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公开(公告)号：US4247384A
公开(公告)日：1981-01-27
申请号：US20601
申请日：1979-03-15
CPC分类号： C10G1/083
摘要： Improved method for solubilizing solid carbonaceous materials, e.g., wood and/or coal in an aromatic petroleum or coal-derived solvent in the presence of alkali and hydrogen transfer agent at elevated temperatures. The liquid products can be used as fuels or further processed into desirable products.
摘要翻译： 在碱和氢转移剂存在下，在升高的温度下，在芳香族石油或来自煤的溶剂中溶解固体碳质材料（例如木材和/或煤）的改进方法。 液体产品可用作燃料或进一步加工成所需产品。
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公开(公告)号：US4470254A
公开(公告)日：1984-09-11
申请号：US378160
申请日：1982-05-14
摘要： The present invention provides two-stage and three-stage fluidized bed process embodiments for burning carbonaceous solids for the generation of heat to produce motive fluids for application in combined cycle power plant systems.The finely-divided refractory solids employed in the fluidized beds may contain sorbent material to neutralize noxious gas constituents and yield a clean flue gas for venting.
摘要翻译： 本发明提供两阶段和三阶段流化床方法实施例，用于燃烧碳质固体以产生热量以产生用于联合循环发电厂系统的运动流体。 在流化床中使用的细碎耐火材料固体可能含有吸附剂材料以中和有害气体成分，并产生用于排气的干净烟道气。
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3.发明授权
公开(公告)号：US5401393A
公开(公告)日：1995-03-28
申请号：US120505
申请日：1993-09-14
CPC分类号： B01J20/264 , B01J20/0266 , B01J20/265 , B01J20/267 , B01J20/28004 , B01J20/28016 , B01J20/28057 , B01J20/3078 , B01J20/321 , B01J20/3234 , C10G25/02 , B01J2220/46
摘要： A method is disclosed for synthesizing a reactive sulfur-containing adsorbent material for removing metals, preferably mercury, from hydrocarbon fluids. The method includes impregnating a porous polystyrene resin with elemental sulfur, and heating the impregnated resin/sulfur mixture to chemically fix the sulfur to the resin. The elemental sulfur may be in solid, liquid, or vapor phase under conditions of contact with the resin. Also disclosed is the reactive adsorbent synthesized by this method. Also, a process is disclosed for removing mercury from hydrocarbon fluids by using a reactive adsorbent of the invention.
摘要翻译： 公开了一种合成用于从烃流体中除去金属（优选汞）的反应性含硫吸附剂材料的方法。 该方法包括用元素硫浸渍多孔聚苯乙烯树脂，并加热浸渍的树脂/硫混合物以将硫化学固定在树脂上。 在与树脂接触的条件下，元素硫可以是固体，液体或气相。 还公开了通过该方法合成的反应性吸附剂。 此外，公开了通过使用本发明的反应性吸附剂从烃流体中除去汞的方法。
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4.发明授权Continuous coking of residual oil and production of gaseous fuel and smokeless solid fuels from coal 失效剩余油的持续焦化以及来自煤的气态燃料和无烟固体燃料的生产
公开(公告)号：US4533463A
公开(公告)日：1985-08-06
申请号：US512505
申请日：1983-07-11
IPC分类号： B01J8/20 , C01B39/04 , C08F2/06 , C08F10/00 , C10B55/10 , C10G1/04 , C10G1/06 , C10G9/00 , C10G9/28 , C10G9/38 , C10G9/32
CPC分类号： C10G9/38 , B01J8/20 , C01B39/04 , C08F10/00 , C10B55/10 , C10G1/042 , C10G1/045 , C10G1/065 , C10G9/005 , C10G9/28 , B01J2219/1946 , Y02P20/582
摘要： Coal and residual oil are simultaneously processed in a reactor with a combustion zone at the bottom and a fluidized bed on top of it. The residual oil is injected into heat exchange relationship with the top of the fluidized bed where it is cracked with heat generated by the combustion.
摘要翻译： 煤和残油在反应器中同时被处理，其中底部具有燃烧区，并在其顶部具有流化床。 将残留的油与流化床的顶部注入与燃烧产生的热量破裂的热交换关系。
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公开(公告)号：US4385042A
公开(公告)日：1983-05-24
申请号：US296763
申请日：1981-08-27
IPC分类号： B01J8/20 , C01B39/02 , C01B39/04 , C08F10/00 , C10B55/00 , C10G1/04 , C10G1/06 , C10G9/00 , C01B33/28
CPC分类号： C10G9/005 , B01J8/20 , C01B39/02 , C01B39/04 , C08F10/00 , C10B55/00 , C10G1/042 , C10G1/045 , C10G1/065 , B01J2219/1946 , Y02P20/582 , Y10S423/09
摘要： A solid product resulting from the nucleated growth of the product on solid material of either the same or different composition and having a density higher than the reaction medium is formed from one or more liquid phase reactants by a method which comprises tangentially introducing the liquid phase reaction medium into the lower, smaller end of an inverted, frusto-conical reactor-separator, thereby imparting an upward swirling motion to the reaction medium in the reactor-separator, the horizontal velocity at the bottom of the reactor-separator being sufficiently large to cause fluidization of larger, solid product particles and concentration of them in the central lower portion of the reactor-separator and the vertical velocity at the top of the reactor-separator being sufficiently small to avoid carry-over of the smaller solid particles but sufficiently large to concentrate them in the upper portion of the reactor-separator; at least periodically recovering the larger, solid product particles in spherical form from the bottom of the reactor-separator; and recovering fluid products from the top of the reactor-separator. The method described is useful in a variety of reactions wherein a solid product forms by a nucleated growth mechanism. Examples of such reactions include thermal upgrading of petroleum derived feedstocks and coal liquids, synthesis of zeolites and Ziegler-Natta polymerization of olefins.
摘要翻译： 由相同或不同组成的固体材料产生的具有比反应介质高的密度产生的固体产物由一种或多种液相反应物形成，该方法包括切向引入液相反应 介质进入倒立的截头圆锥形反应器分离器的较小的较小端，从而向反应器分离器中的反应介质施加向上旋转运动，反应器分离器底部的水平速度足够大以致 更大的固体产物颗粒的流化和它们在反应器分离器的中心下部的浓度以及反应器分离器顶部的垂直速度足够小以避免较小固体颗粒的滞留，但足够大以至 将它们集中在反应器分离器的上部; 从反应器分离器的底部至少周期性地回收球形的更大的固体产物颗粒; 并从反应器分离器的顶部回收流体产物。 所描述的方法可用于通过有核生长机制形成固体产物的各种反应。 这种反应的实例包括石油衍生的原料和煤液体的热升级，沸石的合成和烯烃的齐格勒 - 纳塔聚合。
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6.发明授权
公开(公告)号：US4383094A
公开(公告)日：1983-05-10
申请号：US296765
申请日：1981-08-27
CPC分类号： C10G9/005 , B01J8/20 , C01B39/04 , C08F10/00 , C10G1/042 , C10G1/045 , C10G1/065 , B01J2219/1946 , Y02P20/582
摘要： A solid product resulting from the nucleated growth of the product on solid material of either the same or different composition and having a density higher than the reaction medium is formed from one or more liquid phase reactants by a method which comprises tangentially introducing the liquid phase reaction medium into the lower, smaller end of an inverted, frusto-conical reactor-separator, thereby imparting an upward swirling motion to the reaction medium in the reactor-separator, the horizontal velocity at the bottom of the reactor-separator being sufficiently large to cause fluidization of larger, solid product particles and concentration of them in the central lower portion of the reactor-separator and the vertical velocity at the top of the reactor-separator being sufficiently small to avoid carry-over of the smaller solid particles but sufficiently large to concentrate them in the upper portion of the reactor-separator; at least periodically recovering the larger, solid product particles in spherical form from the bottom of the reactor-separator; and recovering fluid products from the top of the reactor-separator. The method described is useful in a variety of reactions wherein a solid product forms by a nucleated growth mechanism. Examples of such reactions include thermal upgrading of petroleum derived feedstocks and coal liquids, synthesis of zeolites and Ziegler-Natta polymerization of olefins.
摘要翻译： 由相同或不同组成的固体材料产生的具有比反应介质高的密度产生的固体产物由一种或多种液相反应物形成，该方法包括切向引入液相反应 介质进入倒立的截头圆锥形反应器分离器的较小的较小端，从而向反应器分离器中的反应介质施加向上旋转运动，反应器分离器底部的水平速度足够大以致 更大的固体产物颗粒的流化和它们在反应器分离器的中心下部的浓度以及反应器分离器顶部的垂直速度足够小以避免较小固体颗粒的滞留，但足够大以至 将它们集中在反应器分离器的上部; 从反应器分离器的底部至少周期性地回收球形的更大的固体产物颗粒; 以及从反应器分离器的顶部回收流体产物。 所描述的方法可用于通过有核生长机制形成固体产物的各种反应。 这种反应的实例包括石油衍生的原料和煤液体的热升级，沸石的合成和烯烃的齐格勒 - 纳塔聚合。
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公开(公告)号：US4303494A
公开(公告)日：1981-12-01
申请号：US64142
申请日：1979-08-06
IPC分类号： B01J8/20 , C01B39/04 , C08F2/06 , C08F10/00 , C10B55/10 , C10G1/04 , C10G1/06 , C10G9/00 , C10G9/28 , C10G9/38 , C10G1/00
CPC分类号： C10G9/38 , B01J8/20 , C01B39/04 , C08F10/00 , C10B55/10 , C10G1/042 , C10G1/045 , C10G1/065 , C10G9/005 , C10G9/28 , B01J2219/1946 , Y02P20/582
摘要： A solid product resulting from the nucleated growth of the product on solid material of either the same or different composition and having a density higher than the reaction medium is formed from one or more liquid phase reactants by a method which comprises tangentially introducing the liquid phase reaction medium into the lower, smaller end of an inverted, frusto-conical reactor-separator, thereby imparting an upward swirling motion to the reaction medium in the reactor-separator, the horizontal velocity at the bottom of the reactor-separator being sufficiently large to cause fluidization of larger, solid product particles and concentration of them in the central lower portion of the reactor-separator and the vertical velocity at the top of the reactor-separator being sufficiently small to avoid carry-over of the smaller solid particles but sufficiently large to concentrate them in the upper portion of the reactor-separator; at least periodically recovering the larger, solid product particles in spherical form from the bottom of the reactor-separator; and recovering fluid products from the top of the reactor-separator. The method described is useful in a variety of reactions wherein a solid product forms by a nucleated growth mechanism. Examples of such reactions include thermal upgrading of petroleum derived feedstocks and coal liquids, synthesis of zeolites and Ziegler-Natta polymerization of olefins.
摘要翻译： 由相同或不同组成的固体材料产生的具有比反应介质高的密度产生的固体产物由一种或多种液相反应物形成，该方法包括切向引入液相反应 介质进入倒立的截头圆锥形反应器分离器的较小的较小端，从而向反应器分离器中的反应介质施加向上旋转运动，反应器分离器底部的水平速度足够大以致 更大的固体产物颗粒的流化和它们在反应器分离器的中心下部的浓度以及反应器分离器顶部的垂直速度足够小以避免较小固体颗粒的滞留，但足够大以至 将它们集中在反应器分离器的上部; 从反应器分离器的底部至少周期性地回收球形的更大的固体产物颗粒; 并从反应器分离器的顶部回收流体产物。 所描述的方法可用于通过有核生长机制形成固体产物的各种反应。 这种反应的实例包括石油衍生的原料和煤液体的热升级，沸石的合成和烯烃的齐格勒 - 纳塔聚合。
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公开(公告)号：US4522703A
公开(公告)日：1985-06-11
申请号：US554013
申请日：1983-11-21
申请人： Tsoung Y. Yan , Nai Y. Chen
发明人： Tsoung Y. Yan , Nai Y. Chen
摘要： This invention provides a process for upgrading heavy hydrocarbon oil by thermal treatment which in one preferred embodiment involves heating a petroleum residuum type of heavy oil feedstock at a temperature of 450.degree.-550.degree. C. and a pressure of 10-200 psi for a period of about 0.1-1 hour to convert at least 60 weight percent of the heavy oil to gasoline and gas oil range products, and additionally providing a residual tar fraction which has a fusion temperature below about 160.degree. C.About 1-10 weight percent of solid carbonaceous fines are incorporated in the feedstock to suppress the deposition of coke in the thermal treatment zone.
摘要翻译： 本发明提供了一种通过热处理改质重质烃油的方法，在一个优选实施方案中，该方法包括在450-550℃的温度和10-200psi的压力下加热石油渣油类型的重油原料一段时间 约0.1-1小时以将至少60重量％的重油转化为汽油和瓦斯油产品，并且另外提供熔点低于约160℃的残余焦油馏分。约1-10重量％ 将固体碳质细粉掺入原料中以抑制焦炭在热处理区中的沉积。
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公开(公告)号：US4363717A
公开(公告)日：1982-12-14
申请号：US225284
申请日：1981-01-15
申请人： Bruce P. Pelrine , Nai Y. Chen , Tsoung Y. Yan
发明人： Bruce P. Pelrine , Nai Y. Chen , Tsoung Y. Yan
CPC分类号： C10G21/003 , B01D11/0407 , C10G11/08 , C10G47/08
摘要： This invention provides a process for upgrading a heavy hydrocarbon oil to motor fuel products.The heavy hydrocarbon oil is admixed with a metal halide catalyst and a solvent component under supercritical conditions to form (1) a dense-gas solvent phase which contains refined hydrocarbon crackate, and which is substantially free of metal halide catalyst content; and (2) a residual asphaltic phase.
摘要翻译： 本发明提供了一种将重质烃油升级为机动车燃料产品的方法。 在超临界条件下将重质烃油与金属卤化物催化剂和溶剂组分混合以形成（1）含有精炼烃裂化物的致密气体溶剂相，其基本上不含金属卤化物催化剂含量; 和（2）残留沥青相。
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公开(公告)号：US20120228231A1
公开(公告)日：2012-09-13
申请号：US13470340
申请日：2012-05-13
申请人： Ping-Wen Yen , Yuh-Sheve Ho , Hung-Tzu Chiu , Chung-Jong Hwu , June-Cheng Chang , Tzong-Bin Lin , Tsoung Y. Yan , Cheng-Tsung Hong , Hung-Chung Shen , Jeng-Cheng Lee , Fu-Ming Lee
发明人： Ping-Wen Yen , Yuh-Sheve Ho , Hung-Tzu Chiu , Chung-Jong Hwu , June-Cheng Chang , Tzong-Bin Lin , Tsoung Y. Yan , Cheng-Tsung Hong , Hung-Chung Shen , Jeng-Cheng Lee , Fu-Ming Lee
IPC分类号： B03C1/30
CPC分类号： C10G21/28 , B01D29/23 , B01D35/06 , B03C1/0332 , B03C1/286 , B03C1/30 , B03C2201/18 , B03C2201/20 , B03C2201/28 , C10G25/003 , C10G31/09 , C10G32/02
摘要： A novel design of filters for removing iron rust particulates and other polymeric sludge from refinery and chemical process streams that are paramagnetic in nature is provided. The performance of these filters is greatly enhanced by the presence of the magnetic field induced by magnets. Basically, the filter comprises a high-pressure vessel with means to support the plurality of magnets in the form of bars or plates that are encased in stainless steel tubes or columns. Filters with various configurations are disclosed for accommodating the removal of contaminants from the process streams of different industries, with high efficiency for contaminants removal, simple construction, low operational and maintenance costs, and low hazardous operation.
摘要翻译： 提供了一种用于从炼油厂和化学工艺流中去除铁锈微粒和其他聚合污泥的过滤器的新颖设计，其性质是顺磁性的。 这些滤波器的性能由磁铁引起的磁场的存在而大大增强。 基本上，过滤器包括高压容器，该高压容器具有用于将多个以棒或板形式的磁体支撑在不锈钢管或列中的装置。 公开了具有各种结构的过滤器，用于容纳从不同行业的工艺流中去除污染物，高效率地去除污染物，简单的结构，低操作和维护成本以及低危险操作。
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