公开(公告)号：US20100112447A1

公开(公告)日：2010-05-06

申请号：US12270270

申请日：2008-11-13

申请人： Norihiro YAMAMOTO ,  Yutaka Kawatate ,  Hidekazu Hiratsuka ,  Takahiro Sakamoto

发明人： Norihiro YAMAMOTO ,  Yutaka Kawatate ,  Hidekazu Hiratsuka ,  Takahiro Sakamoto

IPC分类号： H01M4/52 ,  H01M4/50

CPC分类号： H01M4/525 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2006/10 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131

摘要： A positive electrode active material for a non-aqueous electrolyte secondary battery is provided. The positive electrode active material includes a composite oxide containing lithium and metal M other than lithium, and M contains Ni, Mn, and Co. The molar ratio of Ni to the total of Ni, Mn, and Co is from 0.45 to 0.65, and the molar ratio of Mn to the total of Ni, Mn, and Co is from 0.15 to 0.35. The positive electrode active material has a pressed density under a compression of 60 MPa of 3.3 g/cm3 or more and 4.3 g/cm3 or less. The positive electrode active material has a volume resistivity under a compression of 60 MPa of 100 Ω·cm or more and less than 1000 Ω·cm.

摘要翻译： 提供了一种非水电解质二次电池用正极活性物质。 正极活性物质包含含有锂的金属和除了锂以外的金属M的复合氧化物，M含有Ni，Mn，Co。Ni与Ni，Mn，Co的合计的摩尔比为0.45〜0.65， Mn与Ni，Mn和Co的总摩尔比为0.15〜0.35。 正极活性物质在60MPa的压缩下的压缩密度为3.3g / cm 3以上且4.3g / cm 3以下。 正极活性物质在60MPa的压缩下具有100Ω·cm·cm以上且小于1000Ω·cm·cm的体积电阻率。

公开(公告)号：US08460822B2

公开(公告)日：2013-06-11

申请号：US12270270

申请日：2008-11-13

申请人： Norihiro Yamamoto ,  Yutaka Kawatate ,  Hidekazu Hiratsuka ,  Takahiro Sakamoto

发明人： Norihiro Yamamoto ,  Yutaka Kawatate ,  Hidekazu Hiratsuka ,  Takahiro Sakamoto

IPC分类号： H01M4/20 ,  H01M4/13 ,  H01M4/00

CPC分类号： H01M4/525 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2006/10 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131

摘要： A positive electrode active material for a non-aqueous electrolyte secondary battery is provided. The positive electrode active material includes a composite oxide containing lithium and metal M other than lithium, and M contains Ni, Mn, and Co. The molar ratio of Ni to the total of Ni, Mn, and Co is from 0.45 to 0.65, and the molar ratio of Mn to the total of Ni, Mn, and Co is from 0.15 to 0.35. The positive electrode active material has a pressed density under a compression of 60 MPa of 3.3 g/cm3 or more and 4.3 g/cm3 or less. The positive electrode active material has a volume resistivity under a compression of 60 MPa of 100 Ω·cm or more and less than 1000 Ω·cm.

摘要翻译： 提供了一种非水电解质二次电池用正极活性物质。 正极活性物质包含含有锂的金属和除了锂以外的金属M的复合氧化物，M含有Ni，Mn，Co。Ni与Ni，Mn，Co的合计的摩尔比为0.45〜0.65， Mn与Ni，Mn和Co的总摩尔比为0.15〜0.35。 正极活性物质在60MPa的压缩下的压缩密度为3.3g / cm 3以上且4.3g / cm 3以下。 正极活性物质在100MPa·cm以上且小于1000Ω·cm的60MPa的压缩下具有体积电阻率。

公开(公告)号：US08173301B2

公开(公告)日：2012-05-08

申请号：US12265231

申请日：2008-11-05

申请人： Hidekazu Hiratsuka ,  Norihiro Yamamoto ,  Yutaka Kawatate ,  Hiroaki Furuta ,  Kensuke Nakura ,  Hiroshi Yoshizawa

发明人： Hidekazu Hiratsuka ,  Norihiro Yamamoto ,  Yutaka Kawatate ,  Hiroaki Furuta ,  Kensuke Nakura ,  Hiroshi Yoshizawa

IPC分类号： H01M4/525 ,  H01M4/13 ,  H01M4/505 ,  C01D15/00

CPC分类号： H01M4/505 ,  C01G53/50 ,  C01P2002/77 ,  C01P2004/03 ,  C01P2004/51 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/366 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  Y02T10/7011

摘要： A positive electrode active material for a non-aqueous electrolyte secondary battery including a lithium-containing transition metal oxide having a closest-packed cubic structure of oxygen, the lithium-containing transition metal oxide having a composition represented by the formula (1): Li[Lip(NixMnyCoz)1-p]O2, where x, y, and z represent element contents of nickel, manganese, and cobalt, respectively, and satisfies 0.2+y≦x≦0.7, 0.15≦y, 0.05≦z, x+y+z=1, and 0≦p≦0.1.

摘要翻译： 1.一种非水电解质二次电池用正极活性物质，其特征在于，包括具有最密堆积立方结构的氧的含锂过渡金属氧化物，所述含锂过渡金属氧化物具有式（1）表示的组成：Li [Lip（NixMnyCoz）1-p] O 2，其中x，y和z分别表示镍，锰和钴的元素含量，满足0.2 + y＆nlE; x＆nlE; 0.7,0.15＆nlE; y，0.05＆ ，x + y + z = 1，0＆nlE; p＆nlE; 0.1。

公开(公告)号：US20090117469A1

公开(公告)日：2009-05-07

申请号：US12265231

申请日：2008-11-05

申请人： Hidekazu Hiratsuka ,  Norihiro Yamamoto ,  Yutaka Kawatate ,  Hiroaki Furuta ,  Kensuke Nakura ,  Hiroshi Yoshizawa

发明人： Hidekazu Hiratsuka ,  Norihiro Yamamoto ,  Yutaka Kawatate ,  Hiroaki Furuta ,  Kensuke Nakura ,  Hiroshi Yoshizawa

IPC分类号： H01M4/58

CPC分类号： H01M4/505 ,  C01G53/50 ,  C01P2002/77 ,  C01P2004/03 ,  C01P2004/51 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/366 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  Y02T10/7011

摘要： A positive electrode active material for a non-aqueous electrolyte secondary battery including a lithium-containing transition metal oxide having a closest-packed cubic structure of oxygen, the lithium-containing transition metal oxide having a composition represented by the formula (1): Li[Lip(NixMnyCoz)1-p]O2, where x, y, and z represent element contents of nickel, manganese, and cobalt, respectively, and satisfies 0.2+y≦x≦0.7, 0.15≦y, 0.05≦z, x+y+z=1, and 0≦p≦0.1.

摘要翻译： 1.一种非水电解质二次电池用正极活性物质，其包含具有最密堆积立方结构的氧的含锂过渡金属氧化物，所述含锂过渡金属氧化物具有式（1）所示的组成： ？在线公式描述=“在线公式”end =“lead”？> Li [Lip（NixMnyCoz）1-p] O2，<？in-line-formula description =“In-line Formulas”end = “尾”→其中x，y和z分别表示镍，锰和钴的元素含量，并且满足<？在线公式描述=“在线公式”end =“lead”≥> 0.2 + y <= x <= 0.7,0.15 <= y，0.05 <= z，x + y + z = 1，<？in-line-formula description =“In-line Formulas”end =“tail”？> ？in-line-formula description =“In-line Formulas”end =“lead”？>和<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line- 公式description =“In-line Formulas”end =“lead”？> 0 <= p <= 0.1 <？in-line-formula description =“In-line Formulas”end =“tail”？>

公开(公告)号：US09325005B2

公开(公告)日：2016-04-26

申请号：US13387241

申请日：2010-07-28

申请人： Satoshi Matsumoto ,  Isao Abe ,  Yutaka Kawatate ,  Norihiro Yamamoto ,  Shinji Arimoto

发明人： Satoshi Matsumoto ,  Isao Abe ,  Yutaka Kawatate ,  Norihiro Yamamoto ,  Shinji Arimoto

IPC分类号： H01B1/02 ,  H01M4/505 ,  C01G53/00 ,  H01M4/13 ,  H01M4/58 ,  H01M4/00

CPC分类号： H01M4/505 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/50 ,  C01P2002/88 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  Y02E60/122 ,  Y02P70/54

摘要： A lithium nickel composite oxide, having small inner resistance, large battery capacity and high thermal stability, can be used as a positive electrode active material for a non-aqueous electrolyte secondary battery. The positive electrode active material is composed of the lithium nickel composite oxide of LibNi1-aMaO2 (wherein M represents at least one element selected from a transition metal element other than Ni, the second group element and the thirteenth group element; a satisfies 0.01≦a≦0.5; and b satisfies 0.9≦b≦1.1). This is obtained by filtering and drying the fired powder after water washing, wherein it is dried at 90° C. or lower, till moisture is reduced to 1% or less by mass in drying, and then at 120° C., and under gas atmosphere where content of compound components containing carbon is 0.01% or less by volume, or under vacuum atmosphere.

摘要翻译： 作为非水电解质二次电池用正极活性物质，可以使用内电阻小，电池容量大，热稳定性高的锂镍复合氧化物。 正极活性物质由LibNi1-aMaO2的锂镍复合氧化物（其中M表示选自Ni以外的过渡金属元素中的至少一种元素，第二族元素和第十三族元素）; a满足0.01＆lt; nlE; a＆nlE; 0.5; b满足0.9＆nlE; b＆nlE; 1.1）。 这是通过在水洗后过滤和干燥烧制粉末而获得的，其中在90℃或更低温度下干燥，直到水分在干燥中降低至1质量％以下，然后在120℃， 含有碳的化合物成分的含量为0.01体积％以下或真空气氛下的气体气氛。

公开(公告)号：US20120119167A1

公开(公告)日：2012-05-17

申请号：US13387241

申请日：2010-07-28

申请人： Satoshi Matsumoto ,  Isao Abe ,  Yutaka Kawatate ,  Norihiro Yamamoto ,  Shinji Arimoto

发明人： Satoshi Matsumoto ,  Isao Abe ,  Yutaka Kawatate ,  Norihiro Yamamoto ,  Shinji Arimoto

IPC分类号： H01B1/00

CPC分类号： H01M4/505 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/50 ,  C01P2002/88 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  Y02E60/122 ,  Y02P70/54

摘要： A lithium nickel composite oxide, having small inner resistance, large battery capacity and high thermal stability, can be used as a positive electrode active material for a non-aqueous electrolyte secondary battery. The positive electrode active material is composed of the lithium nickel composite oxide of LibNi1-aMaO2 (wherein M represents at least one element selected from a transition metal element other than Ni, the second group element and the thirteenth group element; a satisfies 0.01≦a≦0.5; and b satisfies 0.9≦b≦1.1). This is obtained by filtering and drying the fired powder after water washing, wherein it is dried at 90° C. or lower, till moisture is reduced to 1% or less by mass in drying, and then at 120° C., and under gas atmosphere where content of compound components containing carbon is 0.01% or less by volume, or under vacuum atmosphere.

摘要翻译： 作为非水电解质二次电池用正极活性物质，可以使用内电阻小，电池容量大，热稳定性高的锂镍复合氧化物。 正极活性物质由LibNi1-aMaO2的锂镍复合氧化物（其中M表示选自Ni以外的过渡金属元素中的至少一种元素，第二族元素和第十三族元素）; a满足0.01＆lt; nlE; a＆nlE; 0.5; b满足0.9＆nlE; b＆nlE; 1.1）。 这是通过在水洗后过滤和干燥烧制粉末而获得的，其中在90℃或更低温度下干燥，直到水分在干燥中降低至1质量％以下，然后在120℃， 含有碳的化合物成分的含量为0.01体积％以下或真空气氛下的气体气氛。

公开(公告)号：US07399555B2

公开(公告)日：2008-07-15

申请号：US10467398

申请日：2002-06-11

申请人： Hideki Sano ,  Masaya Sugafuji ,  Norihiro Yamamoto ,  Masaki Kitagawa ,  Kiyomi Kato ,  Hiroshi Matsuno ,  Jun Nunome ,  Yutaka Kawatate

发明人： Hideki Sano ,  Masaya Sugafuji ,  Norihiro Yamamoto ,  Masaki Kitagawa ,  Kiyomi Kato ,  Hiroshi Matsuno ,  Jun Nunome ,  Yutaka Kawatate

IPC分类号： H01M2/16

CPC分类号： H01M2/145 ,  H01M2/06 ,  H01M2/1653 ,  H01M2/1686 ,  H01M2/30 ,  H01M6/10 ,  H01M10/05

摘要： A non-aqueous electrolyte secondary battery comprising: an electrode plate assembly; a non-aqueous electrolyte; and an outer jacket accommodating the electrode plate assembly and the non-aqueous electrolyte therein, the electrode plate assembly comprising a positive electrode plate, a negative electrode plate and a separator interposed between the positive electrode plate and the negative electrode plate, the separator comprising a polyolefin resin, wherein (1) the separator comprises at least one layer comprising a polypropylene resin, (2) the layer comprising a polypropylene resin contains an antioxidant with a melting point of 60° C. or higher, and (3) the layer comprising a polypropylene resin and the positive electrode are in contact with one another.

摘要翻译： 一种非水电解质二次电池，包括：电极板组件; 非水电解质; 以及容纳所述电极板组件和所述非水电解质的外护套，所述电极板组件包括正极板，负极板和介于所述正极板和所述负极板之间的隔膜，所述隔膜包括 聚烯烃树脂，其中（1）所述隔板包括至少一层包含聚丙烯树脂的层，（2）包含聚丙烯树脂的层包含熔点为60℃或更高的抗氧化剂，和（3）包含 聚丙烯树脂和正极彼此接触。

公开(公告)号：US20050118510A1

公开(公告)日：2005-06-02

申请号：US10467398

申请日：2002-06-11

申请人： Hideki Sano ,  Masaya Sugafuji ,  Norihiro Yamamoto ,  Masaki Kitagawa ,  Kiyomi Kato ,  Hiroshi Matsuno ,  Jun Nunome ,  Yutaka Kawatate

发明人： Hideki Sano ,  Masaya Sugafuji ,  Norihiro Yamamoto ,  Masaki Kitagawa ,  Kiyomi Kato ,  Hiroshi Matsuno ,  Jun Nunome ,  Yutaka Kawatate

IPC分类号： H01M2/06 ,  H01M2/14 ,  H01M2/16 ,  H01M2/30 ,  H01M6/10 ,  H01M10/05 ,  H01M10/0587

CPC分类号： H01M2/145 ,  H01M2/06 ,  H01M2/1653 ,  H01M2/1686 ,  H01M2/30 ,  H01M6/10 ,  H01M10/05

摘要： A non-aqueous electrolyte secondary battery comprising: an electrode plate assembly; a non-aqueous electrolyte; and an outer jacket accommodating the electrode plate assembly and the non-aqueous electrolyte therein, the electrode plate assembly comprising a positive electrode plate, a negative electrode plate and a separator interposed between the positive electrode plate and the negative electrode plate, the separator comprising a polyolefin resin, wherein (1) the separator comprises at least one layer comprising a polypropylene resin, (2) the layer comprising a polypropylene resin contains an antioxidant with a melting point of 60° C. or higher, and (3) the layer comprising a polypropylene resin and the positive electrode are in contact with one another.

摘要翻译： 一种非水电解质二次电池，包括：电极板组件; 非水电解质; 以及容纳所述电极板组件和所述非水电解质的外护套，所述电极板组件包括正极板，负极板和介于所述正极板和所述负极板之间的隔膜，所述隔膜包括 聚烯烃树脂，其中（1）所述隔板包括至少一层包含聚丙烯树脂的层，（2）包含聚丙烯树脂的层包含熔点为60℃或更高的抗氧化剂，和（3）包含 聚丙烯树脂和正极彼此接触。

公开(公告)号：US10601038B2

公开(公告)日：2020-03-24

申请号：US14119350

申请日：2012-05-28

申请人： Tomoko Iwanaga ,  Hideo Sasaoka ,  Satoshi Matsumoto ,  Yutaka Kawatate ,  Shinji Arimoto

发明人： Tomoko Iwanaga ,  Hideo Sasaoka ,  Satoshi Matsumoto ,  Yutaka Kawatate ,  Shinji Arimoto

IPC分类号： H01M4/525 ,  C01G53/00 ,  H01M10/052

摘要： A positive electrode active material for a nonaqueous electrolyte secondary battery that is constituted by a lithium nickel composite oxide that combines a high capacity with excellent thermal stability, a manufacturing method suitable for industrial production, and a nonaqueous electrolyte secondary battery of high safety. A positive electrode active material for a nonaqueous electrolyte secondary battery includes a lithium nickel composite oxide represented by the following composition formula (1): LibNi1-aM1aO2  (1) (where M1 represents at least one element selected from transition metal elements other than Ni, elements of the second group of the Periodic System and elements of the thirteenth group of the Periodic System; a satisfies the condition 0.01≤a≤0.5; and b satisfies the condition 0.85≤b≤1.05). The content of carbon in the lithium nickel composite oxide is equal to or less than 0.08% by mass.

公开(公告)号：US20120292561A1

公开(公告)日：2012-11-22

申请号：US13574115

申请日：2011-01-13

申请人： Hideo Sasaoka ,  Tomoko Iwanaga ,  Satoshi Matsumoto ,  Yutaka Kawatate ,  Shinji Arimoto

发明人： Hideo Sasaoka ,  Tomoko Iwanaga ,  Satoshi Matsumoto ,  Yutaka Kawatate ,  Shinji Arimoto

IPC分类号： H01M4/525

CPC分类号： H01M4/131 ,  C01G53/04 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2006/12 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  H01M2004/021 ,  H01M2004/028

摘要： A positive electrode active material for non-aqueous electrolyte secondary battery composed of a lithium nickel composite oxide having high capacity and superior heat stability, a production method that is suitable for its industrial production, and a non-aqueous electrolyte secondary battery having high safety. The positive electrode active material for non-aqueous electrolyte secondary battery includes a lithium nickel composite oxide having by the following general formula (1): LibNi1-aM1aO2  (1) (wherein M1 represents at least one kind of element selected from transition metal elements other than Ni, the second group elements and the thirteenth group elements; a satisfies 0.01≦a≦0.5; and b satisfies 0.85≦b≦1.05). The amount of lithium at the surface of the lithium nickel composite oxide is 0.10% by mass or lower. The positive electrode active material is obtained by water washing fired powder at a temperature range of 10 to 40° C., and then filtering and drying the same.

摘要翻译： 一种由具有高容量和优异的热稳定性的锂镍复合氧化物构成的非水电解质二次电池用正极活性物质，适用于其工业生产的制造方法以及安全性高的非水电解质二次电池。 作为非水电解质二次电池用正极活性物质，具有以下通式（1）所示的锂镍复合氧化物：LibNi1-aM1aO2（1）（其中，M1表示选自过渡金属元素等中的至少一种元素 比Ni，第二组元素和第十三组元素; a满足0.01＆nlE; a＆nlE; 0.5; b满足0.85＆nlE; b＆nlE; 1.05）。 锂镍复合氧化物表面的锂量为0.10质量％以下。 正极活性物质通过在10〜40℃的温度范围内水洗烧成粉末，然后过滤并干燥而获得。