公开(公告)号：US07132042B2

公开(公告)日：2006-11-07

申请号：US10266368

申请日：2002-10-08

申请人： William Berlin Genetti ,  Adeana Richelle Bishop ,  Nancy Marie Page ,  Gregg Johnston Howsmon ,  Loren Leon Ansell ,  Jack Wayne Johnson

发明人： William Berlin Genetti ,  Adeana Richelle Bishop ,  Nancy Marie Page ,  Gregg Johnston Howsmon ,  Loren Leon Ansell ,  Jack Wayne Johnson

IPC分类号： C10G47/02 ,  C10G35/04 ,  C07C5/13

CPC分类号： C10G65/16 ,  C10G2/32 ,  C10G2400/10

摘要： Dewaxed fuel and lubricant base stocks are made by (a) producing a synthesis gas from natural gas, (b) reacting the H2 and CO in the gas in the presence of a cobalt Fischer-Tropsch catalyst, at reaction conditions effective to synthesize a waxy hydrocarbon feed boiling in the fuel and lubricant oil ranges, which is hydrodewaxed in a first stage to produce a dewaxed fuel and a partially dewaxed lubricant fraction. The partially dewaxed lubricant fraction is separated into heavy and lower boiling fractions each of which is separately hydrodewaxed, to produce lubricant base stocks. A hydrodewaxing catalyst comprising a hydrogenation component, binder and solid acid component used to hydrodewax at least one, and preferably at least two of the waxy feed and partially dewaxed heavy and lower boiling lubricant fractions.

摘要翻译： 脱蜡的燃料和润滑剂基础油料是通过（a）从天然气生产合成气制备的，（b）使钴 - 费 - 托催化剂存在下气体中的H 2 H 2和CO反应， 在有效合成在第一阶段加氢脱蜡以产生脱蜡燃料和部分脱蜡的润滑剂部分的燃料和润滑油范围中沸腾的蜡质烃进料的反应条件下。 将部分脱蜡的润滑剂部分分离成分别加氢脱蜡的重和低沸点馏分，以产生润滑剂基础油。 一种加氢脱蜡催化剂，其包含氢化组分，粘合剂和固体酸组分，用于将至少一种，优选至少两种蜡状进料和部分脱蜡的重馏分和低沸点润滑剂馏分进行加氢脱蜡。

公开(公告)号：US07344631B2

公开(公告)日：2008-03-18

申请号：US10652390

申请日：2003-08-29

申请人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

发明人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

IPC分类号： C10G73/38

CPC分类号： B01J37/12 ,  B01J29/068 ,  B01J29/67 ,  B01J29/7461 ,  B01J29/7484 ,  B01J37/18 ,  B01J2229/42 ,  C10G2/332 ,  C10G2/333 ,  C10G45/64 ,  C10G2300/1025 ,  C10G2300/4018 ,  C10G2400/10

摘要： Fischer-Tropsch hydrocarbon synthesis using a noncobalt catalyst is used to produce waxy fuel and lubricant oil hydrocarbons from synthesis gas derived from natural gas. The waxy hydrocarbons are hydrodewaxed, with reduced conversion to lower boiling hydrocarbons, by contacting the waxy hydrocarbons, in the presence of hydrogen, with an unsulfided hydrodewaxing catalyst that has been reduced and then treated by contacting it with a stream containing one or more oxygenates.

摘要翻译： 使用非钴催化剂的费 - 托烃合成用于从天然气衍生的合成气生产蜡状燃料和润滑油烃。 将蜡状烃加氢脱蜡，降低转化为低沸点烃，通过在氢气存在下使蜡状烃与未硫化的加氢脱蜡催化剂接触，所述脱硫加氢脱蜡催化剂已被还原，然后通过与含有一种或多种含氧化合物的物流接触进行处理。

公开(公告)号：US20080146437A1

公开(公告)日：2008-06-19

申请号：US12070690

申请日：2008-02-20

申请人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

发明人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

IPC分类号： B01J31/02 ,  B01J23/44 ,  B01J29/068 ,  B01J31/04

CPC分类号： B01J37/12 ,  B01J29/068 ,  B01J29/67 ,  B01J29/7461 ,  B01J29/7484 ,  B01J37/18 ,  B01J2229/42 ,  C10G2/332 ,  C10G2/333 ,  C10G45/64 ,  C10G2300/1025 ,  C10G2300/4018 ,  C10G2400/10

摘要： Fischer-Tropsch hydrocarbon synthesis using a noncobalt catalyst is used to produce waxy fuel and lubricant oil hydrocarbons from synthesis gas derived from natural gas. The waxy hydrocarbons are hydrodewaxed, with reduced conversion to lower boiling hydrocarbons, by contacting the waxy hydrocarbons, in the presence of hydrogen, with an unsulfided hydrodewaxing catalyst that has been reduced and then treated by contacting it with a stream containing one or more oxygenates.

摘要翻译： 使用非钴催化剂的费 - 托烃合成用于从天然气衍生的合成气生产蜡状燃料和润滑油烃。 将蜡状烃加氢脱蜡，降低转化为低沸点烃，通过在氢气存在下使蜡状烃与未硫化的加氢脱蜡催化剂接触，所述脱硫加氢脱蜡催化剂已被还原，然后通过与含有一种或多种含氧化合物的物流接触进行处理。

公开(公告)号：US07201838B2

公开(公告)日：2007-04-10

申请号：US10652391

申请日：2003-08-29

申请人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

发明人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

IPC分类号： C10G73/02

CPC分类号： B01J29/7461 ,  B01J29/068 ,  B01J29/67 ,  B01J29/7453 ,  B01J29/7484 ,  B01J29/7492 ,  B01J31/0201 ,  B01J37/12 ,  B01J37/18 ,  C10G2/332 ,  C10G45/64

摘要： Fischer-Tropsch hydrocarbon synthesis using a cobalt catalyst is used to produce waxy fuel and lubricant oil hydrocarbons from synthesis gas derived from natural gas. The waxy hydrocarbons are hydrodewaxed, with reduced conversion to lower boiling hydrocarbons, by contacting the waxy hydrocarbons, in the presence of hydrogen, with an unsulfided 10-ring, 1-dimensional zeolite catalyst that has been reduced and then treated by contacting it with the synthesized hydrocarbons containing one or more oxygenates, including indigenous oxygenate. Tail gas from the hydrodewaxing reactor can be used for the hydrocarbon synthesis.

摘要翻译： 使用钴催化剂的费 - 托烃合成用于从天然气衍生的合成气中生产蜡状燃料和润滑油烃。 将蜡状碳氢化合物加氢脱蜡，降低转化为低沸点烃，通过在氢气存在下使蜡状烃与未硫化的10环1维沸石催化剂接触，该催化剂已被还原，然后通过与 含有一种或多种含氧化合物的合成烃，包括原生含氧化合物。 来自加氢脱蜡反应器的尾气可以用于烃合成。

公开(公告)号：US07670983B2

公开(公告)日：2010-03-02

申请号：US12070690

申请日：2008-02-20

申请人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

发明人： Adeana Richelle Bishop ,  William Berlin Genetti ,  Jack Wayne Johnson ,  Loren Leon Ansell ,  Nancy Marie Page

IPC分类号： B01J29/06

CPC分类号： B01J37/12 ,  B01J29/068 ,  B01J29/67 ,  B01J29/7461 ,  B01J29/7484 ,  B01J37/18 ,  B01J2229/42 ,  C10G2/332 ,  C10G2/333 ,  C10G45/64 ,  C10G2300/1025 ,  C10G2300/4018 ,  C10G2400/10

摘要： Fischer-Tropsch hydrocarbon synthesis using a noncobalt catalyst is used to produce waxy fuel and lubricant oil hydrocarbons from synthesis gas derived from natural gas. The waxy hydrocarbons are hydrodewaxed, with reduced conversion to lower boiling hydrocarbons, by contacting the waxy hydrocarbons, in the presence of hydrogen, with an unsulfided hydrodewaxing catalyst that has been reduced and then treated by contacting it with a stream containing one or more oxygenates.

摘要翻译： 使用非钴催化剂的费 - 托烃合成用于从天然气衍生的合成气生产蜡状燃料和润滑油烃。 将蜡状烃加氢脱蜡，降低转化为低沸点烃，通过在氢气存在下使蜡状烃与未硫化的加氢脱蜡催化剂接触，所述脱硫加氢脱蜡催化剂已被还原，然后通过与含有一种或多种含氧化合物的物流接触进行处理。

公开(公告)号：US06846778B2

公开(公告)日：2005-01-25

申请号：US10266344

申请日：2002-10-08

申请人： Jack Wayne Johnson ,  Adeana Richelle Bishop ,  William Berlin Genetti ,  Loren Leon Ansell ,  Rocco Anthony Fiato

发明人： Jack Wayne Johnson ,  Adeana Richelle Bishop ,  William Berlin Genetti ,  Loren Leon Ansell ,  Rocco Anthony Fiato

IPC分类号： C10G45/58 ,  C10G45/62 ,  C10G45/64 ,  C10G65/04 ,  C10M101/02 ,  C10M105/04 ,  C10M171/00 ,  C10M171/02

CPC分类号： C10G45/64 ,  C10G45/58 ,  C10G45/62 ,  C10G65/043 ,  C10M101/025 ,  C10M105/04 ,  C10M171/00 ,  C10M171/02 ,  C10M2203/1025 ,  C10M2205/173 ,  C10N2220/022 ,  C10N2220/025 ,  C10N2220/028

摘要： A synthetic, isoparaffinic heavy hydrocarbon composition useful as a heavy lubricant base stock contains hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity is above 8 cSt and has respective initial and end boiling points of at least 850 and 1000° F. (454 and 538° C.). The branching index BI and the branching proximity CH2>4 of the isoparaffinic hydrocarbon molecules, are such that: BI−0.5(CH2>4) 4)

摘要翻译： 可用作重润滑剂基础油料的合成的异链烷烃重烃组合物包含具有连续数目的碳原子的烃分子，是在100℃下的液体，在该温度下，其运动粘度高于8cSt，并具有各自的初始和终沸点 点至少为850和1000°F（454和538°C）。 异链烷烃分子的支化指数BI和分支邻近CH 2> 4是这样的：如在整个烃组分上测得的。

公开(公告)号：US07241375B2

公开(公告)日：2007-07-10

申请号：US10652389

申请日：2003-08-29

申请人： Jack Wayne Johnson ,  Adeana Richelle Bishop ,  William Berlin Genetti ,  Loren Leon Ansell ,  Rocco Anthony Fiato

发明人： Jack Wayne Johnson ,  Adeana Richelle Bishop ,  William Berlin Genetti ,  Loren Leon Ansell ,  Rocco Anthony Fiato

IPC分类号： C10M105/04 ,  C10M101/02

CPC分类号： C10G45/64 ,  C10G45/58 ,  C10G45/62 ,  C10G65/043 ,  C10M101/025 ,  C10M105/04 ,  C10M171/00 ,  C10M171/02 ,  C10M2203/1025 ,  C10M2205/173 ,  C10N2220/022 ,  C10N2220/025 ,  C10N2220/028

摘要： A heavy hydrocarbon composition with utility as a heavy hydrocarbon base stock comprising at least 95 wt % paraffin molecules, of which at least 90 wt % are isoparaffin, containing hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity, as measured by ASTM D-445, is above 8 cSt, has an initial boiling point of least 850° F. (454° C.) and an end boiling point of at least 1000° F. (538° C.), wherein the branching index (BI), as measured by the percentage of methyl hydrogens, and the branching proximity (CH2>4), as measured by the percentage of recurring methylene carbons which are four or more carbon atoms removed from an end group or branch, of said isoparaffinic hydrocarbon molecules, are such that: (a) BI−0.5(CH2>4) 4)

摘要翻译： 具有至少95重量％的石蜡分子的重质烃组合物是含有连续碳原子的烃分子的至少95重量％的链烷烃分子，其中至少90重量％是异链烷烃，是100℃的液体， 在该温度下，其通过ASTM D-445测量的运动粘度高于8cSt，具有至少850°F（454℃）的初始沸点和至少1000°F的终沸点（ 538℃），其中通过甲基氢的百分比测量的支化指数（BI）和通过重复亚甲基碳的百分比测量的支化邻近度（CH 2 N 2） 其是从所述异链烷烃分子的端基或分支中除去的四个或更多个碳原子，使得：（a）BI-0.5（CH 2 2 4）<15; 和（b）BI + 0.85（CH 2 2 > 4）<45; 如在整个重质烃组合物上测得的。

公开(公告)号：US06833064B2

公开(公告)日：2004-12-21

申请号：US09922321

申请日：2001-08-03

申请人： Paul Joseph Berlowitz ,  Robert Jay Wittenbrink ,  Daniel Francis Ryan ,  William Berlin Genetti ,  Jack Wayne Johnson

发明人： Paul Joseph Berlowitz ,  Robert Jay Wittenbrink ,  Daniel Francis Ryan ,  William Berlin Genetti ,  Jack Wayne Johnson

IPC分类号： C10L104

CPC分类号： C10L1/08 ,  Y10S208/95

摘要： A wide cut Fischer-Tropsch derived diesel fuel is produced wherein the distillate boils in a wider range than a conventional diesel fuel while providing favorable low temperature properties and environmentally beneficial effects. In particular, the fuel comprises a hydrocarbon distillate derived from the Fischer-Tropsch process having T90 greater than 640° F. (338° C.) but less than 1000° F. (538° C.) and a cold filter plugging point less than or equal to +5° C.

摘要翻译： 产生广泛的费 - 托衍生的柴油燃料，其中馏出物在比常规柴油燃料更宽的范围内沸腾，同时提供有利的低温性质和环境有益的效果。 特别地，燃料包括衍生自费 - 托法的烃馏出物，其具有T90大于640°F（338℃）但小于1000°F（538℃），冷过滤器堵塞点较少 超过+ 5℃