公开(公告)号：US07579086B2

公开(公告)日：2009-08-25

申请号：US11020063

申请日：2004-12-23

申请人： Norihisa Mino ,  Yuusuke Takada

发明人： Norihisa Mino ,  Yuusuke Takada

IPC分类号： B32B9/04

CPC分类号： C30B29/58 ,  C30B7/00 ,  Y10T428/31663

摘要： A substrate for use in crystallization has a base member, and an organic molecular film on a surface of the base member. The organic molecular film has non-affinity to a liquid, and the surface of the base member and the organic molecular film are covalently bound to each other. The substrate formed with the organic molecular film having non-affinity to the liquid on the surface of the base member is produced by contacting the surface of the base member having an active hydrogen atom or the surface of the base member to which the active hydrogen atom is introduced, with an organic molecule including a terminal-bonding functional group capable of covalently bonding to the surface of the base member at one end thereof, and a functional group showing non-affinity to the liquid at the other end thereof so as to covalently bond the terminal-bonding functional group of the organic molecule to the active hydrogen atom on the surface of the base member by reaction of the terminal-bonding functional group with the active hydrogen atom. The substrate enables to efficiently crystallize polymeric compounds including biomolecules such as proteins, nucleic acids, and sugars; and resins, as well as other organic compounds, and inorganic compounds.

摘要翻译： 用于结晶的基材具有基材，在基材的表面上具有有机分子膜。 有机分子膜对液体具有非亲和性，并且基材和有机分子膜的表面共价键合。 通过使具有活性氢原子的基材的表面或基体的表面与活性氢原子的表面接触，形成有与基材的表面上的液体不亲和的有机分子膜的基材 引入有机分子，其包括能够在其一端与基材的表面共价结合的末端键合官能团和在其另一端显示与液体非亲和性的官能团，以共价方式 通过末端键合官能团与活性氢原子的反应，将有机分子的末端键合官能团与基体的表面上的活性氢原子键合。 底物使得能够有效地结晶包括生物分子如蛋白质，核酸和糖的聚合物; 和树脂，以及其它有机化合物和无机化合物。

公开(公告)号：US20050158208A1

公开(公告)日：2005-07-21

申请号：US11020063

申请日：2004-12-23

申请人： Norihisa Mino ,  Yuusuke Takada

发明人： Norihisa Mino ,  Yuusuke Takada

IPC分类号： C30B7/00 ,  C30B29/58 ,  B01L3/00

CPC分类号： C30B29/58 ,  C30B7/00 ,  Y10T428/31663

摘要： A substrate for use in crystallization has a base member, and an organic molecular film on a surface of the base member. The organic molecular film has non-affinity to a liquid, and the surface of the base member and the organic molecular film are covalently bound to each other. The substrate formed with the organic molecular film having non-affinity to the liquid on the surface of the base member is produced by contacting the surface of the base member having an active hydrogen atom or the surface of the base member to which the active hydrogen atom is introduced, with an organic molecule including a terminal-bonding functional group capable of covalently bonding to the surface of the base member at one end thereof, and a functional group showing non-affinity to the liquid at the other end thereof so as to covalently bond the terminal-bonding functional group of the organic molecule to the active hydrogen atom on the surface of the base member by reaction of the terminal-bonding functional group with the active hydrogen atom. The substrate enables to efficiently crystallize polymeric compounds including biomolecules such as proteins, nucleic acids, and sugars; and resins, as well as other organic compounds, and inorganic compounds.

摘要翻译： 用于结晶的基材具有基材和在基材的表面上的有机分子膜。 有机分子膜对液体具有非亲和性，并且基材和有机分子膜的表面共价键合。 通过使具有活性氢原子的基材的表面或基体的表面与活性氢原子的表面接触，形成有与基材的表面上的液体不亲和的有机分子膜的基材 引入有机分子，其包括能够在其一端与基材的表面共价结合的末端键合官能团和在其另一端显示与液体非亲和性的官能团，以共价方式 通过末端键合官能团与活性氢原子的反应，将有机分子的末端键合官能团与基体的表面上的活性氢原子键合。 底物使得能够有效地结晶包括生物分子如蛋白质，核酸和糖的聚合物; 和树脂，以及其它有机化合物和无机化合物。

公开(公告)号：US07560731B2

公开(公告)日：2009-07-14

申请号：US11633924

申请日：2006-12-05

申请人： Shinichi Yamamoto ,  Norihisa Mino ,  Kazufumi Ogawa

发明人： Shinichi Yamamoto ,  Norihisa Mino ,  Kazufumi Ogawa

IPC分类号： H01L35/24

CPC分类号： G02F1/13439 ,  C08G61/122 ,  G02F1/1343 ,  G02F2001/136295 ,  G02F2202/022 ,  H01L51/0021 ,  H01L51/0035

摘要： An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

摘要翻译： 本发明的有机电子器件包括基板，形成在基板上的至少两个电极，形成在基板上并电连接电极的导电有机薄膜，以及用于涂覆至少一部分 电极。 导电有机薄膜是含有共轭键合基团的有机分子的聚合物，并且每个有机分子的一端化学键合到基底表面，并且有机分子中的共轭键基团与其它分子聚合 共轭键合基团以形成共轭键链。 涂膜将电极与导电性有机薄膜电连接，与直接连接电极和导电性有机薄膜的情况相比，能够实现较小的连接电阻。 作为涂膜，可以使用由金，铂，银等金属制成的膜，导电性聚合物膜，或与电极化学键合的单分子膜。

公开(公告)号：US07468206B1

公开(公告)日：2008-12-23

申请号：US08992049

申请日：1997-12-17

申请人： Tadashi Ootake ,  Yasuo Takebe ,  Norihisa Mino ,  Hiroaki Takezawa

发明人： Tadashi Ootake ,  Yasuo Takebe ,  Norihisa Mino ,  Hiroaki Takezawa

IPC分类号： G11B5/64 ,  B05D1/18

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  Y10T428/26 ,  Y10T428/261 ,  Y10T428/265 ,  Y10T428/31504

摘要： The present invention provides an organic ultra-thin film firmly fixed to a substrate with the film thickness ranging from tens of nm to hundreds of nm. The organic ultra-thin film comprises polymers fixed on a substrate by M2—O—A— bond in which A represents an Si, Ge, Ti, Sn or Zr atom in the polymer, and M2 represents an atom in the substrate) or by a coordinate bond, the polymers are combined with each other by —A1—O—A1′— bond in which A1 and A1′ are Si, Ge, Ti, Sn, Zr or S or by a coordinate bond.

摘要翻译： 本发明提供一种牢固地固定在基板上的有机超薄膜，其膜厚度为数十nm至数百nm。 有机超薄膜包括通过M2-OA-键固定在基材上的聚合物，其中A表示聚合物中的Si，Ge，Ti，Sn或Zr原子，M2表示基材中的原子）或通过坐标 通过-A1-O-A1'-键将聚合物彼此组合，其中A1和A1'是Si，Ge，Ti，Sn，Zr或S或通过配位键。

公开(公告)号：US20070085076A1

公开(公告)日：2007-04-19

申请号：US11633924

申请日：2006-12-05

申请人： Shinichi Yamamoto ,  Norihisa Mino ,  Kazufumi Ogawa

发明人： Shinichi Yamamoto ,  Norihisa Mino ,  Kazufumi Ogawa

IPC分类号： H01L29/08

CPC分类号： G02F1/13439 ,  C08G61/122 ,  G02F1/1343 ,  G02F2001/136295 ,  G02F2202/022 ,  H01L51/0021 ,  H01L51/0035

摘要： An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

公开(公告)号：US20060257588A1

公开(公告)日：2006-11-16

申请号：US11488994

申请日：2006-07-19

申请人： Kazufumi Ogawa ,  Norihisa Mino ,  Shinichi Yamamoto

发明人： Kazufumi Ogawa ,  Norihisa Mino ,  Shinichi Yamamoto

IPC分类号： C09K19/00

CPC分类号： H01L51/0545 ,  B82Y10/00 ,  G02F1/133711 ,  G02F1/133719 ,  G02F1/13378 ,  G02F1/133784 ,  G02F1/133788 ,  G02F2001/133796 ,  G02F2202/027 ,  H01B1/12 ,  H01B1/125 ,  H01B1/127 ,  H01L51/0012 ,  H01L51/0075 ,  H01L51/0508 ,  H01L51/0595 ,  H01L51/42 ,  H01L51/428 ,  Y02E10/549 ,  Y02P70/521 ,  Y10S428/91 ,  Y10T428/10 ,  Y10T428/1005 ,  Y10T428/1014 ,  Y10T428/31663

摘要： It is an object to provide a conductive organic thin film having organic molecules that include at one end a terminal bonding group that is covalently bonded to a substrate surface, a conjugate bonding group that is located at any portion of the organic molecules and that is polymerized with other molecules, and a polar functional group that does not include active hydrogen and that is located at any portion between the terminal bonding group and the conjugate bonding group, wherein the organic molecules are oriented and their conjugate bonding groups are polymerized, forming a conduction network. The conductivity (ρ) of the conductive organic thin film at room temperature (25° C.) is at least 5.5×105 S/cm, and preferably at least 1×107 S/cm, without dopants, having significantly higher conductivity than metals such as gold and silver. In particular, a film of polypyrrole or polythienylene conjugate bonds that is polymerized through polymerization through electrolytic oxidation has high conductivity.

摘要翻译： 本发明的目的是提供一种具有有机分子的导电有机薄膜，该有机分子的一端包含共价结合到基材表面的端键合基团，位于有机分子的任何部分并且被聚合的共轭键合基团 与其它分子，以及不包括活性氢并且位于末端键合基团和共轭键合基团之间的任何部分的极性官能团，其中有机分子取向并且它们的共轭键合基团聚合，形成导电 网络。 导电有机薄膜在室温（25℃）下的电导率（rho）至少为5.5×10 -5 S / cm，优选至少为1×10 7 / S / cm，没有掺杂剂，具有比诸如金和银的金属显着更高的导电率。 特别地，通过电解氧化聚合而聚合的聚吡咯或聚噻吩键共轭键具有高导电性。

公开(公告)号：US20050260478A1

公开(公告)日：2005-11-24

申请号：US10521871

申请日：2003-07-24

申请人： Norihisa Mino ,  Nobuhiko Hojo ,  Aoi Tanaka ,  Takashi Akiyama ,  Okada Yukihiro ,  Kohji Yuasa ,  Yuu Inatomi ,  Taisuke Yamamoto

发明人： Norihisa Mino ,  Nobuhiko Hojo ,  Aoi Tanaka ,  Takashi Akiyama ,  Okada Yukihiro ,  Kohji Yuasa ,  Yuu Inatomi ,  Taisuke Yamamoto

IPC分类号： H01B1/12 ,  H01M6/18 ,  H01M8/10

CPC分类号： H01M8/1053 ,  H01B1/122 ,  H01M6/181 ,  H01M8/1004 ,  H01M8/1011 ,  H01M8/106 ,  H01M8/1062 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02E60/523

摘要： The electrolyte membrane of the present invention is an electrolyte membrane (1) having ionic conductivity that includes a base material (2) and organic molecules having ion exchange groups, wherein the organic molecules are chemically bonded to the surface of the base material (2) to form an organic layer (3), and ions are conducted via the ion exchange groups in the organic layer (3). By providing this type of electrolyte membrane, it is possible to obtain an electrolyte membrane having ionic conductivity whose configuration is different to that of a conventional electrolyte membrane.

摘要翻译： 本发明的电解质膜是具有离子导电性的电解质膜（1），其具有基材（2）和具有离子交换基团的有机分子，其中有机分子与基材（2）的表面化学键合， 形成有机层（3），离子通过有机层（3）中的离子交换基团进行导电。 通过提供这种类型的电解质膜，可以获得具有与常规电解质膜不同的离子导电性的电解质膜。

公开(公告)号：US06485785B1

公开(公告)日：2002-11-26

申请号：US09636225

申请日：2000-08-10

申请人： Norihisa Mino ,  Mitsuo Ebisawa ,  Yoshiaki Oono ,  Kazufumi Ogawa

发明人： Norihisa Mino ,  Mitsuo Ebisawa ,  Yoshiaki Oono ,  Kazufumi Ogawa

IPC分类号： B05D302

CPC分类号： B82Y30/00 ,  B05C1/02 ,  B05C1/06 ,  B05C9/14 ,  B05D1/185 ,  B05D3/0486 ,  B05D5/08 ,  B82Y40/00 ,  C03C17/28 ,  C03C17/30 ,  C04B41/009 ,  C04B41/4933 ,  C04B41/84 ,  C04B35/10

摘要： A compound represented by a general formula (1) ABXn (where A is a carbon-containing group; B is at least one element selected from Si, Ge, Sn, Ti and Zr; X is a hydrolyzable group; and n is 1, 2 or 3), for example, a chlorosilane compound having a fluorocarbon group, is measured in an amount required for one time application, and dropped from a nozzle on a surface of a substrate having an active hydrogen on the surface, and simultaneously it is rubbed with a coater made of a sponge or a nonwoven fabric, etc. Furthermore, it is rubbed with a coater made of a sponge or a nonwoven fabric, etc. while blowing a dry warm air, and an elimination reaction is caused between the active hydrogen on the surface of the substrate and the hydrolyzable group of the compound. Thus, the compound is covalently bonded to the substrate. The molecules of the silane compound also are polymerized with one another to be fixed. Thus can be provided a coating film and a method and an apparatus for producing the same, in which: an amount of a liquid required for forming a film is decreased even when the substrate has an irregular shape and a large size; it is not necessary to be concerned for the pot life of a coating solution; the substrate is manipulated easily; and cost is low.

摘要翻译： 由通式（1）表示的化合物ABXn（其中A是含碳基团; B是选自Si，Ge，Sn，Ti和Zr中的至少一种元素; X是可水解基团; n是1， 2或3）例如具有碳氟化合物基团的氯代硅烷化合物以一次施加所需的量测量，并从表面上具有活性氢的基材的表面上的喷嘴滴落，同时它 用由海绵或无纺布制成的涂布机进行擦拭等。此外，用吹制干燥暖风的海绵或无纺布等涂布机进行擦拭，并且在活性物质之间产生消除反应 底物表面上的氢和化合物的可水解基团。 因此，化合物共价结合到基材上。 硅烷化合物的分子也彼此聚合以固定。 因此，可以提供一种涂膜及其制造方法和装置，其中：即使当基板具有不规则形状和大尺寸时，形成膜所需的液体量也减少; 不必关心涂布液的适用期; 基板操作容易; 成本低廉。

公开(公告)号：US06277444B1

公开(公告)日：2001-08-21

申请号：US08306517

申请日：1994-09-15

申请人： Tadashi Ohtake ,  Norihisa Mino ,  Kazufumi Ogawa

发明人： Tadashi Ohtake ,  Norihisa Mino ,  Kazufumi Ogawa

IPC分类号： B05D138

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  Y10T428/261 ,  Y10T428/31504 ,  Y10T428/31663

摘要： A highly dense chemically adsorbed film is formed by repeating the alternate process of adsorption reaction and washing. Adsorption reaction is directed by contacting the substrate surface, which has or is given an alkali metal or a functional group, with a chemical adsorbent, having halosilyl or alkoxysilyl groups at the end of molecules. An unreacted chemical adsorbent is then washed away from the substrate surface. The alternate treatment of adsorption reaction and washing is repeated, thereby covalently bonding a chemically adsorbed film to the substrate surface. As a result, a chemically adsorbed film is formed in which stem molecules are directly or indirectly covalently bonded to the substrate surface via at least one element chosen from the group consisting of Si, Ge, Sn, Ti, Zr, S or C and graft molecules are covalently bonded to at least one element chosen from Si, Ge, Sn, Ti, Zr, S or C via at least one bond chosen from —SiO—, —GeO—, SnO—, —TiO—, ZrO—, —SO2—, —SO— and —C—.

摘要翻译： 通过重复吸附反应和洗涤的交替过程形成高密度的化学吸附膜。 吸附反应是通过将具有或被赋予碱金属或官能团的底物表面与分子末端具有卤代甲硅烷基或烷氧基甲硅烷基的化学吸附剂接触来进行的。 然后将未反应的化学吸附剂从基底表面上冲走。 重复吸附反应和洗涤的替代处理，从而将化学吸附的膜共价键合到基材表面。 结果，形成化学吸附膜，其中茎分子通过选自Si，Ge，Sn，Ti，Zr，S或C中的至少一种元素直接或间接地共价结合到基底表面，并且接枝 分子通过选自-SiO - ，-GeO-，SnO-，-TiO-，ZrO - ， - 的至少一种键共价结合至选自Si，Ge，Sn，Ti，Zr，S或C中的至少一种元素。 SO2-，-SO-和-C-。

公开(公告)号：US06183558B2

公开(公告)日：2001-02-06

申请号：US09294297

申请日：1999-04-19

申请人： Tadashi Otake ,  Norihisa Mino ,  Tohru Nakagawa ,  Mamoru Soga ,  Kazufumi Ogawa ,  Takaiki Nomura ,  Yasuo Takebe

发明人： Tadashi Otake ,  Norihisa Mino ,  Tohru Nakagawa ,  Mamoru Soga ,  Kazufumi Ogawa ,  Takaiki Nomura ,  Yasuo Takebe

IPC分类号： B05C108

CPC分类号： B82Y30/00 ,  B05D1/283 ,  B05D3/0486 ,  B82Y40/00

摘要： A method for forming a molecular film includes the steps of: coating a surface of a substrate having active hydrogen atoms on its surface with a coating solution containing a silane-based compound having at least one reactive group selected from the group consisting of a chloro group, an alkoxy group and an isocyanate group; and effecting an elimination reaction between the active hydrogen atoms on the surface of the substrate and reactive groups of the silane-based compound, thereby covalently bonding the silane-based compounds to the surface of the substrate. The substrate is supplied to a chamber in which an atmosphere is maintained at a low water vapor density. The surface of the substrate is coated with a coating solution containing the silane-based compound and a solvent by using a transfer element. A dehydrochlorination reaction is effected between the active hydrogen atoms and the chloro groups of the silane-based compounds. Thereafter, any coating solution containing unreacted silane-based compounds after coating is removed inside or outside the chamber.

摘要翻译： 形成分子膜的方法包括以下步骤：用包含具有至少一个选自氯基团的反应性基团的硅烷基化合物的涂布溶液在其表面上涂覆具有活性氢原子的基材的表面 ，烷氧基和异氰酸酯基; 并且进行基板表面上的活性氢原子与硅烷类化合物的反应性基团之间的消除反应，从而将硅烷类化合物共价键合到基板的表面。 将基板供给到气氛保持在低水蒸汽密度的室中。 通过使用转印元件，将含有硅烷系化合物和溶剂的涂布液涂布在基材的表面上。 在活性氢原子和硅烷基化合物的氯基之间进行脱氯化氢反应。 此后，在室内或室外除去涂布后含有未反应的硅烷类化合物的任何涂布溶液。