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公开(公告)号：US20180043341A1
公开(公告)日：2018-02-15
申请号：US15669405
申请日：2017-08-04
Applicant: PC-CUPS Ltd. , Cenovus Energy Inc.
Inventor： Pedro PEREIRA ALMAO , Gerardo VITALE-ROJAS , Maria Josefina PEREZ ZURITA , Lante Antonio CARBOGNANI , Ronald Scott SMITH , Clementina SOSA
CPC classification number: B01J29/048 , B01J23/007 , B01J23/83 , B01J27/22 , B01J29/072 , B01J35/0006 , B01J35/1061 , B01J35/108 , B01J37/082 , B01J37/10 , B01J2229/183 , B01J2229/20 , B01J2229/42 , B01J2523/00 , C01B33/185 , C01B37/005 , C01B39/48 , C10G3/49 , C10G11/05 , C10G29/04 , C10G29/16 , C10G2300/202 , C10G2300/203 , C10G2300/302 , C10G2300/308 , Y02P30/20 , B01J2523/22 , B01J2523/31 , B01J2523/3712 , B01J2523/847
Abstract: The invention relates to the preparation of novel bi- or tri metallic silicate micro-porous and/or meso-porous materials based on cerium, nickel, copper and/or zinc on a porous silicate framework matrix to use its molecular sieve effect to target preferentially the acidic organic molecules present in hydrocarbon feedstocks like crude oil, bitumen, VGO and the like. The chosen metals are selected based on their ability to activate steam and transfer oxygen for completing the oxidation of carboxylic compounds or decarboxylating them. These composite materials can be prepared under hydrothermal synthesis conditions in order to produce suitable porous solids where the metals are well dispersed and preferentially distributed inside the channels of the silicate framework where they can interact only with the molecules that can go inside the channels. According to the invention, the metallo-silicate materials are prepared under hydrothermal synthesis conditions Modification of the physical-chemical properties of the porous silicate materials can be accomplished by partial replacement of the silicon atoms by cerium, nickel, copper and/or zinc atoms in the material by isomorphous substitutions of these elements in a synthesis gel or by post-synthesis modifications like ion-exchange or impregnation/deposition. The materials can be used as prepared catalysts for the steam catalytic reduction of the total acid number (TAN) in acidic crude oil feedstocks and in the presence of steam and/or CO2 as oxidizing agent to complete decarboxylation and to keep the metal oxide active sites from reducing and deactivating as well as other partial upgrading reactions.
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公开(公告)号：US20180029022A1
公开(公告)日：2018-02-01
申请号：US15548928
申请日：2016-02-03
Applicant: PC-CUPS Ltd. , Cenovus Energy Inc.
Inventor： Pedro PEREIRA ALMAO , Gerardo VITALE-ROJAS , Maria Josefina PEREZ ZURITA , Lante Antonio CARBOGNANI , Ronald Scott SMITH , Clementina SOSA
CPC classification number: B01J29/048 , B01J23/007 , B01J23/83 , B01J27/22 , B01J29/072 , B01J35/0006 , B01J35/1061 , B01J35/108 , B01J37/082 , B01J37/10 , B01J2229/183 , B01J2229/20 , B01J2229/42 , B01J2523/00 , C01B33/185 , C01B37/005 , C01B39/48 , C10G3/49 , C10G11/05 , C10G29/04 , C10G29/16 , C10G2300/202 , C10G2300/203 , C10G2300/302 , C10G2300/308 , Y02P30/20 , B01J2523/22 , B01J2523/31 , B01J2523/3712 , B01J2523/847
Abstract: The invention relates to the preparation of novel bi- or tri metallic silicate micro-porous and/or meso-porous materials based on cerium, nickel, copper and/or zinc on a porous silicate framework matrix to use its molecular sieve effect to target preferentially the acidic organic molecules present in hydrocarbon feedstocks like crude oil, bitumen, VGO and the like. The chosen metals are selected based on their ability to activate steam and transfer oxygen for completing the oxidation of carboxylic compounds or decarboxylating them. These composite materials can be prepared under hydrothermal synthesis conditions in order to produce suitable porous solids where the metals are well dispersed and preferentially distributed inside the channels of the silicate framework where they can interact only with the molecules that can go inside the channels. According to the invention, the metallo-silicate materials are prepared under hydrothermal synthesis conditions Modification of the physical-chemical properties of the porous silicate materials can be accomplished by partial replacement of the silicon atoms by cerium, nickel, copper and/or zinc atoms in the material by isomorphous substitutions of these elements in a synthesis gel or by post-synthesis modifications like ion-exchange or impregnation/deposition. The materials can be used as prepared catalysts for the steam catalytic reduction of the total acid number (TAN) in acidic crude oil feedstocks and in the presence of steam and/or CO2 as oxidizing agent to complete decarboxylation and to keep the metal oxide active sites from reducing and deactivating as well as other partial upgrading reactions.
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