摘要:
The present invention relates a nonaqueous electrolyte secondary battery with a porous layer containing inorganic particles formed on a surface of a positive electrode and provides a nonaqueous electrolyte secondary battery capable of reducing the incipient failure and having an excellent shelf life characteristic. The nonaqueous electrolyte secondary battery includes: a positive electrode containing a positive-electrode active material; a negative electrode containing a negative-electrode active material; a nonaqueous electrolyte; and a porous layer provided on a surface of the positive electrode, wherein the porous layer contains silica particles and an aqueous binder.
摘要:
A non-aqueous electrolyte secondary battery has a positive electrode containing a positive electrode active material, a negative electrode containing a negative electrode active material, a non-aqueous electrolyte, a separator interposed between the positive electrode and the negative electrode, and a porous layer provided on a surface of the positive electrode. The porous layer contains titania particles, a dispersing agent, and an aqueous binder. The dispersing agent includes silica having an average particle size of less than 100 nm and less than that of the titania particles.
摘要:
Provided are a non-aqueous electrolyte secondary battery having excellent high-temperature durability and capable of reducing the initial percent defective and a process for producing the same. The non-aqueous electrolyte secondary battery includes: a positive electrode containing a positive-electrode active material; negative electrode containing a negative-electrode active material; a non-aqueous electrolyte; and a porous layer provided on a surface of the positive electrode, wherein the porous layer contains inorganic solid electrolyte particles having a crystalline structure of rhombohedral crystal (R3c) with lithium ion conductivity represented by Li1+x+yAlxTi2-xSiyP3-yO12 (where 0≦x≦1 and 0≦y≦1) and an aqueous binder.
摘要翻译:提供一种非水电解质二次电池,其具有优异的高温耐久性并且能够降低初始百分比的缺陷和其制造方法。 非水电解质二次电池包括:含有正极活性物质的正极; 含有负极活性物质的负极; 非水电解质; 以及设置在所述正极的表面上的多孔层,其中所述多孔层包含具有由Li1 + x + yAlxTi2-xSiyP3-yO12表示的锂离子传导性的菱方晶体(R3c)的结晶结构的无机固体电解质颗粒(其中0 @ x @ 1和0 @ y @ 1)和水性粘合剂。
摘要:
To provide a positive electrode for a nonaqueous electrolyte secondary battery having excellent flexibility and capable of increasing the reliability and productivity, and a nonaqueous electrolyte secondary battery using the positive electrode. The positive electrode for a nonaqueous electrolyte secondary battery includes an active material layer that contains: a positive-electrode active material; a binder made of a fluorine-contained resin containing a vinylidene fluoride unit; and an electrolyte represented by one of the following general formulae (1) and (2): wherein M represents a metal element, R1 and R2 each represent fluorine or a fluorinated alkyl group having one to three carbon atoms and are identical to or different from each other, and n represents an integer of 1 to 3; wherein M represents a metal element, R3 represents a fluorinated alkylene group having two to four carbon atoms, and n represents an integer of 1 to 3.
摘要:
The object is to obtain a positive electrode for a nonaqueous electrolyte secondary battery capable of suppressing gas generation even if continuous charging is performed at a high temperature. Provided is a positive electrode for a nonaqueous electrolyte secondary battery comprising a positive-electrode active material, wherein the positive-electrode active material has a surface-treated layer with a silane coupling agent represented by the following general formula (1): X1-Y—X2 (1) wherein Y is an alkylene group having 10 or less carbon atoms, and X1 and X2 are each represented by the general formula (2): wherein Z is an alkyl group having 10 or less carbon atoms or OR3, and R1, R2 and R3, are each an alkyl group having 5 or less carbon atoms.
摘要:
A positive electrode for a non-aqueous electrolyte secondary battery, having a positive electrode current collector and a positive electrode active material layer formed on the positive electrode current collector and containing LiCoO2 as an active material, PVDF as a binder agent, acetylene black as a conductive agent, and LiCF3SO3.
摘要:
A method of manufacturing a positive electrode for a non-aqueous electrolyte battery is provided. The positive electrode has a current collector and an active material layer formed on the current collector. The method includes: coating a slurry onto the current collector, the slurry having a pH of from 5 to 9 and containing a positive electrode active material, water as a dispersion medium, carboxymethylcellulose, and a pH adjuster; and drying the coated slurry to form the active material layer.
摘要:
A positive electrode for a non-aqueous electrolyte battery includes a positive electrode active material layer containing at least a positive electrode active material and a binder and a coating layer containing a polymer provided on the positive electrode active material layer, wherein the polymer has a block chain A composed of a random copolymer containing a repeating unit (I) represented by formula (I), a repeating unit (II) represented by formula (II), and a block chain B containing a repeating unit (III) represented by formula (III) wherein R1-R3, R4a, R4b, R5-R13 are as defined herein.
摘要:
A method of manufacturing a positive electrode for a non-aqueous electrolyte battery is provided. The positive electrode has a current collector and an active material layer formed on the current collector. The method includes: coating a slurry onto the current collector, the slurry having a pH of from 5 to 9 and containing a positive electrode active material, water as a dispersion medium, carboxymethylcellulose, and a pH adjuster; and drying the coated slurry to form the active material layer.
摘要:
A method of manufacturing a positive electrode for a non-aqueous electrolyte battery includes: applying a positive electrode slurry onto a positive electrode current collector, the positive electrode slurry containing a positive electrode active material, a conductive agent, carboxymethylcellulose, and a latex-based plastic. The method is characterized by including: a first step of dispersing and mixing the carboxymethylcellulose and the conductive agent in an aqueous solution to prepare a conductive agent slurry; and a second step of dispersing and mixing the positive electrode active material and the latex-based plastic in the conductive agent slurry, to prepare the positive electrode slurry.