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    BRANCHED POLYESTERS WITH SULFONATE GROUPS
    1.
    发明申请
    BRANCHED POLYESTERS WITH SULFONATE GROUPS 有权
    分散聚酯与磺酸酯组

    公开(公告)号：US20120322714A1

    公开(公告)日：2012-12-20

    申请号：US13495444

    申请日：2012-06-13

    申请人： Monika HABERECHT ,  Frank Ritting ,  Bernd Bruchmann ,  Claudia Esper ,  Roland Ettl ,  Karl Kolter

    发明人： Monika HABERECHT ,  Frank Ritting ,  Bernd Bruchmann ,  Claudia Esper ,  Roland Ettl ,  Karl Kolter

    IPC分类号： C08G63/91 ,  C11D3/37

    CPC分类号： C11D3/378 ,  C08G63/6888 ,  C08G63/918

    摘要： Branched polyesters with sulfonate groups obtainable by the reaction of the components A, B, optionally C and optionally D to give branched polyesters, where the component A is selected from the group of α,β-olefinically unsaturated dicarboxylic acids, and the component B is selected from the group of tri- or higher-functional alcohols, the optional component C is selected from the group of difunctional alcohols or of difunctional carboxylic acids without α,β-olefinically unsaturated bonds, the optional component D is selected from fatty acids or fatty alcohols, and the subsequent reaction of the resulting branched polyesters with hydrogen sulfite, where the molar amount of hydrogen sulfite is at most 95 mol %, based on the amount of α,β-olefinically unsaturated dicarboxylic acid.

    摘要翻译： 具有磺酸盐基团的支化聚酯可通过组分A，B，任选的C和任选的D反应获得，得到支链聚酯，其中组分A选自α，β-烯属不饱和二羧酸和组分B 选自三官能或更高官能的醇，任选的组分C选自二官能醇或不具有α，β-烯属不饱和键的双官能羧酸，任选的组分D选自脂肪酸 或脂肪醇，以及所得到的支链聚酯与亚硫酸氢盐的随后反应，其中亚硫酸氢盐的摩尔量基于α，α-烯属不饱和二羧酸的量为至多95摩尔％。

    Branched polyesters with sulfonate groups
    2.
    发明授权
    Branched polyesters with sulfonate groups 有权
    具有磺酸基团的支化聚酯

    公开(公告)号：US08846599B2

    公开(公告)日：2014-09-30

    申请号：US13495444

    申请日：2012-06-13

    申请人： Monika Haberecht ,  Frank Rittig ,  Bernd Bruchmann ,  Claudia Esper ,  Roland Ettl ,  Karl Kolter

    发明人： Monika Haberecht ,  Frank Rittig ,  Bernd Bruchmann ,  Claudia Esper ,  Roland Ettl ,  Karl Kolter

    IPC分类号： C11D1/00 ,  B08B3/04 ,  C11D3/37 ,  C08G63/91 ,  C08G63/688

    CPC分类号： C11D3/378 ,  C08G63/6888 ,  C08G63/918

    摘要： Branched polyesters with sulfonate groups obtainable by the reaction of the components A, B, optionally C and optionally D to give branched polyesters, where the component A is selected from the group of α,β-olefinically unsaturated dicarboxylic acids, and the component B is selected from the group of tri- or higher-functional alcohols, the optional component C is selected from the group of difunctional alcohols or of difunctional carboxylic acids without α,β-olefinically unsaturated bonds, the optional component D is selected from fatty acids or fatty alcohols, and the subsequent reaction of the resulting branched polyesters with hydrogen sulfite, where the molar amount of hydrogen sulfite is at most 95 mol %, based on the amount of α,β-olefinically unsaturated dicarboxylic acid.

    摘要翻译： 具有磺酸盐基团的支化聚酯可通过组分A，B，任选的C和任选的D反应获得，得到支链聚酯，其中组分A选自α，β-烯属不饱和二羧酸和组分B 选自三官能或更高官能的醇，任选的组分C选自二官能醇或不具有α，β-烯属不饱和键的双官能羧酸，任选的组分D选自脂肪酸 或脂肪醇，以及所得到的支链聚酯与亚硫酸氢盐的随后反应，其中亚硫酸氢盐的摩尔量基于α，α-烯属不饱和二羧酸的量为至多95摩尔％。

    POLYMERS WITH SACCHARIDE SIDE GROUPS AND THEIR USE
    3.
    发明申请
    POLYMERS WITH SACCHARIDE SIDE GROUPS AND THEIR USE 失效
    聚合物与SACCHARIDE SIDE GROUPS及其使用

    公开(公告)号：US20110313097A1

    公开(公告)日：2011-12-22

    申请号：US13161684

    申请日：2011-06-16

    申请人： Harald KELLER ,  Liqun Ren ,  Roland Ettl ,  Claudia Esper

    发明人： Harald KELLER ,  Liqun Ren ,  Roland Ettl ,  Claudia Esper

    IPC分类号： C08F216/14 ,  C08F216/02 ,  C09D5/00

    CPC分类号： C09D5/14 ,  C08F220/06 ,  C08F220/60

    摘要： A water-soluble or water-dispersible copolymer comprises copolymerized units a) of at least one ethylenically unsaturated monomer with a saccharide side group and b) of at least one hydrophilic ethylenically unsaturated monomer different from (meth)acrylamide, where the weight fraction of the ethylenically unsaturated monomers with a saccharide side group is 5 to 95% by weight. The copolymers exhibit high affinity to inorganic surfaces or hydrophilic fibers, such as cotton. They serve as soil release and/or graying-inhibiting polymers in textile detergents or minimize the risk of microbial colonization of materials coated therewith.

    摘要翻译： 水溶性或水分散性共聚物包含至少一种具有糖侧基的烯属不饱和单体的共聚单元a）和b）至少一种不同于（甲基）丙烯酰胺的亲水性烯属不饱和单体，其中重量分数 具有糖侧基的烯属不饱和单体为5〜95重量％。 共聚物表现出对无机表面或亲水性纤维如棉花的高亲和力。 它们用作织物洗涤剂中的污垢释放和/或变灰抑制聚合物，或者最小化其涂覆材料的微生物定居的风险。

    Polymers with saccharide side groups and their use
    4.
    发明授权
    Polymers with saccharide side groups and their use 失效
    具有糖侧基的聚合物及其用途

    公开(公告)号：US08481639B2

    公开(公告)日：2013-07-09

    申请号：US13161684

    申请日：2011-06-16

    申请人： Harald Keller ,  Liqun Ren ,  Roland Ettl ,  Claudia Esper

    发明人： Harald Keller ,  Liqun Ren ,  Roland Ettl ,  Claudia Esper

    IPC分类号： C08F216/14 ,  C08F216/02

    CPC分类号： C09D5/14 ,  C08F220/06 ,  C08F220/60

    摘要： A water-soluble or water-dispersible copolymer comprises copolymerized units a) of at least one ethylenically unsaturated monomer with a saccharide side group and b) of at least one hydrophilic ethylenically unsaturated monomer different from (meth)acrylamide, where the weight fraction of the ethylenically unsaturated monomers with a saccharide side group is 5 to 95% by weight. The copolymers exhibit high affinity to inorganic surfaces or hydrophilic fibers, such as cotton. They serve as soil release and/or graying-inhibiting polymers in textile detergents or minimize the risk of microbial colonization of materials coated therewith.

    摘要翻译： 水溶性或水分散性共聚物包含至少一种具有糖侧基的烯属不饱和单体的共聚单元a）和b）至少一种不同于（甲基）丙烯酰胺的亲水性烯属不饱和单体，其中重量分数 具有糖侧基的烯属不饱和单体为5〜95重量％。 共聚物表现出对无机表面或亲水性纤维如棉花的高亲和力。 它们用作织物洗涤剂中的污垢释放和/或变灰抑制聚合物，或者最小化其涂覆材料的微生物定居的风险。

    DISHWASHER DETERGENT FORMULATIONS COMPRISING A MIXTURE OF HYDROPHOBICALLY MODIFIED POLYCARBOXYLATES AND HYDROPHILICALLY MODIFIED POLYCARBOXYLATES
    8.
    发明申请
    DISHWASHER DETERGENT FORMULATIONS COMPRISING A MIXTURE OF HYDROPHOBICALLY MODIFIED POLYCARBOXYLATES AND HYDROPHILICALLY MODIFIED POLYCARBOXYLATES 有权
    含有疏水性改性聚碳酸酯和疏水改性聚碳酸酯的混合物的洗涤剂洗涤剂配方

    公开(公告)号：US20100234265A1

    公开(公告)日：2010-09-16

    申请号：US12682260

    申请日：2008-10-10

    申请人： Heike Weber ,  Roland Ettl ,  Juergen Tropsch

    发明人： Heike Weber ,  Roland Ettl ,  Juergen Tropsch

    IPC分类号： C11D3/37

    CPC分类号： C11D3/3757 ,  C11D1/72 ,  C11D3/33 ,  C11D3/3905

    摘要： Phosphate-free detergent formulations for machine dishwashing, comprising, as components: a) from 1 to 20% by weight of a mixture of a1) from 5 to 95% by weight of hydrophobically modified polycarboxylates I formed from a11) from 20 to 80 mol % of at least one monoethylenically unsaturated C3-C10-mono- or -dicarboxylic acid or anhydrides thereof, a12) from 0 to 80 mol % of at least one monomer of the general formula (I)  in which R1, R2 and R3 are each independently H, CH3 or C2H5, and R4 is a linear, branched or cyclic radical having from 1 to 6 carbon atoms or an aromatic radical having from 6 to 12 carbon atoms, and a13) from 0 to 20 mol % of at least one further monomer selected from the group consisting of olefins having 10 or more carbon atoms or mixtures thereof and reactive polyisobutenes having an average of from 12 to 100 carbon atoms, a2) from 5 to 95% by weight of hydrophilically modified polycarboxylates II formed from a21) from 50 to 99 mol % of acrylic acid or acrylic acid salt, a22) from 0 to 50 mol % of a further acidic monomer and/or of a water-soluble salt thereof, a23) from 0.1 to 20 mol % of at least one nonionic monomer of the general formula (II), where the sum of a1) and a2) adds up to 100% by weight, b) from 0 to 50% by weight of complexing agents, c) from 0.1 to 20% by weight of low-foam nonionic surfactants, d) from 0.1 to 30% by weight of bleaches and if appropriate bleach activators, e) from 0 to 60% by weight of further builders, f) from 0 to 8% by weight of enzymes, g) from 0 to 50% by weight of one or more further additives.

    摘要翻译： 包含作为组分的无磷酸盐洗涤剂配方：a）1至20重量％的a1）5至95重量％的疏水改性的多羧酸盐I的混合物，由a11）20至80mol ％的至少一种单烯属不饱和C 3 -C 10 - 单 - 或二羧酸或其酸酐，a 12）0至80摩尔％的至少一种通式（I）的单体，其中R 1，R 2和R 3各自为 独立地是H，CH 3或C 2 H 5，并且R 4是具有1至6个碳原子的直链，支链或环状基团或具有6至12个碳原子的芳族基团，和a 13）0至20摩尔％的至少一种 选自具有10个或更多个碳原子的烯烃或其混合物的单体和平均具有12至100个碳原子的活性聚异丁烯，a2）5至95重量％的亲水改性的聚羧酸盐II，其由 50〜99摩尔％的丙烯酸或丙烯酸 酸性盐，a22）0〜50摩尔％的其它酸性单体和/或其水溶性盐，a23）0.1〜20摩尔％的至少一种通式（II）的非离子单体，其中 a1）和a2）的总和相加至100重量％，b）0至50重量％的络合剂，c）0.1至20重量％的低泡沫非离子表面活性剂，d）0.1至 30％（重量）的漂白剂和适当的漂白活化剂，e）0-60％（重量）的另外助洗剂，f）0-8％（重量）的酶，g）0-50％重量的一种或多种 其他添加剂。

    PAPER SIZE MIXTURES
    9.
    发明申请
    PAPER SIZE MIXTURES 审中-公开
    纸尺寸混合

    公开(公告)号：US20100016478A1

    公开(公告)日：2010-01-21

    申请号：US12518312

    申请日：2007-12-11

    申请人： Andreas Brockmeyer ,  Roland Ettl ,  Rainer Dyllick-Brenzinger

    发明人： Andreas Brockmeyer ,  Roland Ettl ,  Rainer Dyllick-Brenzinger

    IPC分类号： C08L3/02 ,  C08F2/16 ,  C08K5/15 ,  C08L29/04 ,  C08L39/06 ,  C08L33/00 ,  C08G67/00 ,  C08L89/00 ,  C08L33/06 ,  C08L55/00

    CPC分类号： D21H17/34 ,  C08L3/00 ,  C08L2666/26 ,  C09J133/20 ,  D21H17/17 ,  D21H17/72 ,  D21H21/16

    摘要： Paper size mixtures comprising a reactive size dispersed in water and a polymer, which are obtainable by mixing (a) an aqueous dispersion of a reactive size whose dispersed particles have a mean particle diameter of less than 500 nm, the dispersion being obtainable by emulsifying at least one reactive size in water in the presence of at least one surfactant, and (b) at least one emulsion polymer and/or at least one water-soluble polymer which does not have a dispersing effect with respect to reactive sizes and/or a water-dispersible polymer, and use of said paper size mixtures for the engine sizing and surface sizing of paper and paper products.

    摘要翻译： 通过混合（a）具有平均粒径小于500nm的分散颗粒的反应性尺寸的水性分散体可以获得的分散在水中的反应尺寸的聚合物的纸尺寸混合物，所述分散体可通过乳化在 在至少一种表面活性剂存在下，在水中至少一种反应性大小，和（b）至少一种乳液聚合物和/或至少一种水溶性聚合物，其对于反应性大小和/或不具有分散作用 水分散性聚合物，以及使用所述纸尺寸混合物用于纸和纸产品的发动机尺寸和表面施胶。

    SUBSTRATES COATED WITH MALEIC ACID FOR ELECTROPHOTOGRAPHIC PRINTING METHOD
    10.
    发明申请
    SUBSTRATES COATED WITH MALEIC ACID FOR ELECTROPHOTOGRAPHIC PRINTING METHOD 审中-公开
    用于电子印刷方法的用马来酸涂覆的基材

    公开(公告)号：US20090162624A1

    公开(公告)日：2009-06-25

    申请号：US12300584

    申请日：2007-05-16

    申请人： Hildegard Stein ,  Roland Ettl ,  Hubertus Peter Bell

    发明人： Hildegard Stein ,  Roland Ettl ,  Hubertus Peter Bell

    IPC分类号： B32B5/00 ,  G03G13/10

    CPC分类号： G03G7/004 ,  G03G7/0033 ,  G03G7/008 ,  Y10T428/24802 ,  Y10T428/24934

    摘要： A process for printing on substrates, wherein the substrates are pretreated with a composition which comprises a polymer obtainable by free radical polymerization of ethylenically unsaturated compounds (monomers) (referred to below as polymer for short), and at least 1% by weight of the monomers are monomers having two carboxyl groups (dicarboxylic acid) or a dicarboxylic anhydride group (summarized below as anhydride monomer for short).

    摘要翻译： 一种用于在基材上印刷的方法，其中用含有烯键式不饱和化合物（单体）的自由基聚合可获得的聚合物（以下简称聚合物）和至少1重量％ 单体是具有两个羧基（二羧酸）或二羧酸酐基团的单体（以下简称为酸酐单体）。