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    Hydrogen occluding alloy and electrode made of the alloy
    1.
    发明授权
    Hydrogen occluding alloy and electrode made of the alloy 失效
    吸氢合金和电极由合金制成

    公开(公告)号：US5951945A

    公开(公告)日：1999-09-14

    申请号：US648854

    申请日：1996-05-16

    申请人： Norikazu Komada ,  Mitsugu Matsumoto ,  Shinichiro Kakehashi ,  Yoshitaka Tamo

    发明人： Norikazu Komada ,  Mitsugu Matsumoto ,  Shinichiro Kakehashi ,  Yoshitaka Tamo

    IPC分类号： C01B3/00 ,  H01M4/38 ,  C22C19/03

    CPC分类号： H01M4/383 ,  C01B3/0031 ,  C01B3/0057 ,  C01B3/0078 ,  Y02E60/327 ,  Y02P20/129 ,  Y10S75/954 ,  Y10S75/956

    摘要： There is provided a hydrogen occluding alloy exhibiting high absorption and desorption speeds. A hydrogen occluding alloy comprising as an overall composition: 25 to 45 weight % Zr+Hf, wherein the Hf comprises not more than 4%, 1 to 12 weight % Ti, 10 to 20 weight % Mn, 2 to 12 weight % V, 0.6 to 5 weight % rare earth elements, and a balance Ni (of which content is not less than 25 weight %) and unavoidable impurities, and basically having a three-phase structure consisting of: a main phase which constitutes the matrix of the alloy and which is made of a Zr--Ni--Mn based alloy, a dispersed granular phase made of a rare earth elements--Ni type alloy distributed along the grain boundary of the main phase, and a flaky phase which is made of a Ni--Zr type alloy attached to the dispersed granular phase and intermittently distributed along the grain boundary mentioned above.

    摘要翻译： 提供了具有高吸收和解吸速度的吸氢合金。 一种吸氢合金，其包含总重量为25〜45重量％的Zr + Hf，其中Hf包括不超过4％，1至12重量％的Ti，10至20重量％的Mn，2至12重量％的V， 0.6〜5重量％的稀土元素，余量为Ni（含量不小于25重量％）和不可避免的杂质，并且基本上具有三相结构：构成合金基体的主相 由Zr-Ni-Mn系合金构成的分散粒状相，分散在由主相的晶界分布的稀土元素-Ni型合金和由Ni-Zr构成的片状相 附着在分散粒状相上并沿上述晶粒间断分布。

    Hydrogen occluding alloy and electrode made of the alloy
    2.
    发明授权
    Hydrogen occluding alloy and electrode made of the alloy 失效
    吸氢合金和电极由合金制成

    公开(公告)号：US5885378A

    公开(公告)日：1999-03-23

    申请号：US678048

    申请日：1996-07-10

    申请人： Norikazu Komada ,  Mitsugu Matsumoto ,  Shinichiro Kakehashi ,  Yoshitaka Tamo

    发明人： Norikazu Komada ,  Mitsugu Matsumoto ,  Shinichiro Kakehashi ,  Yoshitaka Tamo

    IPC分类号： H01M4/38 ,  C01B6/24 ,  C22C30/00

    CPC分类号： H01M4/383 ,  Y10S420/90

    摘要： This invention provides a hydrogen occluding alloy having a composition comprising, by wt %, 25% to 45% of Zr, 1% to 12% of Ti, 10% to 20% of Mn, 2% to 12% of V, 0.5% to 5% of at least one rare earth element, optionally 0.1% to 4% of Hf, one or more selected from hydrogen, hydrogen+oxygen, and oxygen, and a balance being Ni (25% or more of Ni) and unavoidable impurities, having a structure comprising: a phase made of a hydrogenated-product, dispersedly distributed in a matrix phase made of a Zr--Ni--Mn based alloy. The hydrogenated-product mainly comprises a rare earth element-Ni type alloy and a rare earth element hydride with numerous cracks formed at the time when the hydrogenated-product phase is generated. The hydrogenated-product phase is formed by exposing a hydrogen-containing substance on the surfaces of the cracks. Electrodes made of the alloy are disclosed.

    摘要翻译： 本发明提供一种组合物，该组合物包含Zr的25〜45％，Ti为1〜12％，Mn为10〜20％，V为2〜12％，V为0.5％ 至少一种稀土元素的5％，任选的0.1％至4％的Hf，一种或多种选自氢，氢+氧和氧，余量为Ni（25％或更多的Ni）和不可避免的杂质 具有以下结构：由氢化物制成的相，分散在由Zr-Ni-Mn系合金构成的基体相中。 氢化产物主要包括稀土元素-Ni型合金和在生成氢化产物相时形成许多裂纹的稀土元素氢化物。 氢化产物相通过在裂纹的表面上暴露含氢物质而形成。 公开了由合金制成的电极。

    Hydrogen occluding alloy and electrode made of the alloy
    3.
    发明授权
    Hydrogen occluding alloy and electrode made of the alloy 失效
    吸氢合金和电极由合金制成

    公开(公告)号：US5932369A

    公开(公告)日：1999-08-03

    申请号：US779959

    申请日：1996-12-23

    申请人： Norikazu Komada ,  Shinichiro Kakehashi ,  Mitsugu Matsumoto ,  Yoshitaka Tamo

    发明人： Norikazu Komada ,  Shinichiro Kakehashi ,  Mitsugu Matsumoto ,  Yoshitaka Tamo

    IPC分类号： H01M4/38

    CPC分类号： H01M4/383 ,  Y10S420/90

    摘要： This invention provides a hydrogen occluding alloy exhibiting high absorption/desorption rates, and excellent initial activation, the alloy having a composition comprising, by wt %, 25% to 45% of Zr, 1% to 12% of Ti, 10% to 20 % of Mn, 2% to 12% of V, 0.5% to 5% of at least one rare earth element, preferably comprising La and/or Ce, optionally 0.1% to 4% of Hf, and a balance being Ni (25% or more of Ni) and unavoidable impurities. The alloy has a structure comprising: a main phase made of a Zr--Ni--Mn based alloy, numerous cracks, and a regenerated phase made of rare earth element-Ni type alloy, the regenerated phase being exposed on the surfaces of the cracks, as well as electrodes made of the alloy.

    摘要翻译： 本发明提供一种表现出高吸收/脱附速率和优异的初始活化的吸氢合金，该合金具有以重量计包含Zr的25％-45％，1％至12％的Ti，10％至20％ 的Mn，2〜12％的V，0.5〜5％的至少一种稀土元素，优选包含La和/或Ce，任选0.1〜4％的Hf，余量为Ni（25％ 以上的Ni）和不可避免的杂质。 该合金具有以下结构：由Zr-Ni-Mn系合金制成的主相，多个裂纹，以及由稀土元素-Ni型合金制成的再生相，再生相暴露在裂纹的表面， 以及由合金制成的电极。

    Three phase hydrogen occluding alloy and electrode made of the alloy
    4.
    发明授权
    Three phase hydrogen occluding alloy and electrode made of the alloy 失效
    三相吸氢合金和电极由合金制成

    公开(公告)号：US5810981A

    公开(公告)日：1998-09-22

    申请号：US613990

    申请日：1996-03-08

    申请人： Norikazu Komada ,  Mitsugu Matsumoto ,  Shinichiro Kakehashi ,  Yoshitaka Tamo ,  Chris N. Christodoulou

    发明人： Norikazu Komada ,  Mitsugu Matsumoto ,  Shinichiro Kakehashi ,  Yoshitaka Tamo ,  Chris N. Christodoulou

    IPC分类号： C01B3/00 ,  C22C30/00 ,  H01M4/38

    CPC分类号： C01B3/0057 ,  C01B3/0063 ,  C01B3/0078 ,  C22C30/00 ,  H01M4/383 ,  Y02E60/327 ,  Y10S420/90

    摘要： There is provided a hydrogen occluding alloy exhibiting high absorption and desorption speeds. A hydrogen occluding alloy comprising as an overall composition: 25 to 45 weight % Zr+Hf, wherein the Hf comprises not more than 4%, 1 to 15 weight % Ti, 10 to 20 weight % Mn, 2 to 12 weight % V, 0.6 to 5 weight % rare earth elements, and a balance Ni (of which content is not less than 25 weight %) and unavoidable impurities, and basically having a three-phase structure consisting of: a net-shaped continuous phase which is made of a Ni--Zr type alloy, a main phase (in the net-shaped continuous phase) made of a Zr--Ni--Mn based alloy, and a dispersed granular phase made of a rare earth elements-Ni type alloy distributed along the net-shaped continuous phase.

    摘要翻译： 提供了具有高吸收和解吸速度的吸氢合金。 一种吸氢合金，其总体组成为：25〜45重量％的Zr + Hf，其中，Hf为4重量％以下，Ti为1〜15重量％，10重量％〜20重量％的Mn，2〜12重量％ 0.6〜5重量％的稀土元素，余量为Ni（含量不小于25重量％）和不可避免的杂质，基本上具有三相结构：网状连续相，其由 Ni-Zr型合金，由Zr-Ni-Mn系合金构成的主相（网状连续相），以及分布在沿网状结构分布的稀土元素-Ni型合金的分散粒状相， 形连续相。

    SOLID ELECTROLYTE FUEL CELL AND OPERATING METHOD THEREOF
    6.
    发明申请
    SOLID ELECTROLYTE FUEL CELL AND OPERATING METHOD THEREOF 失效
    固体电解质燃料电池及其操作方法

    公开(公告)号：US20100227245A1

    公开(公告)日：2010-09-09

    申请号：US12160388

    申请日：2007-01-12

    申请人： Takashi Yamada ,  Hiroyuki Eto ,  Norikazu Komada

    发明人： Takashi Yamada ,  Hiroyuki Eto ,  Norikazu Komada

    IPC分类号： H01M8/10

    CPC分类号： H01M8/12 ,  H01M8/0208 ,  H01M8/0228 ,  H01M8/0232 ,  H01M8/04201

    摘要： A solid electrolyte fuel cell having a long service life, comprising a power generating cell (4) having a fuel electrode (3) laminated on one surface of a solid electrolyte (1) and an air electrode (2) laminated on the other surface, an air electrode current collector (5) laminated in contact with the air electrode (2) of the power generating cell (4) and formed of a porous silver material or a silver-coated porous metal material, a fuel electrode current collector (6) laminated in contact with the fuel electrode (3) of the power generating cell (4), an air electrode-side separator (7) having a silver-plated layer (9) formed on its surface on the side contacting the fuel electrode current collector (5), a fuel electrode-side separator (8) laminated in contact with the fuel electrode current collector, and air supply passage (11) provided by being connected with the air electrode-side separator (7) and a fuel supply passage (10) provided by being connected with the fuel electrode-side separator (8), wherein a silver vapor supply unit is provided in the air supply passage to thereby supply silver vapor-containing air to the air electrode current collector (5).

    摘要翻译： 一种使用寿命长的固体电解质型燃料电池，其特征在于，包括在固体电解质（1）的一个面上层叠了燃料电极（3）的发电电池（4）和层叠在另一面上的空气电极（2） 与发电电池（4）的空气电极（2）接触并由多孔银材料或银涂覆的多孔金属材料形成的空气电极集电体（5），燃料电极集电体（6） 与发电单元（4）的燃料电极（3）接触地层叠的空气电极侧隔板（7），在与燃料极集电体（3）接触的一侧的表面上形成有镀银层（9） （5），与燃料电极集电体接触地层叠的燃料电极侧隔板（8）和与空气电极侧隔板（7）连接的供气通路（11）和燃料供给通路 通过与燃料电极侧s连接而提供 （8），其中在所述空气供给通道中设置有银蒸气供给单元，从而向所述空气极集电体（5）供给含有银蒸气的空气。

    Solid oxide fuel cell
    8.
    发明申请
    Solid oxide fuel cell 审中-公开
    固体氧化物燃料电池

    公开(公告)号：US20070015015A1

    公开(公告)日：2007-01-18

    申请号：US11178280

    申请日：2005-07-12

    申请人： Koji Hoshino ,  Norihisa Chitose ,  Takashi Yamada ,  Norikazu Komada ,  Kazunori Adachi ,  Kei Hosoi

    发明人： Koji Hoshino ,  Norihisa Chitose ,  Takashi Yamada ,  Norikazu Komada ,  Kazunori Adachi ,  Kei Hosoi

    IPC分类号： H01M8/06 ,  H01M8/12 ,  H01M4/86

    CPC分类号： H01M8/0637 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/067 ,  C01B2203/1029 ,  C01B2203/1058 ,  C01B2203/1064 ,  H01M8/0232 ,  H01M8/243 ,  H01M8/2432 ,  H01M8/2457 ,  H01M2008/1293 ,  Y02E60/566

    摘要： An object of the present invention is to provide a solid oxide fuel cell assembled with an internal reforming mechanism stable and efficient over a long period. To achieve the object, in the present invention, a fuel-electrode layer 3 and an air-electrode layer 4 are disposed on both surfaces of a solid electrolyte layer 2; a fuel-electrode-side porous metal 6 and an air-electrode-side porous metal 7 are disposed on the outer surfaces of the fuel-electrode layer 3 and the air-electrode layer 4, respectively; and a separator 8 is disposed on each of the outer surfaces of the fuel-electrode-side porous metal 6 and the air-electrode-side porous metal 7. Then, the solid oxide fuel cell is constructed by closely adhering them all. The pores 6a in the fuel-electrode-side porous metal 6 is partially or fully filled with a hydrocarbon reforming catalyst 10, and reforming reaction is driven by the reforming catalyst 10 before a fuel gas reaches the fuel-electrode layer 3.

    摘要翻译： 本发明的目的是提供一种固体氧化物燃料电池，其组装有内部重整机构，其长期稳定且有效率。 为了实现该目的，在本发明中，在固体电解质层2的两面配置燃料电极层3和空气电极层4， 燃料电极侧多孔金属6和空气电极侧多孔金属7分别设置在燃料电极层3和空气电极层4的外表面上; 并且在燃料电极侧多孔金属6和空气电极侧多孔金属7的每个外表面上设置隔板8。 然后，固体氧化物燃料电池通过全部紧密粘合而构成。 燃料电极侧多孔金属6中的孔隙部分6a部分或全部填充有烃重整催化剂10，在燃料气体到达燃料电极层3之前由重整催化剂10驱动重整反应。

    Solid oxide fuel cell and separator
    9.
    发明授权
    Solid oxide fuel cell and separator 有权
    固体氧化物燃料电池和分离器

    公开(公告)号：US07989121B2

    公开(公告)日：2011-08-02

    申请号：US12379804

    申请日：2009-03-02

    申请人： Norikazu Komada ,  Koji Hoshino ,  Jun Akikusa ,  Kei Hosoi

    发明人： Norikazu Komada ,  Koji Hoshino ,  Jun Akikusa ,  Kei Hosoi

    IPC分类号： H01M4/64

    CPC分类号： H01M8/0254 ,  H01M8/0206 ,  H01M8/0228 ,  H01M8/0247 ,  H01M8/0258 ,  H01M8/0265 ,  H01M8/1213 ,  H01M8/1231 ,  H01M8/241 ,  H01M8/2425 ,  H01M8/243 ,  H01M8/2432 ,  H01M8/2457 ,  H01M8/2483 ,  H01M2008/1293

    摘要： A solid oxide fuel cell is formed by arranging a fuel electrode layer and an air electrode layer on both surfaces of a solid electrolyte, respectively, a fuel electrode current collector and an air electrode current collector outside the fuel electrode layer and the air electrode layer, respectively, and separators outside the fuel electrode current collector and the air electrode current collector. A fuel gas and an oxidant gas are supplied from the separators to the fuel electrode layers and the oxidant electrode layers, respectively, through the fuel electrode current collectors and the air electrode current collectors, respectively. Alternatively, indents are provided on the surface of each of the separators, which surface is in contact with one of the current collectors, to increase the dwell volume and hence the retaining time of the gas in the interior of the current collectors.

    摘要翻译： 固体氧化物型燃料电池通过在燃料电极层和空气极层外侧的燃料电极集电体和空气极集电体以及空气极集电体和固体电解质的两面分别设置燃料电极层和空气极层而形成， 以及燃料电极集电体和空气极集电体外的分离器。 燃料气体和氧化剂气体分别通过燃料电极集电体和空气电极集电体从隔板供应到燃料电极层和氧化剂电极层。 或者，在每个分离器的表面上设置有凹痕，该表面与集流器中的一个接触，以增加驻留体积，因此增加气体在集流器内部的保持时间。

    Flat plate laminated type fuel cell and fuel cell stack
    10.
    发明申请
    Flat plate laminated type fuel cell and fuel cell stack 审中-公开
    平板层压型燃料电池和燃料电池堆

    公开(公告)号：US20110151348A1

    公开(公告)日：2011-06-23

    申请号：US11795312

    申请日：2006-01-12

    申请人： Naoya Murakami ,  Takafumi Kotani ,  Norikazu Komada

    发明人： Naoya Murakami ,  Takafumi Kotani ,  Norikazu Komada

    IPC分类号： H01M8/24

    CPC分类号： H01M8/0247 ,  H01M8/0263 ,  H01M8/2425 ,  H01M8/247 ,  H01M8/2483 ,  H01M8/2485

    摘要： A flat plate laminated type high-temperature fuel cell, with internal manifold structure, has a laminated body constructed by alternately laminating power generation cells (5) and separators (8), and by applying a load to the laminated body in the laminating direction to compress elements of the laminated body. Each separator (8) has a connecting section (8b) for connecting a manifold section (8a) of the separator (8) and a section (8c) at which the power generation cell (5) is located, and the connecting section (8b) has flexibility to the load. Thus, it is possible to improve adhesiveness in the power generating section of the fuel cell stack and gas seal performance in the manifold section. Further, each of separators (108) has through-holes (122) extending in the laminating direction, and a fixing rod (123) is inserted into each of the through-holes (122) for restricting movements of the separators (108) in a plane direction due to thermal strain in operation. Thus, the movements of the separators due to thermal strain under high temperature atmosphere at power generation can be restricted and damage to the power generation cells can be prevented.

    摘要翻译： 具有内部歧管结构的平板层压型高温燃料电池具有层叠体，其通过交替层叠发电电池（5）和隔板（8）而构成，并且通过在层叠方向上向叠层体施加负载 压缩层压体的元件。 每个分离器（8）具有用于连接分离器（8）的歧管部分（8a）和发电单元（5）所在的部分（8c）的连接部分（8b）和连接部分（8b） ）具有灵活的负载。 因此，能够提高燃料电池堆的发电部的密合性和歧管部的气体密封性。 此外，每个分离器（108）具有在层叠方向上延伸的通孔（122），并且固定杆（123）插入到每个通孔（122）中，以限制分离器（108）的运动 由于操作中的热应变导致的平面方向。 因此，能够限制发电时在高温环境下的热应变引起的隔板的移动，能够防止发电单元的损坏。