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    Low temperature synthesis of condensation polymers
    5.
    发明授权
    Low temperature synthesis of condensation polymers 失效
    低温合成缩聚物

    公开(公告)号：US4996178A

    公开(公告)日：1991-02-26

    申请号：US461941

    申请日：1990-01-08

    申请人： Naoya Ogata

    发明人： Naoya Ogata

    IPC分类号： C08G63/87 ,  C08G79/02 ,  C08G85/00

    CPC分类号： C08G63/87 ,  C08G79/025 ,  C08G85/00 ,  C08G85/004

    摘要： Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200.degree. C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

    摘要翻译： 高分子量的缩合聚合物，如聚酯，聚脲和聚酰胺，通常在200℃或更高的温度下制备。 然而，通过利用本发明的催化剂体系，可以在更低的温度下合成缩聚物。 本发明的缩聚催化剂体系特别适用于从二羧酸和脂肪族二醇合成脂肪族聚酯，如聚对苯二甲酸乙二醇酯。 本发明更具体地公开了一种用于合成脂族聚酯的方法，其包括在（1）至少一种含磷化合物存在下使至少一种二羧酸与至少一种脂肪族二醇反应，所述至少一种含磷化合物含有至少一种三价或五价磷 直接与至少一个苯基键合的原子，（2）酸受体和（3）至少一种卤化有机化合物。 在本发明的方法中优选使用具有结合的酸受体基团的聚合物作为酸受体。

    Low temperature synthesis of condensation polymers
    6.
    发明授权
    Low temperature synthesis of condensation polymers 失效
    低温合成缩聚物

    公开(公告)号：US4843053A

    公开(公告)日：1989-06-27

    申请号：US180924

    申请日：1988-04-11

    申请人： Naoya Ogata

    发明人： Naoya Ogata

    IPC分类号： C08G63/87 ,  C08G79/02 ,  C08G85/00

    CPC分类号： C08G63/87 ,  C08G79/025 ,  C08G85/00 ,  C08G85/004

    摘要： Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200.degree. C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

    摘要翻译： 高分子量的缩合聚合物，如聚酯，聚脲和聚酰胺，通常在200℃或更高的温度下制备。 然而，通过利用本发明的催化剂体系，可以在更低的温度下合成缩聚物。 本发明的缩聚催化剂体系特别适用于从二羧酸和脂肪族二醇合成脂肪族聚酯，如聚对苯二甲酸乙二醇酯。 本发明更具体地公开了一种用于合成脂肪族聚酯的方法，其包括在至少一种含磷化合物的存在下，使至少一种二羧酸与至少一种脂族二醇反应，所述含磷化合物含有至少一种三价或五价磷 直接与至少一个苯基键合的原子，（2）酸受体和（3）至少一种卤化有机化合物。 在本发明的方法中优选使用具有结合的酸受体基团的聚合物作为酸受体。

    Antithrombogenic synthetic elastomer and process of preparation thereof
    7.
    发明授权
    Antithrombogenic synthetic elastomer and process of preparation thereof 失效
    抗血栓性合成弹性体及其制备方法

    公开(公告)号：US4687831A

    公开(公告)日：1987-08-18

    申请号：US852656

    申请日：1986-04-16

    申请人： Naoya Ogata ,  Kohei Sanui ,  Nobuhiko Yui ,  Kazuhiko Nojima ,  Kazunori Kataoka ,  Teruo Okano ,  Yasuhisa Sakurai

    发明人： Naoya Ogata ,  Kohei Sanui ,  Nobuhiko Yui ,  Kazuhiko Nojima ,  Kazunori Kataoka ,  Teruo Okano ,  Yasuhisa Sakurai

    IPC分类号： C08G18/00 ,  A61L27/00 ,  A61L27/18 ,  A61L33/06 ,  C08G18/10 ,  C08G18/32 ,  C08G18/65 ,  C08G18/66 ,  C08G18/76

    CPC分类号： C08G18/7671 ,  A61L27/18 ,  A61L33/068 ,  C08G18/10

    摘要： Antithrombogenic synthetic elastomer having repeat units comprising portion I which is a soft segment unit containing a polyether and portion II which is a hard segment unit: ##STR1## R is a straight-chain or branched-chain alkylene group containing 2 to 4 carbon atoms, R' is amide a urethane, an urea, n ranges up to 180, m is an integer of 1 to 20, l is an integer of 1 to 10, said polymer having a microdomain structure composed of soft and hard segments, the domains of which have an average size of 10 to 20 nm, and a molecular weight of about 80,000 to about 500,000.The polymer shows little adhesion of blood platelets thereto, little deformation of adhering blood platelets and an excellent antithrombogenic property. This polymer has excellent mechanical properties as an elastomer. This polymer is useful for artificial organs such as blood vessels, kidneys, hearts, and for functional biomaterials and devices such as absorbents for biological components, carriers for sustained release preparations, adhesive materials for living tissue, injectors, blood bags and catheters.

    摘要翻译： 具有重复单元的抗血栓形成合成弹性体，其包含作为包含聚醚的软链段单元的部分I和作为硬链段单元的部分II。R是直链或支链亚烷基 含有2至4个碳原子的基团，R'是酰胺氨基甲酸酯，脲，n范围高达180，m是1至20的整数，l是1至10的整数，所述聚合物具有由以下组成的微区结构： 软和硬链段，其结构域的平均尺寸为10至20nm，分子量为约80,000至约500,000。 聚合物对血小板附着力小，血小板附着变形小，抗血栓性优异。 该聚合物作为弹性体具有优异的机械性能。 该聚合物可用于人造器官如血管，肾脏，心脏，以及用于生物组分的吸收剂，持续释放制剂的载体，活组织的粘合剂材料，注射器，血袋和导管等功能生物材料和装置。

    Batch processing support apparatus and method, and storage medium storing program therefor
    8.
    发明申请
    Batch processing support apparatus and method, and storage medium storing program therefor 审中-公开
    批处理支持装置和方法，以及存储程序的存储介质

    公开(公告)号：US20070006234A1

    公开(公告)日：2007-01-04

    申请号：US11255923

    申请日：2005-10-24

    申请人： Naoya Ogata

    发明人： Naoya Ogata

    IPC分类号： G06F9/46

    CPC分类号： H04N1/00222 ,  G06F3/1204 ,  G06F3/1262 ,  G06F3/1285 ,  H04N1/00225 ,  H04N1/00233 ,  H04N1/00954 ,  H04N1/00957 ,  H04N2201/0081 ,  H04N2201/0082

    摘要： A batch processing support apparatus for supporting batch processing in which a batch of individual processing tasks are sequentially executed, comprises a list display that displays a list of a plurality of individual processing tasks and batch processing tasks in which the plurality individual processing tasks are sequentially combined; a selection unit that selects and displays a plurality of desired processing tasks from the individual processing tasks and batch processing tasks displayed by the list display; a rearrangement unit that rearranges the plurality of processing tasks selected by the selection unit; a registering unit that registers a new batch processing task which sequentially executes the processing tasks in an order rearranged by the rearrangement unit; and a batch processing executing unit that executes the batch processing task registered by the registering unit.

    摘要翻译： 一种用于支持批量处理的批量处理支持装置，其中一批单独处理任务被顺序地执行，包括显示多个单独处理任务的列表的列表显示和其中多个单独处理任务被顺序组合的批处理任务 ; 选择单元，其从所述列表显示显示的各个处理任务和批处理任务中选择并显示多个所需的处理任务; 重新布置由所述选择单元选择的所述多个处理任务的重排单元; 注册单元，其登记按重排单元重排的顺序依次执行处理任务的新批量处理任务; 以及批处理执行单元，其执行由所述登记单元登记的批处理任务。

    Resolution of racemic mixtures using polymers containing chiral units
    9.
    发明授权
    Resolution of racemic mixtures using polymers containing chiral units 失效
    使用含有手性单元的聚合物拆分外消旋混合物

    公开(公告)号：US5994560A

    公开(公告)日：1999-11-30

    申请号：US697751

    申请日：1996-08-29

    申请人： Hyun Nam Yoon ,  Mengshi Lu ,  Naoya Ogata

    发明人： Hyun Nam Yoon ,  Mengshi Lu ,  Naoya Ogata

    IPC分类号： C07B57/00 ,  C07C227/34 ,  C07D209/20 ,  C07C51/43 ,  C07C53/134

    CPC分类号： C07B57/00 ,  C07C227/34 ,  C07D209/20

    摘要： Described herein is a novel process to resolve a racemic compound into its optically active isomers without need for chemical transformation such as salt formation. The process advantageously utilizes polymers containing chiral moieties in their repeat units as well as exhibiting critical solution temperature behavior in a suitable solvent. An embodiment describes the resolution of tryptophan.

    摘要翻译： 本文描述了将外消旋化合物分解成其旋光异构体而不需要化学转化如盐形成的新方法。 该方法有利地使用在其重复单元中含有手性部分的聚合物以及在合适的溶剂中显示临界溶解温度行为。 一个实施方案描述了色氨酸的分辨率。