摘要:
Novel nonlinearly optically active polymers, well suited for electrooptical applications, are prepared by copolymerizing a first difunctional monomer with a second difunctional comonomer, with at least one of such difunctional monomers including a polar charge transfer moiety containing at least one electron acceptor group and at least one electron donor group (D), and further wherein the polymerizable functional groups are borne by the one or more electron donor groups (D).
摘要:
Marterials which are active in nonlinear optics, having a repeating unit of the following formula I: ##STR1## in which R.sub.1 and R.sub.2, are either identical or different, and denote a linear or branched methylenic chain, preferably containing from 2 to 6 carbon atoms; R.sub.3 is an aliphatic, aromatic or arylaliphatic hydrocarbon radical; R.sub.4 and R.sub.5, which are identical or different, denote a nitrogen atom or a CH radical, or alternatively R.sub.4 and R.sub.5 are both carbon with the R.sub.4 -R.sub.5 bond being a double or a triple bond; and Z.sub.1 and Z.sub.2, which are identical or different, denote an aromatic group wherein Z.sub.1 optionally contains one or more substituents R.sub.7 and wherein Z.sub.2 optionally contains one or more substituents R.sub.7 in addition to group A, each substituent R.sub.7 may be lower alkyl, halogen, amido, amino, sulfoxide, hydroxyl radical, alkoxy and trifluoromethyl; and A denotes an electron-acceptor group, with Z.sub.2 having one or more groups A.
摘要:
Novel nonlinearly optically active polyurethane polymers, well suited for electrooptical applications, have recurring structural units of the formula: ##STR1## in which m is a number greater than 5; R.sub.1 and R.sub.2, which may be identical or different, are each a saturated or unsaturated alkyl or aromatic radical; R.sub.3 is a linear aliphatic, or cyclic aromatic or arylaliphatic hydrocarbon radical; and Y is a group including a radical containing dislocated .pi. electrons and an electron acceptor group (A).
摘要翻译:非常适用于电光应用的新型非线性光学活性聚氨酯聚合物具有下式的重复结构单元:其中m是大于5的数字; R 1和R 2可以相同或不同,分别为饱和或不饱和的烷基或芳基; R3是直链脂族或环状芳族或芳基脂族烃基; Y是包含含有位错的π电子的基团和电子受体基团(A)的基团。
摘要:
The present invention relates to new thiphene-related compounds of the general formula (I): ##STR1## in which: n is an integer between 1 and 10, advantageously between 1 and 4;A is an electron-acceptor group; and D is an electron-donor group.These compounds exhibit a high hyperpolarizability and an excellent photochemical stability and are employed especially in optical or electrooptical devices for their activity in nonlinear optics.
摘要:
Nonlinearly optically active monomer species comprising at least two carbon-carbon activated double bonds, i.e., the polymerization of which is facilitated by the presence of an electron attracting function, and a non-centrosymmetric system of pi (.pi.) conjugated bonds bearing at least one electron attracting group on one terminal thereof and at least one electron donor group on the other terminal, are readily (co)polymerized and optionally oriented and crosslinked into shaped articles well adopted for the manufacture of a variety of electrooptical devices; such monomer species can have, for example, the following structural formula (I): ##STR1##
摘要:
Nonlinearly optically active monomer species comprising at least two carbon-carbon activated double bonds, i.e., the polymerization of which is facilitated by the presence of an electron attracting function, and a non-centrosymmetric system of pi (.pi.) conjugated bonds bearing at least one electron attracting group on one terminal thereof and at least one electron donor group on the other terminal, are readily (co)polymerized and optionally oriented and crosslinked into shaped articles well adopted for the manufacture of a variety of electrooptical devices; such monomer species can have, for example, the following structural formula (I): ##STR1##
摘要:
Novel nonlinearly optically active compound's, well suited for electrooptical applications, have the following general formulae: ##STR1## wherein D is an electron donor group; A and A.sub.1, which may be identical or different, are each an electron acceptor group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each a lower alkyl radical or a hydrogen atom.
摘要:
Novel nonlinearly optically active compounds, well suited for electrooptical applications, have the following general formulae: ##STR1## wherein D is an electron donor group; A and A.sub.1, which may be identical or different, are each an electron acceptor group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each a lower alkyl radical or a hydrogen atom.
摘要:
The invention relates to a photovoltaic coating containing a mixture of organic N-type (acceptor) and P-type (donor) semiconductor compounds, which makes it possible, when selecting the donor/acceptor pair, to modulate the semiconductor properties of the photovoltaic coating so as to enable the use thereof within a photovoltaic device, wherein one of the organic semiconductors includes a quinone core.
摘要:
The invention provides a method for preparing functionalized polyorganosiloxane resins (POS) comprising units M: (R3SiO1/2), Q: (SiO4/2) and M′: (YaR3-aSiO1/2) and optionally D: (R2SiO2/2) and/or D′: (RYSiO2/2) and T: (RSiO3/2) and/or T′: (YSiO3/2), wherein in said units R is C1-C10 alkyl or C8-C12 aryl and Y is a functional group (such as Si—H), by redistributing POS resins, using POSf bearing functional groups M′ and/or D′ and/or in the presence of an acid catalyst such as triflic acid or one of its derivatives and a non-basic inert filler: carbon black, diatomaceous earth, zeolite or acid or neutral oxide (Al2O3, Na2O, TiO2, MgO, silica). The invention also provides said catalyst system.
摘要翻译:本发明提供了一种制备官能化聚有机硅氧烷树脂(POS)的方法,所述聚有机硅氧烷树脂(POS)包含单元M:(R 3 SiO 2 1/2),Q:(SiO 4/2 )和M':(Y a a R 3-a SiO 1/2)和任选的D:(R SUB 和/或D':(RYSiO 2/2/2)和T:(RS 3 O 3/2/2) SUB)和/或T':(YSiO 3/2/2),其中在所述单元中R是C 1 -C 10烷基或 C 8 -C 12芳基,Y是官能团(如Si-H),通过重新分配POS树脂,使用具有POS的官能团M'和/或D 和/或在酸催化剂如三氟甲烷或其衍生物之一和非碱性惰性填料:碳黑,硅藻土,沸石或酸或中性氧化物(Al 2 O 3)存在下, O 3,Na 2 O,TiO 2,MgO,二氧化硅)。 本发明还提供了所述催化剂体系。