公开(公告)号：US4149009A

公开(公告)日：1979-04-10

申请号：US853234

申请日：1977-11-21

申请人： Mikio Yoneoka ,  Minoru Osugi

发明人： Mikio Yoneoka ,  Minoru Osugi

IPC分类号： B01J23/00 ,  C07B61/00 ,  C07C67/00 ,  C07C67/40 ,  C07C69/06

CPC分类号： C07C67/00 ,  C07C67/40

摘要： A process for producing methyl formate which comprises dehydrogenating methanol in vapor phase in the presence as a catalyst of copper, zirconium and zinc and optionally aluminum is disclosed.

摘要翻译： 公开了一种生产甲酸甲酯的方法，其包括在作为铜，锆和锌以及任选的铝的催化剂存在下气相中的甲醇脱氢。

公开(公告)号：US4232171A

公开(公告)日：1980-11-04

申请号：US28681

申请日：1979-04-10

申请人： Mikio Yoneoka ,  Minoru Osugi ,  Takeo Ikarashi

发明人： Mikio Yoneoka ,  Minoru Osugi ,  Takeo Ikarashi

IPC分类号： C07C69/06 ,  B01J23/00 ,  B01J23/72 ,  C07C20060101 ,  C07C67/00 ,  C07C67/40

CPC分类号： C07C67/40

摘要： A process for producing methyl formate which comprises dehydrogenating methanol in the vapor phase in the presence of a catalyst containing copper and a cement is disclosed.

摘要翻译： 公开了一种生产甲酸甲酯的方法，该方法包括在含有铜和水泥的催化剂存在下，使气相中的甲醇脱氢。

公开(公告)号：US4014939A

公开(公告)日：1977-03-29

申请号：US584366

申请日：1975-06-05

申请人： Minoru Osugi ,  Takako Endo

发明人： Minoru Osugi ,  Takako Endo

IPC分类号： B01J23/80 ,  B01J37/20 ,  C07C45/00 ,  C07C45/86 ,  C07C45/16 ,  C07C47/04

CPC分类号： C07C45/002 ,  B01J23/80 ,  B01J37/20 ,  C07C45/86

摘要： Methanol is dehydrogenated at 500-750.degree. C. using a catalyst whose active components are copper, zinc and sulfur to form a stable product containing 30 to 85% by weight of formaldehyde, 0 to 2% by weight of water, the balance being methanol.

摘要翻译： 使用活性成分为铜，锌和硫的催化剂，在500-750℃下脱甲醇，形成含有30〜85重量％甲醛，0〜2重量％水的稳定产物，余量为甲醇 。

公开(公告)号：US4386017A

公开(公告)日：1983-05-31

申请号：US205594

申请日：1980-11-10

申请人： Tadasi Nakamura ,  Minoru Osugi ,  Yoriko Obata ,  Shuji Ebata

发明人： Tadasi Nakamura ,  Minoru Osugi ,  Yoriko Obata ,  Shuji Ebata

IPC分类号： C07C29/15 ,  B01J23/80 ,  C07B61/00 ,  C07C27/00 ,  C07C29/154 ,  C07C31/04 ,  C07C67/00 ,  B01J23/08 ,  B01J21/02 ,  B01J27/24

CPC分类号： B01J23/80 ,  C07C29/154 ,  Y02P20/52

摘要： A process for preparing a catalyst composition comprising copper oxide, zinc oxide and aluminum oxide as essential ingredients and optionally containing boron oxide, which comprises(a) a step of precipitating from an aqueous solution of a water-soluble copper salt optionally containing a water-soluble boron compound the copper component, together with the boron component if it is present, using an alkaline substance selected from alkali carbonates and alkali bicarbonates as a precipitant;(b) a step of blowing carbon dioxide gas into an aqueous dispersion of a zinc compound selected from zinc oxide and zinc hydroxide optionally containing a water-soluble boron compound to convert the zinc compound to basic zinc carbonate and simultaneously precipitate the boron component if it is present; and(c) a step of calcining a mixture of the solid products obtained in steps (a) and (b) in the presence of an alumina precursor compound.The resulting catalyst is useful for synthesizing methanol from a gaseous mixture of carbon monoxide and/or carbon dioxide and hydrogen.

摘要翻译： 一种制备包含氧化铜，氧化锌和氧化铝作为必要成分并任选地含有氧化硼的催化剂组合物的方法，其包括（a）从任选含有水溶性铜盐的水溶性铜盐的水溶液中沉淀出的步骤， 使用选自碱金属碳酸盐和碱金属碳酸氢盐的碱性物质作为沉淀剂，将铜组分与硼组分一起存在; （b）将任选含有水溶性硼化合物的锌化合物的锌化合物的水分散体吹入二氧化碳气体的步骤，将锌化合物转化为碱式碳酸锌，同时使硼成分沉淀 存在; 和（c）在氧化铝前体化合物的存在下煅烧步骤（a）和（b）中获得的固体产物的混合物的步骤。 所得催化剂可用于从一氧化碳和/或二氧化碳和氢气的气体混合物合成甲醇。

公开(公告)号：US4547482A

公开(公告)日：1985-10-15

申请号：US515933

申请日：1983-07-20

申请人： Minoru Osugi ,  Tadasi Nakamura ,  Shuji Ebata

发明人： Minoru Osugi ,  Tadasi Nakamura ,  Shuji Ebata

IPC分类号： C07C29/15 ,  B01J27/16 ,  B01J27/18 ,  C07B61/00 ,  C07C27/00 ,  C07C29/153 ,  C07C29/154 ,  C07C31/04 ,  C07C67/00 ,  B01J23/80

CPC分类号： B01J27/1817 ,  C07C29/153 ,  Y02P20/52

摘要： A catalyst composition comprising copper oxide, zinc oxide and an oxyacid of phosphorus or its salt; and a method for producing methanol by reacting carbon monoxide and/or carbon dioxide with hydrogen in the vapor phase in the presence of a catalyst, wherein the catalyst is the aforesaid catalyst composition which has been activated by reduction with a hydrogen-containing gas.

摘要翻译： 包含氧化铜，氧化锌和磷或其盐的含氧酸的催化剂组合物; 以及在催化剂存在下，使气相中的一氧化碳和/或二氧化碳与氢气反应生成甲醇的方法，其中催化剂是通过用含氢气体还原而活化的上述催化剂组合物。

公开(公告)号：US06716403B2

公开(公告)日：2004-04-06

申请号：US09986606

申请日：2001-11-09

申请人： Kenji Otsuka ,  Takashi Shimada ,  Minoru Osugi ,  Kei Kawaguchi

发明人： Kenji Otsuka ,  Takashi Shimada ,  Minoru Osugi ,  Kei Kawaguchi

IPC分类号： C01G300

CPC分类号： C22B3/44 ,  B01J23/92 ,  B01J23/94 ,  B01J38/60 ,  B01J38/68 ,  C22B7/009 ,  C22B15/00 ,  Y02P10/214 ,  Y02P10/234

摘要： The invention provides a method of recovering a copper component or a manganese component from a cleaning agent containing copper oxide, a cleaning agent containing basic copper carbonate, a cleaning agent containing copper hydroxide, or a cleaning agent containing copper oxide and manganese oxide, the cleaning agents having been used for removing, through contact with a harmful gas, a phosphine contained as a harmful component in the harmful gas. Also, the invention provides a method of recovering a copper component or a manganese component from a cleaning agent containing basic copper carbonate, a cleaning agent containing copper hydroxide, or a cleaning agent containing copper oxide and manganese oxide, the cleaning agents having been used for removing, through contact with a harmful gas, a phosphine contained as a harmful component in the harmful gas. According to the present invention, the copper component and/or the manganese component can be effectively recovered from the cleaning agents in a recyclable form.

公开(公告)号：US4054609A

公开(公告)日：1977-10-18

申请号：US697255

申请日：1976-06-17

申请人： Minoru Osugi ,  Takako Uchiyama

发明人： Minoru Osugi ,  Takako Uchiyama

IPC分类号： C07C47/055 ,  B01J23/00 ,  B01J27/057 ,  C07B61/00 ,  C07C45/00 ,  C07C47/052 ,  C07C67/00 ,  C07C47/04

CPC分类号： B01J27/0573 ,  C07C45/002

摘要： A process for the preparation of formaldehyde by subjecting methanol to dehydrogenation in the presence of a catalyst consisting of copper, zinc and selenium as metallic components.

摘要翻译： 在由铜，锌和硒作为金属组分的催化剂存在下使甲醇脱氢而制备甲醛的方法。

公开(公告)号：US07297315B2

公开(公告)日：2007-11-20

申请号：US10768671

申请日：2004-02-02

申请人： Kenji Otsuka ,  Takashi Shimada ,  Minoru Osugi ,  Kei Kawaguchi

发明人： Kenji Otsuka ,  Takashi Shimada ,  Minoru Osugi ,  Kei Kawaguchi

IPC分类号： C01G3/00

CPC分类号： C22B3/44 ,  B01J23/92 ,  B01J23/94 ,  B01J38/60 ,  B01J38/68 ,  C22B7/009 ,  C22B15/00 ,  Y02P10/214 ,  Y02P10/234

摘要： The invention provides a method of recovering a copper component or a manganese component from a cleaning agent containing copper oxide, a cleaning agent containing basic copper carbonate, a cleaning agent containing copper hydroxide, or a cleaning agent containing copper oxide and manganese oxide, the cleaning agents having been used for removing, through contact with a harmful gas, a phosphine contained as a harmful component in the harmful gas. Also, the invention provides a method of recovering a copper component or a manganese component from a cleaning agent containing basic copper carbonate, a cleaning agent containing copper hydroxide, or a cleaning agent containing copper oxide and manganese oxide, the cleaning agents having been used for removing, through contact with a harmful gas, a phosphine contained as a harmful component in the harmful gas. According to the present invention, the copper component and/or the manganese component can be effectively recovered from the cleaning agents in a recyclable form.

摘要翻译： 本发明提供一种从含有氧化铜的清洗剂，含碱性碳酸铜的清洗剂，含有氢氧化铜的清洗剂或含有氧化铜和氧化锰的清洗剂中回收铜成分或锰成分的方法， 已经用于通过与有害气体接触除去在有害气体中作为有害成分含有的磷化氢的试剂。 另外，本发明提供了从含有碱性碳酸铜的清洗剂，含有氢氧化铜的清洗剂或含有氧化铜和氧化锰的清洗剂中回收铜成分或锰成分的方法，所述清洗剂已被用于 通过与有害气体的接触除去在有害气体中作为有害成分含有的磷化氢。 根据本发明，可以以可回收的形式从清洗剂中有效地回收铜成分和/或锰成分。

公开(公告)号：US4806516A

公开(公告)日：1989-02-21

申请号：US77641

申请日：1987-07-24

申请人： Minoru Osugi ,  Tadasi Nakamura ,  Yoriko Obata

发明人： Minoru Osugi ,  Tadasi Nakamura ,  Yoriko Obata

IPC分类号： B01J23/80 ,  B01J37/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/154 ,  C07C29/16 ,  C07C31/04 ,  C07C67/00 ,  B01J21/02 ,  B01J21/06 ,  B01J23/06 ,  B01J23/72

CPC分类号： C07C29/154 ,  B01J23/80 ,  B01J37/0045 ,  Y02P20/52

摘要： A process for producing a fluidized catalyst for synthesis of methanol, which comprises molding a composition comprising(A) 10 to 55% by weight of a mixture composed of water-insoluble copper, zinc and zirconium compounds convertible respectively to copper, zinc and zirconium oxides under calcination conditions, said mixture optionally containing a boron compound,(B) 45 to 90% by weight of water, and(C) 0.01 to 1% by weight of ammonia into fine particles, and calcining the fine particles.

公开(公告)号：US4666945A

公开(公告)日：1987-05-19

申请号：US775114

申请日：1985-09-11

申请人： Minoru Osugi ,  Makoto Takagawa ,  Tadasi Nakamura ,  Takashi Kojima ,  Kinya Tsuji

发明人： Minoru Osugi ,  Makoto Takagawa ,  Tadasi Nakamura ,  Takashi Kojima ,  Kinya Tsuji

IPC分类号： C07C29/15 ,  B01J23/00 ,  B01J23/80 ,  B01J23/847 ,  B01J23/86 ,  B01J27/18 ,  C07B61/00 ,  C07C27/00 ,  C07C29/154 ,  C07C31/04 ,  C07C67/00 ,  C07C27/06 ,  C07C27/08

CPC分类号： B01J23/80 ,  C07C29/154 ,  Y02P20/52

摘要： A catalyst composition comprising copper oxide, zinc oxide and zirconium oxide, the content of zirconium oxide being 30 to 70% by weight. This catalyst composition is useful for synthesis of methanol from carbon monoxide and/or carbon dioxide and hydrogen by a gas-liquid-solid phase fluidized bed method or a gas-solid phase fluidized bed method.

摘要翻译： 包含氧化铜，氧化锌和氧化锆的催化剂组合物，氧化锆的含量为30〜70重量％。 该催化剂组合物可用于通过气 - 液 - 固相流化床法或气 - 固相流化床法从一氧化碳和/或二氧化碳和氢气合成甲醇。