Method for Producing Propene From Propane
    3.
    发明申请
    Method for Producing Propene From Propane 审中-公开
    从丙烷生产丙烯的方法

    公开(公告)号:US20080269536A1

    公开(公告)日:2008-10-30

    申请号:US11817599

    申请日:2006-03-03

    IPC分类号: C07C5/48

    CPC分类号: C07C5/327 C07C5/48 C07C11/06

    摘要: The invention relates to a process for preparing propene from propane, comprising the steps:A) a feed gas stream a comprising propane is provided;B) the feed gas stream a comprising propane, if appropriate steam and if appropriate and an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, nitrogen, carbon monoxide, carbon dioxide, steam, if appropriate hydrogen and if appropriate oxygen;C) the product gas stream b is cooled, if appropriate compressed and steam is removed by condensation to obtain a steam-depleted product gas stream c;D) uncondensable or low-boiling gas constituents are removed by contacting the product gas stream c with an inert absorbent and subsequently desorbing the gases dissolved in the inert absorbent to obtain a C3 hydrocarbon stream d1 and an offgas stream d2 comprising methane, ethane, ethene, nitrogen, carbon monoxide, carbon dioxide, if appropriate hydrogen and if appropriate oxygen;E) the Ca hydrocarbon stream d1 is cooled and if appropriate compressed to obtain a gaseous or liquid Ca hydrocarbon stream e1; F) the C3 hydrocarbon stream e1 is if appropriate fed into a first distillation zone and separated distillatively into a stream f1 composed of propane and propene and a stream f2 comprising ethane and ethene;G) the stream e1 or f1 is fed into a (second) distillation zone and separated distillatively into a product stream g1 composed of propene and a stream g2 composed of propane, the stream g2 being recirculated at least partially into the dehydrogenation zone.

    摘要翻译: 本发明涉及一种从丙烷制备丙烯的方法,包括以下步骤:A)提供包含丙烷的原料气流a; B)包含丙烷的进料气流a(如果合适的话,蒸汽和适当的话)和含氧气流被送入脱氢区,丙烷经脱氢至丙烯以获得包含丙烷,丙烯,甲烷, 乙烷,乙烯,氮气,一氧化碳,二氧化碳,蒸汽,如果合适的氢气和适当的氧气; C)产物气流b被冷却,如果合适的话压缩并通过冷凝除去蒸汽,得到蒸汽消耗产物气流c; D)通过使产物气流c与惰性吸收剂接触并随后将溶解在惰性吸收剂中的气体解吸,得到C 3 O 3烃流d 1和 废气流d 2包括甲烷,乙烷,乙烯,氮气,一氧化碳,二氧化碳,如果合适的氢气和适当的氧气; E)将Ca烃流d 1冷却并适当压缩以获得气态或液态Ca烃流e 1; F)如果适当地将C 3烃流e 1加入第一蒸馏区并蒸馏分离成由丙烷和丙烯组成的料流f 1和包含乙烷和乙烯的料流f 2; 将流e 1或f 1进料到(第二)蒸馏区并蒸馏分离成由丙烯组成的产物流g 1和由丙烷组成的料流g 2,流g 2至少部分再循环至 脱氢区。

    Method for the Production of Propene from Propane
    4.
    发明申请
    Method for the Production of Propene from Propane 审中-公开
    丙烷生产丙烯的方法

    公开(公告)号:US20080221374A1

    公开(公告)日:2008-09-11

    申请号:US11813360

    申请日:2006-01-04

    IPC分类号: C07C5/02

    CPC分类号: C07C5/3337 C07C7/11 C07C11/06

    摘要: A process for preparing propene from propane, comprising the steps: A) a feed gas stream a comprising propane is provided; B) the fed gas stream a comprising propane, if appropriate steam and, if appropriate, an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, carbon monoxide, carbon dioxide, steam, if appropriate hydrogen and, if appropriate, oxygen; C) product gas stream b is cooled, if appropriate condensed and steam is removed by condensation to obtain a steam-depleted product gas stream c; D) product gas stream c is contacted in a first absorption zone with a selective, inert absorbent which selectively absorbs propene to obtain an absorbent stream d1 laden substantially with propene and a gas stream d2 comprising propane, methane, ethane, ethene, carbon monoxide, carbon dioxide and hydrogen; E) if appropriate, the absorbent stream d1 is decompressed to a lower pressure in a first desorption zone to obtain an absorbent stream e1 laden substantially with propene and a gas stream e2 comprising propene, and gas stream e2 is recycled into the first absorption zone, F) from the absorbent stream d1 or e1 laden substantially with propene, in at least one second desorption zone, by decompression, heating and/or stripping the absorbent stream d1 or e1, a gas stream f1 comprising propene is released and the selective absorbent is recovered.

    摘要翻译: 一种从丙烷制备丙烯的方法,包括以下步骤:A)提供包含丙烷的进料气流a; B)包含丙烷的进料气流a(如果合适的话)蒸汽,如果合适的话,将含氧气流送入脱氢区,然后使丙烷脱氢至丙烯,得到包含丙烷,丙烯,甲烷的产物气流b 乙烷,乙烯,一氧化碳,二氧化碳,蒸汽,如果合适的话,以及适当的话,氧气; C)产物气流b被冷却,如果合适的话冷凝和蒸汽通过冷凝除去,得到蒸汽消耗产物气流c; D)产物气流c在第一吸收区域与选择性吸收丙烯的选择性惰性吸收剂接触,从而获得基本上与丙烯一起填充的吸收剂流d1和包含丙烷,甲烷,乙烷,乙烯,一氧化碳, 二氧化碳和氢气; E)如果合适,在第一解吸区中将吸收剂流d1减压至较低的压力,以获得基本上与丙烯和包含丙烯的气流e2并且气流e2再循环到第一吸收区中的吸收剂流e1, F)通过减压,加热和/或汽提吸收剂流d1或e1,从至少一个第二解吸区中基本上与丙烯充分接触的吸收剂流d1或e1,释放包含丙烯的气流f1,并且选择性吸附剂 恢复。

    Process for preparing acrolein or acrylic acid or a mixture thereof from propane
    5.
    发明授权
    Process for preparing acrolein or acrylic acid or a mixture thereof from propane 有权
    从丙烷制备丙烯醛或丙烯酸或其混合物的方法

    公开(公告)号:US07897812B2

    公开(公告)日:2011-03-01

    申请号:US11751202

    申请日:2007-05-21

    IPC分类号: C07C51/16 C07B41/00

    摘要: A process for preparing acrolein or acrylic acid or a mixture thereof as the target product from propane, in which propane is partially dehydrogenated under heterogeneous catalysis in a reaction zone A, molecular hydrogen formed is at least partly combusted to water, any water present in the product gas A formed in reaction zone A is removed therefrom and product gas A is otherwise used to charge a reaction zone B in which propylene formed in reaction zone A is partially oxidized in the presence of remaining propane to give the target product. The target product is removed from the product gas B formed in reaction zone B and propane present in the remaining residual gas is absorbed therefrom into a solvent and, after release from the absorbate, recycled into reaction zone A.

    摘要翻译: 制备丙烯醛或丙烯酸或其混合物的方法作为丙烷的目标产物,其中丙烷在反应区A中在非均相催化下部分脱氢,形成的分子氢至少部分地燃烧到水中,存在于 在反应区A中形成的产物气体A被除去,产物气体A另外用于给反应区B充电,其中反应区A中形成的丙烯在剩余的丙烷存在下被部分氧化,得到目标产物。 将目标产物从反应区B中形成的产物气体B中除去,剩余的残余气体中存在的丙烷从其中吸收到溶剂中,并且在从吸收物质释放后再循环到反应区A中。