Organic material active in nonlinear optics
    2.
    发明授权
    Organic material active in nonlinear optics 失效
    非线性光学有机材料

    公开(公告)号:US5075409A

    公开(公告)日:1991-12-24

    申请号:US520202

    申请日:1990-05-03

    摘要: Marterials which are active in nonlinear optics, having a repeating unit of the following formula I: ##STR1## in which R.sub.1 and R.sub.2, are either identical or different, and denote a linear or branched methylenic chain, preferably containing from 2 to 6 carbon atoms; R.sub.3 is an aliphatic, aromatic or arylaliphatic hydrocarbon radical; R.sub.4 and R.sub.5, which are identical or different, denote a nitrogen atom or a CH radical, or alternatively R.sub.4 and R.sub.5 are both carbon with the R.sub.4 -R.sub.5 bond being a double or a triple bond; and Z.sub.1 and Z.sub.2, which are identical or different, denote an aromatic group wherein Z.sub.1 optionally contains one or more substituents R.sub.7 and wherein Z.sub.2 optionally contains one or more substituents R.sub.7 in addition to group A, each substituent R.sub.7 may be lower alkyl, halogen, amido, amino, sulfoxide, hydroxyl radical, alkoxy and trifluoromethyl; and A denotes an electron-acceptor group, with Z.sub.2 having one or more groups A.

    摘要翻译: 具有下列式I的重复单元的非线性光学活性物质:其中R 1和R 2相同或不同,并且表示直链或支链亚甲基链,优选含有2〜 6个碳原子; R3是脂族,芳族或芳基脂族烃基; R4和R5相同或不同,表示氮原子或CH基团,或者R4和R5都是碳,R4-R5键是双键或三键; 和Z 1和Z 2相同或不同,表示芳族基团,其中Z1任选地含有一个或多个取代基R 7,并且其中Z 2除了基团A任选含有一个或多个取代基R 7,每个取代基R 7可以是低级烷基,卤素, 酰氨基,氨基,亚砜,羟基,烷氧基和三氟甲基; 并且A表示电子受体基团,Z 2具有一个或多个基团A.

    N,N'-bis(maleimide)/alkenyloxyaniline copolymerizate
    4.
    发明授权
    N,N'-bis(maleimide)/alkenyloxyaniline copolymerizate 失效
    N,N'-双(马来酰亚胺)/烯氧基苯胺共聚物

    公开(公告)号:US4839440A

    公开(公告)日:1989-06-13

    申请号:US134043

    申请日:1987-12-17

    申请人: Pascal Barthelemy

    发明人: Pascal Barthelemy

    摘要: Novel thermosetting imido copolymers having improved thermal properties and well adapted for the production, e.g., of molded and cellular shaped articles, and laminates, are formed from (a) at least one N,N'-bis(maleimide), (b) at least one alkenyloxyaniline, and (c) admixture of (i) at least one N-[(meth)allyloxyphenyl]maleimide with (ii) at least one N-[(meth)allyloxy-mono-/di(meth)allylphenyl]maleimide.

    摘要翻译: 由(a)至少一种N,N'-双(马来酰亚胺),(b)在(a)中形成具有改进的热性能并且适于生产的新型热固性亚胺共聚物,例如模制和细胞形状制品和层压材料, 至少一种烯氧基苯胺,和(c)至少一种N - [(甲基)烯丙氧苯基]马来酰亚胺与(ii)至少一种N - [(甲基)烯丙氧基 - 单 - (甲基)烯丙基苯基]马来酰亚胺 。

    Transparent amorphous polyamide having high Tg from hindered aromatic
diamine and branched chain aliphatic diamine
    6.
    发明授权
    Transparent amorphous polyamide having high Tg from hindered aromatic diamine and branched chain aliphatic diamine 失效
    由受阻芳族二胺和支链脂族二胺具有高Tg的透明无定形聚酰胺

    公开(公告)号:US4937315A

    公开(公告)日:1990-06-26

    申请号:US366473

    申请日:1989-06-15

    申请人: Pascal Barthelemy

    发明人: Pascal Barthelemy

    IPC分类号: C08G69/26 C08L77/00

    摘要: Amorphous and transparent copolyamides having glass transition temperatures, Tg, greater than 140.degree. C. and improved thermomechanical properties, well adopted for the production of a wide variety of useful shaped articles, contain specified amounts of terephthalic acid, 2-methylpentamethylenediamine and hindered aromatic diamine recurring structural units.

    摘要翻译: 具有玻璃化转变温度Tg,大于140℃的无定形和透明共聚酰胺,以及良好地用于生产各种有用的成型制品的改进的热机械性能,含有特定量的对苯二甲酸,2-甲基戊二胺和受阻芳族二胺 重复结构单位。

    Polyamide-imide based filaments, and a process for obtaining them
    8.
    发明授权
    Polyamide-imide based filaments, and a process for obtaining them 失效
    聚酰胺酰亚胺基丝,以及获得它们的方法

    公开(公告)号:US5159052A

    公开(公告)日:1992-10-27

    申请号:US790163

    申请日:1991-11-12

    CPC分类号: D01F6/74 D01F6/78

    摘要: The present invention relates to heat-resistant threads, filaments and fibres based on polyamide-imide. They have a polydispersion index I.ltoreq.2.2, a breaking tenacity.gtoreq.45 cN/tex, a Young's modulus.gtoreq.3.8 GPa, an elongation.ltoreq.25% and a color defined by the luminance Y>25%, the degree of whiteness DW 170. In addition they have a very good stability to light, quantified by the retention of the mechanical characteristics. They have wide application in working and protective garments.

    摘要翻译: 本发明涉及耐热丝,长丝和基于聚酰胺 - 酰亚胺的纤维。 它们具有多分散指数I / = 45cN / tex,杨氏模量> / = 3.8GPa,伸长率<25%和由亮度Y> 25%定义的颜色, 白度DW <30,黄色指数YI> 170。 此外,它们具有非常好的光稳定性,通过保留机械特性量化。 它们在工作和防护服上广泛应用。

    Polyamide-imide solutions and a process for obtaining them
    9.
    发明授权
    Polyamide-imide solutions and a process for obtaining them 失效
    聚酰胺酰亚胺溶液及其获得方法

    公开(公告)号:US4950700A

    公开(公告)日:1990-08-21

    申请号:US308009

    申请日:1989-02-09

    摘要: The present invention relates to solutions of polyamide-imides which can be spun and shaped, and to a process for their preparation.They contain 5 to 30% of a polyamide-imide in a solvent mixture comprising 40-80% by weight of butyrolactone and 20-60% of an aprotic amide solvent. They are obtained by the reaction, in butyrolactone as polycondensation solvent, of a diisocyanate, an aromatic acid anhydride, optionally an alkali or alkaline-earth metal dicarboxybenzenesulfonate, and optionally another aromatic diacid, the concentration of polyamide-imide being from 15 to 36%, followed by dilution in an amide solvent, at a temperature between 120.degree. and 165.degree. C.The solutions obtained are clear at room temperature, are storable, and possess improved color.

    摘要翻译: 本发明涉及可以纺丝和成形的聚酰胺 - 酰亚胺的溶液及其制备方法。 它们在包含40-80重量%的丁内酯和20-60%的非质子酰胺溶剂的溶剂混合物中含有5至30%的聚酰胺 - 酰亚胺。 它们通过二异氰酸酯,芳族酸酐,任选的碱金属或碱土金属二羧基苯磺酸酯和任选的另外的芳族二酸在丁内酯作为缩聚溶剂中反应而获得,聚酰胺 - 酰亚胺的浓度为15-36% ,然后在酰胺溶剂中稀释,温度在120〜165℃。所得溶液在室温下是透明的,可储存的,并具有改善的颜色。