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公开(公告)号：US5087677A
公开(公告)日：1992-02-11
申请号：US548083
申请日：1990-07-05
IPC分类号： C08F4/642 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/6192 , C08F4/626 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/6592 , C08F10/00 , C08F32/00 , C08F32/04 , C08F32/08 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/14 , C08F210/16 , C08F232/00 , C08F232/04
CPC分类号： C08F210/00 , C07F17/00 , C08F32/00 , C08F32/08 , C08F210/02 , C08F210/06 , C08F210/14 , C08F210/16 , C08F4/63912 , C08F4/63927 , Y10S526/943
摘要： Polymers of polycyclic olefins of the formulae I to IV having a viscosity number greater than 20 cm.sup.3 /g and a glass transition temperature above 100.degree. C. are obtained without ring opening at a high polymerization rate and at polymerization temperatures advantageous from the technical point of view by means of a catalyst which is composed of a stereo-rigid, chiral metallocene compound of groups IVb to VIb of the Periodic Table of the Elements and an aluminoxane. ##STR1##
摘要翻译： 获得粘度大于20立方厘米/克，玻璃化转变温度高于100℃的式I至IV的多环烯烃聚合物，而不以高聚合速率开环，聚合温度优选为 通过由元素周期表IVb至VIb族的立体刚性手性茂金属化合物和铝氧烷组成的催化剂来观察。 （一）图像（二）<图像>（三）<图像>（四）
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公开(公告)号：US6028152A
公开(公告)日：2000-02-22
申请号：US914387
申请日：1997-08-18
申请人： Andreas Winter , Martin Antberg , Bernd Bachmann , Volker Dolle , Frank Kuber , Jurgen Rohrmann , Walter Spaleck
发明人： Andreas Winter , Martin Antberg , Bernd Bachmann , Volker Dolle , Frank Kuber , Jurgen Rohrmann , Walter Spaleck
IPC分类号： C07F17/00 , C08F4/44 , C08F4/60 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F10/00 , C08F110/06 , C08F297/08 , C08F4/02
CPC分类号： C08F297/083 , C07F17/00 , C08F10/00 , C08F110/06 , C08F4/63912 , C08F4/63916 , C08F4/63927 , Y10S526/943
摘要： Disclosed is a catalyst system and method of polymerizing olefins, wherein the catalyst comprises a bridged metallocene of the following structure: ##STR1## wherein M.sup.1 is a transition metal of groups 4-6, R.sup.1 -R.sup.9 is hydrogen or other groups with the proviso that substituents R.sup.3 and R.sup.6 are not hydrogen, and wherein the metallocene is present in the meso form or in a mixture including both the meso and racemic forms.
摘要翻译： 公开了一种聚合烯烃的催化剂体系和方法，其中催化剂包含具有以下结构的桥连茂金属：其中M1是基团4-6的过渡金属，R 1 -R 9是氢或其它基团，条件是取代基R 3和 R 6不是氢，并且其中茂金属以内消旋形式存在或以包括内消旋形式和外消旋形式的混合物存在。
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公开(公告)号：US5731254A
公开(公告)日：1998-03-24
申请号：US462110
申请日：1995-06-05
IPC分类号： C07F17/00 , C07C15/60 , C08F4/60 , C08F4/602 , C08F4/6192 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F8/00 , C08F10/00 , C08F110/06 , C08F10/04
CPC分类号： C08F110/06 , C08F10/00 , C08F4/63912 , C08F4/63927 , Y10S526/905 , Y10S526/943
摘要： A syndiotactic polyolefin is obtained in a high yield by polymerization or copolymerization of an olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b in the presence of a catalyst consisting of a metallocene of the formula I ##STR1## in which M.sup.1 is titanium, zirconium, vanadium, niobium or tantalum, and an aluminoxane. This polyolefin has a very high molecular weight, a very narrow molecular weight distribution and a very high syndiotactic index. Shaped articles produced from the polymer are distinguished by a high transparency, flexibility, tear resistance and an excellent surface gloss.
摘要翻译： 通过在由式I的金属茂（I）组成的催化剂存在下，通式Ra-CH = CH-Rb的烯烃的聚合或共聚获得高收率的间同立构聚烯烃，其中M1为 钛，锆，钒，铌或钽，以及铝氧烷。 该聚烯烃具有非常高的分子量，非常窄的分子量分布和非常高的间规指数。 由聚合物制成的成形品通过高透明度，柔韧性，抗撕裂性和优异的表面光泽来区分。
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公开(公告)号：US5693836A
公开(公告)日：1997-12-02
申请号：US484457
申请日：1995-06-07
申请人： Andreas Winter , Martin Antberg , Bernd Bachmann , Volker Dolle , Frank Kuber , Jurgen Rohrmann , Walter Spaleck
发明人： Andreas Winter , Martin Antberg , Bernd Bachmann , Volker Dolle , Frank Kuber , Jurgen Rohrmann , Walter Spaleck
IPC分类号： C07F17/00 , C08F4/44 , C08F4/60 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F10/00 , C08F110/06 , C08F297/08 , C08F10/06
CPC分类号： C08F297/083 , C07F17/00 , C08F10/00 , C08F110/06 , C08F4/63912 , C08F4/63916 , C08F4/63927 , Y10S526/943
摘要： A process for the preparation of an olefin polymer by polymerization or copolymerization of an olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b, in which R.sup.a and R.sup.b are identical or different and are a hydrogen atom or a hydrocarbon radical having 1 to 14 carbon atoms, or R.sup.a and R.sup.b, together with the atoms connecting them, can form a ring, at a temperature of from -60.degree. to 200.degree. C., at a pressure of from 0.5 to 100 bar, in solution, in suspension or in the gas phase, in the presence of a catalyst formed from a metallocene in the meso-form or a meso:rac mixture, with meso:rac>1:99, as transition-metal compound and a cocatalyst, wherein the metallocene is a compound of the formula I, ##STR1## in which M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are identical or different and are methyl or chlorine, R.sup.3 and R.sup.6 are identical or different and are methyl, isopropyl, phenyl, ethyl or trifluoromethyl, R.sup.4 and R.sup.5 are hydrogen or as defined for R.sup.3 and R.sup.6, or R.sup.4 forms an aliphatic or aromatic ring with R.sup.6, or adjacent radicals R.sup.4 form a ring of this type, and R.sup.7 is a ##STR2## radical, and m plus n is zero or 1.
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公开(公告)号：US5679811A
公开(公告)日：1997-10-21
申请号：US453953
申请日：1995-05-30
IPC分类号： C08F4/642 , C07F17/00 , C08F4/58 , C08F4/60 , C08F4/6192 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C07F7/10
CPC分类号： C08F10/00 , C08F4/61927 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A very efficient catalyst system for the polymerization of 1-olefins consists of an aluminoxane and a metallocene which is a compound of the formula I ##STR1## in which R.sup.1 and R.sup.2 denote hydrogen atoms, halogen atoms or hydrocarbon radicals and R.sup.3 and R.sup.4 are mononuclear or polynuclear hydrocarbon radicals which can form a sandwich structure with the central atom and which are linked to one another by a --R.sup.6.sub.m --R.sup.5 --R.sup.7.sub.n -- bridge containing a hetero atom and consisting of one or several members. The catalyst system produces polymers having a high molecular weight.
摘要翻译： 用于1-烯烃聚合的非常有效的催化剂体系由铝氧烷和茂金属组成，其是式Ien原子，卤素原子或烃基的化合物，R 3和R 4是可以形成夹心结构的单核或多核烃基 与中心原子并且通过含有杂原子并由一个或多个成员组成的-R6m-R5-R7n-桥连接。 催化剂体系产生具有高分子量的聚合物。
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6.发明授权Process for the preparation of an olefin polymer using metallocenes having specifically substituted indenyl ligands 失效使用具有特异取代的茚基配体的金属茂制备烯烃聚合物的方法
公开(公告)号：US5304614A
公开(公告)日：1994-04-19
申请号：US960893
申请日：1992-10-14
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A very active catalyst system for olefin polymerization comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I or Ia ##STR1## in which, preferably, M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 and R.sup.4 are hydrogen or alkyl, R.sup.5 and R.sup.6 are alkyl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.n is a chain with one or more members, in which R.sup.7 can also be a (substituted) heteroatom, and m+n is zero or 1.
摘要翻译： 用于烯烃聚合的非常活泼的催化剂体系包括助催化剂，优选铝氧烷和式I或Ia的茂金属（*化学结构*），其中优选地是M1是Zr或Hf，R1和R2是烷基或卤素， R3和R4是氢或烷基，R5和R6是烷基， - （CR8R9）m-R7-（CR8R9）n是具有一个或多个成员的链，其中R7也可以是（取代的）杂原子，并且m + n为零或1。
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7.发明授权Metallocenes containing ligands of 2-substituted idenyl derivatives, process for their preparation, and their use as catalysts 失效含有2-取代的烯基衍生物的配体的金属茂，其制备方法及其作为催化剂的用途
公开(公告)号：US5276208A
公开(公告)日：1994-01-04
申请号：US789361
申请日：1991-11-08
IPC分类号： C07F7/00 , C07F7/08 , C07F17/00 , C08F4/60 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/70 , C08F10/00 , C08F110/06 , C07F7/28 , C07F9/00 , C07F11/00
CPC分类号： C07F17/00 , C07F7/0809 , C08F10/00 , C08F110/06 , C08F4/63912 , C08F4/63927 , Y10S526/943
摘要： The novel metallocenes of the formula I ##STR1## in which, preferably, M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 and R.sup.4 are hydrogen, R.sup.5 and R.sup.6 are alkyl or haloalkyl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.n -- is a single- or multi-membered chain in which R.sup.7 may also be a (substituted) hetero atom, m+n is zero or 1, and R.sup.10 is hydrogen, form, together with aluminoxanes as cocatalysts, a very effective catalyst system for the preparation of polyolefins of high stereospecificity and high melting point.
摘要翻译： 其中优选M1是Zr或Hf，R1和R2是烷基或卤素的式Ⅰ'（Ⅰ）的新金属茂，R3和R4是氢，R5和R6是烷基或卤代烷基， - （CR8R9） m-R7-（CR8R9）n-是单或多元链，其中R7也可以是（取代的）杂原子，m + n是0或1，R10是氢，与铝氧烷一起形成， 助催化剂，用于制备高立体定向性和高熔点的聚烯烃的非常有效的催化剂体系。
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公开(公告)号：US5232993A
公开(公告)日：1993-08-03
申请号：US630262
申请日：1990-12-19
IPC分类号： C08L23/16 , C08F2/00 , C08F4/60 , C08F4/622 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F210/06 , C08F210/16 , C08F297/08 , C08L23/00 , C08L23/10 , C08L23/14 , C08L53/00
CPC分类号： C08L23/10 , C08F297/083 , C08L23/142 , C08L23/14 , C08L23/16 , C08L2308/00 , Y10S526/943
摘要： A polypropylene molding composition having syndiotactic polymer chains is obtained in a high yield by the copolymerization of propylene with ethylene or a 1-olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b in the presence of a catalyst comprising a metallocene of the formula I ##STR1## in which M.sup.1 is titanium, zirconium, hafnium, vanadium, riobium or tantalum, and an aluminoxane. This molding composition has a very high molecular weight, a very narrow molecular-weight distribution and very high syndiotaxy. Shaped articles produced from the molding composition are distinguished by high transparency, flexibility, bear strength and excellent surface luster.
摘要翻译： 通过丙烯与乙烯或式Ra-CH = CH-Rb的1-烯烃在含有式I的茂金属的催化剂的存在下共聚而获得具有间同立构聚合物链的聚丙烯模塑组合物， （I）其中M1是钛，锆，铪，钒，核锂或钽，铝氧烷。 该成型组合物具有非常高的分子量，非常窄的分子量分布和非常高的间规。 由模塑组合物制成的成型品的特征在于高透明度，柔韧性，承载强度和优异的表面光泽。
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公开(公告)号：US5081322A
公开(公告)日：1992-01-14
申请号：US479401
申请日：1990-02-13
申请人： Andreas Winter , Volker Dolle , Jurgen Rohrmann , Martin Antberg , Ludwig Bohm , Walter Spaleck
发明人： Andreas Winter , Volker Dolle , Jurgen Rohrmann , Martin Antberg , Ludwig Bohm , Walter Spaleck
IPC分类号： C08F4/58 , C08F4/60 , C08F4/602 , C08F4/62 , C08F4/639 , C08F4/6392 , C08F10/00 , C08F210/06
CPC分类号： C08F210/06 , C08F4/63912 , C08F4/63927 , Y02P20/52 , Y10S526/943 , Y10S585/946
摘要： Polyolefin waxes are obtained in high yield by copolymerizing propylene with small amounts of other olefins in the presence of a catalyst composed of a metallocene of the formula I: ##STR1## and an alumoxane. The waxes are produced as compact, spherical particles having a narrow particle size distribution and high apparent density. In addition, the physical data of these waxes such as, for example, hardness, melting point, melt viscosity etc., are variable within wide limits.The polymer chains are noteworthy for a homogeneous and uniform structure, the comonomer units being predominantly arranged individually between polypropylene blocks.
摘要翻译： 在由式I的金属茂和铝氧烷组成的催化剂的存在下，将丙烯与少量的其它烯烃共聚合，可以高收率地获得聚烯烃蜡。 蜡被制造成具有窄的粒度分布和高表观密度的致密的球形颗粒。 此外，这些蜡的物理数据，例如硬度，熔点，熔体粘度等在宽范围内是可变的。 聚合物链对于均匀且均匀的结构是值得注意的，共聚单体单元主要排列在聚丙烯嵌段之间。
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公开(公告)号：US5962719A
公开(公告)日：1999-10-05
申请号：US461141
申请日：1995-06-05
IPC分类号： C08F10/00 , C07F17/00 , C08F4/60 , C08F4/622 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/6592 , C08F110/06
CPC分类号： C08F110/06 , C07F17/00 , C08F4/63912 , C08F4/63927 , Y10S585/946
摘要： A process for the preparation of a polyolefin wax If a catalyst consisting of an aluminoxane and a metal-locene of the formula I ##STR1## in particular R.sup.5 R.sup.6 C (Ind).sub.2 or R.sup.5 R.sup.6 C (Ind).sub.2 Zr(CH.sub.3).sub.2, is employed for the polymerization of olefins of the formulaR.sup.9 CH.dbd.CHR.sup.10(R.sup.9, R.sup.10 =H or C.sub.1 -C.sub.28 alkyl), the isotacticity of the polymer wax and hence the hardness and melting point can be varied simply by changing the polymerization temperature, without the molecular weight of the polymer being noticeably changed at the same time.
摘要翻译： 用于制备聚烯烃蜡的方法如果由铝氧烷和式I的金属 - 特别是R 5 R 6 C（Ind）2或R 5 R 6 C（Ind）2 Zr（CH 3）2组成的催化剂用于聚合 式R9CH = CHR10（R9，R10 = H或C1-C28烷基）的烯烃，聚合物蜡的全同立构规整度，因此硬度和熔点可以通过改变聚合温度而简单地改变，而不需要聚合物的分子量 同时明显改变。
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