Organic material active in nonlinear optics
    2.
    发明授权
    Organic material active in nonlinear optics 失效
    非线性光学有机材料

    公开(公告)号:US5075409A

    公开(公告)日:1991-12-24

    申请号:US520202

    申请日:1990-05-03

    摘要: Marterials which are active in nonlinear optics, having a repeating unit of the following formula I: ##STR1## in which R.sub.1 and R.sub.2, are either identical or different, and denote a linear or branched methylenic chain, preferably containing from 2 to 6 carbon atoms; R.sub.3 is an aliphatic, aromatic or arylaliphatic hydrocarbon radical; R.sub.4 and R.sub.5, which are identical or different, denote a nitrogen atom or a CH radical, or alternatively R.sub.4 and R.sub.5 are both carbon with the R.sub.4 -R.sub.5 bond being a double or a triple bond; and Z.sub.1 and Z.sub.2, which are identical or different, denote an aromatic group wherein Z.sub.1 optionally contains one or more substituents R.sub.7 and wherein Z.sub.2 optionally contains one or more substituents R.sub.7 in addition to group A, each substituent R.sub.7 may be lower alkyl, halogen, amido, amino, sulfoxide, hydroxyl radical, alkoxy and trifluoromethyl; and A denotes an electron-acceptor group, with Z.sub.2 having one or more groups A.

    摘要翻译: 具有下列式I的重复单元的非线性光学活性物质:其中R 1和R 2相同或不同,并且表示直链或支链亚甲基链,优选含有2〜 6个碳原子; R3是脂族,芳族或芳基脂族烃基; R4和R5相同或不同,表示氮原子或CH基团,或者R4和R5都是碳,R4-R5键是双键或三键; 和Z 1和Z 2相同或不同,表示芳族基团,其中Z1任选地含有一个或多个取代基R 7,并且其中Z 2除了基团A任选含有一个或多个取代基R 7,每个取代基R 7可以是低级烷基,卤素, 酰氨基,氨基,亚砜,羟基,烷氧基和三氟甲基; 并且A表示电子受体基团,Z 2具有一个或多个基团A.

    Process for preparing functionalized polyorganosiloxane resins by redistribution in the presence of triflic acid and/or of at least one derivative thereof and of a nonbasic inert filler
    10.
    发明申请
    Process for preparing functionalized polyorganosiloxane resins by redistribution in the presence of triflic acid and/or of at least one derivative thereof and of a nonbasic inert filler 审中-公开
    在三氟酸和/或其至少一种衍生物和非碱性惰性填料的存在下再分配制备官能化聚有机硅氧烷树脂的方法

    公开(公告)号:US20080255292A1

    公开(公告)日:2008-10-16

    申请号:US12142318

    申请日:2008-06-19

    IPC分类号: C08L83/06 C08K3/34

    CPC分类号: C08G77/10 C08G77/08

    摘要: The invention provides a method for preparing functionalized polyorganosiloxane resins (POS) comprising units M: (R3SiO1/2), Q: (SiO4/2) and M′: (YaR3-aSiO1/2) and optionally D: (R2SiO2/2) and/or D′: (RYSiO2/2) and T: (RSiO3/2) and/or T′: (YSiO3/2), wherein in said units R is C1-C10 alkyl or C8-C12 aryl and Y is a functional group (such as Si—H), by redistributing POS resins, using POSf bearing functional groups M′ and/or D′ and/or in the presence of an acid catalyst such as triflic acid or one of its derivatives and a non-basic inert filler: carbon black, diatomaceous earth, zeolite or acid or neutral oxide (Al2O3, Na2O, TiO2, MgO, silica). The invention also provides said catalyst system.

    摘要翻译: 本发明提供了一种制备官能化聚有机硅氧烷树脂(POS)的方法,所述聚有机硅氧烷树脂(POS)包含单元M:(R 3 SiO 2 1/2),Q:(SiO 4/2 )和M':(Y a a R 3-a SiO 1/2)和任选的D:(R SUB 和/或D':(RYSiO 2/2/2)和T:(RS 3 O 3/2/2) SUB)和/或T':(YSiO 3/2/2),其中在所述单元中R是C 1 -C 10烷基或 C 8 -C 12芳基,Y是官能团(如Si-H),通过重新分配POS树脂,使用具有POS的官能团M'和/或D 和/或在酸催化剂如三氟甲烷或其衍生物之一和非碱性惰性填料:碳黑,硅藻土,沸石或酸或中性氧化物(Al 2 O 3)存在下, O 3,Na 2 O,TiO 2,MgO,二氧化硅)。 本发明还提供了所述催化剂体系。