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公开(公告)号：US4797437A
公开(公告)日：1989-01-10
申请号：US557100
申请日：1983-12-01
CPC分类号： C08K5/315 , C08K5/18 , C08K5/524 , C08L67/025
摘要： Segmented thermoplastic copolyester elastomers containing recurring polymeric long chain ester units derived from phthalic acids and long chain glycols and short chain ester units derived from phthalic acids and 1,4-butanediol or 1,4-butenediol. The elastomers also contain polyvinylpyrrolidone and preferably also contain guanidine stabilizer, phosphorus stabilizer and diphenylamine.
摘要翻译： 包含衍生自邻苯二甲酸和长链二醇的重复的聚合长链酯单元和衍生自邻苯二甲酸和1,4-丁二醇或1,4-丁烯二醇的短链酯单元的分段热塑性共聚酯弹性体。 弹性体还含有聚乙烯吡咯烷酮，优选还含有胍稳定剂，磷稳定剂和二苯胺。
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公开(公告)号：US4778839A
公开(公告)日：1988-10-18
申请号：US557098
申请日：1983-12-01
CPC分类号： C08K5/31 , C08L67/025 , C08L67/06
摘要： Segmented thermoplastic copolyester elastomers containing recurring polymeric long chain ester units derived from phthalic acids and long chain glycols and short chain ester units derived from phthalic acids and 1,4-butanediol or 1,4-butenediol. The elastomers also contain polyvinylpyrrolidone and preferably also contain small amounts of guanidine stabilizer, phosphorus stabilizer and diphenylamine.
摘要翻译： 包含衍生自邻苯二甲酸和长链二醇的重复的聚合长链酯单元和衍生自邻苯二甲酸和1,4-丁二醇或1,4-丁烯二醇的短链酯单元的分段热塑性共聚酯弹性体。 弹性体还含有聚乙烯吡咯烷酮，优选还含有少量的胍稳定剂，磷稳定剂和二苯胺。
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公开(公告)号：US4766164A
公开(公告)日：1988-08-23
申请号：US557099
申请日：1983-12-01
CPC分类号： C08K5/31 , C08L67/025 , C08L67/06
摘要： Segmented thermoplastic copolyester elastomers containing recurring polymeric long chain ester units derived from phthalic acids and long chain glycols and short chain ester units derived from phthalic acids and 1,4-butanediol or 1,4-butenediol. The elastomers also contain polyvinylpyrrolidone and preferably also contain guanidine stabilizer, phosphorus stabilizer and diphenylamine.
摘要翻译： 包含衍生自邻苯二甲酸和长链二醇的重复的聚合长链酯单元和衍生自邻苯二甲酸和1,4-丁二醇或1,4-丁烯二醇的短链酯单元的分段热塑性共聚酯弹性体。 弹性体还含有聚乙烯吡咯烷酮，优选还含有胍稳定剂，磷稳定剂和二苯胺。
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公开(公告)号：US4549007A
公开(公告)日：1985-10-22
申请号：US672211
申请日：1984-11-16
申请人： I. Sioun Lin , Stanley J. Gromelski, Jr. , Jesse Werner , Michael J. Brown , Paritosh M. Chakrabarti
发明人： I. Sioun Lin , Stanley J. Gromelski, Jr. , Jesse Werner , Michael J. Brown , Paritosh M. Chakrabarti
CPC分类号： C08G18/3814 , C08G18/32 , C08G18/3821 , C08G18/3838 , C08G18/384 , C08G18/6529
摘要： A chain extending agent for reaction injection molding (RIM) comprising a normally liquid blend of butanediol and a toluene diamine mono-substituted with an electron withdrawing group and having the formula ##STR1## wherein X is vicinal to an amino radical and is selected from the group of halogen, CN, NO.sub.2, acyl, carboxylate and isomeric mixtures thereof, and wherein the butanediol and diamine are combined in a critical mole ratio of from 4:1 to about 19:1. The above blend is particularly useful in the preparation of large moldings of polyurethane-polyurea elastomer by the RIM or RRIM (reinforced reaction injection molding) process wherein instant preformed blend is added to a mixture of polyol reactant and catalyst before polymerization in the mold with isocyanate to produce a urethane/urea polymer product of improved properties. Accordingly, the invention also concerns an enhanced RIM or RRIM process and improved product by the use of a mixture of the present chain extender blend and polyol reactant maintainable in the liquid state at ambient temperature.
摘要翻译： 一种用于反应注射成型的链增长剂（RIM），其包含丁二醇的正常液体共混物和用吸电子基团单取代的具有式“IMAGE”的甲苯二胺，其中X与氨基相邻，并且选自 卤素，CN，NO 2，酰基，羧酸酯和其异构体混合物，其中丁二醇和二胺以4:1至约19:1的临界摩尔比组合。 上述共混物特别可用于通过RIM或RRIM（增强反应注射成型）方法制备聚氨酯 - 聚脲弹性体的大型模制品，其中在模具中与异氰酸酯聚合之前将即时预制混合物加入到多元醇反应物和催化剂的混合物中 以产生具有改进性能的氨基甲酸酯/脲聚合物产品。 因此，本发明还涉及通过使用本发明的增链剂共混物和在环境温度下保持液态的多元醇反应物的混合物来增强RIM或RRIM方法和改进的产品。
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5.发明授权Castable polyurethane elastomers chain extended with 2,3-bis(hydroxymethyl)bicyclo[2,2,1]heptane 失效用2,3-双（羟甲基）双环[2,2,1]庚烷延伸的可浇注聚氨酯弹性体链
公开(公告)号：US5047494A
公开(公告)日：1991-09-10
申请号：US394908
申请日：1989-08-17
摘要： A castable polyurethane elastomer comprising the polymerization reaction product of a polyurethane prepolymer and 2,3-bis(hydroxymethyl) bicyclo [2,2,1] heptane as a chain extender. The elastomer has an advantageously low rebound property, which makes it particularly useful in shock absorber and anti-vibration mounting applications.
摘要翻译： 包含聚氨酯预聚物和2,3-双（羟甲基）双环[2,2,1]庚烷作为扩链剂的聚合反应产物的浇注聚氨酯弹性体。 弹性体具有有利的低回弹性能，这使得其在减震器和抗振动安装应用中特别有用。
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6.发明授权Copolymerizable ultraviolet light absorber members which are .alpha.,.beta. - 失效可共聚的紫外光吸收体，它们是2-羟基，烷氧基，羟甲基二苯甲酮的α，β-不饱和二羧酸半酯
公开(公告)号：US4312995A
公开(公告)日：1982-01-26
申请号：US168224
申请日：1980-07-10
IPC分类号： C07C59/84
CPC分类号： C07C69/738
摘要： This invention relates to copolymerizable ultraviolet light absorber monomers which are .alpha.,.beta.-unsaturated dicarboxylic half-esters of 2-hydroxy,alkoxy,methylolbenzophenone intermediate compounds. The monomers have the formula: ##STR1## where R is alkyl C.sub.1 -C.sub.8, and n is 1 or 2, andY is a half-acyl radical of a .alpha.,.beta.-unsaturated dicarboxylic acid selected from the group of maleic and itaconic acids.The monomers herein are made by monoesterifying intermediate compounds, prepared by converting a 2-hydroxy,alkoxy,benzophenone to the corresponding methylol derivative by a formylation reaction, with the anhydride of the desired acid.In the preferred embodiments of the invention, the alkoxy group is methoxy in the 4-position, the methylol group which is half-esterified is a monomethylol group located at the 3- or 5- position of the phenyl ring containing the hydroxy group, and the acid anhydride is maleic anhydride.Copolymerization of the monomers herein with vinyl monomers provide improved ultraviolet light stable copolymers for industrial and commercial applications.
摘要翻译： 本发明涉及可共聚的紫外线吸收剂单体，它们是2-羟基，烷氧基，羟甲基二苯甲酮中间体化合物的α，β-不饱和二羧酸半酯。 单体具有下式：其中R是烷基C1-C8，n是1或2，Y是选自马来酸和衣康酸的α，β-不饱和二羧酸的半酰基 。 本文中的单体通过使中间体化合物单酯化而制备，所述中间体化合物通过甲酰化反应将2-羟基，烷氧基，二苯甲酮与相应的羟甲基衍生物与所需酸的酸酐反应制备。 在本发明的优选实施方案中，烷氧基是4-位的甲氧基，半酯化的羟甲基是位于含有羟基的苯环的3-或5-位的单羟基，以及 酸酐是马来酸酐。 本文单体与乙烯基单体的共聚为工业和商业应用提供改进的紫外光稳定共聚物。
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公开(公告)号：US4523004A
公开(公告)日：1985-06-11
申请号：US506250
申请日：1983-06-23
申请人： I. Sioun Lin , Stanley J. Gromelski, Jr. , Jesse Werner , Michael J. Brown , Paritosh M. Chakrabarti
发明人： I. Sioun Lin , Stanley J. Gromelski, Jr. , Jesse Werner , Michael J. Brown , Paritosh M. Chakrabarti
CPC分类号： C08G18/3814 , C08G18/32 , C08G18/3821 , C08G18/3838 , C08G18/384 , C08G18/6529
摘要： A chain extending agent for reaction injection molding (RIM) comprising a normally liquid blend of butanediol and a toluene diamine mono-substituted with an electron withdrawing group and having the formula ##STR1## wherein X is vicinal to an amino radical and is selected from the group of halogen, CN, NO.sub.2, acyl, carboxylate and isomeric mixtures thereof, and wherein the butanediol and diamine are combined in a critical mole ratio of from 4:1 to about 19:1. The above blend is particularly useful in the preparation of large moldings of polyurethane-polyurea elastomer by the RIM or RRIM (reinforced reaction injection molding) process wherein instant preformed blend is added to a mixture of polyol reactant and catalyst before polymerization in the mold with isocyanate to produce a urethane/urea polymer product of improved properties. Accordingly, the intention also concerns an enhanced RIM or RRIM process and improved product by the use of a mixture of the present chain extender blend and polyol reactant maintainable in the liquid state at ambient temperature.
摘要翻译： 一种用于反应注射成型的链增长剂（RIM），其包含丁二醇的正常液体共混物和用吸电子基团单取代的具有式“IMAGE”的甲苯二胺，其中X与氨基相邻，并且选自 卤素，CN，NO 2，酰基，羧酸酯和其异构体混合物，其中丁二醇和二胺以约4:1至约19:1的临界摩尔比组合。 上述共混物特别可用于通过RIM或RRIM（增强反应注射成型）方法制备聚氨酯 - 聚脲弹性体的大型模制品，其中在模具中与异氰酸酯聚合之前将即时预制混合物加入到多元醇反应物和催化剂的混合物中 以产生具有改进性能的氨基甲酸酯/脲聚合物产品。 因此，该意图还涉及通过使用在环境温度下保持液态的本发明扩链剂混合物和多元醇反应物的混合物来增强RIM或RRIM方法和改进的产物。
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公开(公告)号：US4722965A
公开(公告)日：1988-02-02
申请号：US832832
申请日：1986-02-24
IPC分类号： C09D5/00 , C08L33/06 , C09D133/04 , C09D133/06 , C08L35/00 , C08F120/58 , C08F226/02
CPC分类号： C09D133/062 , C08L33/06
摘要： A chalk-adhesion polymer latex for exterior coatings especially suitable for blending with an acrylic formulation, such as vinyl acetate/ acrylic copolymers. The polymer is derived from a monomer precursor composition, including an acrylic moiety, such as an acrylate and a methacrylate, together with small amounts of a nitrogen-containing alkyl acrylate, an acrylamide and propylene glycol. The method of preparing the chalk adhesion polymer includes emulsification stages to accomplish the polymerization.
摘要翻译： 用于外部涂料的白垩粘合聚合物胶乳，特别适用于与丙烯酸制剂如乙酸乙烯酯/丙烯酸共聚物共混。 聚合物衍生自单体前体组合物，包括丙烯酸部分，例如丙烯酸酯和甲基丙烯酸酯，以及少量的含氮丙烯酸烷基酯，丙烯酰胺和丙二醇。 制备白垩粘合聚合物的方法包括乳化阶段以实现聚合。
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公开(公告)号：US4578407A
公开(公告)日：1986-03-25
申请号：US364117
申请日：1982-03-31
IPC分类号： C08L39/00 , C08L7/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L35/08 , C09D5/04 , C09D137/00 , C09D139/06 , C23G1/02 , B08B7/00 , C08L5/00 , C11D3/37 , C11D7/32
CPC分类号： C23G1/025 , C09D139/06 , C08L35/08 , Y10T29/45
摘要： Spreadable thixotropic coating composition suitable for rust removal and containing polyvinylpyrrolidone, water and a thixotropic agent which is either xanthan gum or water-soluble crosslinked interpolymer of maleic anhydride, monovinyl alkyl ether and crosslinking agent. The composition has a pH between about 1.5 and 7.0 is applied to rusty metal surfaces and allowed to dry. During drying the rust becomes incorporated into the coating which is then easily removed.
摘要翻译： 适用于除锈并含有聚乙烯吡咯烷酮，水和触变剂的可膨胀触变性涂料组合物，其为马来酸酐，单乙烯基烷基醚和交联剂的黄原胶或水溶性交联互聚物。 将组合物的pH值介于约1.5和7.0之间，施加到生锈的金属表面并使其干燥。 在干燥过程中，生锈被并入到涂层中，然后容易地去除。
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10.发明授权Ultraviolet light stable copolymer compositions comprising monomers which are .alpha.,62 -unsaturated dicarboxylic acid half-esters of 2-hydroxy, alkoxy, methylolbenzophenones and styrene-butadiene comonomers 失效包含单体的紫外光稳定共聚物组合物，其为2-羟基，烷氧基，羟甲基二苯甲酮和苯乙烯 - 丁二烯共聚单体的α，62-不饱和二羧酸半酯
公开(公告)号：US4301267A
公开(公告)日：1981-11-17
申请号：US181336
申请日：1980-08-26
IPC分类号： C08F222/20 , C08F20/20
CPC分类号： C08F222/20
摘要： This invention relates to ultraviolet light stable copolymer compositions comprising:(a) a monomer which is an .alpha.,.beta.-unsaturated dicarboxylic half-ester of a 2-hydroxy, alkoxy, methylolbenzophenone, and,(b) a comonomer which is styrene or styrene-butadiene, is described.
摘要翻译： 本发明涉及紫外光稳定共聚物组合物，其包含：（a）单体，其为2-羟基，烷氧基，羟甲基二苯甲酮的α，β-不饱和二羧酸半酯，和（b）共聚单体，其为苯乙烯或苯乙烯 丁二烯。
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