公开(公告)号：US3851009A

公开(公告)日：1974-11-26

申请号：US38101873

申请日：1973-07-20

申请人： PHILLIPS PETROLEUM CO

发明人： CICHOWSKI R

IPC分类号： B01J23/75 ,  B01J23/94 ,  B01J27/18 ,  C07C5/48 ,  C07C5/18

CPC分类号： B01J23/75 ,  B01J23/94 ,  B01J27/18 ,  C07C5/48 ,  Y02P20/584

摘要： 1. A PROCESS FOR THE OXIDATIVE DEHYDROGENATION OF A DEHYDROGENATABLE HYDROCARBON FEEDSTOCK HAVING FROM 2 TO 12 CARBON ATOMS WHICH COMPRISES CONTACTING SAID FEEDSTOCK IN THE VAPOR PHASE UNDER DEHYDROGENATION CONDITIONS WITH A CATALYST CONSISTING ESSENTIALLY OF COBALT, IRON PHOSPHORUS AND COMBINED OXYGEN, WHEREIN THE PHOSPHOROUS:COBALT ATOMIC RATIO IS IN THE RANGE OF 0.01-0.5:1, AND THE OXYGEN IS PRESENT IN AN AMOUNT SUFFICIENT TO SATISFY THE VALENCE REQUIREMENTS OF SAID COBALT, IRON AND THE IRON:COBALT ATOMIC RATIO IS IN THE RANGE OF 0.01-3:1, PHOSPHROUS.

公开(公告)号：US3810953A

公开(公告)日：1974-05-14

申请号：US21514772

申请日：1972-01-03

申请人： PHILLIPS PETROLEUM CO

发明人： CICHOWSKI R

IPC分类号： B01J23/75 ,  B01J23/76 ,  B01J27/18 ,  C07C5/48 ,  C07C5/18

CPC分类号： B01J23/75 ,  B01J23/76 ,  B01J27/18 ,  C07C5/48

摘要： ORGANIC COMPOUNDS ARE OXIDATIVELY DEHYDROGENATED IN THE PRESENCE OF A SOLID CATALYST COMPRISING COBALT, PHOSPHORUS, COMBINED OXYGEN AND AT LEAST ONE METAL FOROM THE GROUP INDIUM, MAGNESIUM, ALUMINUM THORIUM, YTTRIUM, CADIMIUM, LEAD, BERYLLINUM, ZINC, MANGANESE, SILVER, CERIUM, ZIRCONIUM, BORON AND CALCIUM.

公开(公告)号：US3784483A

公开(公告)日：1974-01-08

申请号：US3784483D

申请日：1971-05-06

申请人： PHILLIPS PETROLEUM CO

发明人： CICHOWSKI R

IPC分类号： B01J23/75 ,  B01J27/185 ,  C07C5/48 ,  B01J11/82

CPC分类号： B01J23/75 ,  B01J27/1853 ,  C07C5/48 ,  Y10S585/906

摘要： ORGANIC COMPOUNDS ARE DEHYDROGENATED TO COMPOUNDS HAVING A HIGHER DEGREE OF UNSATURATION BY CONTACTING THE FEEDSTOCK IN THE VAPOR PHASSE IN THE PRESENCE OF AN OXYGENCONTAINING GAS WITH A CATALYST CCOMPRISING COBALT IN ASSOCIATION WITH IRON, PHOSPHORUS AND OXYGEN. REPRESENTATIVE OF SUCH CONVERSIONS IS THE OXIDATIVE DEHYDROGENATION OF ISOPENTANCE TO ISOPRENE AND ISOAMYLENES. THE CONVERSION PRODUCTS ARE VALUABLE COMPOUNDS PARTICULARLY USEFUL AS INTERMEDIATES FOR THE PREPARATION OF POLYMERIC MATERIALS SUCH AS SYNTHETIC RUBBERS AND THE LIKE.

公开(公告)号：US3766191A

公开(公告)日：1973-10-16

申请号：US3766191D

申请日：1971-01-22

申请人： PHILLIPS PETROLEUM CO

发明人： CICHOWSKI R

IPC分类号： B01J27/185 ,  C07C5/48 ,  C07C5/18

CPC分类号： B01J27/1853 ,  C07C5/48

摘要： OXIDATIVE DEHYDROGENATION OF ORGANIC COMPOUNDS IS CARRIED OUT IN PRESENCE OF A POTASSIUM/IRON/PHOSPHORUS/OXYGEN CATALYST COMPOSITION. A METHOD OF PREPARING THE CATALYST COMPOSITION COMPRISING ASSOCIATING POTASSIUM WITH IRON AND SUBSEQUENTLY ASSOCIATING THE POTASSIUM-IRON COMPOSITE WITH PHOSPHORUS.

公开(公告)号：US3758609A

公开(公告)日：1973-09-11

申请号：US3758609D

申请日：1971-01-11

申请人： PHILLIPS PETROLEUM CO

发明人： CICHOWSKI R

IPC分类号： B01J23/843 ,  B01J37/14 ,  C07C5/48 ,  C07C5/18 ,  C07C11/18

CPC分类号： C07C5/48 ,  B01J23/8435 ,  B01J37/14 ,  C07C11/12 ,  C07C11/02

摘要： Organic compounds are dehydrogenated to compounds having a higher degree of unsaturation by contacting the feedstock in the vapor phase in the presence of an oxygen-containing gas with a catalyst containing cobalt, iron and antimony in an oxidized state or nickel-iron-antimony in an oxidized state. Representative of such conversions is the oxidative dehydrogenation of isopentane to isoprene over a nickel-ironantimony-oxygen catalyst having a nickel:iron:antimony atomic ratio of 1:3:1. The conversion products are valuable compounds particularly useful as intermediates for the preparation of polymeric materials such as synthetic rubbers and the like.

摘要翻译： 将有机化合物脱氢成具有较高不饱和度的化合物，其中在含氧气体存在下，气相中的原料与含有氧化态的钴，铁和锑的催化剂或镍 - 铁 - 锑 氧化态。 这种转化的代表是在镍：铁：锑原子比为1:3:1的镍铁 - 锑 - 氧催化剂上，异戊烷氧化脱氢成异戊二烯。 转化产物是有价值的化合物，特别可用作制备聚合材料如合成橡胶等的中间体。