公开(公告)号：US20060183012A1

公开(公告)日：2006-08-17

申请号：US10529993

申请日：2003-10-02

申请人： Oemer Uensal ,  Joachim Kiefer ,  Gordon Calundann ,  Michael Sansone ,  Brian Benicewiez ,  Eui Choe

发明人： Oemer Uensal ,  Joachim Kiefer ,  Gordon Calundann ,  Michael Sansone ,  Brian Benicewiez ,  Eui Choe

IPC分类号： H01M8/10 ,  C08J5/22 ,  H01M4/86

CPC分类号： C08J5/2256 ,  B01D71/62 ,  B01D71/82 ,  C08G73/18 ,  H01M8/103 ,  H01M8/1067 ,  H01M8/1072 ,  Y02P70/56

摘要： The present invention relates to proton-conducting polymer membranes which comprise polyazoles containing sulfonic acid groups and is obtainable by a process comprising the steps A) mixing of one or more aromatic and/or heteroaromatic tetraamino compounds with one or more aromatic and/or heteroaromatic carboxylic acids or derivatives thereof which contain at least two acid groups per carboxylic acid monomer, with at least part of the tetraamino compounds and/or the carboxylic acids comprising at least one sulfonic acid group, or mixing of one or more aromatic and/or heteroaromatic diaminocarboxylic acids, of which at least part comprises sulfonic acid groups, in polyphosphoric acid to form a solution and/or dispersion, B) heating of the solution and/or dispersion obtainable according to step A) under inert gas to temperatures of up to 350° C. to form polyazole polymers, C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane from the step C) until it is self-supporting.

摘要翻译： 本发明涉及包含含有磺酸基团的多唑的质子传导性聚合物膜，并且可以通过包括以下步骤的方法获得：A）将一种或多种芳族和/或杂芳族四氨基化合物与一种或多种芳族和/或杂芳族羧酸 每个羧酸单体含有至少两个酸基团的酸或其衍生物，至少部分四氨基化合物和/或羧酸包含至少一个磺酸基团，或一种或多种芳族和/或杂芳族二氨基羧酸 酸，其至少部分包含磺酸基团，在多磷酸中形成溶液和/或分散体; B）将惰性气体下可根据步骤A）得到的溶液和/或分散体加热至高达350℃ C.形成聚唑聚合物，C）使用来自步骤A）和/或B）的混合物将层施加到载体上，D）将膜从 步骤C）直到它自我支持。

公开(公告)号：US20060008690A1

公开(公告)日：2006-01-12

申请号：US10530002

申请日：2003-10-02

申请人： Oemer Uensal ,  Joachim Kiefer ,  Gordon Calundann ,  Michael Sansone ,  Brian Benicewicz ,  Eui Choe

发明人： Oemer Uensal ,  Joachim Kiefer ,  Gordon Calundann ,  Michael Sansone ,  Brian Benicewicz ,  Eui Choe

IPC分类号： H01M8/10 ,  C08J5/22 ,  H01M4/86

CPC分类号： C08G73/18 ,  B01D71/62 ,  B01D71/82 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1044 ,  H01M8/1048

摘要： The present invention relates to proton-conducting polymer membranes which comprise polyazoles containing phosphonic acid groups and are obtainable by a process comprising the steps A) mixing of one or more aromatic and/or heteroaromatic tetraamino compounds with one or more aromatic and/or heteroaromatic carboxylic acids or derivatives thereof which contain at least two acid groups per carboxylic acid monomer, with at least part of the tetraamino compounds and/or the carboxylic acids comprising at least one phosphonic acid group, or mixing of one or more aromatic and/or heteroaromatic diaminocarboxylic acids, of which at least part comprises phosphonic acid groups, in polyphosphoric acid to form a solution and/or dispersion, B) heating of the solution and/or dispersion obtainable according to step A) under inert gas at temperatures of up to 350° C. to form polyazole polymers, C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting.

摘要翻译： 本发明涉及包含含有膦酸基团的多唑类的质子传导聚合物膜，并且可通过包括以下步骤的方法获得：a）将一种或多种芳族和/或杂芳族四氨基化合物与一种或多种芳族和/或杂芳族羧酸 每个羧酸单体含有至少两个酸基的酸或其衍生物，至少部分四氨基化合物和/或羧酸包含至少一个膦酸基团，或一种或多种芳族和/或杂芳族二氨基羧酸 酸，其至少部分包含膦酸基团，在多磷酸中形成溶液和/或分散体; B）在惰性气体下，在高达350℃的温度下加热根据步骤A）可获得的溶液和/或分散体 C.形成聚唑聚合物，C）使用来自步骤A）和/或B）的混合物将层施加到载体上，D）处理膜 在步骤C）中形成，直到其自支撑为止。

公开(公告)号：US20060078774A1

公开(公告)日：2006-04-13

申请号：US10530226

申请日：2003-10-02

申请人： Oemer Uensal ,  Joachim Kiefer ,  Gordon Calundann ,  Michael Sansone ,  Brian Benicewicz ,  Eui Choe

发明人： Oemer Uensal ,  Joachim Kiefer ,  Gordon Calundann ,  Michael Sansone ,  Brian Benicewicz ,  Eui Choe

IPC分类号： H01M8/10 ,  C08J5/22 ,  H01M4/86

CPC分类号： C08J5/2275 ,  B01D71/62 ,  C08G73/18 ,  C08J2379/06 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1034 ,  H01M8/1037 ,  H01M8/1039 ,  H01M8/1041 ,  H01M8/1048 ,  H01M8/1072 ,  H01M8/1081 ,  Y02P70/56

摘要： The present invention relates to a proton-conducting polymer membrane which comprises polyazole blends and is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole (polymer A) and/or one or more compounds which are suitable for forming polyazoles under the action of heat according to step B), B) heating of the mixture obtainable according to step A) under inert gas to temperatures of up to 400° C., C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting, wherein at least one further polymer (polymer B) which is not a polyazole is added to the composition obtainable according to step A) and/or step B) and the weight ratio of polyazole to polymer B is in the range from 0.1 to 50.

摘要翻译： 本发明涉及一种质子传导性聚合物膜，其包含聚唑共混物并且可通过包括以下步骤的方法获得：A）制备包含多磷酸，至少一种聚唑（聚合物A）和/或一种或多种化合物 适用于根据步骤B）在热的作用下形成多唑类; B）将惰性气体下得到的混合物加热至高达400℃的温度; C）使用混合物 从步骤A）和/或B）到支持物，D）处理在步骤C）中形成的膜，直到其自支撑，其中至少一种不是聚唑的另外的聚合物（聚合物B）加入到 根据步骤A）和/或步骤B）可获得的组合物，并且聚唑与聚合物B的重量比在0.1至50的范围内。