 将DC电压与AC电压组合施加到介电电泳室; 以及从所述介电电泳腔室收集第一洗脱液，其中所述第一洗脱液包含所述第一馏分并且耗尽所述第二馏分，其中所述第一和第二馏分通过传导率，直径，长度及其组合中的至少一个而不同。
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公开(公告)号：US08097141B2
公开(公告)日：2012-01-17
申请号：US12281444
申请日：2007-03-02
IPC分类号： B03C5/02
CPC分类号： B03C5/005 , B03C5/026 , B82Y30/00 , B82Y40/00 , C01B32/172 , C01B2202/02 , C01B2202/22 , Y10S977/742 , Y10S977/751
摘要： According to some embodiments, a method for separating a first fraction of a single wall carbon nanotubes and a second fraction of single wall carbon nanotubes includes, but is not limited to: flowing a solution comprising the nanotubes into a dielectrophoresis chamber; applying a DC voltage, in combination with an AC voltage, to the dielectrophoresis chamber; and collecting a first eluent from the dielectrophoresis chamber, wherein the first eluent comprises the first fraction and is depleted of the second fraction, wherein the first and second fractions differ by at least one of conductivity, diameter, length, and combinations thereof.
摘要翻译： 根据一些实施方案，用于分离单壁碳纳米管和第二部分单壁碳纳米管的第一部分的方法包括但不限于：将包含纳米管的溶液流动到介电电泳室中; 将DC电压与AC电压组合施加到介电电泳室; 以及从所述介电电泳腔室收集第一洗脱液，其中所述第一洗脱液包含所述第一馏分并且耗尽所述第二馏分，其中所述第一和第二馏分通过传导率，直径，长度及其组合中的至少一个而不同。
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