公开(公告)号：US20100136273A1

公开(公告)日：2010-06-03

申请号：US12444871

申请日：2007-10-09

申请人： Miguel A. Prieto ,  Peter Sandkuehler ,  Antonio Batistini ,  Sandra Hofmann ,  Stephen F. Hahn ,  Mohamed Esseghir ,  Monika Plass ,  Mark F. Sonnenschein ,  H. Craig Silvis ,  Hamed Lakrout ,  Kevin J. Bouck ,  Muthu Subramanian ,  Jinder Jow ,  Thiam Aik Lim ,  Stephen Y. Cheng ,  Lester Yeong

发明人： Miguel A. Prieto ,  Peter Sandkuehler ,  Antonio Batistini ,  Sandra Hofmann ,  Stephen F. Hahn ,  Mohamed Esseghir ,  Monika Plass ,  Mark F. Sonnenschein ,  H. Craig Silvis ,  Hamed Lakrout ,  Kevin J. Bouck ,  Muthu Subramanian ,  Jinder Jow ,  Thiam Aik Lim ,  Stephen Y. Cheng ,  Lester Yeong

IPC分类号： B32B27/36 ,  B32B1/08

CPC分类号： C08J5/12 ,  B32B7/12 ,  B32B27/02 ,  B32B27/08 ,  B32B27/32 ,  B32B27/36 ,  Y10T428/1393 ,  Y10T428/31797

摘要： The present invention is an article of construction formed from an article adhesively-bonded to a layering material through (a) reactive coupling of a functionalized nitroxide or (b) the adhesion of components in a polymer matrix made from or containing a polymer, an organic peroxide, and a functionalized nitroxide. The initial article may be expanded. It may also be polar or nonpolar. Similarly, the layering material may be polar or nonpolar. Other embodiments of the present invention are described, including other articles and methods for preparing the articles. The useful articles of the present invention include shoe outsoles and midsoles, paints, overmolded articles, weather stripping, gaskets, profiles, belts, hoses, tubes, durable goods, tires, construction panels, leisure and sports equipment foams, energy management foams, acoustic management foams, insulation foams, other foams, automotive parts (including bumper fascias, vertical panels, soft thermoplastic polyolefin skins, and interior trim), toys, supported films (including single-ply and co-extruded films), glass laminations, leather articles (synthetic and natural), personal health care and hygiene articles, other metal laminates, wood composites, automotive belts, hoses, tubes, conveyor belts, footwear, sporting goods, and filled articles.

摘要翻译： 本发明是通过（a）官能化氮氧化物的反应性偶联或（b）由聚合物或有机聚合物制成的聚合物基质中的组分的粘合而形成的粘合剂与层压材料形成的制品， 过氧化物和官能化的氮氧化物。 最初的文章可能会扩大。 它也可以是极性或非极性。 类似地，分层材料可以是极性或非极性的。 描述了本发明的其它实施例，包括用于制备制品的其它制品和方法。 本发明的有用制品包括鞋底和中底，油漆，包覆制品，气候剥离，垫片，型材，皮带，软管，管，耐用品，轮胎，建筑面板，休闲和运动设备泡沫，能量管理泡沫，声学 管理泡沫，绝缘泡沫，其他泡沫，汽车零件（包括保险杠，垂直面板，软质热塑性聚烯烃外皮和内饰），玩具，支撑膜（包括单层和共挤出膜），玻璃叠片，皮革制品 （合成和天然），个人保健和卫生用品，其他金属层压板，木材复合材料，汽车皮带，软管，管，输送带，鞋类，运动用品和填充物品。

公开(公告)号：US20080087380A1

公开(公告)日：2008-04-17

申请号：US11580402

申请日：2006-10-13

申请人： Miguel A. Prieto Goubert ,  Peter Sandkuehler ,  Antonio Batistini ,  Sandra Hofmann ,  Stephen F. Hahn ,  Mohamed Esseghir ,  Monika Plass ,  Mark F. Sonnenschein ,  H. Craig Silvis ,  Hamed Lakrout ,  Kevin J. Bouck

发明人： Miguel A. Prieto Goubert ,  Peter Sandkuehler ,  Antonio Batistini ,  Sandra Hofmann ,  Stephen F. Hahn ,  Mohamed Esseghir ,  Monika Plass ,  Mark F. Sonnenschein ,  H. Craig Silvis ,  Hamed Lakrout ,  Kevin J. Bouck

IPC分类号： C09J5/02 ,  C08F285/00

CPC分类号： C08J5/12 ,  B32B7/12 ,  B32B27/02 ,  B32B27/08 ,  B32B27/32 ,  B32B27/36 ,  Y10T428/1393 ,  Y10T428/31797

摘要： The present invention is an article of construction formed from an article adhesively-bonded to a layering material through (a) reactive coupling of a functionalized nitroxide or (b) the adhesion of components in a polymer matrix made from or containing a polymer, an organic peroxide, and a functionalized nitroxide. The initial article may be expanded. The initial article may be expanded. It may also be polar or nonpolar. Similarly, the layering material may be polar or nonpolar. Other embodiments of the present invention are described, including other articles and methods for preparing the articles.The useful articles of the present invention include shoe outsoles and midsoles, paints, overmolded articles, weather stripping, gaskets, profiles, durable goods, tires, construction panels, leisure and sports equipment foams, energy management foams, acoustic management foams, insulation foams, other foams, automotive parts (including bumper fascias, vertical panels, soft thermoplastic polyolefin skins, and interior trim), toys, supported films (including single-ply and co-extruded films), glass laminations, leather articles (synthetic and natural), personal health care and hygiene articles, other metal laminates, wood composites, and filled articles.

摘要翻译： 本发明是通过（a）官能化氮氧化物的反应性偶联或（b）由聚合物或有机聚合物制成的聚合物基质中的组分的粘合而形成的粘合剂与层压材料形成的制品， 过氧化物和官能化的氮氧化物。 最初的文章可能会扩大。 最初的文章可能会扩大。 它也可以是极性或非极性。 类似地，分层材料可以是极性或非极性的。 描述了本发明的其它实施例，包括用于制备制品的其它制品和方法。 本发明的有用制品包括鞋底和中底，油漆，包覆成型制品，气候剥离，垫片，型材，耐用品，轮胎，建筑面板，休闲和运动设备泡沫，能量管理泡沫，声学管理泡沫，绝缘泡沫， 其他泡沫，汽车零件（包括保险杠，垂直面板，软质热塑性聚烯烃表面和内饰），玩具，支撑膜（包括单层和共挤出膜），玻璃叠片，皮革制品（合成和天然） 个人保健和卫生用品，其他金属层压板，木质复合材料和填充物品。

公开(公告)号：US20130059165A1

公开(公告)日：2013-03-07

申请号：US13697276

申请日：2011-04-20

申请人： David L. Malotky ,  Sandra Hofmann ,  Charles F. Diehl ,  Michael D. Read ,  Antonio Batistini ,  H. Craig Silvis ,  Cristiano Betté

发明人： David L. Malotky ,  Sandra Hofmann ,  Charles F. Diehl ,  Michael D. Read ,  Antonio Batistini ,  H. Craig Silvis ,  Cristiano Betté

IPC分类号： C09D123/36 ,  B05D5/10 ,  B32B27/32

CPC分类号： C08L51/00 ,  C08F2438/02 ,  C08L51/003 ,  C08L2205/02 ,  Y10T428/31938 ,  C08L2666/24

摘要： The instant invention is an adhesion promoter system, and method of producing the same. The adhesion promoter system according to the present invention comprises an aqueous dispersion comprising the melt kneading product of: (a) at least 60 percent by weight of a first functionalized polyolefin, based on the total weight of the solid content; (b) optionally from 0.5 to less than 40 percent by weight of a second functionalized polyolefin, based on the total weight of the solid content, wherein said second functionalized polyolefin comprises homopolymers of propylene or copolymers of propylene with hexene, octene and/or other like alpha-olefins, the homopolymers or copolymers having a single unsaturation, a terminal succinic anhydride moiety, and additional succinic anhydride substitutions on the polypropylene backbone, where the succinic anhydride substitution ranges from about 5 to about 45 weight percent of second functionalized polyolefin; (c) from 0.1 to less than 20 percent by weight of a stabilizing agent, based on the total weight of the solid content; and (d) in the presence of water and optionally one or more neutralizing agents, for example, at a temperature in the range of 25° C. to 200° C.

摘要翻译： 本发明是一种粘合促进剂体系及其制造方法。 根据本发明的粘合促进剂体系包含水分散体，其包含熔融捏合产物，其基于固体含量的总重量：（a）至少60重量％的第一官能化聚烯烃; （b）基于固体含量的总重量，任选地0.5至小于40重量％的第二官能化聚烯烃，其中所述第二官能化聚烯烃包括丙烯均聚物或丙烯与己烯，辛烯和/或其它物质的共聚物 类似α-烯烃，具有单一不饱和键的均聚物或共聚物，末端琥珀酸酐部分和在聚丙烯主链上的另外的琥珀酸酐取代基，其中琥珀酸酐取代为约5至约45重量％的第二官能化聚烯烃; （c）基于固体含量的总重量，0.1至小于20重量％的稳定剂; 和（d）在水和任选的一种或多种中和剂的存在下，例如在25℃至200℃的温度范围内。

公开(公告)号：US20130059163A1

公开(公告)日：2013-03-07

申请号：US13697262

申请日：2011-04-20

申请人： Sandra Hofmann ,  Bart Noordover ,  Cristiano Betté ,  Antonio Batistini ,  Elisa Passaglia ,  H. Craig Silvis

发明人： Sandra Hofmann ,  Bart Noordover ,  Cristiano Betté ,  Antonio Batistini ,  Elisa Passaglia ,  H. Craig Silvis

IPC分类号： C09D123/26 ,  B05D5/10 ,  B32B7/12 ,  C09J7/02 ,  B32B27/32

CPC分类号： C09D123/02 ,  C08L2205/02 ,  C08L2666/24 ,  C09J123/02 ,  Y10T428/31938

摘要： The instant invention is an adhesion promoter system, and method of producing the same. The adhesion promoter system comprises the admixing product of: (a) at least 60 percent by weight of a first functionalized polyolefin, based on the total weight of the solid content; (b) less than 40 percent by weight of a second functionalized polyolefin, based on the total weight of the solid content, wherein said second functionalized polyolefin comprise homopolymers of propylene or copolymers of propylene with hexene, octene and/or other like alpha-olefins, the homopolymers or copolymers having a single unsaturation, a terminal succinic anhydride moiety, and additional succinic anhydride substitutions on the polypropylene backbone, where the succinic anhydride substitution ranges from about 5 to about 45 weight percent of second functionalized polyolefin; (c) in the presence of one or more solvents.

摘要翻译： 本发明是一种粘合促进剂体系及其制造方法。 粘合促进剂体系包括以下物质的混合产物：（a）至少60重量％的第一官能化聚烯烃，基于固体含量的总重量; （b）基于固体含量的总重量小于40重量％的第二官能化聚烯烃，其中所述第二官能化聚烯烃包含丙烯的均聚物或丙烯与己烯，辛烯和/或其它类似的α-烯烃的共聚物 ，具有单一不饱和键的均聚物或共聚物，末端琥珀酸酐部分和在聚丙烯主链上的另外的琥珀酸酐取代，其中琥珀酸酐取代为约5至约45重量％的第二官能化聚烯烃; （c）在一种或多种溶剂的存在下。

公开(公告)号：US11225584B2

公开(公告)日：2022-01-18

申请号：US13697262

申请日：2011-04-20

申请人： Sandra Hofmann ,  Bart Noordover ,  Cristiano Betté ,  Antonio Batistini ,  Elisa Passaglia ,  H. Craig Silvis

发明人： Sandra Hofmann ,  Bart Noordover ,  Cristiano Betté ,  Antonio Batistini ,  Elisa Passaglia ,  H. Craig Silvis

IPC分类号： C09D123/26 ,  C09D123/02 ,  C09J123/02

摘要： Adhesion promoter systems and methods of producing same, the systems including the admixing product of at least 60 percent by weight of a first functionalized polyolefin, and less than 40 percent by weight of a second functionalized polyolefin, based on the total weight of the solid content, and one or more solvents. The second functionalized polyolefin includes homopolymers of propylene or copolymers of propylene with hexene, octene and/or other alpha-olefins. The homopolymers or copolymers have a single unsaturation a terminal succinic anhydride moiety, and additional succinic anhydride substitutions on the polypropylene backbone. The succinic anhydride substitution ranges from about 5 to about 45 weight percent of second functionalized polyolefin.

公开(公告)号：US06767931B2

公开(公告)日：2004-07-27

申请号：US10332683

申请日：2003-01-09

申请人： Felipe Martinez ,  Antonio Batistini ,  Jerker B. L. Kjellqvist ,  Ronald Wevers

发明人： Felipe Martinez ,  Antonio Batistini ,  Jerker B. L. Kjellqvist ,  Ronald Wevers

IPC分类号： C08J900

CPC分类号： C08J9/0061 ,  C08J9/00 ,  C08J9/10 ,  C08J2325/08 ,  C08J2423/00 ,  C08L23/08 ,  C08L23/0838 ,  C08L23/0853 ,  C08L25/06 ,  C08L31/04 ,  C08L51/06 ,  C08L53/02 ,  C08L83/00 ,  C08L83/04 ,  C08L2203/14 ,  C08L2666/04 ,  C08L2666/02

摘要： A foamable polymer composition is described which comprises: a1) a substantially random interpolymer produced from: i) one or more &agr;-olefin monomers; and ii) one or more vinyl or vinylidene aromatic monomers and/or one or more sterically hindered aliphatic or cycloaliphiatic vinyl or vinylidene monomers; and optionally iii) other polymerizable ethylenically unsaturated monomer(s); or a2) an interpolymer comprising polymerized units of ethylene and vinyl acetate; or a3) a combination of the polymers a1) and a2); and b) a polydiorganosiloxane having a viscosity of at least one million centistoke at 25° C.; and c) a foaming agent. The polydiorganosiloxane is useful for improving the abrasion resistance of foams comprising the substantially random interpolymer a1) and/or the ethylene/vinyl acetate interpolymer a2).

摘要翻译： 描述了一种可发泡聚合物组合物，其包含：a1）由以下物质制备的基本上无规的互聚物：i）一种或多种α-烯烃单体; 和ii）一种或多种乙烯基或亚乙烯基芳族单体和/或一种或多种空间位阻的脂族或环烯基乙烯基或亚乙烯基单体; 和任选地iii）其它可聚合的烯属不饱和单体; 或a2）包含乙烯和乙酸乙烯酯的聚合单元的互聚物; 或a3）聚合物a1）和a2）的组合; 和b）在25℃下具有至少百万厘沲的粘度的聚二有机硅氧烷; 和c）发泡剂。 聚二有机硅氧烷可用于改善包含基本上无规共聚体a1）和/或乙烯/乙酸乙烯酯互聚物a2）的泡沫的耐磨性。

公开(公告)号：US07727286B2

公开(公告)日：2010-06-01

申请号：US12472739

申请日：2009-08-05

申请人： Rona L. Reid ,  Thoi H. Ho ,  Selim Bensason ,  Rajen M. Patel ,  Antonio Batistini

发明人： Rona L. Reid ,  Thoi H. Ho ,  Selim Bensason ,  Rajen M. Patel ,  Antonio Batistini

IPC分类号： D06L3/08 ,  D06L3/00

CPC分类号： D04B21/16 ,  D06M11/30 ,  D06M11/40 ,  D06M11/50 ,  D06M13/08 ,  G01N33/36 ,  Y10T442/2861

摘要： Durable stretch fabrics are made and processed from one or more crosslinked, heat-resistant olefin elastic fibers, e.g., a substantially linear, homogeneously branched ethylene polymer. The fabrics can be made by any process, e.g., weaving, knitting, etc., and from any combination of crosslinked, heat-resistant olefin elastic and inelastic (“hard”) fibers, e.g., cotton and wool. These fabrics exhibit excellent chemical, e.g., chlorine, resistance and durability, e.g., they retain their shape and feel (“hand”) over repeated exposure to processing conditions, e.g., stone-washing, dye-stripping, PET-dyeing and the like, and service conditions, e.g., washing, drying, etc.

摘要翻译： 耐久的拉伸织物由一种或多种交联的耐热烯烃弹性纤维制成和加工，例如基本上线性均匀支化的乙烯聚合物。 织物可以通过任何方法制造，例如编织，编织等，以及交联，耐热烯烃弹性和非弹性（“硬”）纤维如棉和羊毛的组合。 这些织物表现出优异的化学性质，例如氯，耐性和耐久性，例如，它们在反复暴露于加工条件（例如石洗，染料剥离，PET染色等）中保持其形状和手感（“手”） 和服务条件，如洗涤，干燥等

公开(公告)号：US06709742B2

公开(公告)日：2004-03-23

申请号：US09945532

申请日：2001-08-31

申请人： Mladen Ladika ,  John Klier ,  Ashish Sen ,  Erin D. O'Driscoll ,  Nancy J. Schrock ,  Antonio Batistini

发明人： Mladen Ladika ,  John Klier ,  Ashish Sen ,  Erin D. O'Driscoll ,  Nancy J. Schrock ,  Antonio Batistini

IPC分类号： D02G300

CPC分类号： D04B21/18 ,  A61F13/4902 ,  C08L23/04 ,  C08L23/0815 ,  C08L23/0838 ,  C08L23/10 ,  D01F1/10 ,  D01F6/30 ,  D01F6/46 ,  D01F8/06 ,  Y10T428/2913 ,  Y10T428/2933 ,  Y10T428/2967 ,  Y10T428/2969 ,  C08L2666/04

摘要： Elastic fibers are described that comprise (i) a polyolefin polymer, e.g., a homogeneously branched, preferably substantially linear, ethylene polymer, and (ii) a photoinitiator, e.g., an aromatic ketone, in an amount sufficient to effect at least a partial cross-linking of the polymer when the fiber is exposed to sufficient UV-radiation to activate the photoinitiator. Articles, e.g., fabrics, comprising fibers of this invention, either alone or in combination with one or more other fibers, e.g., cellulose, nylon, etc., exhibit good heat resistance and elasticity at elevated temperatures.

摘要翻译： 描述了弹性纤维，其包含（i）聚烯烃聚合物，例如均匀支化的，优选基本上线性的乙烯聚合物，和（ii）光引发剂，例如芳族酮，其量足以实现至少部分交叉 当纤维暴露于足够的UV辐射以激活光引发剂时聚合物的连接。 单独或与一种或多种其它纤维（例如纤维素，尼龙等）组合的包含本发明纤维的制品，例如织物在升高的温度下表现出良好的耐热性和弹性。

公开(公告)号：US06184290B2

公开(公告)日：2001-02-06

申请号：US08979388

申请日：1997-11-26

申请人： Wasif K. Ahmed ,  Antonio Batistini ,  Stephen R. Betso ,  Martin J. Guest ,  Thoi H. Ho ,  George W. Knight ,  Deepak R. Parikh ,  Rajen M. Patel

发明人： Wasif K. Ahmed ,  Antonio Batistini ,  Stephen R. Betso ,  Martin J. Guest ,  Thoi H. Ho ,  George W. Knight ,  Deepak R. Parikh ,  Rajen M. Patel

IPC分类号： C08L4700

CPC分类号： C09D153/02 ,  C08L23/0815 ,  C08L53/02 ,  C08L2314/06 ,  C08L2666/02 ,  C08L2666/04 ,  C09J153/02

摘要： The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having: i. storage moduli throughout the range of −26° C. to 24° C. of less than about 3.5×109 dynes/cm2, ii. a ratio of storage modulus at −26° C. to storage modulus at 24° C. of less than about 4, and iii. storage moduli at −26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at −26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.

摘要翻译： 本发明是至少一种包含至少一种嵌段共聚物的双组分热塑性弹性体组合物，其中组合物与组合物未未改性的未稀释（纯）嵌段共聚物部分具有基本上相同的比较弹性，高温可使用性和硬度。 该组合物还显示出增强的热稳定性和加工性，并且非常适用于制造弹性模制品，薄膜和纤维，以及用沥青，粘合剂和密封剂配制。 新型热塑性弹性体组合物包含（a）约50至约99重量％的至少一种嵌段共聚物和（b）约1至约50重量％的至少一种乙烯互聚物，其密度约为0.855克/ cc至约0.905g / cc，其中所用量的乙烯互聚物是嵌段共聚物的基本惰性的增量剂，组合物进一步表征为具有： 在-26℃至24℃的范围内的储存模量小于约3.5×10 9达因/厘米2，ii。 在-26℃下的储能模量与24℃下的储能模量的比小于约4，和iii。 在-26℃和24℃下的储存模量分别比组合物的纯嵌段共聚物部分的-26℃和24℃下的储存模量高约0.2至约3倍。

公开(公告)号：US20100024134A1

公开(公告)日：2010-02-04

申请号：US12472739

申请日：2009-08-05

申请人： Rona L. Reid ,  Thoi H. Ho ,  Selim Bensason ,  Rajen M. Patel ,  Antonio Batistini

发明人： Rona L. Reid ,  Thoi H. Ho ,  Selim Bensason ,  Rajen M. Patel ,  Antonio Batistini

IPC分类号： D06M11/40 ,  D06M11/38 ,  D06M11/30 ,  D06M11/50

CPC分类号： D04B21/16 ,  D06M11/30 ,  D06M11/40 ,  D06M11/50 ,  D06M13/08 ,  G01N33/36 ,  Y10T442/2861

摘要： Durable stretch fabrics are made and processed from one or more crosslinked, heat-resistant olefin elastic fibers, e.g., a substantially linear, homogeneously branched ethylene polymer. The fabrics can be made by any process, e.g., weaving, knitting, etc., and from any combination of crosslinked, heat-resistant olefin elastic and inelastic (“hard”) fibers, e.g., cotton and wool. These fabrics exhibit excellent chemical, e.g., chlorine, resistance and durability, e.g., they retain their shape and feel (“hand”) over repeated exposure to processing conditions, e.g., stone-washing, dye-stripping, PET-dyeing and the like, and service conditions, e.g., washing, drying, etc.

摘要翻译： 耐久的拉伸织物由一种或多种交联的耐热烯烃弹性纤维制成和加工，例如基本上线性均匀支化的乙烯聚合物。 织物可以通过任何方法制造，例如编织，编织等，以及交联，耐热烯烃弹性和非弹性（“硬”）纤维如棉和羊毛的组合。 这些织物表现出优异的化学性质，例如氯，耐性和耐久性，例如，它们在反复暴露于加工条件（例如石洗，染料剥离，PET染色等）中保持其形状和手感（“手”） 和服务条件，如洗涤，干燥等