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公开(公告)号：US5384377A
公开(公告)日：1995-01-24
申请号：US197527
申请日：1994-02-16
IPC分类号： C08G63/68 , C08G63/685 , C08G63/688 , C08J5/00 , C08K5/35 , C08K5/43 , C08L67/00 , C08L67/02 , C09B67/22 , C08F20/38
CPC分类号： C08G63/6856 , C08G63/6886 , C09B67/0038 , Y10T428/1352 , Y10T428/1397
摘要： This invention provides certain blue substituted 1,4-bis(2,6-dialkylanilino) anthraquinones in combination with selected red anthraquinone and anthrapyridone (3H-dibenz[f,ij]isoquinoline-2,7-dione) compounds which provide a toner system useful in imparting a desirable neutral to slightly blue hue to polyesters having a yellow appearance. The thermally stable colored compounds can have polyester reactive groups and are preferably incorporated into the polyester polymer structure during polymerization.
摘要翻译： 本发明提供了一些蓝色取代的1,4-双（2,6-二烷基苯胺基）蒽醌与选择的红色蒽醌和蒽吡啶酮（3H-二苯并[f，ij]异喹啉-2,7-二酮）化合物的组合，其提供调色剂体系 可用于赋予具有黄色外观的聚酯的期望的中性至略微的蓝色色调。 热稳定着色的化合物可以具有聚酯反应性基团，并且在聚合期间优选并入聚酯聚合物结构中。
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公开(公告)号：US5372864A
公开(公告)日：1994-12-13
申请号：US116419
申请日：1993-09-03
IPC分类号： C08G63/68 , C08G63/685 , C08G63/688 , C08J5/00 , C08K5/35 , C08K5/43 , C08L67/00 , C08L67/02 , C09B67/22 , B29D23/00 , C08G69/44
CPC分类号： C08G63/6856 , C08G63/6886 , C09B67/0038 , Y10T428/1352 , Y10T428/1397
摘要： This invention provides certain blue substituted 1,4-bis(2,6-dialkylanilino) anthraquinones in combination with selected red anthraquinone and anthrapyridone (3H-dibenz[f,ij] isoquinoline-2,7-dione) compounds which provide a toner system useful in imparting a desirable neutral to slightly blue hue to polyesters having a yellow appearance. The thermally stable colored compounds can have polyester reactive groups and are preferably incorporated into the polyester polymer structure during polymerization.
摘要翻译： 本发明提供了一些蓝色取代的1,4-双（2,6-二烷基苯胺基）蒽醌与选择的红色蒽醌和蒽吡啶酮（3H-二苯并[f，ij]异喹啉-2,7-二酮）化合物的组合，其提供调色剂体系 可用于赋予具有黄色外观的聚酯的期望的中性至略微的蓝色色调。 热稳定着色的化合物可以具有聚酯反应性基团，并且在聚合期间优选并入聚酯聚合物结构中。
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3.发明授权Ultraviolet light-absorbing compounds and sunscreen formulations and polymeric materials containing such compounds or residues thereof 失效紫外光吸收化合物和防晒制剂以及含有这些化合物或其残基的聚合材料
公开(公告)号：US5374419A
公开(公告)日：1994-12-20
申请号：US994069
申请日：1992-12-18
申请人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Terry A. Oldfield , William W. Parham , Wayne P. Pruett
发明人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Terry A. Oldfield , William W. Parham , Wayne P. Pruett
IPC分类号： A61K8/00 , A61K8/04 , A61K8/40 , A61K8/46 , A61K8/85 , A61Q17/04 , C07C69/734 , C07C69/736 , C07C255/23 , C07C255/32 , C07C255/34 , C07C255/37 , C07C255/41 , C07C255/53 , C07C271/26 , C07C317/46 , C07C321/28 , C07C323/12 , C07C323/19 , C07C323/32 , C07C323/62 , C08G63/16 , C08G63/20 , C08G63/44 , C08G63/676 , C08G63/685 , C08G63/688 , C08G85/00 , C08J5/18 , C08K5/00 , C08L67/00 , C08L67/02 , C09K3/00 , A61K7/42 , A61K7/44 , C07C255/00
CPC分类号： A61Q17/04 , A61K8/40 , A61K8/46 , A61K8/85 , C07C255/41 , C08G63/676 , C08G63/6858 , C08G63/6888 , C08G85/00 , Y10S514/938 , Y10T428/13 , Y10T428/1352
摘要： Disclosed are sunscreen compositions containing certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --O-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.
摘要翻译： 公开了含有具有式“IMAGE”的某些多次甲基化合物的防晒组合物，其中每个R 1独立地选自氰基; 羧基; 烯氧基羰基; 未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 未取代或取代的碳环或杂环芳基; 未取代或取代的烷酰基，环烷酰基或芳酰基; 未取代或取代的氨基甲酰基; 或未取代或取代的烷基磺酰基，环烷基磺酰基或芳基磺酰基; 每个R 2独立地选自氰基或未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 每个A独立地选自未取代或取代的1,2-亚苯基或1,2-亚萘基; 每个Z独立地选自-O-或-S-; L是通过非氧代碳原子键合到每个Z原子上的有机连接基团。 还公开了含有至少一种多次甲基化合物或其反应残余物的防晒制剂和聚合物组合物。
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公开(公告)号：US5281659A
公开(公告)日：1994-01-25
申请号：US971001
申请日：1992-11-02
申请人： Max A. Weaver , Clarence A. Coates , William W. Parham , Samuel D. Hilbert , James J. Krutak , Wayne P. Pruett
发明人： Max A. Weaver , Clarence A. Coates , William W. Parham , Samuel D. Hilbert , James J. Krutak , Wayne P. Pruett
IPC分类号： C08G63/685 , C08G63/688 , C08L101/00 , C08J3/20 , C08G63/00 , C08L23/00 , C08L77/00
CPC分类号： C08L101/00 , C08G63/6854 , C08G63/6884
摘要： Provided are polyester compositions having thermally stable colorants copolymerized therein, said colorants comprised of at least one electron-rich aromatic moiety attached to a negatively substituted 2,5-dioxypyrrolin-3-yl moiety and containing at least one, and preferably, two polyester reactive groups. Also provided are polyester color concentrates and blends of the colored polyester compositions with other thermoplastic polymers and shaped or formed articles comprised of same.
摘要翻译： 提供了在其中共聚有热稳定着色剂的聚酯组合物，所述着色剂由至少一个富含电子的芳族部分连接到负取代的2,5-二氧基吡咯啉-3-基部分上并含有至少一个，优选两个聚酯反应性 团体 还提供了聚酯颜色浓缩物和着色聚酯组合物与其它热塑性聚合物的混合物和由其组成的成形或成型制品。
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5.发明授权Ultraviolet light-absorbing compounds and sunscreen formulations and polymeric materials containing such compounds or residues thereof 失效紫外光吸收化合物和防晒制剂以及含有这些化合物或其残基的聚合材料
公开(公告)号：US5442086A
公开(公告)日：1995-08-15
申请号：US308863
申请日：1994-09-19
申请人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Terry A. Oldfield , William W. Parham , Wayne P. Pruett
发明人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Terry A. Oldfield , William W. Parham , Wayne P. Pruett
IPC分类号： A61K8/00 , A61K8/04 , A61K8/40 , A61K8/46 , A61K8/85 , A61Q17/04 , C07C69/734 , C07C69/736 , C07C255/23 , C07C255/32 , C07C255/34 , C07C255/37 , C07C255/41 , C07C255/53 , C07C271/26 , C07C317/46 , C07C321/28 , C07C323/12 , C07C323/19 , C07C323/32 , C07C323/62 , C08G63/16 , C08G63/20 , C08G63/44 , C08G63/676 , C08G63/685 , C08G63/688 , C08G85/00 , C08J5/18 , C08K5/00 , C08L67/00 , C08L67/02 , C09K3/00 , C07C255/00
CPC分类号： A61Q17/04 , A61K8/40 , A61K8/46 , A61K8/85 , C07C255/41 , C08G63/676 , C08G63/6858 , C08G63/6888 , C08G85/00 , Y10S514/938 , Y10T428/13 , Y10T428/1352
摘要： Disclosed are certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --0-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.
摘要翻译： 公开了具有式“IMAGE”的某些聚次甲基化合物，其中每个R 1独立地选自氰基; 羧基; 烯氧基羰基; 未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 未取代或取代的碳环或杂环芳基; 未取代或取代的烷酰基，环烷酰基或芳酰基; 未取代或取代的氨基甲酰基; 或未取代或取代的烷基磺酰基，环烷基磺酰基或芳基磺酰基; 每个R 2独立地选自氰基或未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 每个A独立地选自未取代或取代的1,2-亚苯基或1,2-亚萘基; 每个Z独立地选自-O-或-S-; L是通过非氧代碳原子键合到每个Z原子上的有机连接基团。 还公开了含有至少一种多次甲基化合物或其反应残余物的防晒制剂和聚合物组合物。
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6.发明授权Ultraviolet light-absorbing compounds and sunscreen formulations and polymeric materials containing such compounds or residues thereof 失效紫外光吸收化合物和防晒制剂以及含有这些化合物或其残基的聚合材料
公开(公告)号：US5302740A
公开(公告)日：1994-04-12
申请号：US968917
申请日：1992-10-30
申请人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Terry A. Oldfield , William W. Parham , Wayne P. Pruett
发明人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Terry A. Oldfield , William W. Parham , Wayne P. Pruett
IPC分类号： A61K8/00 , A61K8/04 , A61K8/40 , A61K8/46 , A61K8/85 , A61Q17/04 , C07C69/734 , C07C69/736 , C07C255/23 , C07C255/32 , C07C255/34 , C07C255/37 , C07C255/41 , C07C255/53 , C07C271/26 , C07C317/46 , C07C321/28 , C07C323/12 , C07C323/19 , C07C323/32 , C07C323/62 , C08G63/16 , C08G63/20 , C08G63/44 , C08G63/676 , C08G63/685 , C08G63/688 , C08G85/00 , C08J5/18 , C08K5/00 , C08L67/00 , C08L67/02 , C09K3/00
CPC分类号： A61Q17/04 , A61K8/40 , A61K8/46 , A61K8/85 , C07C255/41 , C08G63/676 , C08G63/6858 , C08G63/6888 , C08G85/00 , Y10S514/938 , Y10T428/13 , Y10T428/1352
摘要： Disclosed are certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --O-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.
摘要翻译： 公开了具有式“IMAGE”的某些聚次甲基化合物，其中每个R 1独立地选自氰基; 羧基; 烯氧基羰基; 未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 未取代或取代的碳环或杂环芳基; 未取代或取代的烷酰基，环烷酰基或芳酰基; 未取代或取代的氨基甲酰基; 或未取代或取代的烷基磺酰基，环烷基磺酰基或芳基磺酰基; 每个R 2独立地选自氰基或未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 每个A独立地选自未取代或取代的1,2-亚苯基或1,2-亚萘基; 每个Z独立地选自-O-或-S-; L是通过非氧代碳原子键合到每个Z原子上的有机连接基团。 还公开了含有至少一种多次甲基化合物或其反应残余物的防晒制剂和聚合物组合物。
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公开(公告)号：US5102980A
公开(公告)日：1992-04-07
申请号：US679819
申请日：1991-04-01
申请人： James J. Krutak , Max A. Weaver , Clarence A. Coates , William W. Parham , Terry A. Oldfield , Wayne P. Pruett , Samuel D. Hilbert
发明人： James J. Krutak , Max A. Weaver , Clarence A. Coates , William W. Parham , Terry A. Oldfield , Wayne P. Pruett , Samuel D. Hilbert
IPC分类号： C08G63/688 , C09B69/10
CPC分类号： C09B69/10 , C08G63/688
摘要： Provided are novel polyester compositions containing copper phthalocyanine sulfonamide colorants copolymerized therein. Also provided are amorphous color concentrates, partially-crystalline color concentrates and semi-crystalline color concentrates. These polyester compositions are particularly useful for use as colored packaging materials and for colorants for personal, medical, and home care products where non-extractability of the colorant residue is important.
摘要翻译： 提供了含有铜酞菁磺酰胺着色剂的新型聚酯组合物。 还提供了无定形浓缩液，部分结晶色浓缩物和半结晶色浓缩物。 这些聚酯组合物特别可用作彩色包装材料和用于个人，医疗和家庭护理产品的着色剂，其中着色剂残余物的非萃取性是重要的。
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公开(公告)号：US5194571A
公开(公告)日：1993-03-16
申请号：US746832
申请日：1991-08-19
申请人： Max A. Weaver , Clarence A. Coates , William W. Parham , Samuel D. Hilbert , James J. Krutak , Wayne P. Pruett
发明人： Max A. Weaver , Clarence A. Coates , William W. Parham , Samuel D. Hilbert , James J. Krutak , Wayne P. Pruett
IPC分类号： C08G63/685 , C08G63/688 , C08L101/00
CPC分类号： C08L101/00 , C08G63/6854 , C08G63/6884
摘要： Provided are polyester compositions having thermally stable colorants copolymerized therein, said colorants comprised of at least one electron-rich aromatic moiety attached to a negatively substituted 2,5-dioxypyrrolin-3-yl moiety and containing at least one, and preferably, two polyester reactive groups. Also provided are polyester color concentrates and blends of the colored polyester compositions with other thermoplastic polymers and shaped or formed articles comprised of same.
摘要翻译： 提供了在其中共聚有热稳定着色剂的聚酯组合物，所述着色剂由至少一个富含电子的芳族部分连接到负取代的2,5-二氧基吡咯啉-3-基部分上并含有至少一个，优选两个聚酯反应性 团体 还提供了聚酯颜色浓缩物和着色聚酯组合物与其它热塑性聚合物的混合物和由其组成的成形或成型制品。
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9.发明授权Ultraviolet light-absorbing compounds and sunscreen formulations and polymeric materials containing such compounds or residues thereof 失效超紫外线吸收化合物和含有这种化合物或其残基的SUNCREEN配方和聚合物
公开(公告)号：US5057594A
公开(公告)日：1991-10-15
申请号：US395386
申请日：1989-08-17
申请人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Terry A. Oldfield , William W. Parham , Wayne P. Pruett
发明人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Terry A. Oldfield , William W. Parham , Wayne P. Pruett
IPC分类号： A61K8/00 , A61K8/04 , A61K8/40 , A61K8/46 , A61K8/85 , A61Q17/04 , C07C69/734 , C07C69/736 , C07C255/23 , C07C255/32 , C07C255/34 , C07C255/37 , C07C255/41 , C07C255/53 , C07C271/26 , C07C317/46 , C07C321/28 , C07C323/12 , C07C323/19 , C07C323/32 , C07C323/62 , C08G63/16 , C08G63/20 , C08G63/44 , C08G63/676 , C08G63/685 , C08G63/688 , C08G85/00 , C08J5/18 , C08K5/00 , C08L67/00 , C08L67/02 , C09K3/00
CPC分类号： A61Q17/04 , A61K8/40 , A61K8/46 , A61K8/85 , C07C255/41 , C08G63/676 , C08G63/6858 , C08G63/6888 , C08G85/00 , Y10S514/938 , Y10T428/13 , Y10T428/1352
摘要： Disclosed are certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --O-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.
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10.发明授权
公开(公告)号：US4999418A
公开(公告)日：1991-03-12
申请号：US401270
申请日：1989-08-31
申请人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Wayne P. Pruett , William W. Parham
发明人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Wayne P. Pruett , William W. Parham
CPC分类号： C09B1/26 , C08G63/6856 , C09B69/101
摘要： Disclosed are colored polyester compositions comprising a polyester having reacted therewith or copolymerized therein at least one residue of an anthraquinone compound having the formula ##STR1## wherein AQ is the residue of a 9,10-anthraquinone radical; R.sup.1 and R.sup.2 are the same or different and are unsubstituted or substituted alkyl, cycloalkyl or aryl; X is a group reactive with at least one of the functional groups of the monomers from which the polyester is prepared; and n is 1 or 2. The described anthraquinone compounds possess improved thermal stability and thus are not decomposed at the high temperatures at which polyesters are prepared. Also disclosed are shaped articles, particularly containers, fabricated from the colored polyester compositions.
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