摘要:
A process for preparing 2-(2-tert-butylaminoethoxy)ethanol (tert-butylaminodiglycol, TBADG) by reacting diethylene glycol (DG) with tert-butylamine (TBA) in the presence of hydrogen and of a copper catalyst, by effecting the reaction at a temperature in the range from 160 to 220° C. in the presence of a copper- and aluminum oxide-containing catalyst, where the catalytically active material of the catalyst, before the reduction thereof with hydrogen, comprises 20 to 75% by weight of aluminum oxide (Al2O3), 20 to 75% by weight of oxygen compounds of copper, calculated as CuO, and ≦5% by weight of oxygen compounds of nickel, calculated as NiO.
摘要翻译:通过在氢气和铜催化剂的存在下使二甘醇(DG)与叔丁胺(TBA)反应,通过进行反应来制备2-(2-叔丁基氨基乙氧基)乙醇(叔丁基氨基二甘醇,TBADG) 在含有铜和氧化铝的催化剂的存在下,在160-220℃的温度下,催化剂的催化活性物质在用氢还原之前包含20-75重量% 的氧化铝(Al 2 O 3),20〜75重量%的作为CuO计算的铜的氧化合物,和5重量%的以NiO计的镍的氧化合物。
摘要:
An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution of a) of at least one metal salt of an aminocarboxylic acid, and b) of at least one acid promoter, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The acid promoter is selected from mineral acids, carboxylic acids, sulfonic acids, organic phosphonic acids and partial esters thereof. The absorption medium, compared with absorption media based on amino acid salts, has a reduced regeneration energy requirement without significantly reducing the absorption capacity of the solution for acid gases. In a process for removing acid gases from the fluid stream, the fluid stream is brought into contact with the absorption medium.
摘要:
An absorption medium for the removal of acid gases from a fluid stream comprises an aqueous solution a) of at least one amine and b) at least one phosphonic acid, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The phosphonic acid is, e.g., 1-hydroxyethane-1,1-diphosphonic acid. The absorption medium exhibits a reduced regeneration energy requirement compared with absorption media based on amines or amine/promoter combinations, without significantly decreasing the absorption capacity of the solution for acid gases.
摘要:
A process for preparing 2-(2-tert-butylaminoethoxy)ethanol (tert-butylaminodiglycol, TBADG) by reacting diethylene glycol (DG) with tert-butylamine (TBA) in the presence of hydrogen and of a copper catalyst, by effecting the reaction at a temperature in the range from 160 to 220° C. in the presence of a copper- and aluminum oxide-containing catalyst, where the catalytically active material of the catalyst, before the reduction thereof with hydrogen, comprises 20 to 75% by weight of aluminum oxide (Al2O3), 20 to 75% by weight of oxygen compounds of copper, calculated as CuO, and ≦5% by weight of oxygen compounds of nickel, calculated as NiO.
摘要翻译:通过在氢气和铜催化剂的存在下使二甘醇(DG)与叔丁胺(TBA)反应,通过进行反应来制备2-(2-叔丁基氨基乙氧基)乙醇(叔丁基氨基二甘醇,TBADG) 在含有铜和氧化铝的催化剂的存在下,在160-220℃的温度下,催化剂的催化活性物质在用氢还原之前包含20-75重量% 的氧化铝(Al 2 O 3),20〜75重量%的作为CuO计算的铜的氧化合物和NiN计算的5重量%的镍氧化合物。
摘要:
A process for removing carbon dioxide from a fluid comprises the steps of: (a) treating the fluid by bringing it into countercurrent contact with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone to absorb at least part of the carbon dioxide contained in the fluid into the absorbent; (b) depressurizing the loaded absorbent to release a first stream of carbon dioxide and yield a partially regenerated absorbent; (c) recycling a first stream of the partially regenerated absorbent into the first absorption zone; (d) heating a second stream of the partially regenerated absorbent to release a second stream of carbon dioxide and yield a regenerated absorbent; (e) recycling the regenerated absorbent into the second absorption zone; (f) condensing water vapor entrained in the second stream of carbon dioxide by cooling the second stream of carbon dioxide and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange. The invention provides a two-stage carbon dioxide recovery process wherein the overall energy required for carbon dioxide recovery is reduced and/or wherein at least part of the carbon dioxide is recovered at a pressure higher than atmospheric pressure so as to reduce the energy required for compression of the carbon dioxide, e.g., for sequestration. Also disclosed is a plant for removing carbon dioxide from a fluid.
摘要:
An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution (A) of an alkali metal salt of an N,N-di-C1-C4-alkylaminocarboxylic acid and (B) N-hydroxyethylpiperazine. The absorption medium has a low vapor pressure and an increased resistance to oxygen. Preferred fluid streams are combustion exhaust gases or biogas.
摘要:
The present invention relates to a process for separating off at least one acidic gas from a gas mixture comprising at least one acidic gas, which comprises the step of contacting of the gas mixture with a porous metal-organic framework, where the framework adsorbs the at least one acidic gas and the framework comprises at least one at least bidentate organic compound coordinated to at least one metal ion, wherein the porous metal-organic framework is impregnated with an amine suitable for a gas scrub. The invention further provides such impregnated metal-organic frameworks.
摘要:
A process for removing carbon dioxide from a fluid comprises the steps of: (a) treating the fluid by bringing it into countercurrent contact with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone to absorb at least part of the carbon dioxide contained in the fluid into the absorbent; (b) depressurizing the loaded absorbent to release a first stream of carbon dioxide and yield a partially regenerated absorbent; (c) recycling a first stream of the partially regenerated absorbent into the first absorption zone; (d) heating a second stream of the partially regenerated absorbent to release a second stream of carbon dioxide and yield a regenerated absorbent; (e) recycling the regenerated absorbent into the second absorption zone; (f) condensing water vapour entrained in the second stream of carbon dioxide by cooling the second stream of carbon dioxide and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange. The invention provides a two-stage carbon dioxide recovery process wherein the overall energy required for carbon dioxide recovery is reduced and/or wherein at least part of the carbon dioxide is recovered at a pressure higher than atmospheric pressure so as to reduce the energy required for compression of the carbon dioxide, e.g., for sequestration. Also disclosed is a plant for removing carbon dioxide from a fluid.
摘要:
An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution of a) of at least one metal salt of an aminocarboxylic acid, and b) of at least one acid promoter, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The acid promoter is selected from mineral acids, carboxylic acids, sulfonic acids, organic phosphonic acids and partial esters thereof. The absorption medium, compared with absorption media based on amino acid salts, has a reduced regeneration energy requirement without significantly reducing the absorption capacity of the solution for acid gases. In a process for removing acid gases from the fluid stream, the fluid stream is brought into contact with the absorption medium.
摘要:
A method for obtaining an acid gas stream having a pressure of from 3 to 30 bar by removal of acid gases from a fluid stream containing H2S, the molar fraction of H2S based on the total amount of acid gases being at least 50 mol %, the method comprising bringing the fluid stream into intimate contact with a liquid absorption medium, thus producing a fluid stream substantially freed from acid gases and an acid-gas-loaded liquid absorption medium; separating the fluid stream and the liquid absorption medium; separating, by heating and optionally by expansion or stripping, the liquid absorption medium into an acid gas stream and a regenerated liquid absorption medium; passing the regenerated liquid absorption medium into a heat exchanger and cooling it there by using part of its thermal energy to heat up the acid-gas-loaded liquid absorption medium; and recirculating the regenerated liquid absorption medium.