公开(公告)号：US06663767B1

公开(公告)日：2003-12-16

申请号：US09562452

申请日：2000-05-02

申请人： Paul Joseph Berlowitz ,  Daniel Francis Ryan ,  Robert Jay Wittenbrink ,  Jack Wayne Johnson ,  John Richard Bateman

发明人： Paul Joseph Berlowitz ,  Daniel Francis Ryan ,  Robert Jay Wittenbrink ,  Jack Wayne Johnson ,  John Richard Bateman

IPC分类号： C10L108

CPC分类号： C10L1/08

摘要： A blended fuel, useful as a diesel fuel, wherein the fuel blend contains an undercut conventional diesel fuel, blended with a Fischer-Tropsch derived diesel fuel, such that the blend demonstrates better than expected emissions and a reduced sulfur content. In particular, the blend is an asymmetric diesel fuel blend comprising a Fischer-Tropsch derived hydrocarbon distillate having a T95 of at least 600° F., blended with a petroleum derived hydrocarbon distillate having an initial boiling point and a T95 no greater than 640° F.

摘要翻译： 用作柴油燃料的混合燃料，其中燃料混合物含有与费 - 托衍生的柴油混合的底切常规柴油，使得共混物表现出比预期的排放更好并且硫含量降低。 特别地，该共混物是不对称柴油燃料混合物，其包含具有至少600°F的T95的费 - 托衍生烃馏分，与起始沸点和T95不大于640°F的石油衍生烃馏分混合 F。

公开(公告)号：US06787022B1

公开(公告)日：2004-09-07

申请号：US09562453

申请日：2000-05-02

申请人： Paul Joseph Berlowitz ,  Daniel Francis Ryan ,  Robert Jay Wittenbrink ,  W. Berlin Genetti ,  Jack Wayne Johnson

发明人： Paul Joseph Berlowitz ,  Daniel Francis Ryan ,  Robert Jay Wittenbrink ,  W. Berlin Genetti ,  Jack Wayne Johnson

IPC分类号： C10G6510

CPC分类号： C10G65/043

摘要： A process for the production of a winter diesel fuel from wax containing hydrocarbons produced by the Fischer-Tropsch hydrocarbon synthesis process. A 300° F.+ Fischer-Tropsch fraction is upgraded first by hydroisomerization followed by catalytic dewaxing resulting in a diesel fuel suitable for use as a winter diesel fuel having excellent cold flow properties and reduced emissions.

摘要翻译： 一种由费 - 托烃合成方法生产的含蜡烃生产冬季柴油的方法。 首先通过加氢异构化升级300°F +费 - 托馏分，然后进行催化脱蜡，得到适合用作具有优异冷流特性和减少排放的冬季柴油燃料的柴油燃料。

公开(公告)号：US06833064B2

公开(公告)日：2004-12-21

申请号：US09922321

申请日：2001-08-03

申请人： Paul Joseph Berlowitz ,  Robert Jay Wittenbrink ,  Daniel Francis Ryan ,  William Berlin Genetti ,  Jack Wayne Johnson

发明人： Paul Joseph Berlowitz ,  Robert Jay Wittenbrink ,  Daniel Francis Ryan ,  William Berlin Genetti ,  Jack Wayne Johnson

IPC分类号： C10L104

CPC分类号： C10L1/08 ,  Y10S208/95

摘要： A wide cut Fischer-Tropsch derived diesel fuel is produced wherein the distillate boils in a wider range than a conventional diesel fuel while providing favorable low temperature properties and environmentally beneficial effects. In particular, the fuel comprises a hydrocarbon distillate derived from the Fischer-Tropsch process having T90 greater than 640° F. (338° C.) but less than 1000° F. (538° C.) and a cold filter plugging point less than or equal to +5° C.

摘要翻译： 产生广泛的费 - 托衍生的柴油燃料，其中馏出物在比常规柴油燃料更宽的范围内沸腾，同时提供有利的低温性质和环境有益的效果。 特别地，燃料包括衍生自费 - 托法的烃馏出物，其具有T90大于640°F（338℃）但小于1000°F（538℃），冷过滤器堵塞点较少 超过+ 5℃

公开(公告)号：US5958819A

公开(公告)日：1999-09-28

申请号：US986056

申请日：1997-12-05

申请人： Jack Wayne Johnson ,  John Francis Brody

发明人： Jack Wayne Johnson ,  John Francis Brody

IPC分类号： B01J21/16 ,  B01D53/86 ,  B01J29/04 ,  C10G45/60 ,  C10G47/18

CPC分类号： C10G45/60 ,  B01J29/049

摘要： Stable, zirconia-pillared clays of reduced gallery height, useful as supports for hydroconversion catalysts, are prepared by treating clays with a zirconium compound, a surfactant and water, and compositing the reduced gallery height clay with suitable metal or metals.

摘要翻译： 通过用锆化合物，表面活性剂和水处理粘土，并将还原后的高架土与合适的金属或金属合成，制备了可用作加氢转化催化剂载体的稳定的氧化锆柱状粘土。

公开(公告)号：US5902759A

公开(公告)日：1999-05-11

申请号：US789326

申请日：1997-01-21

申请人： John Pickett Dismukes ,  Jack Wayne Johnson ,  Edward William Corcoran, Jr. ,  Joseph Vallone ,  James J. Pizzulli, Jr. ,  Michael P. Anderson

发明人： John Pickett Dismukes ,  Jack Wayne Johnson ,  Edward William Corcoran, Jr. ,  Joseph Vallone ,  James J. Pizzulli, Jr. ,  Michael P. Anderson

IPC分类号： C04B38/06 ,  C04B38/00

CPC分类号： C04B38/0022

摘要： The present invention provides for microporous ceramic materials having a surface area in excess of 70 m.sup.2 /gm and an open microporous cell structure wherein the micropores have a mean width of less than 20 Angstroms and wherein said microporous structure comprises a volume of greater than about 0.03 cm.sup.3 /gm of the ceramic. The invention also provides for a preceramic composite intermediate composition comprising a mixture of a ceramic precursor and finely divided silicon carbide or silicon nitride, whose pyrolysis product in inert atmosphere or in an ammonia atmosphere at temperatures of up to less than about 1100.degree. C. gives rise to the microporous ceramics of the invention. Also provided is a process for the preparation of the microporous ceramics of the invention involving pyrolysis of the ceramic intermediate under controlled conditions of heating up to temperatures of less than 1100.degree. C. to form a microporous ceramic product.

摘要翻译： 本发明提供了具有超过70m 2 / gm的表面积的微孔陶瓷材料和一种开孔微孔孔结构，其中微孔具有小于20埃的平均宽度，其中所述微孔结构包括大于约0.03的体积 cm3 / gm的陶瓷。 本发明还提供了一种陶瓷前体陶瓷复合材料中间体组合物，其包含陶瓷前体和细分碳化硅或氮化硅的混合物，其热解产物在惰性气氛中或在氨气氛中在高于约1100℃的温度下给出 上升到本发明的微孔陶瓷。 还提供了制备本发明的微孔陶瓷的方法，其包括在加热至低于1100℃的温度的受控条件下陶瓷中间体的热解，以形成微孔陶瓷产品。

公开(公告)号：US07670983B2

公开(公告)日：2010-03-02

申请号：US12070690

申请日：2008-02-20

申请人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

发明人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

IPC分类号： B01J29/06

CPC分类号： B01J37/12 ,  B01J29/068 ,  B01J29/67 ,  B01J29/7461 ,  B01J29/7484 ,  B01J37/18 ,  B01J2229/42 ,  C10G2/332 ,  C10G2/333 ,  C10G45/64 ,  C10G2300/1025 ,  C10G2300/4018 ,  C10G2400/10

摘要： Fischer-Tropsch hydrocarbon synthesis using a noncobalt catalyst is used to produce waxy fuel and lubricant oil hydrocarbons from synthesis gas derived from natural gas. The waxy hydrocarbons are hydrodewaxed, with reduced conversion to lower boiling hydrocarbons, by contacting the waxy hydrocarbons, in the presence of hydrogen, with an unsulfided hydrodewaxing catalyst that has been reduced and then treated by contacting it with a stream containing one or more oxygenates.

摘要翻译： 使用非钴催化剂的费 - 托烃合成用于从天然气衍生的合成气生产蜡状燃料和润滑油烃。 将蜡状烃加氢脱蜡，降低转化为低沸点烃，通过在氢气存在下使蜡状烃与未硫化的加氢脱蜡催化剂接触，所述脱硫加氢脱蜡催化剂已被还原，然后通过与含有一种或多种含氧化合物的物流接触进行处理。

公开(公告)号：US07241375B2

公开(公告)日：2007-07-10

申请号：US10652389

申请日：2003-08-29

申请人： Jack Wayne Johnson ,  Adeana Richelle Bishop ,  William Berlin Genetti ,  Loren Leon Ansell ,  Rocco Anthony Fiato

发明人： Jack Wayne Johnson ,  Adeana Richelle Bishop ,  William Berlin Genetti ,  Loren Leon Ansell ,  Rocco Anthony Fiato

IPC分类号： C10M105/04 ,  C10M101/02

CPC分类号： C10G45/64 ,  C10G45/58 ,  C10G45/62 ,  C10G65/043 ,  C10M101/025 ,  C10M105/04 ,  C10M171/00 ,  C10M171/02 ,  C10M2203/1025 ,  C10M2205/173 ,  C10N2220/022 ,  C10N2220/025 ,  C10N2220/028

摘要： A heavy hydrocarbon composition with utility as a heavy hydrocarbon base stock comprising at least 95 wt % paraffin molecules, of which at least 90 wt % are isoparaffin, containing hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity, as measured by ASTM D-445, is above 8 cSt, has an initial boiling point of least 850° F. (454° C.) and an end boiling point of at least 1000° F. (538° C.), wherein the branching index (BI), as measured by the percentage of methyl hydrogens, and the branching proximity (CH2>4), as measured by the percentage of recurring methylene carbons which are four or more carbon atoms removed from an end group or branch, of said isoparaffinic hydrocarbon molecules, are such that: (a) BI−0.5(CH2>4) 4)

摘要翻译： 具有至少95重量％的石蜡分子的重质烃组合物是含有连续碳原子的烃分子的至少95重量％的链烷烃分子，其中至少90重量％是异链烷烃，是100℃的液体， 在该温度下，其通过ASTM D-445测量的运动粘度高于8cSt，具有至少850°F（454℃）的初始沸点和至少1000°F的终沸点（ 538℃），其中通过甲基氢的百分比测量的支化指数（BI）和通过重复亚甲基碳的百分比测量的支化邻近度（CH 2 N 2） 其是从所述异链烷烃分子的端基或分支中除去的四个或更多个碳原子，使得：（a）BI-0.5（CH 2 2 4）<15; 和（b）BI + 0.85（CH 2 2 > 4）<45; 如在整个重质烃组合物上测得的。

公开(公告)号：US06624228B1

公开(公告)日：2003-09-23

申请号：US08668640

申请日：1996-06-21

申请人： John Pickett Dismukes ,  Jack Wayne Johnson ,  Edward William Corcoran, Jr. ,  Joseph Vallone

发明人： John Pickett Dismukes ,  Jack Wayne Johnson ,  Edward William Corcoran, Jr. ,  Joseph Vallone

IPC分类号： C08K334

CPC分类号： C04B38/0022 ,  C04B35/56 ,  C04B38/0058 ,  C04B35/58

摘要： The present invention provides for microporous ceramic materials having a surface area in excess of 50 m2/gm and an open microporous cell structure wherein the micropores have a mean width of less than 20 Angstroms and wherein said microporous structure comprises a volume of greater than about 0.015 cm3/gm of the ceramic. The invention also provides for a preceramic composite intermediate composition comprising a mixture of a ceramic precursor and finely divided particles comprising a non-silicon containing ceramic, carbon, or an inorganic compound having a decomposition temperature in excess of 400° C., whose pyrolysis product in inert atmosphere or in an ammonia atmosphere at temperatures of up to less than about 1100° C. gives rise to the microporous ceramics of the invention. Also provided is a process for the preparation of the microporous ceramics of the invention involving pyrolysis of the ceramic intermediate under controlled conditions of heating up to temperatures of less than 1100° C. to form a microporous ceramic product.

摘要翻译： 本发明提供具有超过50m 2 / gm的表面积的开孔微孔结构，其中微孔具有小于20埃的平均宽度的微孔陶瓷材料，并且其中所述微孔结构包括更大的体积 大于约0.015cm 3 / gm的陶瓷。 本发明还提供了一种预陶瓷复合中间体组合物，其包含陶瓷前体和包含非硅含量陶瓷，碳或分解温度超过400℃的无机化合物的细碎颗粒的混合物，其热分解产物 在惰性气氛中或在高达少于约1100℃的氨气氛中，产生本发明的微孔陶瓷。 还提供了制备本发明的微孔陶瓷的方法，其包括在加热至低于1100℃的温度的受控条件下陶瓷中间体的热解，以形成微孔陶瓷产品。

公开(公告)号：US07344631B2

公开(公告)日：2008-03-18

申请号：US10652390

申请日：2003-08-29

申请人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

发明人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

IPC分类号： C10G73/38

CPC分类号： B01J37/12 ,  B01J29/068 ,  B01J29/67 ,  B01J29/7461 ,  B01J29/7484 ,  B01J37/18 ,  B01J2229/42 ,  C10G2/332 ,  C10G2/333 ,  C10G45/64 ,  C10G2300/1025 ,  C10G2300/4018 ,  C10G2400/10

摘要： Fischer-Tropsch hydrocarbon synthesis using a noncobalt catalyst is used to produce waxy fuel and lubricant oil hydrocarbons from synthesis gas derived from natural gas. The waxy hydrocarbons are hydrodewaxed, with reduced conversion to lower boiling hydrocarbons, by contacting the waxy hydrocarbons, in the presence of hydrogen, with an unsulfided hydrodewaxing catalyst that has been reduced and then treated by contacting it with a stream containing one or more oxygenates.

摘要翻译： 使用非钴催化剂的费 - 托烃合成用于从天然气衍生的合成气生产蜡状燃料和润滑油烃。 将蜡状烃加氢脱蜡，降低转化为低沸点烃，通过在氢气存在下使蜡状烃与未硫化的加氢脱蜡催化剂接触，所述脱硫加氢脱蜡催化剂已被还原，然后通过与含有一种或多种含氧化合物的物流接触进行处理。

公开(公告)号：US07132042B2

公开(公告)日：2006-11-07

申请号：US10266368

申请日：2002-10-08

申请人： William Berlin Genetti ,  Adeana Richelle Bishop ,  Nancy Marie Page ,  Gregg Johnston Howsmon ,  Loren Leon Ansell ,  Jack Wayne Johnson

发明人： William Berlin Genetti ,  Adeana Richelle Bishop ,  Nancy Marie Page ,  Gregg Johnston Howsmon ,  Loren Leon Ansell ,  Jack Wayne Johnson

IPC分类号： C10G47/02 ,  C10G35/04 ,  C07C5/13

CPC分类号： C10G65/16 ,  C10G2/32 ,  C10G2400/10

摘要： Dewaxed fuel and lubricant base stocks are made by (a) producing a synthesis gas from natural gas, (b) reacting the H2 and CO in the gas in the presence of a cobalt Fischer-Tropsch catalyst, at reaction conditions effective to synthesize a waxy hydrocarbon feed boiling in the fuel and lubricant oil ranges, which is hydrodewaxed in a first stage to produce a dewaxed fuel and a partially dewaxed lubricant fraction. The partially dewaxed lubricant fraction is separated into heavy and lower boiling fractions each of which is separately hydrodewaxed, to produce lubricant base stocks. A hydrodewaxing catalyst comprising a hydrogenation component, binder and solid acid component used to hydrodewax at least one, and preferably at least two of the waxy feed and partially dewaxed heavy and lower boiling lubricant fractions.

摘要翻译： 脱蜡的燃料和润滑剂基础油料是通过（a）从天然气生产合成气制备的，（b）使钴 - 费 - 托催化剂存在下气体中的H 2 H 2和CO反应， 在有效合成在第一阶段加氢脱蜡以产生脱蜡燃料和部分脱蜡的润滑剂部分的燃料和润滑油范围中沸腾的蜡质烃进料的反应条件下。 将部分脱蜡的润滑剂部分分离成分别加氢脱蜡的重和低沸点馏分，以产生润滑剂基础油。 一种加氢脱蜡催化剂，其包含氢化组分，粘合剂和固体酸组分，用于将至少一种，优选至少两种蜡状进料和部分脱蜡的重馏分和低沸点润滑剂馏分进行加氢脱蜡。