公开(公告)号：US3843611A

公开(公告)日：1974-10-22

申请号：US25586872

申请日：1972-05-22

Applicant: PHILLIPS PETROLEUM CO

Inventor： CAMPBELL R

IPC: C08G69/26 ,  C08G20/20

CPC classification number: C08G69/265

Abstract: An improved copolyamide is derived from terephthalic acid, at least one straight-chain alkanedioic acid having from 8 to 14 carbon atoms, the terephthalic acid constituting from 50 to about 90 mole percent of the acids, and at least one straight-chain alpha, omega-alkanediamine having from 6 to 14 carbon atoms. This copolyamide is useful as a molding resin and in the production of fibers.

公开(公告)号：US3840501A

公开(公告)日：1974-10-08

申请号：US26909872

申请日：1972-07-05

Applicant: PHILLIPS PETROLEUM CO

Inventor： SHUE R ,  CAMPBELL R

IPC: C08G69/26 ,  C08G20/20

CPC classification number: C08G69/265

Abstract: 1. A COMPOSITION OF MATTER CAPABLE OF BEING COMPRESSION MOLDED AND CONSISTING ESSENTIALLY OF THE COPOLYAMIDE OF (A) AT LEAST ONE OF 2,2-BIS(4-AMINOCYCLOHEXYL) PROPANE OR METHYL DERIVATIVE THEREOF HAVING THE FORMULA

H2N-(R-CYCLOHEX-1,4-YLENE)-C(-CH3)2-(R-

CYCLOHEX-1,4-YLENE)-NH2

WHEREIN R IS HYDROGEN OR METHYL AND, (B) A MIXTURE OF DICARBOXYLIC ACIDS CONSISTING ESSENTIALLY OF FROM ABOUT 20 TO ABOUT 65 MOLE PERCENT OF ADIPIC ACID AND FROM ABOUT 35 TO ABOUT 80 MOLE PERCENT OF AT LEAST ONE ACID SELECTED FROM THE GROUP CONSISTING OF SUBERIC ACID, AZELAIC ACID, SEBACIC ACID AND DODECANEDIOIC ACID, SAID 2,2-BIS(4-AMINOCYCLOHEXYL)PROPANE AND METHYL DERIVATIVE BEING EMPLOYED IN A RATIO OF ABOUT 1 MOLE PER MOLE OF SAID MIXTURE OF DICARBOXYLIC ACIDS.

公开(公告)号：US3839299A

公开(公告)日：1974-10-01

申请号：US30969572

申请日：1972-11-27

Applicant: PHILLIPS PETROLEUM CO

Inventor： CAMPBELL R ,  STAPP P ,  HOLTZ H

IPC: C08G69/26 ,  C08G20/20

CPC classification number: C08G69/26 ,  C08G69/265

Abstract: Substantially amorphous, optically clear polyamides are produced from a bis(4-aminocyclohexyl)methane or methyl derivative thereof and a bis(carboxyphenyl)methane or methyl derivative thereof. Copolyamides having desirable processing properties are produced by polymerizing the above monomers and at least one straight chain dicarboxylic acid as an additional monomer. The resulting polymers are useful as fibers as well as molding resins.

Abstract translation: 基本无定形的光学透明聚酰胺由双（4-氨基环己基）甲烷或其甲基衍生物和双（羧基苯基）甲烷或其甲基衍生物制备。 具有所需加工性质的共聚酰胺通过将上述单体和至少一种直链二羧酸作为附加单体进行聚合来制备。 所得聚合物可用作纤维以及模制树脂。

公开(公告)号：US3817903A

公开(公告)日：1974-06-18

申请号：US26909672

申请日：1972-07-05

Applicant: PHILLIPS PETROLEUM CO

Inventor： HILL H ,  CAMPBELL R

IPC: C08J3/09 ,  C08J5/12 ,  C08G51/34

CPC classification number: C08J5/122 ,  C08J3/091 ,  C08J2377/00

Abstract: COPOLYAMIDES PRODUCED FROM A BIS-(4-AMINOCYCLOHEXYL) METHANE OR METHYL DERIVATIVE THEREOF, A PHENYLINDANEDICARBOXYLIC ACID OR ALKYL DERIVATIVE THEREOF, AND AT LEAST ONE STRAIGHT CHAIN DICARBOXYLIC ACID ARE DISSOLVED IN A SOLVENT SYSTEM COMPRISING A MIXTURE OF A LOWER ALCOHOL AND A CHLOROCARBON, PARTICULARLY EFFECTIVE SOLVENT SYSTEMS COMPRISING A MIXTURE OF EITHER METHANOL OR ETHANOL AND MIXTURES THEREOF WITH AT LEAST ONE CHLOROCARBON SELECTED FROM CHLOROFORM, METHYLENE CHLORIDE, CARBON TETRACHLORIDE, TRICHLOROETHYLENE, 1,1,2- TRICHLOROETHANE, 1,1,2,2TETRACHLOROETHANE AND MIXTURES THEREOF. THE COPOLYAMIDE SOLUTIONS ARE USEFUL IN A VARIETY OF APPLICATIONS SUCH AS IN CASTING FILMS IN COATING OBJECTS, IN PREPARING FINELY DIVIDED COPOLYAMIDES FOT FURTHER USE, IN MAKING LAMINATES, IN PREPARING FIBERS, IN SOLVENT WELDING, AND THE LIKE.

公开(公告)号：US3725358A

公开(公告)日：1973-04-03

申请号：US3725358D

申请日：1971-04-12

Applicant: PHILLIPS PETROLEUM CO

Inventor： CAMPBELL R

IPC: C08G69/26 ,  C08G20/20

CPC classification number: C08G69/265 ,  C08G69/26

Abstract: Polyamide fibers employing 1,3-bis(4-piperidyl)-propane as a comonomer in combination with bis(p-aminocyclohexyl)methane or methyl derivative thereof and an acyclic C8 to C16 dicarboxylic acid are disclosed, the fibers having improved dyeability with retention of crystallinity.

Abstract translation: 公开了使用1,3-双（4-哌啶基） - 丙烷作为共聚单体与双（对氨基环己基）甲烷或其甲基衍生物和非环状的C 8至C 16二羧酸的组合的聚酰胺纤维，其具有改善的可染性和保留性 的结晶度。

公开(公告)号：US3842045A

公开(公告)日：1974-10-15

申请号：US26909572

申请日：1972-07-05

Applicant: PHILLIPS PETROLEUM CO

Inventor： CAMPBELL R

IPC: C08G69/26 ,  C08G20/20

CPC classification number: C08G69/265

Abstract: 1. A SUBSTANTIALLY AMORPHOUS, OPTICALLY CLEAR SOLID POLYAMIDE RESIN CONSISTING ESSENTIALLY OF THE POLYMERIC CONDENSATION REACTION PRODUCT OF (A) BIS(4-AMINOCYCLOHEXYL)METHANE OF 40-54 PERCENT TRANS,TRANS CONFIGURATION AND (B) A MIXTURE OF 50-70 MOLE PERCENT DODECANEDIOIC ACID AND 50-30 MOLE PERCENT SUBERIC ACID OR A MIXTURE OF 50-70 MOLE PERCENT DODECANEDIOCI ACID AND 50-30 MOLE PERCENT AZELAIC ACID.

公开(公告)号：US3839296A

公开(公告)日：1974-10-01

申请号：US25577572

申请日：1972-05-22

Applicant: PHILLIPS PETROLEUM CO

Inventor： CAMPBELL R

IPC: C08G69/28 ,  C08G20/20

CPC classification number: C08G69/28

Abstract: A salt of dicarboxylic acid and diamine, at least 50 mole percent of the dicarboxylic acid being terephthalic acid, is condensed to form a polyterephthalamide by heating the salt to a temperature in the range of about 200*C. to about 230*C. and maintaining the salt at that temperature for about 1/2 hour to about 6 hours before increasing the temperature of the salt to at least 250*C. In one specific embodiment the salt contains from about 2 to about 8 mole percent excess acid.

Abstract translation: 二羧酸和二胺的盐，至少50摩尔％的二羧酸为对苯二甲酸，通过将盐加热至约200℃至约230℃的温度并冷凝而形成聚对苯二甲酰胺，并且 将盐在该温度下保持约1/2小时至约6小时，然后将盐的温度升至至少250℃。在一个具体实施方案中，盐含有约2至约8摩尔％的过量酸。

公开(公告)号：US3838111A

公开(公告)日：1974-09-24

申请号：US21059871

申请日：1971-12-21

Applicant: PHILLIPS PETROLEUM CO

Inventor： CAMPBELL R

IPC: C08G69/26 ,  C08G20/20

CPC classification number: C08G69/265

Abstract: SUBSTANTIALLY AMORPHOUS OPTICALLY CLEAR POLYAMIDES ARE PRODUCED FROM A BIS(4-AMINOCYCLOHEXYL)METHANE OR METHYL DERIVATIVE THEREOF AND A PHENYLINDANEDICARBOXYLIC ACID OR ALKYL DERIVATIVE THEREOF. COPOLYAMIDES HAVING DESIRABLE PROCESSING PROPERTIES ARE PRODUCED BY POLYMERIZING THE ABOVE MONOMERS AND AT LEAST ONE STRAIGHT CHAIN DICARBOXYLIC ACID AS AN ADDITIONAL MONOMER. THE RESULTING POLYMERS ARE USEFUL AS FIBERS AS WELL AS MOLDING RESINS.

公开(公告)号：US3821072A

公开(公告)日：1974-06-28

申请号：US26909772

申请日：1972-07-05

Applicant: PHILLIPS PETROLEUM CO

Inventor： CAMPBELL R ,  MARRS O

IPC: B32B27/04 ,  C09J177/00 ,  C09J179/08 ,  B32B27/34 ,  B32B15/08

CPC classification number: C09J177/00 ,  B32B27/04 ,  C09J179/08 ,  Y10T428/31681

Abstract: Adhesives useful for uniting the surfaces of various elements are provided comprising a substantially amorphous polyamide or poly(amide-imide) prepared by polymerization of at least one of bis(4-aminocyclohexyl)methane (PACM) or 2,2-bis(4aminocyclohexyl)propane (PACP) or methyl derivatives thereof with at least one polycarboxylic acid or a crystalline polymer of bis(4-aminocyclohexyl)methane (PACM) and azelaic acid. The polymeric compositions can be applied to surfaces as a hot melt adhesive or solvent cement.

公开(公告)号：US3721653A

公开(公告)日：1973-03-20

申请号：US3721653D

申请日：1971-04-12

Applicant: PHILLIPS PETROLEUM CO

Inventor： CAMPBELL R

IPC: C08G69/26 ,  C08G20/20

CPC classification number: C08G69/265 ,  C08G69/26

Abstract: Polyamide fibers employing 4,4''-methylenedianiline or a methyl derivative thereof as a comonomer in combination with bis(paminocyclohexyl)methane or methyl derivative thereof and an acyclic C8 to C16 dicarboxylic acid have improved dyeability with retention of crystallinity.