公开(公告)号：US20050221212A1

公开(公告)日：2005-10-06

申请号：US10815118

申请日：2004-03-31

申请人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Juozas Grazulevicius ,  I. Paulauskaite ,  Jose Reina Lozano ,  Valentas Gaidelis ,  Vygintas Jankauskas

发明人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Juozas Grazulevicius ,  I. Paulauskaite ,  Jose Reina Lozano ,  Valentas Gaidelis ,  Vygintas Jankauskas

IPC分类号： C07D209/86 ,  C08G65/22 ,  C08G75/06 ,  C08G75/08 ,  C08G85/00 ,  G03G5/04 ,  G03G5/06 ,  G03G5/07 ,  G03G9/12 ,  H01L51/00

CPC分类号： H01L51/004 ,  C07D209/86 ,  G03G5/0616 ,  G03G5/0629 ,  G03G5/071 ,  G03G5/073 ,  G03G5/075

摘要： An improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material comprising a polymer having the formula where X1 and X2 are, each independently, a bond or a linking group; Y comprises a bond or an arylamine group; Z comprises a bond, O, S, or NR4; R1 and R4 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; R2 and R3 comprise, each independently, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; and n is a distribution of integers between 1 and 100,000 with an average value of greater than one; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, imaging methods, and methods of forming the charge transport material are described.

摘要翻译： 改进的有机光感受器包括在导电基底上的导电基底和光电导元件，光导元件包括：（a）电荷输送材料，其包含具有下式的聚合物：其中X 1和X 2 > 2 各自独立地为键或连接基团; Y包含键或芳基胺基; Z包括键，O，S或NR 4; R 1和R 4各自独立地包含H，烷基，烯基，炔基，芳族基团或杂环基团; R 2和R 3各自独立地包括烷基，烯基，炔基，芳族基团或杂环基团; 并且n是整数在1和100,000之间的平均值大于1的分布; 和（b）电荷产生化合物。 描述了相应的电子照相设备，成像方法和形成电荷传输材料的方法。

公开(公告)号：US20050266329A1

公开(公告)日：2005-12-01

申请号：US10857267

申请日：2004-05-28

申请人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Juozas Grazulevicius ,  Vygintas Jankauskas ,  Ingrida Paulauskaite ,  Jurate Simokaitiene ,  Albina Stanisauskaite ,  Valentas Gaidelis

发明人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Juozas Grazulevicius ,  Vygintas Jankauskas ,  Ingrida Paulauskaite ,  Jurate Simokaitiene ,  Albina Stanisauskaite ,  Valentas Gaidelis

IPC分类号： G03G5/04 ,  C07C323/12 ,  C07C323/48 ,  C07D209/86 ,  C07D279/22 ,  C07D279/28 ,  G03G5/06 ,  C07D209/82 ,  C07D279/18

CPC分类号： G03G5/0616 ,  C07C323/12 ,  C07C323/48 ,  C07D209/86 ,  C07D279/28 ,  G03G5/0614 ,  G03G5/062 ,  G03G5/0627 ,  G03G5/0629 ,  G03G5/0638

摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Z1 and Z2 comprise, each independently, a bond, a vinyl group, a —CR1═N—NR2— group, or a —CR3═N—N═CR4— group; Y1 and Y2 comprise, each independently, an aromatic group; X1 and X2 are, each independently, a linking group; W1 and W2 are, each independently, a —(CH2)n— group or a —(CH2)n-1—C(═O)— group, where n is an integer between 1 and 10, inclusive; Q1 and Q2 are, each independently, O, S, or NR; and R1, R2, R3, R4, R, R′, and R″ comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an acyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

摘要翻译： 改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输材料：其中Z 1和Z 2， 各自独立地包含键，乙烯基，-CR 1 -N-NR 2 - 基或-CR 3 - 基团; -NN-CR 4 - 基团; Y 1和Y 2 2各自独立地包含芳族基团; X 1和X 2各自独立地为连接基团; W 1和W 2各自独立地为 - （CH 2）n - n - 或 - （CH 2）n - （CH 2）n-1 -C（-O） - 基，其中n是1和10之间的整数，包括1和10; Q 1和Q 2各自独立地为O，S或NR; 和R 1，R 2，R 3，R 4，R，R'和R“ 各自独立地包含H，烷基，烯基，炔基，酰基，杂环基或芳族基; 和（b）电荷产生化合物。 描述相应的电子照相设备和成像方法。

公开(公告)号：US07326506B2

公开(公告)日：2008-02-05

申请号：US10857267

申请日：2004-05-28

申请人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Juozas V. Grazulevicius ,  Vygintas Jankauskas ,  Ingrida Paulauskaite ,  Jurate Simokaitiene ,  Albina Stanisauskaite ,  Valentas Gaidelis

发明人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Juozas V. Grazulevicius ,  Vygintas Jankauskas ,  Ingrida Paulauskaite ,  Jurate Simokaitiene ,  Albina Stanisauskaite ,  Valentas Gaidelis

IPC分类号： G03G15/02 ,  G03G15/00 ,  C07C251/00 ,  C07C259/00

CPC分类号： G03G5/0616 ,  C07C323/12 ,  C07C323/48 ,  C07D209/86 ,  C07D279/28 ,  G03G5/0614 ,  G03G5/062 ,  G03G5/0627 ,  G03G5/0629 ,  G03G5/0638

摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Z1 and Z2 comprise, each independently, a bond, a vinyl group, a —CR1═N—NR2— group, or a —CR3═N—N═CR4— group; Y1 and Y2 comprise, each independently, an aromatic group; X1 and X2 are, each independently, a linking group; W1 and W2 are, each independently, a —(CH2)n— group or a —(CH2)n-1—C(═O)— group, where n is an integer between 1 and 10, inclusive; Q1 and Q2 are, each independently, O, S, or NR; and R1, R2, R3, R4, R, R′, and R″ comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an acyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

摘要翻译： 改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输材料：其中Z 1和Z 2， 各自独立地包含键，乙烯基，-CR 1 -N-NR 2 - 基或-CR 3 - 基团; -NN-CR 4 - 基团; Y 1和Y 2 2各自独立地包含芳族基团; X 1和X 2各自独立地为连接基团; W 1和W 2各自独立地为 - （CH 2）n - n - 或 - （CH 2）n - （CH 2）n-1 -C（-O） - 基，其中n是1和10之间的整数，包括1和10; Q 1和Q 2各自独立地为O，S或NR; 和R 1，R 2，R 3，R 4，R，R'和R“ 各自独立地包含H，烷基，烯基，炔基，酰基，杂环基或芳族基; 和（b）电荷产生化合物。 描述相应的电子照相设备和成像方法。

公开(公告)号：US07320849B2

公开(公告)日：2008-01-22

申请号：US10749269

申请日：2003-12-31

申请人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Tadas Malinauskas ,  Vygintas Jankauskas ,  Valentas Gaidelis

发明人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Tadas Malinauskas ,  Vygintas Jankauskas ,  Valentas Gaidelis

IPC分类号： G03G5/06

CPC分类号： C07D405/14 ,  C07D303/06

摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y1 and Y2 are, each independently, an arylamine group; R1 and R2 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; X1 and X2, each independently, are bridging groups; E1 and E2 are, each independently, an epoxy group; and Z is a linking group comprising an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. The charge transport materials can be crosslinked to a polymeric bind, either directly or through a crosslinking agent. Corresponding electrophotographic apparatuses and imaging methods are described.

摘要翻译： 改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输材料：其中Y 1和Y 2 < 各自独立地为芳基胺基; R 1和R 2分别独立地包含H，烷基，烯基，杂环基或芳族基; X 1和X 2各自独立地是桥连基团; E 1和E 2各自独立地为环氧基; Z为包含烷基，烯基，杂环基或芳基的连接基团; 和（b）电荷产生化合物。 电荷输送材料可以直接或通过交联剂交联成聚合物结合物。 描述相应的电子照相设备和成像方法。

公开(公告)号：US07169521B2

公开(公告)日：2007-01-30

申请号：US10836667

申请日：2004-04-30

申请人： Zbigniew Tokarski ,  Nusrallah Jubran ,  Vytautas Getautis ,  Jonas Sidaravicius ,  Edmundas Montrimas ,  Maryte Daskeviciene ,  Valentas Gaidelis ,  Vygintas Jankauskas ,  Albina Stanisauskaite

发明人： Zbigniew Tokarski ,  Nusrallah Jubran ,  Vytautas Getautis ,  Jonas Sidaravicius ,  Edmundas Montrimas ,  Maryte Daskeviciene ,  Valentas Gaidelis ,  Vygintas Jankauskas ,  Albina Stanisauskaite

IPC分类号： G03G5/047

CPC分类号： G03G5/0616 ,  C07C323/25 ,  G03G5/0614 ,  G03G5/0618 ,  G03G5/062

摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula  where R1 and R2 are, each independently, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; R3 and R4 are, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; X1 and X2 are, each independently, a linking group; Y1 and Y2, each independently, comprise an arylamine group; and Z is a bridging group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

摘要翻译： 改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输材料：其中R 1和R 2， 各自独立地为烷基，烯基，炔基，芳族基或杂环基; R 3和R 4各自独立地为H，烷基，烯基，炔基，芳族基团或杂环基; X 1和X 2各自独立地为连接基团; Y 1和Y 2各自独立地包括芳基胺基; Z是桥接基团; 和（b）电荷产生化合物。 描述相应的电子照相设备和成像方法。

公开(公告)号：US20050147905A1

公开(公告)日：2005-07-07

申请号：US10749269

申请日：2003-12-31

申请人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Tadas Malinauskas ,  Vygintas Jankauskas ,  Valentas Gaidelis

发明人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Tadas Malinauskas ,  Vygintas Jankauskas ,  Valentas Gaidelis

IPC分类号： C07D303/06 ,  C07D405/14 ,  G03G5/06 ,  G03G5/07

CPC分类号： C07D405/14 ,  C07D303/06

摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y1 and Y2 are, each independently, an arylamine group; R1 and R2 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; X1 and X2, each independently, are bridging groups; E1 and E2 are, each independently, an epoxy group; and Z is a linking group comprising an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. The charge transport materials can be crosslinked to a polymeric bind, either directly or through a crosslinking agent. Corresponding electrophotographic apparatuses and imaging methods are described.

摘要翻译： 改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输材料：其中Y 1和Y 2 < 各自独立地为芳基胺基; R 1和R 2分别独立地包含H，烷基，烯基，杂环基或芳族基; X 1和X 2各自独立地是桥连基团; E 1和E 2各自独立地为环氧基; Z为包含烷基，烯基，杂环基或芳基的连接基团; 和（b）电荷产生化合物。 电荷输送材料可以直接或通过交联剂交联成聚合物结合物。 描述相应的电子照相设备和成像方法。

公开(公告)号：US06991882B2

公开(公告)日：2006-01-31

申请号：US10644547

申请日：2003-08-20

申请人： Vytautas Getautis ,  Edmundas Montrimas ,  Ingrida Paulauskaite ,  Valentas Gaidelis ,  Vygintas Jankauskas ,  Zbigniew Tokarski ,  Nusrallah Jubran ,  Kam W. Law

发明人： Vytautas Getautis ,  Edmundas Montrimas ,  Ingrida Paulauskaite ,  Valentas Gaidelis ,  Vygintas Jankauskas ,  Zbigniew Tokarski ,  Nusrallah Jubran ,  Kam W. Law

IPC分类号： G03G5/06

CPC分类号： C07D209/86 ,  C07C251/86 ,  G03G5/06 ,  G03G5/0616 ,  G03G5/0618 ,  Y10S430/103

摘要： This invention relates to a novel organophotoreceptor that includes a photoconductive layer having a) a novel charge transport compound having the formula  where R1 is a carbazole group, a julolidine group, or a p-(N,N-disubstituted)arylamine, R2, R3, R4, R5 and R6 are, independently, an alkyl group or an aryl group, R7 and R8 are, independently, hydrogen, an alkyl group, or an aryl group, X is oxygen, sulfur, or a NR′ group where R′ is hydrogen, an alkyl, or an aryl group, and Y is a trivalent aryl group; (b) a charge generating compound; and wherein the at least one photoconductive layer is carried on an electrically conductive substrate.

摘要翻译： 本发明涉及一种新型有机光感受器，其包括具有a）具有下式的新型电荷传输化合物的光电导层：其中R 1是咔唑基，多洛兰基或对 - （N，N 二取代）芳基胺，R 2，R 3，R 4，R 5和R 6 独立地是烷基或芳基，R 7和R 8独立地是氢，烷基或芳基， X是氧，硫或NR'基团，其中R'是氢，烷基或芳基，Y是三价芳基; （b）电荷产生化合物; 并且其中所述至少一个光电导层承载在导电基底上。

公开(公告)号：US20050095519A1

公开(公告)日：2005-05-05

申请号：US10699364

申请日：2003-10-31

申请人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Juozas Grazulevicius ,  Vytautas Getautis ,  Jolita Ostrauskaite ,  Jurate Simokaitiene ,  Vygintas Jankauskas

发明人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Juozas Grazulevicius ,  Vytautas Getautis ,  Jolita Ostrauskaite ,  Jurate Simokaitiene ,  Vygintas Jankauskas

IPC分类号： C07D279/22 ,  G03G5/047 ,  G03G5/06 ,  G03G9/12 ,  G03G5/05 ,  C07D265/34 ,  C07D279/18 ,  C07D335/08

CPC分类号： C07D279/22

摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, H, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; Y comprises a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR7 group where R7 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a multivalent structure selected to form n bonds with the corresponding X groups; and Z comprises a heterocyclic group selected from the group consisting of phenothiazine group, phenoxazine group, phenoxathiin group, dibenzo(1,4)dioxin group, thianthrene group, and phenazine group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

公开(公告)号：US07291433B2

公开(公告)日：2007-11-06

申请号：US10815118

申请日：2004-03-31

申请人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Juozas Vidas Grazulevicius ,  Ingrida Paulauskaitÿ ,  Jose Antonio Reina Lozano ,  Valentas Gaidelis ,  Vygintas Jankauskas

发明人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Vytautas Getautis ,  Juozas Vidas Grazulevicius ,  Ingrida Paulauskaitÿ ,  Jose Antonio Reina Lozano ,  Valentas Gaidelis ,  Vygintas Jankauskas

IPC分类号： G03G5/00

CPC分类号： H01L51/004 ,  C07D209/86 ,  G03G5/0616 ,  G03G5/0629 ,  G03G5/071 ,  G03G5/073 ,  G03G5/075

摘要： An improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material comprising a polymer having the formula where X1 and X2 are, each independently, a bond or a linking group; Y comprises a bond or an arylamine group; Z comprises a bond, O, S, or NR4; R1 and R4 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; R2 and R3 comprise, each independently, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; and n is a distribution of integers between 1 and 100,000 with an average value of greater than one; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, imaging methods, and methods of forming the charge transport material are described.

摘要翻译： 改进的有机光感受器包括在导电基底上的导电基底和光电导元件，光导元件包括：（a）电荷输送材料，其包含具有下式的聚合物：其中X 1和X 2 > 2 各自独立地为键或连接基团; Y包含键或芳基胺基; Z包括键，O，S或NR 4; R 1和R 4各自独立地包含H，烷基，烯基，炔基，芳族基团或杂环基团; R 2和R 3各自独立地包括烷基，烯基，炔基，芳族基团或杂环基团; 并且n是整数在1和100,000之间的平均值大于1的分布; 和（b）电荷产生化合物。 描述了相应的电子照相设备，成像方法和形成电荷传输材料的方法。

公开(公告)号：US20060127794A1

公开(公告)日：2006-06-15

申请号：US11274942

申请日：2006-02-21

申请人： Zbigniew Tokarski ,  Nusrallah Jubran ,  Vytautas Getautis ,  Edmundas Montrimas ,  Maryte Daskeviciene ,  Valentas Gaidelis ,  Vygintas Jankauskas

发明人： Zbigniew Tokarski ,  Nusrallah Jubran ,  Vytautas Getautis ,  Edmundas Montrimas ,  Maryte Daskeviciene ,  Valentas Gaidelis ,  Vygintas Jankauskas

IPC分类号： G03G15/10

CPC分类号： C07C251/86 ,  C07C2603/16 ,  C07C2603/24 ,  G03G5/0605 ,  G03G5/0614 ,  G03G5/0616

摘要： Improved organophotoreceptors comprise: (a) a charge transport compound having the formula where n is an integer from 0 to 1; X is an (N,N-disubstituted)arylamine group; Ar is an aryl group or a heterocyclic group; A is a first linking group with the formula —(CH2)p— which can be branched or linear, where p is an integer from 3 to 20 inclusive and where one or more methylene groups can be optionally replaced by O, S, a carbonyl group, urethane, urea, an ester group, a —NR21 group, a CHR22 group, or a CR23R24 group where R21, R22, R23 and R24 are, independently, H, hydroxyl, thiol, an amine group, an alkyl group, an alkaryl group, an aryl group, or part of a ring; and B is a second linking group having the formula -Q-Z-Q′-, where Q and Q′ are, independently, O, S, or NR1; wherein when Q or Q′ is NR1 or Q=O and Q′=S, Z comprises an aryl group, and wherein when Q=Q′=S or Q=Q′=O, Z comprises a multi-ring conjugated group or —Y—W—Y′— wherein Y and Y′ comprise, independently, an aryl group and W comprises a CR2R3 group; wherein R1 is hydrogen or comprises an alkyl group or an aryl group; R2 is a hydrogen or comprises an alkyl group, or an aryl group; and R3 comprises an alkyl group or an aryl group or may form a ring structure along with the R2 group; (b) a charge generating compound; and (c) an electrically conductive substrate over which said charge transport compound and said charge generating compound are located.

摘要翻译： 改进的有机光感受体包括：（a）具有下式的电荷传输化合物，其中n是0至1的整数; X是（N，N-二取代）芳基胺基; Ar是芳基或杂环基; A是具有式 - （CH 2）2 - 的第一连接基团，其可以是支链或直链的，其中p是3至20的整数，其中一个 或更多个亚甲基可以任选地被O，S，羰基，氨基甲酸酯，脲，酯基，-NR 21基团，CHR 22基团， 或其中R 21，R 22，R 23，R 23，R 23，R 23， >和R 24独立地是H，羟基，硫醇，胺基，烷基，烷芳基，芳基或环的一部分; 并且B是具有式-Q-Z-Q'-的第二连接基团，其中Q和Q'独立地是O，S或NR 1; 其中当Q或Q'为NR 1或Q = O且Q'= S时，Z包括芳基，并且其中当Q = Q'= S或Q = Q'= O时，Z 包括多环共轭基团或-YW-Y'-，其中Y和Y'独立地包含芳基，W包含CR 2 R 3 N 3基团; 其中R 1是氢或包含烷基或芳基; R 2是氢或包含烷基或芳基; R 3和R 3包括烷基或芳基，或者可以与R 2基团一起形成环结构; （b）电荷产生化合物; 和（c）所述电荷输送化合物和所述电荷产生化合物所位于的导电基底。