公开(公告)号：US5705473A

公开(公告)日：1998-01-06

申请号：US232468

申请日：1994-04-22

申请人： Mutsumi Kuroda ,  Hiroshi Ohtsuka ,  Hiroyuki Yamashita ,  Mikio Sakaguchi ,  Hiroyuki Kondo ,  Kouichi Hatano ,  Fumio Sai

发明人： Mutsumi Kuroda ,  Hiroshi Ohtsuka ,  Hiroyuki Yamashita ,  Mikio Sakaguchi ,  Hiroyuki Kondo ,  Kouichi Hatano ,  Fumio Sai

IPC分类号： C11D1/66 ,  C11D1/72 ,  C11D3/12 ,  C11D10/02

CPC分类号： C11D3/128 ,  C11D1/66 ,  C11D1/72 ,  C11D3/124

摘要： To provide a nonionic powdery detergent free from oozing of a liquid nonionic surfactant at ambient temperature and having excellent powder fluidity and non-caking properties and a solubility which is not deteriorated with time. The nonionic powdery detergent composition comprises (a) 12 to 35% by weight of a nonionic surfactant having a melting point of not higher than 40.degree. C. and an HLB in the range of 9.0 to 16.0, (b) 10 to 60% by weight of a crystalline aluminosilicate and (c) 5 to 20% by weight of an amorphous oil-absorbing carrier containing at least 30% by weight of silicon (in terms of SiO.sub.2) versus the weight of said carrier in an anhydrous state and having an oil-absorbing capacity of at least 80 ml/100 g, said carrier giving a dispersion with a pH of at least 9 or being soluble in a 2% aqueous NaOH solution in an amount of 0.5 g or below.

摘要翻译： 提供在环境温度下不含液体非离子表面活性剂渗出的非离子型粉末洗涤剂，具有优异的粉末流动性和非结块性以及随时间而不劣化的溶解度。 非离子型粉末洗涤剂组合物包含（a）12〜35重量％的熔点不高于40℃的非离子表面活性剂和9.0〜16.0的（b）为10〜60质量％ 结晶硅铝酸盐的重量和（c）5至20重量％的无定形油吸收载体，其含有至少30重量％的硅（以SiO 2计）相对于所述载体的重量为无水状态，并具有 吸油能力至少为80ml / 100g，所述载体以0.5g或更低的pH提供pH至少为9或可溶于2％NaOH水溶液的分散体。

公开(公告)号：US5427711A

公开(公告)日：1995-06-27

申请号：US246711

申请日：1994-05-20

申请人： Mikio Sakaguchi ,  Ichiro Sakamoto ,  Mutsumi Kuroda ,  Masaki Tsumadori ,  Motomitsu Hasumi ,  Yuichi Sakamoto ,  Ryuichi Akagi ,  Fumio Sai

发明人： Mikio Sakaguchi ,  Ichiro Sakamoto ,  Mutsumi Kuroda ,  Masaki Tsumadori ,  Motomitsu Hasumi ,  Yuichi Sakamoto ,  Ryuichi Akagi ,  Fumio Sai

IPC分类号： B01J39/08 ,  B01J39/14 ,  C01B33/20 ,  C01B33/36 ,  C11D3/12 ,  C11D3/386 ,  C01B33/24 ,  C01B33/32 ,  C11D7/02

CPC分类号： C11D3/38636 ,  B01J39/085 ,  B01J39/14 ,  C01B33/20 ,  C01B33/36 ,  C11D3/1246 ,  C11D3/126

摘要： The synthesized crystalline ion exchange material or a hydrate thereof has a chain structure and a composition represented by the following general formula (A) in an anhydride form:xM.sub.2 O.ySiO.sub.2.zM'O, (A)wherein M represents Na and/or K; M' represents Ca and/or Mg; y/x is 0.5 to 2.0; and z/x is 0.005 to 1.0. The chain structure exhibits at least one main scattering peak at 970.+-.20 cm.sup.-1 in Raman spectra. The detergent composition contains the above synthesized inorganic crystalline ion exchange material. The inorganic ion exchange material of the present invention is excellent in both cationic exchange capacity and anti-solubility, making it useful to be used for a water softener and alkalinity regulator in detergents. The detergent composition of the present invention contains an inorganic ion exchange material which has anti-solubility as well as excellent ion exchange capacity and alkaline capacity, thereby offering excellent washing effects and is suitable for the concentration of detergent.

摘要翻译： 合成的结晶离子交换材料或其水合物具有以下通式（A）表示的链状结构和酸酐形式的组成：xM2O.ySiO2.zM'O，（A）其中M表示Na和/或K ; M'表示Ca和/或Mg; y / x为0.5〜2.0; z / x为0.005〜1.0。 该链结构在拉曼光谱中显示出970 +/- 20cm-1处的至少一个主散射峰。 洗涤剂组合物含有上述合成的无机结晶离子交换材料。 本发明的无机离子交换材料的阳离子交换容量和抗溶解性均优异，因此可用于洗涤剂中的软水剂和碱度调节剂。 本发明的洗涤剂组合物含有具有抗溶解性以及优异的离子交换容量和碱性能的无机离子交换材料，从而提供优异的洗涤效果，适用于洗涤剂的浓缩。

公开(公告)号：US4028283A

公开(公告)日：1977-06-07

申请号：US725184

申请日：1976-09-21

申请人： Moriyasu Murata ,  Fumio Sai ,  Takashi Fujino

发明人： Moriyasu Murata ,  Fumio Sai ,  Takashi Fujino

IPC分类号： C11D1/12 ,  C11D1/74 ,  C11D3/37 ,  C11D1/06 ,  C11D1/37

CPC分类号： C11D1/12 ,  C11D1/74 ,  C11D3/37 ,  C11D3/3761

摘要： A granular or powdery detergent composition comprising (I) as an active detergent component a surface active agent having a tendency to cake, and (II) as an anti-caking agent, from 0.2 to 20% by weight, based on the total weight of the detergent composition, of a carboxylic acid or an alkali metal salt thereof obtained by reacting (A) a polyalkylene glycol and (B) an acid anhydride, at an (A)/(B) mole ratio of from 1/2 to 1/1, said polyalkylene glycol being selected from (i) polyethylene glycols having an average molecular weight of 2000 to 10000 and (ii) nonionic surface active agents having the formula: ##STR1## wherein a, b and c are numbers satisfying the relations:140 .ltoreq. A + C .ltoreq. 200 AND 30 .ltoreq. B .ltoreq. 40,and the acid anhydride is selected from the group consisting of maleic anhydride, phthalic anhydride and succinic anhydride, and wherein the weight ratio of (II)/(I) is from 1/10 to 3/2.

摘要翻译： 一种粒状或粉末洗涤剂组合物，其包含（I）作为活性洗涤剂组分的具有饼干倾向的表面活性剂，和（II）作为抗结块剂，基于总重量的0.2至20重量％ 洗涤剂组合物，通过使（A）聚亚烷基二醇和（B）酸酐以（A）/（B）摩尔比为1/2至1/1的比例反应获得的羧酸或其碱金属盐， 1，所述聚亚烷基二醇选自（i）平均分子量为2000至10000的聚乙二醇和（ii）具有下式的非离子表面活性剂：其中a，b和c是满足下列关系的数：

公开(公告)号：US3960780A

公开(公告)日：1976-06-01

申请号：US627701

申请日：1975-10-31

申请人： Moriyasu Murata ,  Makoto Yamanaka ,  Fumio Sai

发明人： Moriyasu Murata ,  Makoto Yamanaka ,  Fumio Sai

IPC分类号： B01F17/02 ,  C11D1/29 ,  C11D3/37 ,  C11D1/14 ,  C11D17/06

CPC分类号： C11D3/3707 ,  C11D1/29

摘要： A granular or powdery detergent composition comprising from 3 to 25% by weight of a surfactant selected from ether sulfates having the formulae (I) and (II): ##EQU1## and ##EQU2## wherein R.sub.1 and R.sub.2 are hydrogen, alkyl having 1 to 21 carbon atoms or alkenyl having 1 to 21 carbon atoms, provided that the sum of the carbon atoms of R.sub.1 and R.sub.2 is 11 to 21, R.sub.3 is alkyl having 8 to 16 carbon atoms, n is a number of 1 to 10, and M is an alkali metal or an alkaline earth metal,And 10 to 100% by weight, based on said ether sulfate, of a polyethylene glycol having a molecular weight of 2,000 to 50,000.

摘要翻译： 包含3至25重量％的选自具有式（I）和（II）的醚硫酸盐的表面活性剂的颗粒或粉末洗涤剂组合物：R1 ANGLE CH-O-（CH2CH2O）nSO3M（I）R2和O-（ CH 2 CH 2 O）n SO 3 M（II）其中R 1和R 2为氢，具有1至21个碳原子的烷基或具有1至21个碳原子的烯基，条件是R 1和R 2的碳原子总数为11至21，R 3为具有 8〜16个碳原子，n为1〜10的数，M为碱金属或碱土金属，10重量％以重量计，基于硫酸钠，具有分子量的聚乙烯甘油 2,000至50,000。

公开(公告)号：US5411674A

公开(公告)日：1995-05-02

申请号：US943123

申请日：1992-09-10

申请人： Shuji Tagata ,  Fumio Sai

发明人： Shuji Tagata ,  Fumio Sai

IPC分类号： C11D1/28 ,  C11D1/12 ,  C11D1/14 ,  C11D1/22 ,  C11D1/29 ,  C11D1/52 ,  C11D1/66 ,  C11D1/72 ,  C11D1/75 ,  C11D1/83 ,  C11D10/04 ,  C11D1/10 ,  C11D1/04

CPC分类号： C11D10/045 ,  C11D10/04 ,  C11D10/042 ,  C11D1/123 ,  C11D1/14 ,  C11D1/143 ,  C11D1/22 ,  C11D1/29 ,  C11D1/523 ,  C11D1/662 ,  C11D1/72 ,  C11D1/75

摘要： A detergent composition which has an excellent detergency against muddy dirt of clothing. It comprises (a) nonionic surfactant, (b) fatty acid or salt thereof and (c) sulfosuccinic amide, and further (d) anionic surfactant as occasion demands.

摘要翻译： 一种洗涤剂组合物，其对衣物的泥土污垢具有优异的去污力。 它包括（a）非离子表面活性剂，（b）脂肪酸或其盐和（c）磺基琥珀酰胺，以及（d）阴离子表面活性剂。

公开(公告)号：US4208295A

公开(公告)日：1980-06-17

申请号：US5656

申请日：1979-01-22

申请人： Fumio Sai ,  Takashi Fujino

发明人： Fumio Sai ,  Takashi Fujino

IPC分类号： C11D3/12 ,  C11D3/39 ,  C11D3/395 ,  C11D7/54

CPC分类号： C11D3/3942 ,  C11D3/128

摘要： A bleaching detergent composition comprises (i) a water-insoluble aluminosilicate having a degree of crystallization of 0 to 75% or a water-insoluble aluminosilicate having exchangeable cations partially substituted by calcium and/or magnesium ions, (ii) a surface active agent and (iii) sodium percarbonate. It is very much improved in respect to the storage stability of the sodium percarbonate.

摘要翻译： 漂白洗涤剂组合物包含（i）具有0至75％结晶度的水不溶性硅铝酸盐或具有部分被钙和/或镁离子取代的可交换阳离子的水不溶性硅铝酸盐，（ii）表面活性剂和 （iii）过碳酸钠。 在过碳酸钠的储存稳定性方面有很大的改善。

公开(公告)号：US4163732A

公开(公告)日：1979-08-07

申请号：US853245

申请日：1977-11-21

申请人： Fumio Sai ,  Moriyasu Murata

发明人： Fumio Sai ,  Moriyasu Murata

IPC分类号： C11D3/12 ,  C11D3/36 ,  C11D3/08 ,  C11D7/36

CPC分类号： C11D3/128

摘要： A detergent composition containing, as a builder component, a water-insoluble, phosphorus-containing alkali metal aluminosilicate having the formulaX(M.sub.2 O).multidot.Al.sub.2 O.sub.3 .multidot.Y(SiO.sub.2).multidot.z(P.sub.2 O.sub.5).multidot.w(H.sub.2 O)wherein0.50.ltoreq.x.ltoreq.1.100.80.ltoreq.y.ltoreq.2.500.05.ltoreq.z.ltoreq.0.80and w is zero or an optional positive number.

摘要翻译： 一种洗涤剂组合物，其含有具有式X（M 2 O）x Al 2 O 3 x Y（SiO 2）x z（P 2 O 5）xw（H 2 O）的水不溶性的含磷碱金属硅铝酸盐作为助洗剂组分，其中0.050≤X= 1。

公开(公告)号：US4999138A

公开(公告)日：1991-03-12

申请号：US376006

申请日：1989-07-06

申请人： Tutomu Nebashi ,  Shinichi Yabe ,  Nobuyoshi Yamaguchi ,  Shuichi Takizawa ,  Fumio Sai

发明人： Tutomu Nebashi ,  Shinichi Yabe ,  Nobuyoshi Yamaguchi ,  Shuichi Takizawa ,  Fumio Sai

IPC分类号： C11D3/37 ,  C11D3/42 ,  C11D3/60 ,  C11D17/06

CPC分类号： C11D3/3707 ,  C11D17/065 ,  C11D3/42

摘要： A high density-having, granular, concentrated detergent composition comprises:(1) 30 to 50 wt. % of an anionic surface active agent,(2) 40 to 60 wt. % of an inorganic builder,(3) a fluorescent dye,(a) 5 to 25 wt. % of potassium salt of an anionic surfactant or 2 to 10 wt. % of potassium carbonate or potassium sulfate,(b) 0.1 to 3 wt. % of sodium chloride and(c) 0.2 to 5 wt. % of polyethylene glycol having a molecular weight of 6,000 to 20,000.

公开(公告)号：US4992198A

公开(公告)日：1991-02-12

申请号：US297842

申请日：1989-01-13

申请人： Tutomu Nebashi ,  Shinichi Yabe ,  Fumio Sai ,  Yu Izumi ,  Takashi Fujieda

发明人： Tutomu Nebashi ,  Shinichi Yabe ,  Fumio Sai ,  Yu Izumi ,  Takashi Fujieda

IPC分类号： C11D3/50

CPC分类号： C11D3/505

摘要： A high density-having, granular, concentrated detergent composition comprises a detergent component(s) and clathrate granules of a perfume-clathrate compound comprising a perfume and a compound having a clathration capability. The clathrate granules have an average size of 100 to 1500 micrometers.

公开(公告)号：US4869843A

公开(公告)日：1989-09-26

申请号：US212124

申请日：1988-06-24

申请人： Kozo Saito ,  Fumio Sai ,  Moriyasu Murata

发明人： Kozo Saito ,  Fumio Sai ,  Moriyasu Murata

IPC分类号： C11D3/02 ,  C11D17/00 ,  C11D17/06

CPC分类号： C11D3/046 ,  C11D17/0039 ,  C11D17/065 ,  C11D3/06 ,  C11D3/10

摘要： A granular detergent composition having a high density comprises an organic surfactant, a water-soluble, crystalline, inorganic salt, another inorganic salt and/or an organic sequestering agent for a divalent metal and a granular, water-soluble, crystalline, alkaline, inorganic salt, said alkaline salt having been blended in the dry state with a base comprising the above other three components. Instead of the alkaline salt, a granular, water-soluble, crystalline, inorganic salt having carried thereon an organic substance being capable of inhibiting hydration may be used.

摘要翻译： 具有高密度的颗粒状洗涤剂组合物包含有机表面活性剂，水溶性结晶无机盐，另一种无机盐和/或二价金属和颗粒状，水溶性，结晶，碱性，无机的无机盐和/或有机螯合剂 盐，所述碱性盐在干燥状态下与包含上述其它三种组分的碱组合。 可以使用其上承载有能够抑制水合的有机物质的颗粒状，水溶性的结晶的无机盐，而不是碱性盐。