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公开(公告)号：US06204399B1
公开(公告)日：2001-03-20
申请号：US09101709
申请日：1998-07-16
IPC分类号： C07D30338
CPC分类号： C07D307/08
摘要： Process and arrangement for producing tetrahydrofuran from a hydrous butane diol solution contaminated by light volatile, organic compounds, comprising the following process stages: a) Distillative removal (K1) of the light volatile, organic compounds contained in the hydrous butane diol solution 1. b) Dehydrating (R) of the thus prepurified hydrous butane diol solution 3 over an acidic aluminum oxide catalyst. c) One-step or multi-step distillation (K2) of the thus obtained high-tetrahydrofuran fraction 8 for obtaining a pure tetrahydrofuran. In addition, a separation of the water from the hydrous butane diol solution to water contents of from 2 to 70% by weight, particularly 2 to 10% by weight, can take place before the dehydrating of the butane diol.
摘要翻译： 包含以下工艺步骤的含有由挥发性有机化合物污染的水合丁二醇溶液制备四氢呋喃的方法和装置：a）含水丁二醇溶液1.b中含有的挥发性有机化合物的蒸馏除去（K1） ）在酸性氧化铝催化剂上将如此预纯化的含水丁二醇溶液3脱水（c）。c）由此获得的用于获得纯四氢呋喃的高四氢呋喃馏分8的一步或多步蒸馏（K2）。 此外，在二丁醇脱水之前，可以将水从含水丁二醇溶液中分离至含水量为2-70重量％，特别是2-10重量％。
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公开(公告)号：US08486367B2
公开(公告)日：2013-07-16
申请号：US13001849
申请日：2009-06-09
CPC分类号： C01B3/38 , B01D53/229 , B01D2256/16 , B01J19/2475 , B01J2219/00162 , C01B3/505 , C01B2203/0233 , C01B2203/041 , C01B2203/047 , C01B2203/1241
摘要： The invention relates to a method and a device for generating hydrogen (5), wherein an input (1) comprising carbon is fed longitudinally through a tube-shaped reaction chamber (Z), together with water steam (2), and is thereby converted by steam reforming, and hydrogen (4) formed during steam reforming is continuously drawn off out of the reaction chamber (Z) through a separating wall (T), said wall being selectively hydrogen-permeable at least in segments, and at a pressure less than the pressure in the reaction chamber (Z) and greater than the ambient pressure, having greater purity than product (5), characterized in that a separating wall (T) is used, the selectively hydrogen-permeability segments thereof being disposed such that a hydrogen partial pressure drop exists over the entire surface of each of such segments between the reaction chamber side and the hydrogen extraction side (W).
摘要翻译： 本发明涉及一种用于产生氢气的方法和装置（5），其中包括碳的输入（1）与水蒸汽（2）一起纵向地供给管状反应室（Z），并由此转化 通过蒸汽重整，并且在蒸汽重整期间形成的氢（4）通过分隔壁（T）被连续地从反应室（Z）中排出，所述壁至少在段中是选择性地可渗透氢的，并且在较小的压力 比反应室（Z）中的压力大并且大于环境压力，其具有比产物（5）更高的纯度，其特征在于使用分离壁（T），其选择性氢气渗透性段被设置成使得 在反应室侧和氢气提取侧（W）之间的每个这样的段的整个表面上存在氢分压。
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公开(公告)号：US20110171118A1
公开(公告)日：2011-07-14
申请号：US13001849
申请日：2009-06-09
CPC分类号： C01B3/38 , B01D53/229 , B01D2256/16 , B01J19/2475 , B01J2219/00162 , C01B3/505 , C01B2203/0233 , C01B2203/041 , C01B2203/047 , C01B2203/1241
摘要： The invention relates to a method and a device for generating hydrogen (5), wherein an input (1) comprising carbon is fed longitudinally through a tube-shaped reaction chamber (Z), together with water steam (2), and is thereby converted by steam reforming, and hydrogen (4) formed during steam reforming is continuously drawn off out of the reaction chamber (Z) through a separating wall (T), said wall being selectively hydrogen-permeable at least in segments, and at a pressure less than the pressure in the reaction chamber (Z) and greater than the ambient pressure, having greater purity than product (5), characterized in that a separating wail (T) is used, the selectively hydrogen-permeability segments thereof being disposed such that a hydrogen partial pressure drop exists over the entire surface of each of such segments between the reaction chamber side and the hydrogen extraction side (W).
摘要翻译： 本发明涉及一种用于产生氢气的方法和装置（5），其中包括碳的输入（1）与水蒸汽（2）一起纵向地供给管状反应室（Z），并由此转化 通过蒸汽重整，并且在蒸汽重整期间形成的氢（4）通过分隔壁（T）被连续地从反应室（Z）中排出，所述壁至少在段中是选择性地氢可渗透的，并且在较小的压力 比反应室（Z）中的压力大并且大于环境压力，其具有比产物（5）更高的纯度，其特征在于使用分离壁（T），其选择性氢气渗透性段被设置成使得 在反应室侧和氢气提取侧（W）之间的每个这样的段的整个表面上存在氢分压。
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4.发明申请PROCESS AND APPARATUS FOR GENERATING HYDROGEN AND HYDROGEN-CONTAINING GAS MIXTURES 审中-公开用于生成含氢和含氢气体混合物的方法和装置公开(公告)号：US20080014126A1
公开(公告)日：2008-01-17
申请号：US11775737
申请日：2007-07-10
CPC分类号： C01B3/16 , C10J3/78 , C10J3/82 , C10J2300/092 , C10J2300/1621 , C10K1/101 , C10K3/04
摘要： A process and apparatus for converting starting materials containing hydrocarbon into a hydrogen-rich product gas is disclosed. A raw synthesis gas containing hydrogen (H2) and carbon monoxide (CO) is generated from the hydrocarbon-containing starting materials in a first process step of which at least a part undergoes a catalytically supported water-gas shift reaction to increase the percentage of hydrogen. The water-gas shift reaction is carried out at temperatures between 50 and 200° C., preferably between 60 and 150° C., and at temperatures between 1 and 10 bar, preferably between 1 and 5 bar, in a reactor in which a suitable catalyst is present.
摘要翻译： 公开了一种用于将含有烃的原料转化为富氢产物气的方法和装置。 在第一工艺步骤中，从含烃原料生成含有氢（H 2 H 2）和一氧化碳（CO）的原料合成气，其中至少部分经历催化负载的水气 转移反应以增加氢的百分比。 水煤气变换反应在50至200℃，优选在60至150℃之间的温度下进行，在1至10巴，优选1至5巴之间的温度下进行，其中a 存在合适的催化剂。
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