摘要:
The present invention relates to a process for hydrogenating oligo- and/or polyesters obtainable by esterifying a DCS with a diol or diol mixture, said hydrogenation being performed in the presence of a catalyst whose catalyst precursor comprises copper oxide, aluminum oxide and at least one oxide of lanthanum, of iron, of tungsten, of molybdenum, of titanium or of zirconium, and to a process for preparing 1,6-hexanediol by catalytically hydrogenating ester mixtures which comprise, as main components, oligo- and polyesters of adipic acid and 6-hydroxycaproic acid, and are obtained by esterifying DCS with diols, especially 1,6-hexanediol or diol mixtures.
摘要:
The present invention relates to a process for hydrogenating oligo- and/or polyesters obtainable by esterifying a DCS with a diol or diol mixture, said hydrogenation being performed in the presence of a catalyst whose catalyst precursor comprises copper oxide, aluminum oxide and at least one oxide of lanthanum, of iron, of tungsten, of molybdenum, of titanium or of zirconium, and to a process for preparing 1,6-hexanediol by catalytically hydrogenating ester mixtures which comprise, as main components, oligo- and polyesters of adipic acid and 6-hydroxycaproic acid, and are obtained by esterifying DCS with diols, especially 1,6-hexanediol or diol mixtures.
摘要:
In a process for preparing a supported hydrogenation catalyst with increased hydrogenation activity, which comprises a hydrogenating metal and/or an oxide of a hydrogenating metal on an Al2O3-containing support material, said calcined supported hydrogenation catalyst is treated before or after the final shaping thereof and before use thereof in the hydrogenation with a base solution having a pH of >10 at a temperature in the range from 20 to 120° C. for 1 to 300 hours.
摘要翻译:在含有Al 2 O 3的载体材料上制备含氢化金属和/或氢化金属的氢化物的氢化活性增加的负载型氢化催化剂的方法中,所述煅烧的负载氢化催化剂在其最终成型之前或之后进行处理 并且在使用之前,在温度为20〜120℃的pH为> 10的碱溶液中氢化1〜300小时。
摘要:
In a process for preparing a supported hydrogenation catalyst with increased hydrogenation activity, which comprises a hydrogenating metal and/or an oxide of a hydrogenating metal on an Al2O3-containing support material, said calcined supported hydrogenation catalyst is treated before or after the final shaping thereof and before use thereof in the hydrogenation with a base solution having a pH of >10 at a temperature in the range from 20 to 120° C. for 1 to 300 hours.
摘要翻译:在含有Al 2 O 3的载体材料上制备含氢化金属和/或氢化金属的氢化物的氢化活性增加的负载型氢化催化剂的方法中,所述煅烧的负载氢化催化剂在其最终成型之前或之后进行处理 并且在使用之前,在温度为20〜120℃的pH为> 10的碱溶液中氢化1〜300小时。
摘要:
The invention relates to a process for preparing ε-caprolactone from 6-hydroxycaproic ester in the gas phase in the presence of activated carbon as a catalyst and subsequent distillation.
摘要:
The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).
摘要:
The present invention provides a process for preparing ε-caprolactone in a purity of more than 99% by cyclizing 6-hydroxycaproic esters in the liquid phase at from 150 to 400° C. and from 1 to 1020 hPa abs., and removing and condensing the compounds which are volatile under cyclization conditions, which comprises thermally treating the remaining bottom product of the cyclization in at least one further reactor, removing and condensing volatile compounds and obtaining ε-caprolactone by distillation from the condensates.
摘要:
The present invention provides a process for preparing ε-caprolactone in a purity of more than 99% by cyclizing 6-hydroxycaproic esters in the liquid phase at from 150 to 400° C. and from 1 to 1020 hPa abs., and removing and condensing the compounds which are volatile under cyclization conditions, which comprises thermally treating the remaining bottom product of the cyclization in at least one further reactor, removing and condensing volatile compounds and obtaining ε-caprolactone by distillation from the condensates.
摘要:
The present application relates to an improved process for preparing 6-hydroxycaproic esters from the by-product mixtures which are obtained in the oxidation of cyclohexane to cyclohexanol and cyclohexanone with oxygen or oxygen-comprising gas mixtures.
摘要:
The invention relates to a process for preparing ε-caprolactone from 6-hydroxycaproic ester in the gas phase in the presence of activated carbon as a catalyst and subsequent distillation.