摘要:
Novel nonlinearly optically active polymers, well suited for electrooptical applications, are prepared by copolymerizing a first difunctional monomer with a second difunctional comonomer, with at least one of such difunctional monomers including a polar charge transfer moiety containing at least one electron acceptor group and at least one electron donor group (D), and further wherein the polymerizable functional groups are borne by the one or more electron donor groups (D).
摘要:
Marterials which are active in nonlinear optics, having a repeating unit of the following formula I: ##STR1## in which R.sub.1 and R.sub.2, are either identical or different, and denote a linear or branched methylenic chain, preferably containing from 2 to 6 carbon atoms; R.sub.3 is an aliphatic, aromatic or arylaliphatic hydrocarbon radical; R.sub.4 and R.sub.5, which are identical or different, denote a nitrogen atom or a CH radical, or alternatively R.sub.4 and R.sub.5 are both carbon with the R.sub.4 -R.sub.5 bond being a double or a triple bond; and Z.sub.1 and Z.sub.2, which are identical or different, denote an aromatic group wherein Z.sub.1 optionally contains one or more substituents R.sub.7 and wherein Z.sub.2 optionally contains one or more substituents R.sub.7 in addition to group A, each substituent R.sub.7 may be lower alkyl, halogen, amido, amino, sulfoxide, hydroxyl radical, alkoxy and trifluoromethyl; and A denotes an electron-acceptor group, with Z.sub.2 having one or more groups A.
摘要:
Novel nonlinearly optically active polyurethane polymers, well suited for electrooptical applications, have recurring structural units of the formula: ##STR1## in which m is a number greater than 5; R.sub.1 and R.sub.2, which may be identical or different, are each a saturated or unsaturated alkyl or aromatic radical; R.sub.3 is a linear aliphatic, or cyclic aromatic or arylaliphatic hydrocarbon radical; and Y is a group including a radical containing dislocated .pi. electrons and an electron acceptor group (A).
摘要翻译:非常适用于电光应用的新型非线性光学活性聚氨酯聚合物具有下式的重复结构单元:其中m是大于5的数字; R 1和R 2可以相同或不同,分别为饱和或不饱和的烷基或芳基; R3是直链脂族或环状芳族或芳基脂族烃基; Y是包含含有位错的π电子的基团和电子受体基团(A)的基团。
摘要:
Novel thermosetting imido copolymers having improved thermal properties and well adapted for the production, e.g., of molded and cellular shaped articles, and laminates, are formed from (a) at least one N,N'-bis(maleimide), (b) at least one alkenyloxyaniline, and (c) admixture of (i) at least one N-[(meth)allyloxyphenyl]maleimide with (ii) at least one N-[(meth)allyloxy-mono-/di(meth)allylphenyl]maleimide.
摘要:
Thermally stable block copolymers, well adapted for the production of coating films, include recurring imide/amide blocks of the formula: ##STR1## and recurring urea/siloxane blocks of the formula:--NH--CO--NH--A--NH--CO--NH-- (II)wherein A is a divalent diorganosiloxane radical of the formula ##STR2##
摘要:
Amorphous and transparent copolyamides having glass transition temperatures, Tg, greater than 140.degree. C. and improved thermomechanical properties, well adopted for the production of a wide variety of useful shaped articles, contain specified amounts of terephthalic acid, 2-methylpentamethylenediamine and hindered aromatic diamine recurring structural units.
摘要:
Novel heat-resistant maleimido polymers, well adopted for the production of molded/laminated shaped articles, are copolymerizates of (a) a hydrocarbyl N,N'-bis(maleimide); (b) an N,N'-bis(maleimide) containing a diorganopolysiloxane bridge; (c) a diprimary diamine; optionally, (d) at least one other comonomer copolymerizable therewith; and, optionally, (e) a catalyst therefor.
摘要:
The present invention relates to heat-resistant threads, filaments and fibres based on polyamide-imide. They have a polydispersion index I.ltoreq.2.2, a breaking tenacity.gtoreq.45 cN/tex, a Young's modulus.gtoreq.3.8 GPa, an elongation.ltoreq.25% and a color defined by the luminance Y>25%, the degree of whiteness DW 170. In addition they have a very good stability to light, quantified by the retention of the mechanical characteristics. They have wide application in working and protective garments.
摘要:
The present invention relates to solutions of polyamide-imides which can be spun and shaped, and to a process for their preparation.They contain 5 to 30% of a polyamide-imide in a solvent mixture comprising 40-80% by weight of butyrolactone and 20-60% of an aprotic amide solvent. They are obtained by the reaction, in butyrolactone as polycondensation solvent, of a diisocyanate, an aromatic acid anhydride, optionally an alkali or alkaline-earth metal dicarboxybenzenesulfonate, and optionally another aromatic diacid, the concentration of polyamide-imide being from 15 to 36%, followed by dilution in an amide solvent, at a temperature between 120.degree. and 165.degree. C.The solutions obtained are clear at room temperature, are storable, and possess improved color.
摘要:
Novel heat-resistant maleimido polymers, well adopted for the production of molded/laminated shaped articles, are copolymerizates of (a) a hydrocarbyl N,N'-bis(maleimide); (b) a diamine containing a diorganopolysiloxane bridge; optionally, (c) an N,N'-bis(maleimide) containing a diorganopolysiloxane bridge; optionally, (d) at least one other comonomer copolymerizable therewith; and, optionally, (e) a catalyst therefor.