Non-aqueous electrolyte secondary cell

    公开(公告)号:US11616228B2

    公开(公告)日:2023-03-28

    申请号:US16640223

    申请日:2018-10-10

    Abstract: The non-aqueous electrolyte secondary cell according to the present invention comprises: an electrode body constituted by a positive electrode including a positive electrode active material comprising a lithium-containing transition metal oxide, a negative electrode including a negative electrode current collector onto which metallic lithium is deposited during charging, and a separator disposed between the positive electrode and the negative electrode; and a non-aqueous electrolyte. The molar ratio of the total lithium content of the positive electrode and the negative electrode to the transition metal content of the positive electrode is 1.1 or less. During discharging, the positive electrode capacitance α(mAh) of the positive electrode and the volume X (mm3) of a hollow constituted by a space formed in the center of the electrode body 14 satisfy the relationship 0.5≤X/α≤4.0.

    Nonaqueous electrolyte secondary battery and method for producing same

    公开(公告)号:US11508987B2

    公开(公告)日:2022-11-22

    申请号:US16640159

    申请日:2018-10-10

    Abstract: The nonaqueous electrolyte secondary battery comprises the following: a positive electrode including a positive electrode active material that includes a lithium-containing transition metal oxide, a negative electrode including a negative electrode current collector wherein lithium metal deposits on the negative electrode current collector during charging, a separator disposed between the positive electrode and the negative electrode, and a nonaqueous electrolyte. The molar ratio of the total amount of lithium held by the positive electrode and the negative electrode to the amount of transition metal in the positive electrode is not more than 1.1. In addition, in the discharged state, a space layer is present between the negative electrode and the separator, and the positive electrode capacity per unit area, α (mAh/cm2), of the positive electrode and the average in thickness, X (μm), of the space layer 50 satisfy 0.05≤α/X≤0.2.

    LITHIUM SECONDARY BATTERY
    7.
    发明申请

    公开(公告)号:US20210305583A1

    公开(公告)日:2021-09-30

    申请号:US17261945

    申请日:2019-07-05

    Inventor: Tomohiro Harada

    Abstract: A lithium secondary battery, including: a positive electrode; a negative electrode; a non-aqueous electrolyte having lithium ion conductivity; and a separator interposed between the positive electrode and the negative electrode. The positive electrode includes a positive electrode mixture layer containing a positive electrode active material, and a positive electrode current collector. The positive electrode active material includes a composite oxide containing lithium and a transition metal. A molar ratio: MLi/MTM of a total lithium amount per unit area MLi in the positive electrode and the negative electrode to a transition metal amount per unit area MTM in the positive electrode is 1.1 or less. The negative electrode includes a negative electrode current collector, and a plurality of porous films laminated on the negative electrode current collector and having electrically insulating properties.

    LITHIUM SECONDARY BATTERY
    8.
    发明申请

    公开(公告)号:US20210280919A1

    公开(公告)日:2021-09-09

    申请号:US17261355

    申请日:2019-02-20

    Inventor: Tomohiro Harada

    Abstract: A lithium secondary battery with a positive electrode active material including a composite oxide containing lithium and a transition metal. A molar ratio: MLi/MTM of a total lithium amount per unit area MLi in a positive electrode and a negative electrode to a transition metal amount per unit area MTM in the positive electrode is 1.1 or less. The negative electrode includes a negative electrode current collector larger in area than the positive electrode mixture layer. In the wound electrode group in an unwound state, center lines dividing the positive electrode mixture layer and the negative electrode current collector along their winding direction into two halves are not on the same straight line. The negative electrode lead is connected at its one end to a non-facing region not facing the positive electrode mixture layer of the negative electrode current collector.

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