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1.发明授权
公开(公告)号：US5935499A
公开(公告)日：1999-08-10
申请号：US987883
申请日：1997-12-08
摘要： Fibers and yarns of polyethylene terephthalate (PET) and PET copolymers with a sheath/filamentous core microstructure are formed from unoriented and non crystalline "as spun" source fibers and yarns by drawing to high draw ratios in one step. Fibers and yarns with the sheath/filamentous core microstructure are stiffer than commercial PET fibers. Fibers and yarns with the sheath/filamentous core microstructure may be annealed and relaxed to increase their dimensional stability without loss of the sheath/filamentous core microstructure.
摘要翻译： 聚对苯二甲酸乙二醇酯（PET）的纤维和纱线和具有鞘/丝状核心微观结构的PET共聚物由无取向和非结晶的“纺丝”源纤维和纱线通过在一个步骤中拉伸至高拉伸比而形成。 具有鞘/丝状核微结构的纤维和纱线比商业PET纤维更硬。 具有鞘/丝状核微观结构的纤维和纱线可以退火和松弛以增加其尺寸稳定性，而不损失护套/丝状核心微结构。
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2.发明授权
公开(公告)号：US4293499A
公开(公告)日：1981-10-06
申请号：US119682
申请日：1980-02-08
申请人： O. Richard Hughes
发明人： O. Richard Hughes
IPC分类号： C07C67/05
CPC分类号： C07C67/04
摘要： This invention provides a process for producing a carboxylate ester from a monoolefin and a carboxylic acid, in the presence of a solid catalyst comprising a composite of 5-sulfoisophthalic acid and a carrier substrate having a surface area between about 1-1000 m.sup.2 /gram.A carboxylate ester such as ethyl propionate is produced with a STY efficiency of at least 100 grams/liter hour.
摘要翻译： 本发明提供了在包含5-磺基间苯二甲酸和表面积约1-1000m 2 /克的载体基质的复合物的固体催化剂存在下，由单烯烃和羧酸制备羧酸酯的方法。 产生羧酸酯如丙酸乙酯，其STY效率为至少100克/升小时。
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公开(公告)号：US4077906A
公开(公告)日：1978-03-07
申请号：US783693
申请日：1977-04-01
申请人： O. Richard Hughes
发明人： O. Richard Hughes
CPC分类号： B01J31/1658 , B01J31/1825 , B01J31/20 , C07C45/49 , C07C45/50 , B01J2231/321 , B01J2531/822
摘要： An improved catalyst is provided which is useful in hydroformylation reactions comprising a rhodium carbonyl complex and a polybenzimidazole fiber support wherein under hydroformylation conditions the rhodium carbonyl and complex forms a catalytically active polybenzimidazole complex with the benzimidazole units of the polybenzimidazole fiber surface acting as donor ligands for the rhodium carbonyl complex. This fiber supported catalyst may be readily separated from the products of the hydroformylation reaction by simple filtration.
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公开(公告)号：US08226876B1
公开(公告)日：2012-07-24
申请号：US11434575
申请日：2006-05-09
IPC分类号： C08J5/00
CPC分类号： B29C47/54 , B29C43/003 , B29C43/203 , B29C47/0021 , B29C47/065 , B29K2027/16
摘要： Disclosed herein is a method to produce a semi-crystalline fluoro-polymer film. A semi-crystalline fluoro-polymer material is used. The material is compressed to produce the film. During compression, the material is maintained at a temperature below the melting point of the material. The compression step can be cycled to allow cooling of the material between compression stages. Alternative methods are provided for compressing the material with a co-extrusion substrate, extruding the material and utilizing mandrel expansion for the material.
摘要翻译： 本文公开了一种制备半结晶氟聚合物膜的方法。 使用半结晶氟聚合物材料。 该材料被压缩以产生该膜。 在压缩期间，材料保持在低于材料熔点的温度。 可以循环压缩步骤以允许在压缩级之间冷却材料。 提供替代方法用于使用共挤出基底压缩材料，挤出材料并利用材料的心轴扩张。
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公开(公告)号：US5147895A
公开(公告)日：1992-09-15
申请号：US810611
申请日：1991-12-19
申请人： O. Richard Hughes , Dieter Kurschus
发明人： O. Richard Hughes , Dieter Kurschus
CPC分类号： B01J19/26 , C08J3/122 , C08J9/28 , B01J2219/00184 , C08J2201/0542 , C08J2207/04
摘要： A process for forming polymer powders by dissolving one or more polymers in a suitable solvent, followed by atomizing the solution into a droplet atmosphere of a non-solvent to precipitate polymer particles. The particles are separated from the non-solvent, washed and dried to produce a powder with a rounded particle morphology, high internal porosity and surface area, and high apparent density.Polymer powders with these properties can be pressed to dense shaped articles suitable for sintering in automated presses because the powders have good low and compressibility characteristics. The process if particularly useful when applied to soluble polymners that are not readily shaped by melt processing means.
摘要翻译： 通过将一种或多种聚合物溶解在合适的溶剂中形成聚合物粉末的方法，然后将溶液雾化成非溶剂的液滴气氛以沉淀聚合物颗粒。 将颗粒与非溶剂分离，洗涤并干燥以产生具有圆形颗粒形态，高内部孔隙率和表面积以及高表观密度的粉末。 具有这些性能的聚合物粉末可以压制成适合于自动压力机中烧结的致密成形制品，因为粉末具有良好的低和可压缩特性。 该方法在应用于不容易通过熔融加工装置成型的可溶性聚合物时特别有用。
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公开(公告)号：US4201728A
公开(公告)日：1980-05-06
申请号：US825896
申请日：1977-08-19
申请人： O. Richard Hughes
发明人： O. Richard Hughes
CPC分类号： C07F15/008 , B01J23/16 , C07C45/49 , C07C45/50
摘要： This invention provides a catalyst and process for achieving highly selective straight chain aldehyde formation from alpha-olefins under hydroformylation conditions. The improved hydroformylation results are obtained under mild conditions of temperature and pressure in the presence of a stabilized catalyst complex of rhodium metal, bidentate ligand and monodentate ligand represented by the formula: ##STR1## Illustrative of a preferred bidentate ligand is trans 1,2-bis(diphenylphosphinomethyl)cyclobutane. Illustrative of a preferred monodentate ligand is diphenylethylphosphine. It is an essential feature of the invention process that the monodentate ligand is provided in a molar excess with respect to the rhodium metal in the stabilized catalyst complex.
摘要翻译： 本发明提供了一种用于在加氢甲酰化条件下从α-烯烃形成高选择性直链醛的催化剂和方法。 在温和和温度条件下，在铑金属，二齿配体和由下式表示的单齿配体的稳定的催化剂络合物的存在下，获得改进的加氢甲酰化结果：优选的二齿配体的例子是反式1,2- 双（二苯基膦基甲基）环丁烷。 优选的单齿配体的例子是二苯基乙基膦。 本发明方法的一个基本特征是单稳态配体以相对于稳定的催化剂络合物中的铑金属摩尔过量提供。
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公开(公告)号：US4169861A
公开(公告)日：1979-10-02
申请号：US825894
申请日：1977-08-19
申请人： O. Richard Hughes
发明人： O. Richard Hughes
CPC分类号： B01J31/2409 , B01J31/1805 , B01J31/185 , B01J31/1895 , B01J31/20 , B01J31/2404 , C07C45/49 , C07C45/50 , B01J2231/321 , B01J2531/0205 , B01J2531/0288 , B01J2531/822
摘要： This invention provides a process for achieving straight chain aldehyde formation from alpha-olefins with improved selectivity efficiency under hydroformylation conditions. The improved hydroformylation results are obtained under mild conditions of temperature and pressure in the presence of a stabilized catalyst complex of rhodium metal, bidentate ligand and monodentate ligand represented by the formula: ##STR1## Illustrative of a preferred bidentate ligand L is 1,1'-bis-(diphenylphosphino)ferrocene. Illustrative of a preferred monodentate ligand L' is diphenylethylphosphine. It is an essential feature of the invention process that the monodentate ligand is provided in a molar excess with respect to the rhodium metal in the stabilized catalyst complex.
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公开(公告)号：US5844036A
公开(公告)日：1998-12-01
申请号：US829625
申请日：1997-03-31
申请人： O. Richard Hughes
发明人： O. Richard Hughes
摘要： Injection moldable, highly filled polymer composites are provided which exhibit high dimensional stability at temperatures above the glass transition temperature of the matrix polymer. The heat distortion temperature of the composites approaches that of the crystal melting temperature of the matrix polymer. The composite includes a polyaryletherketone matrix and at least two types of fillers each providing unique properties. The first filler is a reinforcing fiber filler which provides high strength and stiffness. The second filler is an non-thermoplastic immobilizing filler to immobilize the amorphous portion of the partially crystalline polyaryletherketone polymer and provide resistance to high temperature distortion. Notwithstanding its improved mechanical and heat resistant properties, the composite remains injection moldable and thus capable of low cost manufacturing.
摘要翻译： 提供可注塑的，高度填充的聚合物复合材料，其在高于基体聚合物的玻璃化转变温度的温度下表现出高的尺寸稳定性。 复合材料的热变形温度接近基体聚合物的晶体熔融温度。 复合材料包括聚芳醚酮基质和至少两种类型的填料，各自提供独特的性质。 第一填料是提供高强度和刚度的增强纤维填料。 第二填料是非热塑性固定填料，用于固定部分结晶聚芳醚酮聚合物的非晶部分并提供耐高温变形性。 尽管其机械和耐热性能得到改善，但复合材料仍然是可注射成型的，因此能够实现低成本制造。
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9.发明授权
公开(公告)号：US4788096A
公开(公告)日：1988-11-29
申请号：US18210
申请日：1987-02-24
CPC分类号： G04F5/063 , H01L41/37 , Y10S84/24 , Y10T428/24744
摘要： Cubelets are made from a piezoelectrically active ceramic material having holes therein which may be cross-cored. The holes are selectively filled with a liquid curable resin, such as an epoxy. The cubelets may also be formed from bonded or sintered "half-shapes" containing half cores, wherein a face bisects one hole or an array of holes or cross-cored holes to form one or an array of semicircular grooves or crossed semicircular grooves. The cubelets, whether filled with resin or having unfilled internal volume, are arranged in a precision array within the snug-fitting cavities of a lattice, whereby the holes are sealed off, to form a cubelet/lattice assembly which is then electroded and poled in an electric field and encapsulated in polymer to form a part of a hydrophone assembly, for example.
摘要翻译： Cubelets由其中具有孔的压电活性陶瓷材料制成，其可以是交叉芯的。 这些孔选择性地填充有诸如环氧树脂的液体可固化树脂。 小穗也可以由包含半芯的结合或烧结的“半形”形成，其中一个面平分一个孔或一组孔或交叉核心孔，以形成一个或一组半圆形槽或交叉半圆形槽。 无论是填充有树脂还是具有未填充的内部体积的小球，以精确阵列布置在格子的贴合空腔内，由此将孔密封，以形成立方体/格子组件，然后将其电镀和极化 例如电场并封装在聚合物中以形成水听器组件的一部分。
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公开(公告)号：US4330434A
公开(公告)日：1982-05-18
申请号：US250191
申请日：1981-04-02
申请人： O. Richard Hughes
发明人： O. Richard Hughes
CPC分类号： B01J31/0225 , C07C67/04 , B01J21/08 , B01J2231/323 , B01J35/1023
摘要： This invention provides a process for producing a carboxylate ester from a monoolefin and a carboxylic acid, in the presence of a solid catalyst comprising a composite of 5-sulfoisophthalic acid and a carrier substrate having a surface area between about 1-1000 m.sup.2 /gram.A carboxylate ester such as ethyl propionate is produced with a STY efficiency of at least 100 grams/liter hour.
摘要翻译： 本发明提供了在包含5-磺基间苯二甲酸和表面积约1-1000m 2 /克的载体基质的复合物的固体催化剂存在下，由单烯烃和羧酸制备羧酸酯的方法。 产生羧酸酯如丙酸乙酯，其STY效率为至少100克/升小时。
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