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    Aldehyde-functionalized polymers with enhanced stability
    2.
    发明授权
    Aldehyde-functionalized polymers with enhanced stability 有权
    具有增强稳定性的醛官能化聚合物

    公开(公告)号：US08288502B2

    公开(公告)日：2012-10-16

    申请号：US12641557

    申请日：2009-12-18

    申请人： Heinrich E. Bode ,  Michael R. St. John ,  Mei Liu ,  Robert M. Lowe

    发明人： Heinrich E. Bode ,  Michael R. St. John ,  Mei Liu ,  Robert M. Lowe

    IPC分类号： C08G2/00

    CPC分类号： D21H21/18 ,  C08L33/26 ,  C08L97/00 ,  D21H17/34 ,  D21H17/375 ,  D21H17/47 ,  D21H17/66 ,  D21H19/56

    摘要： The current invention includes a composition having stability additives of selected inorganic salts and/or organic incorporated into an aldehyde-functionalized polymer product. The stability additive can be post added to the finished polymer product, added to the reaction vessel prior to inducing functionalization of the non-functionalized polymer, or added at any stage during the functionalization reaction. Methods for forming the composition and using the composition to produce a cellulosic fiber-based medium are also disclosed.

    摘要翻译： 本发明包括具有选定的无机盐和/或有机掺入到醛官能化聚合物产品中的稳定添加剂的组合物。 稳定性添加剂可以在添加到成品聚合物产物中后，在引入非官能化聚合物的官能化之前添加到反应容器中，或者在官能化反应期间的任何阶段加入。 还公开了形成组合物和使用该组合物生产纤维素纤维基培养基的方法。

    Method of using aldehyde-functionalized polymers to increase papermachine performance and enhance sizing
    3.
    发明授权
    Method of using aldehyde-functionalized polymers to increase papermachine performance and enhance sizing 有权
    使用醛官能化聚合物增加造纸机性能并增强尺寸的方法

    公开(公告)号：US08709207B2

    公开(公告)日：2014-04-29

    申请号：US12938017

    申请日：2010-11-02

    申请人： Mark Grimm ,  Michael R. St. John

    发明人： Mark Grimm ,  Michael R. St. John

    IPC分类号： D21H11/00

    CPC分类号： D21H21/16 ,  C08L57/10 ,  C08L57/12 ,  D21H17/06 ,  D21H17/47 ,  D21H19/24

    摘要： Novel sizing mixtures to achieve improved sizing along with other benefits is disclosed and claimed. The invention is a composition comprising a sizing mixture having a stabilizing amount of one or more aldehyde-functionalized polymers and a sizing amount of a sizing composition. The invention is also a method of improving paper and paperboard production and enhancing sizing through adding an effective amount of the disclosed sizing mixture to the paper machine and a method of producing a medium having cellulosic fibers, wherein the method includes adding the disclosed sizing mixture to the medium at any point in a papermaking process.

    摘要翻译： 揭示和要求保护的新型上浆混合物以实现改进的施胶以及其它益处。 本发明是一种组合物，其包含具有稳定量的一种或多种醛官能化聚合物和施胶量的施胶组合物的施胶混合物。 本发明还是通过向造纸机中添加有效量的所述上浆混合物以及制备具有纤维素纤维的介质的方法来改进纸和纸板生产并提高尺寸的方法，其中所述方法包括将所公开的施胶混合物添加到 介质在造纸过程中的任何一点。

    Method of operating a papermaking process
    4.
    发明申请
    Method of operating a papermaking process 有权
    操作造纸工艺的方法

    公开(公告)号：US20080082198A1

    公开(公告)日：2008-04-03

    申请号：US11522578

    申请日：2006-09-18

    申请人： Ross T. Gray ,  Michael R. St. John ,  James L. Thomas ,  David I. Weinstein ,  John M. Hawes ,  Mary M. Toney

    发明人： Ross T. Gray ,  Michael R. St. John ,  James L. Thomas ,  David I. Weinstein ,  John M. Hawes ,  Mary M. Toney

    IPC分类号： G06F7/66

    CPC分类号： D21F3/00 ,  D21H17/37 ,  D21H21/10

    摘要： A method of operating a papermaking process containing a press section with at least one press nip is disclosed. The method comprises simultaneously performing the following steps: (a) providing a press media for said papermaking process that has a MFP size that is less than the MFP size of a press media that was originally supplied to said papermaking process; (b) adding an effective amount of one or more press sheet dewatering additives to said papermaking process prior to the last press nip of said papermaking process; (c) providing a sheet moisture ratio of a paper sheet entering a press nip of said press section to between about 2 to about 9; and (d) applying an optimum rate of pressure development at one or more press nips of said papermaking process, wherein said steps a, b, c, and d either: result in the production of a more uniform paper sheet without the reduction in paper solids exiting the press section that would be expected from performing a, c, and d, alone or in combination with one another; or result in the production of a more uniform paper sheet with an increase in solids content of said paper sheet exiting the press section.

    摘要翻译： 公开了一种操作含有至少一个压榨压区的压榨部的造纸工艺的方法。 该方法包括同时执行以下步骤：（a）提供具有MFP尺寸小于原始提供给所述造纸过程的印刷媒体的MFP尺寸的所述造纸过程的压制介质; （b）在所述造纸工艺的最后压榨压区之前，在所述造纸工艺中加入有效量的一种或多种压片脱水添加剂; （c）提供进入所述压榨部的压榨辊隙的纸张的片材湿度比在约2至约9之间; 和（d）在所述造纸方法的一个或多个压榨压力下施加最佳压力显影速率，其中所述步骤a，b，c和d也可以产生更均匀的纸张，而不会减少纸张 离开压榨段的固体，预期单独或彼此组合执行a，c和d; 或者导致离开压榨部的所述纸张的固体含量增加而生产更均匀的纸张。

    Hydrogen production by biomass product depolarized water electrolysis
    5.
    发明授权
    Hydrogen production by biomass product depolarized water electrolysis 失效
    氢生产生物质产品去极化水电解

    公开(公告)号：US4395316A

    公开(公告)日：1983-07-26

    申请号：US369534

    申请日：1982-04-19

    申请人： Michael R. St. John

    发明人： Michael R. St. John

    IPC分类号： C25B1/04

    CPC分类号： C25B1/04 ,  Y02E60/366

    摘要： A process for hydrogen production by water electrolysis and a process of depolarizing the anode of a water electrolysis cell by oxidizing a biomass product which may be monosaccharides, lignins, and mixtures thereof. The process of this invention avoids molecular oxygen evolution and results in high purity hydrogen at cell potentials substantially less than required for normal water electrolysis involving oxygen evolution. The process utilizes biomass products which are readily available and cost effective. High consumption of biomass product is achieved with an anode of lead-rich ruthenium polychlore compounds.

    摘要翻译： 通过水电解产生氢的方法和通过氧化可能是单糖，木质素及其混合物的生物质产物使水电解池的阳极去极化的方法。 本发明的方法避免了分子氧的释放，并导致电池电位下的高纯度氢，基本上低于涉及氧气析出的正常水电解所需的氢。 该方法利用生物质产品，其易于获得并具有成本效益。 用富含铅的钌多金属化合物的阳极实现高消耗的生物质产品。

    ALDEHYDE-FUNCTIONALIZED POLYMERS
    6.
    发明申请
    ALDEHYDE-FUNCTIONALIZED POLYMERS 有权
    ALDEHYDE-功能化聚合物

    公开(公告)号：US20100089542A1

    公开(公告)日：2010-04-15

    申请号：US12636932

    申请日：2009-12-14

    申请人： Michael R. St. John ,  Angel P. Zagala

    发明人： Michael R. St. John ,  Angel P. Zagala

    IPC分类号： C08G12/04 ,  D21H23/02

    CPC分类号： D21H17/55 ,  C08F8/28 ,  C08F2800/10 ,  D21H17/375 ,  D21H21/10 ,  D21H21/20 ,  C08F220/56

    摘要： A composition for enhancing the dewatering of a paper sheet on a paper machine and a method for using the composition is disclosed. The composition comprising one or more aldehyde-functionalized polymers comprising amino or amido groups wherein at least about 15 mole percent of the amino or amido groups are functionalized by reacting with one or more aldehydes and wherein the aldehyde functionalized polymers have a molecular weight of at least about 100,000. The method comprising adding the composition to the paper machine at a dosage of about 0.05 lb/ton to about 15 lb/ton, based on dry fiber.

    摘要翻译： 公开了一种用于增强纸机上纸张脱水的组合物和使用该组合物的方法。 所述组合物包含一种或多种包含氨基或酰胺基的醛官能化聚合物，其中至少约15摩尔％的氨基或酰氨基通过与一种或多种醛反应而官能化，其中醛官能化聚合物的分子量至少为 约十万。 该方法包括基于干纤维将组合物以约0.05磅/吨至约15磅/吨的剂量加入到造纸机中。

    Method of using aldehyde-functionalized polymers to enhance paper machine dewatering
    7.
    发明授权
    Method of using aldehyde-functionalized polymers to enhance paper machine dewatering 有权
    使用醛官能化聚合物增强造纸机脱水的方法

    公开(公告)号：US07641766B2

    公开(公告)日：2010-01-05

    申请号：US10764935

    申请日：2004-01-26

    申请人： Michael R. St. John ,  Angel P. Zagala

    发明人： Michael R. St. John ,  Angel P. Zagala

    IPC分类号： D21H17/55 ,  D21H21/10

    CPC分类号： D21H17/55 ,  C08F8/28 ,  C08F2800/10 ,  D21H17/375 ,  D21H21/10 ,  D21H21/20 ,  C08F220/56

    摘要： A method of enhancing the dewatering of a paper sheet on a paper machine comprising adding to the paper sheet about 0.05 lb/ton to about 15 lb/ton, based on dry fiber, of one or more aldehyde functionalized polymers comprising amino or amido groups wherein at least about 15 mole percent of the amino or amido groups are functionalized by reacting with one or more aldehydes and wherein the aldehyde functionalized polymers have a molecular weight of at least about 100,000.

    摘要翻译： 一种增强纸机上的纸张的脱水的方法，其包括将基于干纤维的包含氨基或酰氨基的一种或多种醛官能化聚合物添加到纸张约0.05磅/吨至约15磅/吨的纸张，其中 至少约15摩尔％的氨基或酰氨基通过与一种或多种醛反应而官能化，其中醛官能化聚合物具有至少约100,000的分子量。

    Method of operating a papermaking process
    9.
    发明授权
    Method of operating a papermaking process 有权
    操作造纸工艺的方法

    公开(公告)号：US07556714B2

    公开(公告)日：2009-07-07

    申请号：US11522578

    申请日：2006-09-18

    申请人： Ross T. Gray ,  Michael R. St. John ,  James L. Thomas ,  David I. Weinstein ,  John M. Hawes ,  Mary M. Toney

    发明人： Ross T. Gray ,  Michael R. St. John ,  James L. Thomas ,  David I. Weinstein ,  John M. Hawes ,  Mary M. Toney

    IPC分类号： D21F11/00

    CPC分类号： D21F3/00 ,  D21H17/37 ,  D21H21/10

    摘要： A method of operating a papermaking process containing a press section with at least one press nip is disclosed. The method comprises simultaneously performing the following steps: (a) providing a press media for said papermaking process that has a MFP size that is less than the MFP size of a press media that was originally supplied to said papermaking process; (b) adding an effective amount of one or more press sheet dewatering additives to said papermaking process prior to the last press nip of said papermaking process; (c) providing a sheet moisture ratio of a paper sheet entering a press nip of said press section to between about 2 to about 9; and (d) applying an optimum rate of pressure development at one or more press nips of said papermaking process, wherein said steps a, b, c, and d either: result in the production of a more uniform paper sheet without the reduction in paper solids exiting the press section that would be expected from performing a, c, and d, alone or in combination with one another; or result in the production of a more uniform paper sheet with an increase in solids content of said paper sheet exiting the press section.

    摘要翻译： 公开了一种操作含有至少一个压榨压区的压榨部的造纸工艺的方法。 该方法包括同时执行以下步骤：（a）提供具有MFP尺寸小于原始提供给所述造纸过程的印刷媒体的MFP尺寸的所述造纸过程的压制介质; （b）在所述造纸工艺的最后压榨压区之前，在所述造纸工艺中加入有效量的一种或多种压片脱水添加剂; （c）提供进入所述压榨部的压榨辊隙的纸张的片材湿度比在约2至约9之间; 和（d）在所述造纸方法的一个或多个压榨压力下施加最佳压力显影速率，其中所述步骤a，b，c和d也可以产生更均匀的纸张，而不会减少纸张 离开压榨段的固体，预期单独或彼此组合执行a，c和d; 或者导致离开压榨部的所述纸张的固体含量增加而生产更均匀的纸张。

    Hydrophobic cationic terpolymers from acrylamide, dimethylaminoethylacrylate methyl chloride or sulfate and vinyl acetate
    10.
    发明授权
    Hydrophobic cationic terpolymers from acrylamide, dimethylaminoethylacrylate methyl chloride or sulfate and vinyl acetate 失效
    来自丙烯酰胺，丙烯酸二甲基氨基乙酯甲基氯化物或硫酸盐和乙酸乙烯酯的疏水性阳离子三元共聚物

    公开(公告)号：US5051487A

    公开(公告)日：1991-09-24

    申请号：US325841

    申请日：1989-03-20

    申请人： Bhupati R. Bhattacharyya ,  Michael R. St. John

    发明人： Bhupati R. Bhattacharyya ,  Michael R. St. John

    IPC分类号： C02F1/54 ,  C08F220/34 ,  C08F220/56

    CPC分类号： C02F1/54 ,  C08F220/34 ,  C08F220/56

    摘要： Hydrophobic cationic terpolymers resulting from the polymerization of a mixture of monomers of (a) acrylamide and/or methacrylamide, (b) dimethylaminoethylacrylate methyl chloride and/or dimethylaminoethylacrylate methyl sulfate, and (c) vinyl acetate; water-in-oil and oil-in-water emulsions containing said terpolymers; and dewatering of wastes and sludges utilizing said oil-in-water emulsions in which the terpolymers are present essentially in the aqueous phase.

    摘要翻译： （a）丙烯酰胺和/或甲基丙烯酰胺，（b）二甲基氨基乙基丙烯酸甲酯氯化物和/或二甲基氨基乙基丙烯酸甲酯硫酸盐的混合物的聚合得到的疏水性阳离子三元共聚物，和（c）乙酸乙烯酯; 含有所述三元共聚物的油包水和水包油乳液; 以及利用所述三水聚合物基本上在水相中存在的水包油乳液来对废物和淤泥进行脱水。