O o'-diol bisperoxycarbonates
    1.
    发明授权
    O o'-diol bisperoxycarbonates 失效
    O O'-DIOL BISPEROXYCARBONATES

    公开(公告)号:US3652631A

    公开(公告)日:1972-03-28

    申请号:US87169169

    申请日:1969-11-19

    摘要: DESCRIBED ARE DIESTERS OF DIOLS OF POLY(OXYALKYLENE) DIOLS AND TWO ACID PEROXYESTERS OF A MONOHYDRIC ALCOHOL AND CARBONIC ACID WHEREIN THE CARBONYL GROUPS OF THE PEROXYESTERS ARE ESTERIFIED WITH THE DIOL. THESE COMPOUNDS ARE REPRESENTED BY THE STRUCTURE
    R1-O-O-COO-R2-OOC-O-O-R3

    R1 AND R3 ARE ORGANIC RADICALS HAVING UP TO 10 CARBON ATOMS AND R2 IS THE DIVALENT RADICAL OF A DIOL. METHOD OF THEIR PREPARATIONS INVOLVE REACTION OF A BISCHLOROFORMATE OF THE DIOL WITH AN ORAGNIC HYDROPEROXIDE. THESE COMPOUNDS AND COMPOSITIONS THEREOF WITH AN ORGANIC HYDROPEROXIDE AND/OR DIPEROXIDE ARE DESCRIBED. THE COMPOUNDS AND COMPOSITIONS ARE USEFUL FOR POLYMERIZING OLEFINICALLY UNSATURATED MONOMERS.